BR112014016089A2 - processo para polimerização de um monômero epóxido, polímero e uso do polímero de óxido de etileno - Google Patents

processo para polimerização de um monômero epóxido, polímero e uso do polímero de óxido de etileno

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Publication number
BR112014016089A2
BR112014016089A2 BR112014016089A BR112014016089A BR112014016089A2 BR 112014016089 A2 BR112014016089 A2 BR 112014016089A2 BR 112014016089 A BR112014016089 A BR 112014016089A BR 112014016089 A BR112014016089 A BR 112014016089A BR 112014016089 A2 BR112014016089 A2 BR 112014016089A2
Authority
BR
Brazil
Prior art keywords
polymer
polymerization
alkaline earth
ethylene oxide
modified
Prior art date
Application number
BR112014016089A
Other languages
English (en)
Other versions
BR112014016089A8 (pt
BR112014016089B1 (pt
Inventor
G Hippler Jeffrey
M Kenney John
R Simms John
S Landon Robert
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of BR112014016089A2 publication Critical patent/BR112014016089A2/pt
Publication of BR112014016089A8 publication Critical patent/BR112014016089A8/pt
Publication of BR112014016089B1 publication Critical patent/BR112014016089B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2651—Alkaline earth metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2672—Nitrogen or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)
  • Epoxy Compounds (AREA)

Abstract

resumo “processo para polimerização de um monômero epóxido, polímero e uso do polímero de óxido de etileno” um processo para polimerização de um monômero de epóxido, preferivelmente, óxido de etileno, compreendendo realizar o processo na presença de uma quantidade cataliticamente ativa de um catalisador obtido por um processo de preparação compreendendo: misturar pelo menos um metal alcalino terroso, amônia líquida, um óxido de alquileno, que é opcionalmente substituído por radicais aromáticos, e uma nitrila orgânica tendo pelo menos um átomo de hidrogênio ácido para preparar um mosto de hexamina alcalina terrosa modificada em amônia líquida; transferir continuamente o mosto de hexamina alcalina terrosa modificada em amônia líquida dentro de um recipiente extrator e evaporar continuamente amônia, acumulando desse modo o catalisador modificado no recipiente extrator; e completar a transferência do mosto da hexamina terrosa alcalina dentro do recipiente extrator, envelhecer o catalisador modificado para obter o catalisador de polimerização final; e um polímero obtido por este processo. 1/1
BR112014016089-9A 2012-01-30 2013-01-21 processo para polimerização de um monômero epóxido, polímero de óxido de etileno e uso do polímero de óxido de etileno BR112014016089B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261592207P 2012-01-30 2012-01-30
US61/592,207 2012-01-30
PCT/US2013/022385 WO2013116027A1 (en) 2012-01-30 2013-01-21 Process for preparing high molecular weight polymers by polymerizing epoxide monomers

Publications (3)

Publication Number Publication Date
BR112014016089A2 true BR112014016089A2 (pt) 2017-06-13
BR112014016089A8 BR112014016089A8 (pt) 2017-07-04
BR112014016089B1 BR112014016089B1 (pt) 2021-02-09

Family

ID=47630594

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014016089-9A BR112014016089B1 (pt) 2012-01-30 2013-01-21 processo para polimerização de um monômero epóxido, polímero de óxido de etileno e uso do polímero de óxido de etileno

Country Status (7)

Country Link
US (1) US9598536B2 (pt)
EP (1) EP2809703B1 (pt)
JP (1) JP6196240B2 (pt)
CN (1) CN104039866A (pt)
BR (1) BR112014016089B1 (pt)
CA (1) CA2861224A1 (pt)
WO (1) WO2013116027A1 (pt)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103539931A (zh) * 2013-11-01 2014-01-29 上海联胜化工有限公司 一种用于合成中低分子量聚氧化乙烯催化剂的制备方法
CA2946162A1 (en) 2014-04-30 2015-11-05 Dow Global Technologies Llc Treatment of aqueous mineral suspensions with polymeric flocculants
MX2016013542A (es) 2014-04-30 2017-02-14 Dow Global Technologies Llc Floculantes polimericos para el tratamiento de suspensiones minerales acuosas.
US20170216791A1 (en) 2014-07-31 2017-08-03 Dow Global Technologies Llc In-line dynamic mixing apparatus for flocculating and dewatering oil sands fine tailings
WO2017034790A1 (en) 2015-08-25 2017-03-02 Dow Global Technologies Llc Flocculation of high-solids mineral slurries
AR108480A1 (es) 2016-05-27 2018-08-22 Dow Global Technologies Llc Método de tratamiento de suspensiones minerales con alto contenido de sólidos con floculantes poliméricos
US20190233310A1 (en) 2016-07-25 2019-08-01 Dow Global Technologies Llc Acoustic mixing for flocculant addition to mineral suspensions
CA3038070A1 (en) 2016-09-23 2018-03-29 Dow Global Technologies Llc Process for tailings remediation
CA3038046A1 (en) 2016-09-27 2018-04-05 Dow Global Technologies Llc Process for dewatering an aqueous process stream
US20210278390A1 (en) 2016-10-31 2021-09-09 Dow Global Technologies Llc Online analysis of oil sands tailings content
CA3078827A1 (en) 2017-10-13 2019-04-18 Dow Global Technologies Llc Method to improve tailings flowability for pipeline transport
CN115109246B (zh) * 2022-07-01 2023-07-14 佳化化学科技发展（上海）有限公司 一种炔基醇醚及其制备方法与应用

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US1539650A (en) 1923-12-20 1925-05-26 Dombeck Kazimer Bush trimmer
US3037943A (en) 1958-12-29 1962-06-05 Union Carbide Corp Preparation of catalysts for the polymerization of epoxides
US2969402A (en) 1958-12-29 1961-01-24 Union Carbide Corp Preparation of catalysts for the polymerization of epoxides
US3281312A (en) 1961-07-05 1966-10-25 Mead Corp Fibrous product containing resinous material and polyethylene oxide and process thereof
US3499847A (en) 1966-08-08 1970-03-10 Petrolite Corp Process for controlling the molecular weight of ultrahigh molecular weight oxyalkylene - containing polymers from alkylene oxides free of groups other than oxirane groups
AT285950B (de) 1968-08-12 1970-11-25 Basf Ag Verfahren zur Herstellung von hochmolekularen Polyäthern
US3729441A (en) 1971-11-04 1973-04-24 Jefferson Chem Co Inc Stabilized high molecular weight poly(ethylene oxide)
CA1111409A (en) * 1976-11-11 1981-10-27 George L. Goeke Process for preparing olefin oxide polymerization catalysts
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Also Published As

Publication number Publication date
BR112014016089A8 (pt) 2017-07-04
US20150166724A1 (en) 2015-06-18
JP2015504966A (ja) 2015-02-16
US9598536B2 (en) 2017-03-21
BR112014016089B1 (pt) 2021-02-09
EP2809703A1 (en) 2014-12-10
EP2809703B1 (en) 2016-08-03
JP6196240B2 (ja) 2017-09-13
CN104039866A (zh) 2014-09-10
WO2013116027A1 (en) 2013-08-08
CA2861224A1 (en) 2013-08-08

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/01/2013, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved

Owner name: THE DOW CHEMICAL COMPANY (US)

B25A Requested transfer of rights approved

Owner name: DDP SPECIALTY ELECTRONIC MATERIALS US, INC. (US)

B25D Requested change of name of applicant approved

Owner name: DDP SPECIALTY ELECTRONIC MATERIALS US, LLC (US)

B25A Requested transfer of rights approved

Owner name: NUTRITION AND BIOSCIENCES USA 1, LLC (US)