BR8505349A - Processo para a producao de gas de sintese - Google Patents

Processo para a producao de gas de sintese

Info

Publication number
BR8505349A
BR8505349A BR8505349A BR8505349A BR8505349A BR 8505349 A BR8505349 A BR 8505349A BR 8505349 A BR8505349 A BR 8505349A BR 8505349 A BR8505349 A BR 8505349A BR 8505349 A BR8505349 A BR 8505349A
Authority
BR
Brazil
Prior art keywords
production
synthesis gas
synthesis
gas
Prior art date
Application number
BR8505349A
Other languages
English (en)
Inventor
Peter Heinrich
Klaus Knop
Friedbert Rube
Original Assignee
Maschf Augsburg Nuernberg Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Maschf Augsburg Nuernberg Ag filed Critical Maschf Augsburg Nuernberg Ag
Publication of BR8505349A publication Critical patent/BR8505349A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/463Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/02Dust removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/04Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1884Heat exchange between at least two process streams with one stream being synthesis gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00Gas: heating and illuminating
    • Y10S48/01Recirculation of gases produced to lower part of fuel bed

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Industrial Gases (AREA)
BR8505349A 1984-10-27 1985-10-25 Processo para a producao de gas de sintese BR8505349A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19843439487 DE3439487A1 (de) 1984-10-27 1984-10-27 Energieguenstiges verfahren zur erzeugung von synthesegas mit einem hohen methangehalt

Publications (1)

Publication Number Publication Date
BR8505349A true BR8505349A (pt) 1986-08-05

Family

ID=6248977

Family Applications (1)

Application Number Title Priority Date Filing Date
BR8505349A BR8505349A (pt) 1984-10-27 1985-10-25 Processo para a producao de gas de sintese

Country Status (7)

Country Link
US (1) US4678480A (pt)
EP (1) EP0182992B1 (pt)
AU (1) AU578312B2 (pt)
BR (1) BR8505349A (pt)
DE (2) DE3439487A1 (pt)
IN (1) IN166503B (pt)
ZA (1) ZA857652B (pt)

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3633212A1 (de) * 1986-09-30 1988-04-14 Kwu Umwelttechnik Gmbh Pyrolyseanlage
US4929585A (en) * 1989-06-09 1990-05-29 Gas Research Institute Mixed-solid solution tri-metallic oxide/sulfide catalyst and process for its preparation
US5002752A (en) * 1989-06-09 1991-03-26 Gas Research Institute Process for hydroforming hydrocarbon liquids
US6152984A (en) * 1998-09-10 2000-11-28 Praxair Technology, Inc. Integrated direct reduction iron system
US6322763B1 (en) 1998-12-15 2001-11-27 Teco, Inc. Method and apparatus for removing carbonyl sulfide from a gas stream via wet scrubbing
US8114176B2 (en) * 2005-10-12 2012-02-14 Great Point Energy, Inc. Catalytic steam gasification of petroleum coke to methane
US7922782B2 (en) * 2006-06-01 2011-04-12 Greatpoint Energy, Inc. Catalytic steam gasification process with recovery and recycle of alkali metal compounds
AU2008282518B2 (en) * 2007-08-02 2012-03-01 Greatpoint Energy, Inc. Catalyst-loaded coal compositions, methods of making and use
WO2009048723A2 (en) * 2007-10-09 2009-04-16 Greatpoint Energy, Inc. Compositions for catalytic gasification of a petroleum coke and process for conversion thereof to methane
WO2009086383A2 (en) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Catalytic gasification process with recovery of alkali metal from char
US20090165383A1 (en) * 2007-12-28 2009-07-02 Greatpoint Energy, Inc. Catalytic Gasification Process with Recovery of Alkali Metal from Char
WO2009086407A2 (en) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Steam generating slurry gasifier for the catalytic gasification of a carbonaceous feedstock
WO2009086377A2 (en) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Catalytic gasification process with recovery of alkali metal from char
US20090165382A1 (en) * 2007-12-28 2009-07-02 Greatpoint Energy, Inc. Catalytic Gasification Process with Recovery of Alkali Metal from Char
US20090165384A1 (en) * 2007-12-28 2009-07-02 Greatpoint Energy, Inc. Continuous Process for Converting Carbonaceous Feedstock into Gaseous Products
WO2009086370A2 (en) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Processes for making syngas-derived products
WO2009086363A1 (en) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Coal compositions for catalytic gasification and process for its preparation
WO2009086366A1 (en) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Processes for making synthesis gas and syngas-derived products
US20090220406A1 (en) * 2008-02-29 2009-09-03 Greatpoint Energy, Inc. Selective Removal and Recovery of Acid Gases from Gasification Products
WO2009111331A2 (en) 2008-02-29 2009-09-11 Greatpoint Energy, Inc. Steam generation processes utilizing biomass feedstocks
WO2009111342A2 (en) 2008-02-29 2009-09-11 Greatpoint Energy, Inc Carbonaceous fines recycle
US8652222B2 (en) 2008-02-29 2014-02-18 Greatpoint Energy, Inc. Biomass compositions for catalytic gasification
US8297542B2 (en) 2008-02-29 2012-10-30 Greatpoint Energy, Inc. Coal compositions for catalytic gasification
US8286901B2 (en) 2008-02-29 2012-10-16 Greatpoint Energy, Inc. Coal compositions for catalytic gasification
US8114177B2 (en) * 2008-02-29 2012-02-14 Greatpoint Energy, Inc. Co-feed of biomass as source of makeup catalysts for catalytic coal gasification
WO2009111345A2 (en) * 2008-02-29 2009-09-11 Greatpoint Energy, Inc. Catalytic gasification particulate compositions
US20090217582A1 (en) * 2008-02-29 2009-09-03 Greatpoint Energy, Inc. Processes for Making Adsorbents and Processes for Removing Contaminants from Fluids Using Them
US8361428B2 (en) * 2008-02-29 2013-01-29 Greatpoint Energy, Inc. Reduced carbon footprint steam generation processes
US7926750B2 (en) * 2008-02-29 2011-04-19 Greatpoint Energy, Inc. Compactor feeder
CA2718295C (en) 2008-04-01 2013-06-18 Greatpoint Energy, Inc. Processes for the separation of methane from a gas stream
WO2009124019A2 (en) * 2008-04-01 2009-10-08 Greatpoint Energy, Inc. Sour shift process for the removal of carbon monoxide from a gas stream
WO2009158579A2 (en) * 2008-06-27 2009-12-30 Greatpoint Energy, Inc. Three-train catalytic gasification systems
US9157042B2 (en) * 2008-07-16 2015-10-13 Kellogg Brown & Root Llc Systems and methods for producing substitute natural gas
US9132401B2 (en) * 2008-07-16 2015-09-15 Kellog Brown & Root Llc Systems and methods for producing substitute natural gas
AU2009293087B2 (en) 2008-09-19 2012-11-15 Sure Champion Investment Limited Processes for gasification of a carbonaceous feedstock
CN102159687B (zh) 2008-09-19 2016-06-08 格雷特波因特能源公司 使用炭甲烷化催化剂的气化方法
US8647402B2 (en) 2008-09-19 2014-02-11 Greatpoint Energy, Inc. Processes for gasification of a carbonaceous feedstock
WO2010048493A2 (en) 2008-10-23 2010-04-29 Greatpoint Energy, Inc. Processes for gasification of a carbonaceous feedstock
WO2010053865A1 (en) * 2008-11-04 2010-05-14 Katana Energy Llc Integration of gasification and hydroprocessing for low emissions refining
KR101290453B1 (ko) 2008-12-30 2013-07-29 그레이트포인트 에너지, 인크. 촉매된 탄소질 미립자의 제조 방법
EP2370549A1 (en) 2008-12-30 2011-10-05 Greatpoint Energy, Inc. Processes for preparing a catalyzed coal particulate
US8268899B2 (en) * 2009-05-13 2012-09-18 Greatpoint Energy, Inc. Processes for hydromethanation of a carbonaceous feedstock
CN102459525B (zh) 2009-05-13 2016-09-21 格雷特波因特能源公司 进行含碳原料的加氢甲烷化的方法
CN104119956B (zh) 2009-05-13 2016-05-11 格雷特波因特能源公司 含碳原料的加氢甲烷化方法
WO2011017630A1 (en) * 2009-08-06 2011-02-10 Greatpoint Energy, Inc. Processes for hydromethanation of a carbonaceous feedstock
AU2010310846B2 (en) 2009-10-19 2013-05-30 Greatpoint Energy, Inc. Integrated enhanced oil recovery process
CN102597417B (zh) 2009-10-19 2014-10-01 格雷特波因特能源公司 整合的强化采油方法
AU2010339952B8 (en) 2009-12-17 2013-12-19 Greatpoint Energy, Inc. Integrated enhanced oil recovery process
US8769964B2 (en) * 2010-01-05 2014-07-08 General Electric Company System and method for cooling syngas produced from a gasifier
WO2011106285A1 (en) 2010-02-23 2011-09-01 Greatpoint Energy, Inc. Integrated hydromethanation fuel cell power generation
US8652696B2 (en) 2010-03-08 2014-02-18 Greatpoint Energy, Inc. Integrated hydromethanation fuel cell power generation
DE102010028181A1 (de) * 2010-04-26 2011-10-27 Siemens Aktiengesellschaft Produktionsanlage für Chemierohstoffe oder Brennstoffe sowie ein Verfahren zum Betrieb einer solchen Produktionsanlage
US8557878B2 (en) 2010-04-26 2013-10-15 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with vanadium recovery
KR101506381B1 (ko) 2010-05-28 2015-03-26 그레이트포인트 에너지, 인크. 액체 중질 탄화수소 공급원료의 가스상 생성물로의 전환
KR101424941B1 (ko) 2010-08-18 2014-08-01 그레이트포인트 에너지, 인크. 탄소질 공급원료의 히드로메탄화
CA2815243A1 (en) 2010-11-01 2012-05-10 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock
US8648121B2 (en) 2011-02-23 2014-02-11 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with nickel recovery
WO2012166879A1 (en) 2011-06-03 2012-12-06 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock
US9012524B2 (en) 2011-10-06 2015-04-21 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock
CN104704204B (zh) 2012-10-01 2017-03-08 格雷特波因特能源公司 用于从原始的低煤阶煤原料产生蒸汽的方法
US9273260B2 (en) 2012-10-01 2016-03-01 Greatpoint Energy, Inc. Agglomerated particulate low-rank coal feedstock and uses thereof
US9034058B2 (en) 2012-10-01 2015-05-19 Greatpoint Energy, Inc. Agglomerated particulate low-rank coal feedstock and uses thereof
WO2014055349A1 (en) 2012-10-01 2014-04-10 Greatpoint Energy, Inc. Agglomerated particulate low-rank coal feedstock and uses thereof
US9840445B2 (en) 2013-03-14 2017-12-12 Synthesis Energy Systems, Inc. Method and apparatus for recycling methane
US9109171B2 (en) 2013-11-15 2015-08-18 General Electric Company System and method for gasification and cooling syngas
US10464872B1 (en) 2018-07-31 2019-11-05 Greatpoint Energy, Inc. Catalytic gasification to produce methanol
US10344231B1 (en) 2018-10-26 2019-07-09 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization
US10435637B1 (en) 2018-12-18 2019-10-08 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization and power generation
US10618818B1 (en) 2019-03-22 2020-04-14 Sure Champion Investment Limited Catalytic gasification to produce ammonia and urea
CN110129100B (zh) * 2019-05-28 2023-12-22 彭万旺 高效燃烧系统及方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1800856A (en) * 1926-04-07 1931-04-14 Bradley Linn Treating iron ore
US2113774A (en) * 1934-11-26 1938-04-12 Schmalfeldt Hans Process for the gasification of dust or fine-grained fuels with circulating gas
US2928730A (en) * 1957-01-15 1960-03-15 Inland Steel Co Iron ore reduction process
US3698882A (en) * 1970-09-30 1972-10-17 Occidental Petroleum Corp Continuous process for the conversion of carbonaceous solids into pipeline gas
US3888658A (en) * 1970-11-02 1975-06-10 Westinghouse Electric Corp Process for the direct reduction of iron ore to steel
US4094650A (en) * 1972-09-08 1978-06-13 Exxon Research & Engineering Co. Integrated catalytic gasification process
US3853538A (en) * 1973-07-20 1974-12-10 Steel Corp Use of reducing gas by coal gasification for direct iron ore reduction
DE2431537A1 (de) * 1974-07-01 1976-01-22 Metallgesellschaft Ag Verfahren zur direktreduktion mit reduzierten gasen
US4011058A (en) * 1975-10-01 1977-03-08 Phillips Petroleum Company Production of substitute natural gas from gasification of coal char
US4260412A (en) * 1980-01-16 1981-04-07 Midrex Corporation Method of producing direct reduced iron with fluid bed coal gasification
ES8300304A1 (es) * 1980-12-09 1982-11-01 Linde Ag Procedimiento de absorcion para descomponer por lo menos dos corrientes de gas crudo .
DE3223702C2 (de) * 1982-06-25 1984-06-28 M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 4200 Oberhausen Verfahren zur Erzeugung von Synthesegas und Reaktor zur Durchführung des Verfahrens
DE3237334A1 (de) * 1982-10-08 1984-04-12 M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 4200 Oberhausen Verfahren zum betreiben eines reaktors zur erzeugung von synthesegas und vorrichtung zur durchfuehrung des verfahrens
DE3306371A1 (de) * 1983-02-24 1984-08-30 Bergwerksverband Gmbh, 4300 Essen Verfahren zur erzeugung eines methanreichen gasgemisches, insbesondere aus grubengas

Also Published As

Publication number Publication date
DE3565996D1 (en) 1988-12-08
AU4786585A (en) 1986-05-01
EP0182992A3 (en) 1987-01-21
IN166503B (pt) 1990-05-19
DE3439487C2 (pt) 1987-09-24
DE3439487A1 (de) 1986-06-26
US4678480A (en) 1987-07-07
EP0182992A2 (de) 1986-06-04
ZA857652B (en) 1986-05-28
AU578312B2 (en) 1988-10-20
EP0182992B1 (de) 1988-11-02

Similar Documents

Publication Publication Date Title
BR8505349A (pt) Processo para a producao de gas de sintese
BR8501133A (pt) Processo para a producao de nitrobenzeno
BR8503903A (pt) Processo para a producao de oxigenio de pureza ultra-elevada
BR8504323A (pt) Processo para a producao de compostos de fosfatos
BR8604261A (pt) Processo para carbonilacao;processo de hidroformilacao para a producao de aldeidos;composicao precursora de catalisador de hidroformilacao
BR8107591A (pt) Processo para a producao de oxigenio gasoso
BR8506421A (pt) Processo para producao de composto dicetonico ciclico acilado
BR8600341A (pt) Processo para a producao de ferro bruto
ES540309A0 (es) Un procedimiento de produccion de gas de sintesis
BR8604182A (pt) Processo para producao de eteres
PT86469A (pt) Processo continuo para a producao de pastilhas comestiveis anti-acidas
BR8600882A (pt) Processo para a producao de vanilina
PT83862B (pt) Processo aperfeicoado para a producao de cerveja
BR8602855A (pt) Processo para a producao de tetra-alcoil-2,2,6,6-piperidilaminas-4
BR8105352A (pt) Processo para a producao de gas
BR8406105A (pt) Processo para producao de uma nitrodiarilaminas
BR8706790A (pt) Processo para a producao de aglomerados de pelotas queimadas
PT81410B (pt) Processo para a producao de um capacete composito
BR8603141A (pt) Processo para a producao de elementos semicondutores
BR8203060A (pt) Processo para a producao de derivados de aminopiperidina
BR8200810A (pt) Processo para a producao de um dissulfeto de tiurama
BR8305921A (pt) Processo e dispositivo para a producao de gas de sintese
PT90353A (pt) Processo para a producao de polipeptideos
BR8802526A (pt) Processo para a producao de uma mistura de gas
BR8001761A (pt) Processo para a producao de gas de reducao

Legal Events

Date Code Title Description
B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 25/10/2000