BR112014015337B1 - método de supressão de isomerização de um produto de metátese de olefina - Google Patents

método de supressão de isomerização de um produto de metátese de olefina Download PDF

Info

Publication number
BR112014015337B1
BR112014015337B1 BR112014015337A BR112014015337A BR112014015337B1 BR 112014015337 B1 BR112014015337 B1 BR 112014015337B1 BR 112014015337 A BR112014015337 A BR 112014015337A BR 112014015337 A BR112014015337 A BR 112014015337A BR 112014015337 B1 BR112014015337 B1 BR 112014015337B1
Authority
BR
Brazil
Prior art keywords
methods
isomerization
metathesis
olefin metathesis
ester
Prior art date
Application number
BR112014015337A
Other languages
English (en)
Other versions
BR112014015337A2 (pt
BR112014015337A8 (pt
Inventor
E Firth Bruce
e kirk Sharon
Original Assignee
Elevance Renewable Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/335,517 external-priority patent/US9133416B2/en
Priority claimed from US13/335,601 external-priority patent/US9222056B2/en
Application filed by Elevance Renewable Sciences filed Critical Elevance Renewable Sciences
Publication of BR112014015337A2 publication Critical patent/BR112014015337A2/pt
Publication of BR112014015337A8 publication Critical patent/BR112014015337A8/pt
Publication of BR112014015337B1 publication Critical patent/BR112014015337B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/304—Pour point, cloud point, cold flow properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/308—Gravity, density, e.g. API
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/705—Passivation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

(54) title: methods for suppressing isomerization of olefin metathesis products, methods of refining natural oils, and methods of producing fuel compositions (57) abstract: a method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. the isomerization suppression agent includes (i) a salt and/or an ester of a phosphorous oxo acid, and/or (ii) a derivative of the phosphorous oxo acid in which at least one p-h bond has been replaced by a p-c bond, and/or (iii) a salt and/or an ester of the derivative. methods of refining natural oils and methods of producing fuel compositions are described. tradução do resumo resumo patente de invenção: "métodos para suprimir isomerização de produtos de metátese de olefina, métodos para refinar óleos naturais, e métodos para a produção de composições de combustível". a presente invenção refere-se a um método para suprimir a isomerização de um produto de metátese de olefina produzido numa reação de metátese inclui a adição de um agente de supressão de isomerização em uma mistura que inclui o produto de metátese de olefinas e o catalisador de metátese residual a partir da reação de metátese, em condições que são suficientes para passivar pelo menos uma porção de catalisador de metátese residual. o agente de supressão de isomerização inclui (i) um sal e/ou um éster de um ácido oxo-fosforoso, e/ou (ii) um derivado do ácido oxo-fosforoso em que pelo menos uma ligação p-h foi substituída por uma ligação de p-c, e/ou (iii) um sal e/ou um éster do derivado. são ainda descritos métodos de refinação de óleos naturais e métodos de produção de composições de combustível.
BR112014015337A 2011-12-22 2012-12-19 método de supressão de isomerização de um produto de metátese de olefina BR112014015337B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/335,517 US9133416B2 (en) 2011-12-22 2011-12-22 Methods for suppressing isomerization of olefin metathesis products
US13/335,601 US9222056B2 (en) 2009-10-12 2011-12-22 Methods of refining natural oils, and methods of producing fuel compositions
PCT/US2012/070550 WO2013096413A2 (en) 2011-12-22 2012-12-19 Methods for suppressing isomerization of olefin metathesis products, methods of refining natural oils, and methods of producing fuel compositions

Publications (3)

Publication Number Publication Date
BR112014015337A2 BR112014015337A2 (pt) 2017-06-13
BR112014015337A8 BR112014015337A8 (pt) 2017-06-13
BR112014015337B1 true BR112014015337B1 (pt) 2020-04-28

Family

ID=47559679

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014015337A BR112014015337B1 (pt) 2011-12-22 2012-12-19 método de supressão de isomerização de um produto de metátese de olefina

Country Status (9)

Country Link
EP (1) EP2794523B1 (pt)
CN (1) CN104080757B (pt)
AU (1) AU2012359071B2 (pt)
BR (1) BR112014015337B1 (pt)
CA (1) CA2860196C (pt)
EA (1) EA025633B1 (pt)
MX (1) MX348233B (pt)
MY (1) MY165147A (pt)
WO (1) WO2013096413A2 (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3099637A4 (en) * 2014-01-30 2017-08-23 Elevance Renewable Sciences, Inc. Methods and systems for treating an aqueous effluent
CN110320307A (zh) * 2019-08-02 2019-10-11 中国科学院新疆理化技术研究所 一种可控制安石榴苷异构体比例的低温进样方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3150205A (en) 1960-09-07 1964-09-22 Standard Oil Co Paraffin isomerization process
US3351566A (en) 1963-10-21 1967-11-07 Exxon Research Engineering Co Stabilized high-activity catalyst
US4210771A (en) 1978-11-02 1980-07-01 Union Carbide Corporation Total isomerization process
NL190750C (nl) 1984-06-21 1994-08-01 Unilever Nv Nikkelaluminaat katalysator, de bereiding daarvan en het hydrogeneren van onverzadigde organische verbindingen daarmee.
US5095169A (en) 1988-03-30 1992-03-10 Uop Normal paraffin hydrocarbon isomerization process using activated zeolite beta
US6215019B1 (en) 1998-09-01 2001-04-10 Tilliechem, Inc. Synthesis of 5-decenyl acetate and other pheromone components
US6214764B1 (en) 1999-06-01 2001-04-10 Uop Llc Paraffin-isomerization catalyst and process
ATE298318T1 (de) 1999-11-18 2005-07-15 Richard L Pederson Methathesesynthese von pheromonen oder ihrer bestandteile
GB0017839D0 (en) 2000-07-21 2000-09-06 Ici Plc Hydrogenation catalysts
DE10393514T5 (de) * 2002-10-24 2005-09-29 Dow Global Technologies, Inc., Midland Stabilisierung von Produktmischungen aus der Olefinmetathese
CN101558032B (zh) * 2006-10-13 2013-06-19 埃莱文斯可更新科学公司 包括氢化的复分解方法及与其相关的组合物
US8692006B2 (en) 2007-08-09 2014-04-08 Elevance Renewable Sciences, Inc. Thermal methods for treating a metathesis feedstock
BRPI0814994A2 (pt) 2007-08-09 2015-02-03 Elevance Renewable Sciences Métodos químicos para tratamento de uma matéria-prima de metátese
MY152067A (en) * 2008-09-04 2014-08-15 Lummus Technology Inc Olefin isomerization and metathesis catalyst
RU2565057C2 (ru) 2009-10-12 2015-10-20 Елевансе Реневабле Сайенсез, Инк. Способы очистки и производства топлива из натурального масляного исходного сырья

Also Published As

Publication number Publication date
AU2012359071A1 (en) 2014-07-17
CN104080757B (zh) 2016-01-13
CN104080757A (zh) 2014-10-01
WO2013096413A2 (en) 2013-06-27
CA2860196C (en) 2020-02-25
MY165147A (en) 2018-02-28
EP2794523B1 (en) 2016-04-06
AU2012359071B2 (en) 2017-04-06
MX348233B (es) 2017-05-30
EP2794523A2 (en) 2014-10-29
EA025633B1 (ru) 2017-01-30
MX2014007747A (es) 2015-01-12
EA201400700A1 (ru) 2014-11-28
BR112014015337A2 (pt) 2017-06-13
CA2860196A1 (en) 2013-06-27
BR112014015337A8 (pt) 2017-06-13
WO2013096413A3 (en) 2013-11-14

Similar Documents

Publication Publication Date Title
BR112012008608B8 (pt) Método de refinação de óleo natural
BR112013024156A2 (pt) processo de síntese de derivados de cetobenzofurano
AR076800A1 (es) Metodo para producir una preparacion de inmunoglobulina con un alto rendimiento
BRPI0714716B8 (pt) Método para produção de um combustível ou um solvente a partir de uma fonte de ácido graxo
BRPI0705106A (pt) composições de toner
BR112014016033A8 (pt) processo para isolamento de uma composição de proteína e uma composição de gordura de aves domésticas mecanicamente desossadas
FI20115217L (fi) Menetelmä polttoainekomponenttien tuottamiseksi
BR112012028369A2 (pt) processo de preparo de aminoácidos ou ésteres saturados, compreendendo uma etapa de metástase.
BRPI0720991A8 (pt) Preparação da romidepsina
BR112014032741A2 (pt) lipase em esterificação de ácidos graxos de cadeia curta
BR112015006248A2 (pt) métodos de refino e produção de ésteres e ácidos dibásicos a partir de óleos naturais como matéria-prima
EA201590636A1 (ru) Способ получения каталитической композиции для гидрирования и каталитическая композиция для гидрирования
IN2015DN03784A (pt)
BR112015000993A2 (pt) método para a síntese de um ácido alfaaminoalquileno fosfônico ou de um éster do mesmo
WO2015050656A3 (en) Methods and industrial processes for the generation of free fatty acids derivatives thereof from oil gums
BR112014015337B1 (pt) método de supressão de isomerização de um produto de metátese de olefina
BR112012019307A2 (pt) processo para produzir composições de etanol anidras
BR112012024214A2 (pt) método para melhorar a palatabilidade de composições comestíveis.
CO6390033A2 (es) Ácido graso pliinsaturado y éster de diol como agente anti-acné
BR112014015334A8 (pt) métodos para supressão de isomerização de produtos de metátese de olefina, métodos de refino de óleos naturais e métodos de produção de composições de combustível
UA108425C2 (uk) Хімічна композиція, яка містить пероксид водню та наноемульсію довголанцюгових спиртів
BR112014014842A2 (pt) processo para preparação do ácido azeláico a partir do ácido 9-octadecenodióico
UA114082C2 (xx) Спосіб одержання водорозчинних селеноглікопротеїнів та композиція, що їх містить
MX2011007188A (es) Metodos para incrementar niveles de plasmalogenos endogenos.
BR112017025177A2 (pt) produção de esteróis

Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/12/2012, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved

Owner name: WILMAR TRADING PTE LTD (SG)