BR9713038A - Processo para preparação de éteres benzìlicos - Google Patents
Processo para preparação de éteres benzìlicosInfo
- Publication number
- BR9713038A BR9713038A BR9713038-9A BR9713038A BR9713038A BR 9713038 A BR9713038 A BR 9713038A BR 9713038 A BR9713038 A BR 9713038A BR 9713038 A BR9713038 A BR 9713038A
- Authority
- BR
- Brazil
- Prior art keywords
- alkyl
- group
- general formula
- haloalkyl
- alkenyl
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical class C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 6
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000001188 haloalkyl group Chemical group 0.000 abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- -1 methylenedioxy Chemical group 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
- C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
- C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
- C07D317/54—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA PREPARAçãO DE éTERES BENZìLICOS" O assunto da invenção é o processo para preparação de éteres mistos da fórmula geral (I) onde Ar representa uma porção alicíclica, aromática ou uma ou mais porções heterocíclicas contendo heteroátomo, opcionalmente substituída por um ou mais alcóxi C~ 1-4~, metilenodióxi, alquila C~ 1-4~, halogênio, haloalquila C~ 1-4~ ou grupo nitro, e/ou condensado com um anel benzeno, R^ 1^ e R^ 2^ independentemente representam grupo hidrogênio, alquila C~ 1-4~, haloalquila C~ 1-4~, alquenila C~ 2-4~, fenila, fenila substituída, grupo cicloalquila C~ 3-6~, R^ 3^ significa grupo alquila C~ 1-6~, alquenila C~ 3-6~ ou aquinila C~ 3-6~, opcionalmente substituído por um ou mais grupos alquila C~ 1-6~, alquenila C~ 3-6~, alquinila, C~ 3-6~, haloalquila C~ 1-6~ou átomo de halogênio; ou um grupo alquilóxi C~ 1-4~-alquilóxi C~ 1-4~-alquila C~ 1-4~, <B>CARACTERIZADO<D> pelo fato dos compostos da fórmula geral II, onde X significa hidróxi, halogênio ou grupo de partida sulfoéster, serem reagidos, em presença de ácido, ácido de Lewis, óxido metálico ou carbonato metálico com 1-3 equivalentes molares do álcool da fórmula geral III, R~ 3~-OH onde o significado do substituto é conforme definido acima, o éter resultante da fórmula geral I é isolado, caso desejado, estabilizado por adição de uma base e/ou um antioxidante, e, caso desejado, o excesso do álcool é recuperado.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU9603179A HU220573B1 (hu) | 1996-11-18 | 1996-11-18 | Eljárás benzil-éterek előállítására |
PCT/HU1997/000073 WO1998022416A1 (en) | 1996-11-18 | 1997-11-12 | Process for the preparation of benzyl-ethers |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9713038A true BR9713038A (pt) | 2000-04-11 |
Family
ID=89994454
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9713038-9A BR9713038A (pt) | 1996-11-18 | 1997-11-12 | Processo para preparação de éteres benzìlicos |
Country Status (30)
Country | Link |
---|---|
US (1) | US6320085B1 (pt) |
EP (1) | EP0939749B1 (pt) |
JP (1) | JP2001505200A (pt) |
KR (1) | KR20000053346A (pt) |
CN (1) | CN1118448C (pt) |
AR (1) | AR008527A1 (pt) |
AT (1) | ATE203231T1 (pt) |
AU (1) | AU736832B2 (pt) |
BG (1) | BG63626B1 (pt) |
BR (1) | BR9713038A (pt) |
CA (1) | CA2272384A1 (pt) |
CZ (1) | CZ292054B6 (pt) |
DE (1) | DE69705738T2 (pt) |
DK (1) | DK0939749T3 (pt) |
EA (1) | EA001467B1 (pt) |
EE (1) | EE03679B1 (pt) |
ES (1) | ES2161452T3 (pt) |
GR (1) | GR3036878T3 (pt) |
HR (1) | HRP970609B1 (pt) |
HU (1) | HU220573B1 (pt) |
IL (1) | IL129759A0 (pt) |
NO (1) | NO313094B1 (pt) |
NZ (1) | NZ336287A (pt) |
PL (1) | PL333422A1 (pt) |
PT (1) | PT939749E (pt) |
SK (1) | SK283757B6 (pt) |
TR (1) | TR199901087T2 (pt) |
TW (1) | TW472036B (pt) |
WO (1) | WO1998022416A1 (pt) |
ZA (1) | ZA9710322B (pt) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2788269B1 (fr) | 1999-01-08 | 2001-02-09 | Rhodia Chimie Sa | Procede de preparation d'un ether de type benzylique |
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US20050038310A1 (en) | 2003-07-15 | 2005-02-17 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US20060229228A1 (en) * | 2005-04-11 | 2006-10-12 | Zachary John Anthony Komon | Method of making alkoxylates |
KR101335397B1 (ko) | 2006-02-03 | 2013-12-02 | 지알티, 인코포레이티드 | 할로겐으로부터 가벼운 기체를 분리하는 방법 |
NZ588129A (en) | 2006-02-03 | 2012-06-29 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
CA2687589A1 (en) | 2007-05-24 | 2008-12-04 | Grt, Inc. | Zone reactor incorporating reversible hydrogen halide capture and release |
US8282810B2 (en) * | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
KR101740419B1 (ko) | 2008-07-18 | 2017-05-26 | 지알티, 인코포레이티드 | 천연 가스를 액체 탄화수소로 변환시키는 연속 공정 |
JP2012524744A (ja) * | 2009-04-22 | 2012-10-18 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップ | 低泡性非ゲル化界面活性剤の調製方法及び組成物 |
EP2289889A1 (en) | 2009-08-18 | 2011-03-02 | Endura S.p.a. | Substituted alkynyl phenoxy compounds and their uses |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
GB201104156D0 (en) | 2011-03-11 | 2011-04-27 | Rothamstead Res Ltd | Compositions and methods for controlling pesticide resistant pests |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE833190C (de) * | 1949-01-28 | 1952-03-06 | Hans Werner Zopf | Verfahren zur Herstellung von AEthern |
FR2029290A5 (en) * | 1969-01-23 | 1970-10-16 | Rhone Poulenc Sa | Dehydrating alcohols on noble metal derivs |
BE1007421A3 (nl) * | 1993-08-20 | 1995-06-13 | Tessenderlo Chem Nv | Werkwijze voor het selectief alkyleren van een alifatische alcohol tegenover een fenolverbinding. |
DE4434823B4 (de) * | 1994-09-29 | 2004-02-05 | Merck Patent Gmbh | Verfahren zur Herstellung von Hydroxybenzylalkylethern |
-
1996
- 1996-11-18 HU HU9603179A patent/HU220573B1/hu not_active IP Right Cessation
-
1997
- 1997-11-12 US US09/297,824 patent/US6320085B1/en not_active Expired - Fee Related
- 1997-11-12 CZ CZ19991741A patent/CZ292054B6/cs not_active IP Right Cessation
- 1997-11-12 DE DE69705738T patent/DE69705738T2/de not_active Expired - Fee Related
- 1997-11-12 PL PL97333422A patent/PL333422A1/xx unknown
- 1997-11-12 CA CA002272384A patent/CA2272384A1/en not_active Abandoned
- 1997-11-12 SK SK641-99A patent/SK283757B6/sk unknown
- 1997-11-12 EA EA199900472A patent/EA001467B1/ru not_active IP Right Cessation
- 1997-11-12 NZ NZ336287A patent/NZ336287A/xx unknown
- 1997-11-12 AT AT97913348T patent/ATE203231T1/de not_active IP Right Cessation
- 1997-11-12 BR BR9713038-9A patent/BR9713038A/pt unknown
- 1997-11-12 ES ES97913348T patent/ES2161452T3/es not_active Expired - Lifetime
- 1997-11-12 AU AU50643/98A patent/AU736832B2/en not_active Ceased
- 1997-11-12 CN CN97199819A patent/CN1118448C/zh not_active Expired - Fee Related
- 1997-11-12 PT PT97913348T patent/PT939749E/pt unknown
- 1997-11-12 IL IL12975997A patent/IL129759A0/xx unknown
- 1997-11-12 KR KR1019990704370A patent/KR20000053346A/ko not_active Application Discontinuation
- 1997-11-12 EP EP97913348A patent/EP0939749B1/en not_active Expired - Lifetime
- 1997-11-12 TR TR1999/01087T patent/TR199901087T2/xx unknown
- 1997-11-12 WO PCT/HU1997/000073 patent/WO1998022416A1/en not_active Application Discontinuation
- 1997-11-12 DK DK97913348T patent/DK0939749T3/da active
- 1997-11-12 EE EEP199900196A patent/EE03679B1/xx not_active IP Right Cessation
- 1997-11-12 JP JP52337398A patent/JP2001505200A/ja not_active Ceased
- 1997-11-13 HR HR970609A patent/HRP970609B1/xx not_active IP Right Cessation
- 1997-11-14 ZA ZA9710322A patent/ZA9710322B/xx unknown
- 1997-11-18 AR ARP970105382A patent/AR008527A1/es unknown
- 1997-12-27 TW TW086119823A patent/TW472036B/zh not_active IP Right Cessation
-
1999
- 1999-05-18 NO NO19992375A patent/NO313094B1/no unknown
- 1999-05-28 BG BG103446A patent/BG63626B1/bg unknown
-
2001
- 2001-10-11 GR GR20010401741T patent/GR3036878T3/el not_active IP Right Cessation
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 8A E 9A ANUIDADES. |