BR9916525A - Processo para realizar reações orgânicas para a catálise bifásica, e, processo para a preparação de compostos organofosforados sulfonados hidrossolúveis - Google Patents

Processo para realizar reações orgânicas para a catálise bifásica, e, processo para a preparação de compostos organofosforados sulfonados hidrossolúveis

Info

Publication number
BR9916525A
BR9916525A BR9916525-2A BR9916525A BR9916525A BR 9916525 A BR9916525 A BR 9916525A BR 9916525 A BR9916525 A BR 9916525A BR 9916525 A BR9916525 A BR 9916525A
Authority
BR
Brazil
Prior art keywords
sulfonated
organic reactions
hydrosoluble
preparation
organophosphate
Prior art date
Application number
BR9916525-2A
Other languages
English (en)
Inventor
Larbi Aouni
Paolo Burattin
Pierre Coqueret
Marc Huser
Original Assignee
Rhodia Polyamide Intermediates
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Polyamide Intermediates filed Critical Rhodia Polyamide Intermediates
Publication of BR9916525A publication Critical patent/BR9916525A/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5095—Separation; Purification; Stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/342—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones
    • B01J2231/343—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones to prepare cyanhydrines, e.g. by adding HCN or TMSCN
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/17—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/27—Cadmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/28—Mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA REALIZAR REAçõES ORGâNICAS PARA A CATáLISE BIFáSICA, E, PROCESSO PARA A PREPARAçãO DE COMPOSTOS ORGANOFOSFORADOS SULFONADOS HIDROSSOLúVEIS". A presente invenção refere-se a um processo de preparação de compostos organofosforados sulfonados hidrossolúveis, notadamente convenientes para as reações orgânicas realizadas com uma catálise bifásica. De acordo com a invenção, o composto organofosforado sulfonado hidrossolúvel, é tratado previamente à sua utilização como ligando de catalisador para eliminar pelo menos parcialmente os radicais e compostos sulfitos. A invenção refere-se igualmente às reações orgânicas catalisadas por um sistema bifásico compreendendo um ligando organofosforado sulfonado tratado para eliminar os sulfitos.
BR9916525-2A 1998-12-23 1999-12-21 Processo para realizar reações orgânicas para a catálise bifásica, e, processo para a preparação de compostos organofosforados sulfonados hidrossolúveis BR9916525A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9816586A FR2787786B1 (fr) 1998-12-23 1998-12-23 Procede de preparation de composes organophosphores sulfones hydrosolubles et la realisation de reactions organiques avec catalyse biphasique
PCT/FR1999/003234 WO2000039134A1 (fr) 1998-12-23 1999-12-21 Preparation de composes organophosphores sulfones hydrosolubles

Publications (1)

Publication Number Publication Date
BR9916525A true BR9916525A (pt) 2001-10-02

Family

ID=9534631

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9916525-2A BR9916525A (pt) 1998-12-23 1999-12-21 Processo para realizar reações orgânicas para a catálise bifásica, e, processo para a preparação de compostos organofosforados sulfonados hidrossolúveis

Country Status (17)

Country Link
US (2) US6613939B2 (pt)
EP (1) EP1140951B1 (pt)
JP (1) JP4267829B2 (pt)
KR (1) KR100604687B1 (pt)
CN (1) CN1197868C (pt)
BR (1) BR9916525A (pt)
CA (1) CA2356817A1 (pt)
CZ (1) CZ20012308A3 (pt)
DE (1) DE69931186T2 (pt)
FR (1) FR2787786B1 (pt)
MX (1) MXPA01006381A (pt)
PL (1) PL352362A1 (pt)
RU (1) RU2240324C2 (pt)
SK (1) SK9112001A3 (pt)
TW (1) TW476664B (pt)
WO (1) WO2000039134A1 (pt)
ZA (1) ZA200105933B (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19918284C1 (de) * 1999-04-22 2000-12-14 Celanese Chem Europe Gmbh Verfahren zur Herstellung von sulfonierten Arylphosphinen
FR2815344B1 (fr) 2000-10-13 2004-01-30 Rhodia Polyamide Intermediates Procede d'hydrocyanation de composes organiques a insaturation ethylenique
BRPI0617017B1 (pt) * 2005-09-15 2016-03-15 Dow Global Technologies Inc processo para preparar monossulfonato de fosfina aromática na forma zwiteriônica, processo para preparar sal metálico alcalino de monossulfonato de diciclohexilfenilfosfina, e monossulfonato de fosfina aromática na forma zwiteriônica
EP2242760B1 (en) * 2008-01-15 2014-03-05 Dow Global Technologies LLC Sulfonated organophosphine compounds and use in hydroformylation processes
WO2009091670A1 (en) * 2008-01-15 2009-07-23 Dow Global Technologies Inc. Sulfonated organophosphine compounds and use thereof in hydroformylation processes
BRPI0905699A2 (pt) * 2008-01-15 2015-07-14 Dow Global Technologies Inc Composição, catalisador complexo ou composição de precursor de catalisador complexo, solução de catalisador complexo ou solução de percursor de catalisador complexo e processo de hidroformilação
CN111068789B (zh) * 2019-12-31 2021-10-08 中国科学院过程工程研究所 一种用于co2参与的烯烃羰基酯化反应的催化剂
KR102702919B1 (ko) * 2020-10-28 2024-09-03 한화솔루션 주식회사 설폰화 아릴 포스핀의 제조방법

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3579560A (en) * 1967-11-06 1971-05-18 Du Pont Isomerization of nitriles
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
FR2549840B1 (fr) * 1983-07-28 1986-03-21 Rhone Poulenc Sante Nouvelles phosphines chirales sulfonees, leur preparation et leur emploi en catalyse asymetrique
FR2550202B1 (fr) * 1983-08-03 1986-03-21 Rhone Poulenc Rech Procede de preparation de tri(m-sulfophenyl) phosphine
DE3431643A1 (de) 1984-08-29 1986-03-13 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur abtrennung und reindarstellung von salzen der diphenylphosphinphenyl-m-sulfonsaeure, phenylphosphin-di(m-phenylsulfonsaeure) und/oder triphenylphosphin-tri(m-sulfonsaeure)
US5935892A (en) * 1994-02-22 1999-08-10 California Institute Of Technology Supported phase catalyst
US5736480A (en) * 1994-02-22 1998-04-07 California Institute Of Technology Supported phase chiral sulfonated BINAP catalyst solubilized in alcohol and method of asymmetric hydrogenation
BE1008343A3 (nl) * 1994-05-06 1996-04-02 Dsm Nv Bidentaat fosfineligand
DE19506279A1 (de) * 1995-02-23 1996-08-29 Hoechst Ag Sulfonierte Diphosphane und ein Verfahren zu ihrer Herstellung
FR2743010B1 (fr) * 1995-12-29 1998-02-20 Rhone Poulenc Fibres Procede de preparation par hydrogenation de catalyseurs a base de metal de transition et de phosphine
US5929273A (en) * 1996-04-18 1999-07-27 Celanese International Corp Process for preparing diphospines ligands and catalysts containing the same

Also Published As

Publication number Publication date
CZ20012308A3 (cs) 2001-12-12
DE69931186T2 (de) 2006-09-07
RU2240324C2 (ru) 2004-11-20
US6613939B2 (en) 2003-09-02
TW476664B (en) 2002-02-21
KR20010101317A (ko) 2001-11-14
CN1352648A (zh) 2002-06-05
CA2356817A1 (fr) 2000-07-06
JP4267829B2 (ja) 2009-05-27
WO2000039134A1 (fr) 2000-07-06
DE69931186D1 (de) 2006-06-08
EP1140951A1 (fr) 2001-10-10
US20030204109A1 (en) 2003-10-30
PL352362A1 (en) 2003-08-11
FR2787786B1 (fr) 2001-02-02
KR100604687B1 (ko) 2006-07-26
ZA200105933B (en) 2002-10-18
MXPA01006381A (es) 2002-06-04
FR2787786A1 (fr) 2000-06-30
EP1140951B1 (fr) 2006-05-03
JP2002533467A (ja) 2002-10-08
CN1197868C (zh) 2005-04-20
SK9112001A3 (en) 2001-12-03
US20020016497A1 (en) 2002-02-07

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