BR112017010681A2 - processo para polimerização de etileno - Google Patents
processo para polimerização de etilenoInfo
- Publication number
- BR112017010681A2 BR112017010681A2 BR112017010681A BR112017010681A BR112017010681A2 BR 112017010681 A2 BR112017010681 A2 BR 112017010681A2 BR 112017010681 A BR112017010681 A BR 112017010681A BR 112017010681 A BR112017010681 A BR 112017010681A BR 112017010681 A2 BR112017010681 A2 BR 112017010681A2
- Authority
- BR
- Brazil
- Prior art keywords
- polymerization process
- ethylene polymerization
- alkylaluminiums
- cocatalyst
- thi
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6493—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/18—Bulk density
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Emergency Medicine (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
trata-se de álcoois halogenados usados em polimerização de fase gasosa de etileno em combinação com um componente de catalisador à base de ti e alquilalumínios como cocatalisador que permitem suprimir de modo eficaz a formação de etano e para aumentar de modo simultâneo a atividade de polimerização.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14196869.3 | 2014-12-09 | ||
EP14196869 | 2014-12-09 | ||
PCT/EP2015/078127 WO2016091644A1 (en) | 2014-12-09 | 2015-12-01 | Process for the polymerization of ethylene |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112017010681A2 true BR112017010681A2 (pt) | 2017-12-26 |
BR112017010681B1 BR112017010681B1 (pt) | 2022-04-12 |
Family
ID=52015961
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112017010681-7A BR112017010681B1 (pt) | 2014-12-09 | 2015-12-01 | Processo para a preparação de um (co)polímero de etileno bem como método para reduzir a geração de etano em um processo de polimerização |
Country Status (8)
Country | Link |
---|---|
US (1) | US10077322B2 (pt) |
EP (1) | EP3230324B1 (pt) |
JP (1) | JP6334064B2 (pt) |
KR (1) | KR101851523B1 (pt) |
CN (1) | CN107001519B (pt) |
BR (1) | BR112017010681B1 (pt) |
RU (1) | RU2660910C1 (pt) |
WO (1) | WO2016091644A1 (pt) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3763753A4 (en) * | 2018-03-07 | 2021-12-29 | Mitsui Chemicals, Inc. | Propylene-based block copolymer, production method therefor, and solid titanium catalyst ingredient for olefin polymerization |
CA3162303A1 (en) * | 2019-12-19 | 2021-06-24 | Angela I. Padilla-Acevedo | Gas-phase biphenylphenol polymerization catalysts |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4954470A (en) * | 1988-01-14 | 1990-09-04 | Mobil Oil Corporation | Chlorinated alcohol-containing catalyst composition for polymerizing alpha-olefins |
US5093443A (en) * | 1988-01-14 | 1992-03-03 | Mobil Oil Corporation | Alpha-olefins polymerization with chlorinated alcohol-containing catalyst composition |
US4849389A (en) * | 1988-01-14 | 1989-07-18 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefin polymers of narrow molecular weight distribution |
JP2782537B2 (ja) * | 1989-08-28 | 1998-08-06 | 東燃株式会社 | オレフィン重合用触媒成分の製造方法 |
US5070057A (en) * | 1990-04-02 | 1991-12-03 | Union Carbide Chemicals And Plastics Technology Corporation | Simplified polyethylene catalyst system |
FR2666337B1 (fr) | 1990-08-31 | 1994-04-08 | Bp Chemicals Snc | Procede regule de polymerisation d'olefine en phase gazeuse effectue a l'aide d'un catalyseur de type ziegler-natta. |
FR2680793B1 (fr) | 1991-08-30 | 1994-09-09 | Bp Chemicals Snc | Procede de fabrication d'un polymere de l'ethylene. |
JP3539873B2 (ja) * | 1998-07-29 | 2004-07-07 | 出光石油化学株式会社 | エチレン系重合体製造用触媒及び該触媒を用いるエチレン系重合体の製造方法 |
WO2002048207A1 (fr) | 2000-12-15 | 2002-06-20 | China Petro-Chemical Corporation | Catalyseur spherique pour (co)polymerisation d'ethylene, sa preparation et son utilisation |
KR100522617B1 (ko) | 2000-12-15 | 2005-10-19 | 차이나 페트로-케미칼 코포레이션 | 에틸렌 (공)중합용 담지촉매, 그 제조 방법 및 이용 방법 |
US6660817B2 (en) * | 2001-07-24 | 2003-12-09 | Eastman Chemical Company | Process for the polymerization of ethylene and interpolymers thereof |
US20090318643A1 (en) | 2005-10-31 | 2009-12-24 | China Petroleum & Chemical Corporation | Catalyst Component for Ethylene Polymerization, Preparation Thereof and Catalyst Comprising the Same |
CN102432709B (zh) * | 2010-09-29 | 2013-06-05 | 中国石油化工股份有限公司 | 一种用于乙烯聚合含钛球型催化剂组分及催化剂 |
-
2015
- 2015-12-01 US US15/533,856 patent/US10077322B2/en active Active
- 2015-12-01 CN CN201580064693.3A patent/CN107001519B/zh active Active
- 2015-12-01 EP EP15812976.7A patent/EP3230324B1/en active Active
- 2015-12-01 JP JP2017528120A patent/JP6334064B2/ja active Active
- 2015-12-01 RU RU2017121495A patent/RU2660910C1/ru active
- 2015-12-01 KR KR1020177016132A patent/KR101851523B1/ko active IP Right Grant
- 2015-12-01 BR BR112017010681-7A patent/BR112017010681B1/pt active IP Right Grant
- 2015-12-01 WO PCT/EP2015/078127 patent/WO2016091644A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
US10077322B2 (en) | 2018-09-18 |
US20170327603A1 (en) | 2017-11-16 |
JP6334064B2 (ja) | 2018-05-30 |
CN107001519B (zh) | 2019-05-07 |
JP2017535660A (ja) | 2017-11-30 |
RU2660910C1 (ru) | 2018-07-11 |
EP3230324A1 (en) | 2017-10-18 |
KR20170084244A (ko) | 2017-07-19 |
CN107001519A (zh) | 2017-08-01 |
WO2016091644A1 (en) | 2016-06-16 |
BR112017010681B1 (pt) | 2022-04-12 |
KR101851523B1 (ko) | 2018-04-24 |
EP3230324B1 (en) | 2018-09-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
BR112018006183A2 (pt) | pró-catalisador e processo de polimerização usando o mesmo | |
BR112019001111A2 (pt) | catalisadores bis-bifenil-fenóxi com pontes de silila para polimerização de olefinas | |
BR112016029439A2 (pt) | processo para polimerização de olefinas | |
BR112015024640A2 (pt) | processo para a preparação de um polímero antibacteriano, polímero antibacteriano, uso do polímero e produto antibacteriano | |
BR112017023560A2 (pt) | composição de polímero reforçada com fibra, e, artigo. | |
BR112015032833A2 (pt) | métodos e aparelhos para criar um efeito visual em um artigo de borracha | |
BR112015030912A2 (pt) | processo para preparar um homopolímero ou copolímero de olefina | |
BR112017023516A2 (pt) | composição de polímero reforçado com fibra, e, artigo. | |
BR112016021834A2 (pt) | Copolímero de propileno heteroplástico, processo para preparação de um copolímero de propileno heteroplástico, e, artigo | |
BR112017003977A2 (pt) | tecido, e, produto têxtil. | |
BR112016026938A8 (pt) | pró-catalisador para a polimerização de olefinas, processo para preparar o referido pró-catalisador, sistema catalisador de polimerização, poliolefina e artigo formatado compreendendo a mesma | |
BR112017001799A2 (pt) | catalisador ziegler-natta para polimerização de alta temperatura | |
BR112016005865A2 (pt) | Mistura de polímero, artigo multicamadas contendo a mesma e processo para preparar o artigo multicamadas | |
EP3302657A4 (en) | PUNCH PIN WITH CONCRETED NON-PATIENT END AND REUSABLE PENCIL INTERFACE | |
EP3294454A4 (en) | PROCESS FOR PRODUCING MODIFIED CLAY, SUPPORTED METALLOCENE POLYMERIZATION CATALYST, CATALYST PRODUCED AND USE THEREOF | |
DK3183276T3 (da) | Ethylencopolymerer fremstillet med single site-katalysator | |
BR112018016487A2 (pt) | processo para produzir um compósito de polímero/fibra termoformável compósito de polímero/fibra termoformável, processo para produzir uma moldagem de polímero/fibra, moldagem de polímero/fibra, e, uso de um compósito de polímero/fibra termoformável e de uma moldagem de polímero/fibra. | |
CL2015002201A1 (es) | Composiciones de polimero a base de etileno con procesabilidad mejorada. | |
BR112016010938A2 (pt) | Componente de catalisador sólido para polimerização de olefinas, métodos para produzir um componente de catalisador sólido para polimerização de olefinas e um polímero de olefina, e, catalisador de polimerização de olefinas | |
SG11201509482XA (en) | Catalyst component for olefin polymerization, catalyst, and use thereof | |
BR112015008004A2 (pt) | processo de extração butadiene flexível | |
ES1239889Y (es) | Fibra de viscosa modificada | |
BR112017010681A2 (pt) | processo para polimerização de etileno | |
BR112015008599A2 (pt) | um cordonel de pneumático | |
BR112016022220A2 (pt) | composição polimérica, componente híbrido, lâmina compreendendo a referida composição polimérica, produto plástico semiacabado, processo para a produção do referido produto plástico semiacabado e componente híbrido |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 01/12/2015, OBSERVADAS AS CONDICOES LEGAIS. |