BR112019001321A2 - processo para a desidrogenação oxidativa de etano em etileno. - Google Patents

processo para a desidrogenação oxidativa de etano em etileno.

Info

Publication number
BR112019001321A2
BR112019001321A2 BR112019001321-0A BR112019001321A BR112019001321A2 BR 112019001321 A2 BR112019001321 A2 BR 112019001321A2 BR 112019001321 A BR112019001321 A BR 112019001321A BR 112019001321 A2 BR112019001321 A2 BR 112019001321A2
Authority
BR
Brazil
Prior art keywords
ethane
oxidative dehydrogenation
providing
refrigerant
feed gas
Prior art date
Application number
BR112019001321-0A
Other languages
English (en)
Other versions
BR112019001321B1 (pt
Inventor
Jan Schoonebeek Ronald
Van Rossum Guus
Nicolaas Renée Bos Alouisius
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Publication of BR112019001321A2 publication Critical patent/BR112019001321A2/pt
Publication of BR112019001321B1 publication Critical patent/BR112019001321B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00513—Controlling the temperature using inert heat absorbing solids in the bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/06—Details of tube reactors containing solid particles
    • B01J2208/065—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50—Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/55—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50—Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/56—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60—Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/64—Tellurium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60—Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/68—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

trata-se de processos e sistemas de reação associados para a desidrogenação oxidativa de etano. em particular, é fornecido um processo que compreende fornecer um gás de alimentação que compreende etano e oxigênio a um reator de leito fixo multitubular, permitir que o etano e o oxigênio reajam na presença de um catalisador de desidrogenação oxidativa para produzir um efluente de reator que compreende etileno; fornecer um refrigerante a uma região a montante de um espaço de invólucro interior do reator em um padrão de fluxo que é contracorrente com o fluxo do gás de alimentação; e remover o refrigerante da região a montante e fornecer pelo menos uma porção do refrigerante removido da região a montante para a região a jusante em um padrão de fluxo que é cocorrente com o fluxo do gás de alimentação.
BR112019001321-0A 2016-07-26 2017-07-24 Processo para a desidrogenação oxidativa de etano em etileno. BR112019001321B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16181294 2016-07-26
EP16181294.6 2016-07-26
PCT/EP2017/068614 WO2018019760A1 (en) 2016-07-26 2017-07-24 Oxidative dehydrogenation (odh) of ethane

Publications (2)

Publication Number Publication Date
BR112019001321A2 true BR112019001321A2 (pt) 2019-04-30
BR112019001321B1 BR112019001321B1 (pt) 2022-06-07

Family

ID=56550787

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112019001321-0A BR112019001321B1 (pt) 2016-07-26 2017-07-24 Processo para a desidrogenação oxidativa de etano em etileno.

Country Status (14)

Country Link
US (1) US10752564B2 (pt)
EP (1) EP3490961B1 (pt)
KR (1) KR20190039168A (pt)
CN (1) CN109476563B (pt)
AU (1) AU2017304582B2 (pt)
BR (1) BR112019001321B1 (pt)
CA (1) CA3031560A1 (pt)
EA (1) EA038258B1 (pt)
HU (1) HUE054048T2 (pt)
MX (1) MX2019000808A (pt)
PL (1) PL3490961T3 (pt)
SA (1) SA519400942B1 (pt)
WO (1) WO2018019760A1 (pt)
ZA (1) ZA201900889B (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3094451A1 (en) 2018-03-13 2019-09-19 Nova Chemicals Corporation Process to produce ethylene and vinyl acetate monomer and derivatives thereof
WO2019175731A1 (en) 2018-03-13 2019-09-19 Nova Chemicals (International) S.A. Mitigating oxygen, carbon dioxide and/or acetylene output from an odh process
EP3733279A1 (en) * 2019-05-03 2020-11-04 Yara International ASA High pressure strippers for use in urea plants
EP4015495A1 (de) 2020-12-18 2022-06-22 Linde GmbH Verfahren und anlage zur herstellung einer zielverbindung
CN116997409A (zh) * 2021-03-19 2023-11-03 巴斯夫欧洲公司 用于管束反应器中的热点检测的设备和方法
EP4116283A1 (de) 2021-07-06 2023-01-11 Linde GmbH Verfahren und anlage zur herstellung von vinylacetat
EP4122591A1 (de) 2021-07-23 2023-01-25 Linde GmbH Verfahren und anlage zur herstellung einer zielverbindung
WO2023214222A1 (en) * 2022-05-04 2023-11-09 Nova Chemicals (International) S.A. Reactor systems for oxidative dehydrogenation (odh) of ethane

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6977064B1 (en) * 2000-05-05 2005-12-20 Saudi Basic Industries Corporation Apparatus for the controlled optimized addition of reactants in continuous flow reaction systems
ES2192983B1 (es) 2002-01-31 2004-09-16 Universidad Politecnica De Valencia. Un catalizador para la deshidrogenacion oxidativa de etano a eteno.
WO2003072237A1 (de) * 2002-02-27 2003-09-04 Basf Aktiengesellschaft Reaktor und verfahren zur herstellung von phosgen
US7038082B2 (en) 2002-10-17 2006-05-02 Basf Aktiengesellschaft Preparation of a multimetal oxide material
US20040147393A1 (en) 2003-01-29 2004-07-29 Basf Akiengesellschaft Preparation of a multimetal oxide composition
CA2655841C (en) 2009-02-26 2016-06-21 Nova Chemicals Corporation Supported oxidative dehydrogenation catalyst
US8519210B2 (en) 2009-04-02 2013-08-27 Lummus Technology Inc. Process for producing ethylene via oxidative dehydrogenation (ODH) of ethane
EP2716622A1 (de) * 2012-10-05 2014-04-09 Linde Aktiengesellschaft Reaktoreinrichtung und Verfahren zur oxidativen Dehydrierung von Alkanen
CA2833822C (en) * 2013-11-21 2020-08-04 Nova Chemicals Corporation Inherently safe odh operation

Also Published As

Publication number Publication date
US10752564B2 (en) 2020-08-25
SA519400942B1 (ar) 2021-11-30
PL3490961T3 (pl) 2021-09-20
CA3031560A1 (en) 2018-02-01
ZA201900889B (en) 2020-10-28
EP3490961A1 (en) 2019-06-05
CN109476563A (zh) 2019-03-15
US20190248716A1 (en) 2019-08-15
BR112019001321B1 (pt) 2022-06-07
MX2019000808A (es) 2019-10-07
AU2017304582B2 (en) 2019-08-22
EP3490961B1 (en) 2021-03-10
EA201990381A1 (ru) 2019-06-28
KR20190039168A (ko) 2019-04-10
CN109476563B (zh) 2021-09-03
WO2018019760A1 (en) 2018-02-01
AU2017304582A1 (en) 2019-02-28
HUE054048T2 (hu) 2021-08-30
EA038258B1 (ru) 2021-07-30

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Legal Events

Date Code Title Description
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/07/2017, OBSERVADAS AS CONDICOES LEGAIS