BR112018077415A2 - composições de pró-catalisador úteis para baixa incorporação de comonômero e processo para preparar as mesmas - Google Patents

composições de pró-catalisador úteis para baixa incorporação de comonômero e processo para preparar as mesmas

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Publication number
BR112018077415A2
BR112018077415A2 BR112018077415A BR112018077415A BR112018077415A2 BR 112018077415 A2 BR112018077415 A2 BR 112018077415A2 BR 112018077415 A BR112018077415 A BR 112018077415A BR 112018077415 A BR112018077415 A BR 112018077415A BR 112018077415 A2 BR112018077415 A2 BR 112018077415A2
Authority
BR
Brazil
Prior art keywords
pro
compositions useful
catalyst compositions
preparing same
comonomer incorporation
Prior art date
Application number
BR112018077415A
Other languages
English (en)
Other versions
BR112018077415B1 (pt
Inventor
S Ginger Douglas
Chen Linfeng
A Springs Marc
Demirors Mehmet
P Karjala Teresa
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of BR112018077415A2 publication Critical patent/BR112018077415A2/pt
Publication of BR112018077415B1 publication Critical patent/BR112018077415B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C08F4/6555—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

a presente divulgação se refere a novas composições de pró-catalisador incluindo uma fração de titânio, um suporte de haleto de magnésio, uma solução de hidrocarboneto na qual o suporte de haleto de magnésio é formado e um modificador de doador de elétron tendo a fórmula (i). a presente divulgação se refere ainda a um processo de um pote para preparar as novas composições de pró-catalisador, bem como ao uso das novas composições de pró-catalisador em processos de solução para polimerização de etileno e pelo menos um monômero polimerizável adicional para formar uma composição de polímero
BR112018077415-4A 2016-06-30 2017-06-29 Processo para preparar uma composição de pró-catalisador e processo de solução para polimerização de etileno e pelo menos um monômero polimerizável adicional para formar uma composição de polímero BR112018077415B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662356866P 2016-06-30 2016-06-30
US62/356,866 2016-06-30
PCT/US2017/039986 WO2018005789A1 (en) 2016-06-30 2017-06-29 Procatalyst compositions useful for low comonomer incorporation and process for preparing the same

Publications (2)

Publication Number Publication Date
BR112018077415A2 true BR112018077415A2 (pt) 2019-07-16
BR112018077415B1 BR112018077415B1 (pt) 2023-03-14

Family

ID=59363232

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018077415-4A BR112018077415B1 (pt) 2016-06-30 2017-06-29 Processo para preparar uma composição de pró-catalisador e processo de solução para polimerização de etileno e pelo menos um monômero polimerizável adicional para formar uma composição de polímero

Country Status (9)

Country Link
US (1) US20190322774A1 (pt)
EP (2) EP3805277A1 (pt)
JP (1) JP2019524922A (pt)
KR (1) KR20190025648A (pt)
CN (1) CN109563203A (pt)
BR (1) BR112018077415B1 (pt)
ES (1) ES2866924T3 (pt)
SG (2) SG10202013131WA (pt)
WO (1) WO2018005789A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3727854B1 (en) * 2017-12-20 2022-09-07 Dow Global Technologies Llc Multilayer cast films and methods of making thereof
WO2019231986A1 (en) 2018-06-01 2019-12-05 Dow Global Technologies Llc Ziegler-natta catalyst with an electron donor compound for increasing polymer molecular weight
JP2022543558A (ja) * 2019-07-31 2022-10-13 ダウ グローバル テクノロジーズ エルエルシー 高分子量を有するポリエチレンを生成するための重合触媒

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4612300A (en) * 1985-06-06 1986-09-16 The Dow Chemical Company Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
IT1227258B (it) * 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
JP3279675B2 (ja) * 1992-10-12 2002-04-30 三菱化学株式会社 α−オレフィン重合体の製造法
IT1264679B1 (it) * 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori per la (co)polimerizzazione di etilene
AU2214997A (en) 1996-03-27 1997-10-17 Dow Chemical Company, The Highly soluble olefin polymerization catalyst activator
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
MY125673A (en) * 1996-06-10 2006-08-30 Mitsui Chemicals Inc Solid titanium catalyst component for olefin polymerization,process for preparing the same, olefin plymerization catalyst containing the catalyst component and olefin polymerization process using thecatalyst
JP4163220B2 (ja) * 1996-06-10 2008-10-08 三井化学株式会社 オレフィン重合用触媒およびこの触媒を用いるオレフィンの重合方法
US6485662B1 (en) 1996-12-03 2002-11-26 Union Carbide Chemicals & Plastics Technology Corporation Process for preparing a simulated in situ polyethylene blend
US6319989B1 (en) 1997-07-21 2001-11-20 The Dow Chemical Company Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
ATE258958T1 (de) 1997-09-19 2004-02-15 Dow Chemical Co Ethylen-kopolymer-mischungen mit enger molekulargewichtsverteilung und optimierter zusammensetzung, verfahren zu ihrer herstellung und ihre verwendung
CN1247627C (zh) * 2003-04-23 2006-03-29 中国科学院化学研究所 一种丙烯聚合的催化剂体系及其制备方法和用途
CN100348624C (zh) * 2005-01-13 2007-11-14 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分和催化剂
WO2007136494A2 (en) 2006-05-17 2007-11-29 Dow Global Technologies Inc. Ethylene/ alpha-olefin/ diene solution polymerization process
US20110003940A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
WO2012166469A1 (en) * 2011-06-01 2012-12-06 Dow Global Technologies Llc Multi -metallic ziegler - natta procatalysts and catalysts prepared therefrom for olefin polymerizations
US20130109789A1 (en) * 2011-10-28 2013-05-02 Sumitomo Chemical Company, Limited Olefin polymerization catalyst, process for producing olefin polymer, polypropylene resin composition and article comprising the same
US9481741B2 (en) * 2012-11-26 2016-11-01 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof
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Also Published As

Publication number Publication date
SG11201811677QA (en) 2019-01-30
CN109563203A (zh) 2019-04-02
EP3478730A1 (en) 2019-05-08
US20190322774A1 (en) 2019-10-24
EP3805277A1 (en) 2021-04-14
WO2018005789A1 (en) 2018-01-04
ES2866924T3 (es) 2021-10-20
KR20190025648A (ko) 2019-03-11
EP3478730B1 (en) 2021-03-10
JP2019524922A (ja) 2019-09-05
SG10202013131WA (en) 2021-02-25
BR112018077415B1 (pt) 2023-03-14

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B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2729 DE 25-04-2023 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.