BRPI0409093B1 - método de preparação de um eletrólito baseado em céria com uma densidade maior do que 97% da densidade teórica alcançável, eletrólito baseado em céria, e, montagem de meia-célula - Google Patents

método de preparação de um eletrólito baseado em céria com uma densidade maior do que 97% da densidade teórica alcançável, eletrólito baseado em céria, e, montagem de meia-célula

Info

Publication number
BRPI0409093B1
BRPI0409093B1 BRPI0409093-4B1A BRPI0409093A BRPI0409093B1 BR PI0409093 B1 BRPI0409093 B1 BR PI0409093B1 BR PI0409093 A BRPI0409093 A BR PI0409093A BR PI0409093 B1 BRPI0409093 B1 BR PI0409093B1
Authority
BR
Brazil
Prior art keywords
ceria
based electrolyte
density
preparing
cell assembly
Prior art date
Application number
BRPI0409093-4B1A
Other languages
English (en)
Inventor
Brian Charles Hilton Steele
Gene Lewis
Naoki Oishi
Ahmet Selcuk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of BRPI0409093A publication Critical patent/BRPI0409093A/pt
Publication of BRPI0409093B1 publication Critical patent/BRPI0409093B1/pt

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H01M8/1246Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
    • H01M8/126Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing cerium oxide
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00Compounds of rare earth metals
    • C01F17/10Preparation or treatment, e.g. separation or purification
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/50Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206Magnesium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3229Cerium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3241Chromium oxides, chromates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C04B2235/3265Mn2O3
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3275Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658Atmosphere during thermal treatment
    • C04B2235/6582Hydrogen containing atmosphere
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658Atmosphere during thermal treatment
    • C04B2235/6583Oxygen containing atmosphere, e.g. with changing oxygen pressures
    • C04B2235/6584Oxygen containing atmosphere, e.g. with changing oxygen pressures at an oxygen percentage below that of air
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Conductive Materials (AREA)
  • Inert Electrodes (AREA)
BRPI0409093-4B1A 2003-04-09 2004-03-25 método de preparação de um eletrólito baseado em céria com uma densidade maior do que 97% da densidade teórica alcançável, eletrólito baseado em céria, e, montagem de meia-célula BRPI0409093B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0308215A GB2400486B (en) 2003-04-09 2003-04-09 Densification of ceria based electrolytes
PCT/GB2004/001293 WO2004089848A1 (en) 2003-04-09 2004-03-25 Densification of ceria based electrolytes

Publications (2)

Publication Number Publication Date
BRPI0409093A BRPI0409093A (pt) 2006-04-11
BRPI0409093B1 true BRPI0409093B1 (pt) 2013-08-27

Family

ID=9956496

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0409093-4B1A BRPI0409093B1 (pt) 2003-04-09 2004-03-25 método de preparação de um eletrólito baseado em céria com uma densidade maior do que 97% da densidade teórica alcançável, eletrólito baseado em céria, e, montagem de meia-célula

Country Status (16)

Country Link
US (2) US7947212B2 (pt)
EP (1) EP1608605B1 (pt)
JP (1) JP5048322B2 (pt)
KR (1) KR101065949B1 (pt)
CN (1) CN100381395C (pt)
AU (1) AU2004228427B2 (pt)
BR (1) BRPI0409093B1 (pt)
CA (1) CA2521901C (pt)
DK (1) DK1608605T3 (pt)
EA (1) EA009103B1 (pt)
ES (1) ES2444217T3 (pt)
GB (1) GB2400486B (pt)
HK (1) HK1069680A1 (pt)
MX (1) MXPA05010789A (pt)
WO (1) WO2004089848A1 (pt)
ZA (1) ZA200508144B (pt)

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WO2008003976A1 (en) 2006-07-07 2008-01-10 Ceres Intellectual Property Company Limited Metal substrate for fuel cells
US8617456B1 (en) 2010-03-22 2013-12-31 The United States Of America As Represented By The Secretary Of The Air Force Bulk low-cost interface-defined laminated materials and their method of fabrication
US9120245B1 (en) 2007-05-09 2015-09-01 The United States Of America As Represented By The Secretary Of The Air Force Methods for fabrication of parts from bulk low-cost interface-defined nanolaminated materials
US9162931B1 (en) * 2007-05-09 2015-10-20 The United States Of America As Represented By The Secretary Of The Air Force Tailored interfaces between two dissimilar nano-materials and method of manufacture
KR101478207B1 (ko) * 2007-11-23 2015-01-02 삼성전자주식회사 이동통신 단말에서 블루투스를 이용하여 자바푸시를요구하는 기기들을 식별하기 위한 방법 및 장치
GB2461115A (en) 2008-04-23 2009-12-30 Ceres Power Ltd Fuel Cell Module Support
ES2387212T3 (es) 2008-08-21 2012-09-18 Ceres Intellectual Property Company Limited Flujo de aire mejorado de la campana de flujo de un apilamiento de celdas de combustible utilizando un dispositivo de distribución de aire
FR2948821B1 (fr) 2009-08-03 2011-12-09 Commissariat Energie Atomique Cellule electrochimique a metal support et son procede de fabrication
CN101654366B (zh) * 2009-09-10 2012-10-24 中国矿业大学(北京) 复合助烧剂及其用于低温制备纳米晶陶瓷的方法
DE102012211669A1 (de) * 2012-07-04 2014-01-09 Behr Gmbh & Co. Kg Klimaanlage
GB2517928B (en) 2013-09-04 2018-02-28 Ceres Ip Co Ltd Metal supported solid oxide fuel cell
GB2517927B (en) * 2013-09-04 2018-05-16 Ceres Ip Co Ltd Process for forming a metal supported solid oxide fuel cell
RU2677269C2 (ru) 2014-03-12 2019-01-16 Серес Интеллекчуал Проперти Компани Лимитед Устройство батареи топливных элементов
GB2534124B (en) 2014-12-19 2017-04-19 Ceres Ip Co Ltd A swirl burner assembly and method
US11527766B2 (en) 2014-12-19 2022-12-13 Ceres Intellectual Property Company Limited Fuel cell system and tail gas burner assembly and method
GB2563848B (en) 2017-06-26 2022-01-12 Ceres Ip Co Ltd Fuel cell stack assembly
GB201713141D0 (en) 2017-08-16 2017-09-27 Ceres Ip Co Ltd Fuel cell unit
GB201913907D0 (en) 2019-09-26 2019-11-13 Ceres Ip Co Ltd Fuel cell stack assembly apparatus and method
GB201915294D0 (en) 2019-10-22 2019-12-04 Ceres Ip Co Ltd Alignment apparatus and methods of alignment
GB201915438D0 (en) 2019-10-24 2019-12-11 Ceres Ip Co Ltd Metal-supported cell unit
GB2591462B (en) 2020-01-27 2022-04-20 Ceres Ip Co Ltd Interlayer for solid oxide cell
GB202009687D0 (en) 2020-06-25 2020-08-12 Ceres Ip Co Ltd Layer
AU2022381461A1 (en) 2021-11-08 2024-05-02 Rhodia Operations Cerium-gadolinium composite oxide
AU2022381337A1 (en) 2021-11-08 2024-05-02 Rhodia Operations Cerium-gadolinium composite oxide
GB202304341D0 (en) 2023-03-24 2023-05-10 Ceres Ip Co Ltd Solid oxide electrochemical cell

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Also Published As

Publication number Publication date
GB2400486B (en) 2006-05-10
US7947212B2 (en) 2011-05-24
US20110177427A1 (en) 2011-07-21
ZA200508144B (en) 2006-10-25
ES2444217T3 (es) 2014-02-24
WO2004089848A1 (en) 2004-10-21
EA200501588A1 (ru) 2006-04-28
MXPA05010789A (es) 2006-03-30
HK1069680A1 (en) 2005-05-27
CN100381395C (zh) 2008-04-16
GB2400486A (en) 2004-10-13
AU2004228427A1 (en) 2004-10-21
EP1608605B1 (en) 2013-08-28
CN1771212A (zh) 2006-05-10
US20070020498A1 (en) 2007-01-25
JP2006523002A (ja) 2006-10-05
DK1608605T3 (da) 2013-12-09
BRPI0409093A (pt) 2006-04-11
EA009103B1 (ru) 2007-10-26
CA2521901A1 (en) 2004-10-21
KR101065949B1 (ko) 2011-09-19
KR20060012271A (ko) 2006-02-07
GB0308215D0 (en) 2003-05-14
CA2521901C (en) 2011-09-06
JP5048322B2 (ja) 2012-10-17
AU2004228427B2 (en) 2009-09-17
EP1608605A1 (en) 2005-12-28

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