BR112019008432A2 - tubo de catalisador para reforma - Google Patents

tubo de catalisador para reforma

Info

Publication number
BR112019008432A2
BR112019008432A2 BR112019008432A BR112019008432A BR112019008432A2 BR 112019008432 A2 BR112019008432 A2 BR 112019008432A2 BR 112019008432 A BR112019008432 A BR 112019008432A BR 112019008432 A BR112019008432 A BR 112019008432A BR 112019008432 A2 BR112019008432 A2 BR 112019008432A2
Authority
BR
Brazil
Prior art keywords
catalyst tube
catalyst
process gas
annular channel
reforming catalyst
Prior art date
Application number
BR112019008432A
Other languages
English (en)
Other versions
BR112019008432B1 (pt
Inventor
Farace Antonio
Walspurger Stephane
Original Assignee
Technip France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Technip France filed Critical Technip France
Publication of BR112019008432A2 publication Critical patent/BR112019008432A2/pt
Publication of BR112019008432B1 publication Critical patent/BR112019008432B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00176Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00194Tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • B01J2208/00221Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00504Controlling the temperature by means of a burner
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/0053Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00539Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00548Flow
    • B01J2208/00557Flow controlling the residence time inside the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743Feeding or discharging of solids
    • B01J2208/00752Feeding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743Feeding or discharging of solids
    • B01J2208/00761Discharging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00893Feeding means for the reactants
    • B01J2208/0092Perforated plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/06Details of tube reactors containing solid particles
    • B01J2208/065Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00018Construction aspects
    • B01J2219/00024Revamping, retrofitting or modernisation of existing plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • B01J2219/192Details relating to the geometry of the reactor polygonal
    • B01J2219/1923Details relating to the geometry of the reactor polygonal square or square-derived
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • B01J2219/192Details relating to the geometry of the reactor polygonal
    • B01J2219/1928Details relating to the geometry of the reactor polygonal hexagonal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

a invenção é direcionada a um novo desenho para tubos de catalisador, o que torna possível aplicar o conceito de reforma regenerativa em reformadores a vapor tendo entradas e saídas de tubos de catalisador em lados opostos da câmara de forno. o tubo de catalisador compreende uma entrada para o gás de processo para entrar no tubo de catalisador e uma saída para o gás de processo para sair do tubo de catalisador, cuja entrada e saída estão localizadas em extremidades opostas do tubo de catalisador. o tubo de catalisador compreende ainda um primeiro canal anular compreendendo o catalisador, um segundo canal anular para o gás de processo fluir em contra-corrente ou co-corrente para o gás de processo que flui através do primeiro canal anular.
BR112019008432-0A 2016-10-25 2017-10-25 Tubo de catalisador para reforma BR112019008432B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16195490 2016-10-25
WO16195490.4 2016-10-25
PCT/EP2017/077345 WO2018077969A1 (en) 2016-10-25 2017-10-25 Catalyst tube for reforming

Publications (2)

Publication Number Publication Date
BR112019008432A2 true BR112019008432A2 (pt) 2019-07-09
BR112019008432B1 BR112019008432B1 (pt) 2023-01-31

Family

ID=57211313

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112019008432-0A BR112019008432B1 (pt) 2016-10-25 2017-10-25 Tubo de catalisador para reforma

Country Status (14)

Country Link
US (1) US10472236B2 (pt)
EP (1) EP3532430B1 (pt)
JP (1) JP7010940B2 (pt)
KR (1) KR102447384B1 (pt)
CN (1) CN109996760B (pt)
BR (1) BR112019008432B1 (pt)
CA (1) CA3041056A1 (pt)
DK (1) DK3532430T3 (pt)
ES (1) ES2806697T3 (pt)
MX (1) MX2019004715A (pt)
RU (1) RU2750041C2 (pt)
SA (1) SA519401639B1 (pt)
WO (1) WO2018077969A1 (pt)
ZA (1) ZA201902597B (pt)

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US20220234018A1 (en) * 2019-06-28 2022-07-28 Technip Energies France Method of loading a tubular reactor with a catalyst tube assembly, and a catalyst tube assembly for a tubular reactor
US11433367B2 (en) * 2020-01-21 2022-09-06 Zoneflow Reactor Technologies, LLC Support structure for structured catalyst packings
US10894244B1 (en) * 2020-03-17 2021-01-19 Bayotech, Inc. Hydrogen generation systems
US11891302B2 (en) * 2020-03-17 2024-02-06 Bayotech, Inc. Hydrogen generation systems
US11608266B2 (en) 2020-03-17 2023-03-21 Bayotech, Inc. Hydrogen generation systems
WO2022040700A1 (en) * 2020-08-20 2022-02-24 Jonathan Jay Feinstein High pressure and temperature steam reforming reactor
US20230416085A1 (en) 2020-11-13 2023-12-28 Technip Energies France A process for producing a hydrogen-comprising product gas from a hydrocarbon
EP4105170A1 (en) * 2021-06-18 2022-12-21 Technip Energies France Process and plant for flexible production of syngas from hydrocarbons
AU2022389791A1 (en) 2021-11-18 2024-06-27 8 Rivers Capital, Llc Method for hydrogen production
KR102656869B1 (ko) * 2021-12-16 2024-04-18 한국에너지기술연구원 고열전달이 가능한 관형 반응기 및 이를 이용한 흡열 반응의 실시 방법
EP4238642A1 (en) * 2022-03-02 2023-09-06 Technip Energies France Sealing system for a tubular reactor
EP4279446B1 (en) 2022-05-17 2024-04-17 Technip Energies France Plant and process for producing hydrogen from hydrocarbons
EP4279445B1 (en) 2022-05-17 2024-04-17 Technip Energies France Plant and process for producing and separating syngas

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BR112014031938B1 (pt) * 2012-10-12 2021-09-21 Methanex New Zealand Limited Método para o monitoramento da temperatura de um tubo de reformador em um reator de reformador, e reator que utiliza o método
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Also Published As

Publication number Publication date
JP2019532904A (ja) 2019-11-14
CN109996760A (zh) 2019-07-09
JP7010940B2 (ja) 2022-02-10
EP3532430A1 (en) 2019-09-04
CN109996760B (zh) 2022-09-02
ES2806697T3 (es) 2021-02-18
RU2750041C2 (ru) 2021-06-21
RU2019115952A (ru) 2020-11-27
CA3041056A1 (en) 2018-05-03
WO2018077969A1 (en) 2018-05-03
KR20190077388A (ko) 2019-07-03
EP3532430B1 (en) 2020-07-01
DK3532430T3 (da) 2020-07-27
BR112019008432B1 (pt) 2023-01-31
ZA201902597B (en) 2020-07-29
US10472236B2 (en) 2019-11-12
MX2019004715A (es) 2019-09-18
KR102447384B1 (ko) 2022-09-28
RU2019115952A3 (pt) 2020-12-03
SA519401639B1 (ar) 2022-06-26
US20190233284A1 (en) 2019-08-01

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