BR112014005383B8 - complexo bis-iminopiridina de lantanídeos, sistema catalítico compreendendo o dito complexo bisiminopiridina e processo para a (co)polimerização de dienos conjugados - Google Patents

complexo bis-iminopiridina de lantanídeos, sistema catalítico compreendendo o dito complexo bisiminopiridina e processo para a (co)polimerização de dienos conjugados

Info

Publication number
BR112014005383B8
BR112014005383B8 BR112014005383A BR112014005383A BR112014005383B8 BR 112014005383 B8 BR112014005383 B8 BR 112014005383B8 BR 112014005383 A BR112014005383 A BR 112014005383A BR 112014005383 A BR112014005383 A BR 112014005383A BR 112014005383 B8 BR112014005383 B8 BR 112014005383B8
Authority
BR
Brazil
Prior art keywords
complex
iminopyridine
bis
polymerization
conjugated dienes
Prior art date
Application number
BR112014005383A
Other languages
English (en)
Other versions
BR112014005383A2 (pt
BR112014005383B1 (pt
Inventor
Boglia Aldo
Sommazzi Anna
Masi Francesco
Ricci Giovanni
Leone Giuseppe
Caldararo Maria
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of BR112014005383A2 publication Critical patent/BR112014005383A2/pt
Publication of BR112014005383B1 publication Critical patent/BR112014005383B1/pt
Publication of BR112014005383B8 publication Critical patent/BR112014005383B8/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Pyridine Compounds (AREA)

Abstract

complexo bis-iminopiridina de lantanídeos, sistema catalítico compreendendo o dito complexo bis-iminopiridina e processo para a (co) polimerização de dienos conjugados. um complexo bis-iminopiridina de lantanídeos com a fórmula geral (i): o dito complexo bis-iminopiridina de lantanídeos com a fórmula geral (i) podendo ser vantajosamente usado em um sistema catalítico para a (co)polimerização de dienos conjugados.
BR112014005383A 2011-09-14 2012-09-13 complexo bis-iminopiridina de lantanídeos, sistema catalítico compreendendo o dito complexo bisiminopiridina e processo para a (co)polimerização de dienos conjugados BR112014005383B8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI20111651 ITMI20111651A1 (it) 2011-09-14 2011-09-14 Complesso bis-immino piridinico di lantanidi, sistema catalitico comprendente detto complesso bis-immino piridinico e procedimento per la (co)polimerizzazione di dieni coniugati
ITMI2011A001651 2011-09-14
PCT/EP2012/067992 WO2013037913A1 (en) 2011-09-14 2012-09-13 Bis-imine pyridine complex of lanthanides, catalytic system comprising said bis-imine pyridine complex and process for the (co)polymerization of conjugated dienes

Publications (3)

Publication Number Publication Date
BR112014005383A2 BR112014005383A2 (pt) 2017-03-28
BR112014005383B1 BR112014005383B1 (pt) 2020-11-03
BR112014005383B8 true BR112014005383B8 (pt) 2021-02-09

Family

ID=44907949

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112014005383A BR112014005383B8 (pt) 2011-09-14 2012-09-13 complexo bis-iminopiridina de lantanídeos, sistema catalítico compreendendo o dito complexo bisiminopiridina e processo para a (co)polimerização de dienos conjugados
BR112014005383D BR112014005383C8 (pt) 2011-09-14 2012-09-13 complexo bis-iminopiridina de lantanídeos, sistema catalítico compreendendo o dito complexo bis-iminopiridina e processo para a (co)polimerização de dienos conjugados

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR112014005383D BR112014005383C8 (pt) 2011-09-14 2012-09-13 complexo bis-iminopiridina de lantanídeos, sistema catalítico compreendendo o dito complexo bis-iminopiridina e processo para a (co)polimerização de dienos conjugados

Country Status (17)

Country Link
US (2) US20140213433A1 (pt)
EP (1) EP2756011B1 (pt)
KR (2) KR102080427B1 (pt)
CN (1) CN103842392B (pt)
BR (2) BR112014005383B8 (pt)
CA (1) CA2845874C (pt)
ES (1) ES2722227T3 (pt)
HU (1) HUE044903T2 (pt)
IT (1) ITMI20111651A1 (pt)
MY (1) MY193205A (pt)
PL (1) PL2756011T3 (pt)
PT (1) PT2756011T (pt)
RU (1) RU2616005C2 (pt)
TR (1) TR201906505T4 (pt)
TW (1) TWI548660B (pt)
WO (1) WO2013037913A1 (pt)
ZA (1) ZA201400664B (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101781699B1 (ko) * 2014-11-20 2017-09-25 주식회사 엘지화학 공액 디엔의 중합용 촉매 조성물
IT201700109176A1 (it) 2017-09-29 2019-03-29 Versalis Spa Complesso bis-imminico di titanio, sistema catalitico comprendente detto complesso bis-imminico di titanio e procedimento per la (co)polimerizzazione di dieni coniugati
US11584808B2 (en) 2019-12-30 2023-02-21 Bridgestone Corporation Polymerization catalyst composition and method of employing same
CN112175123B (zh) * 2020-09-27 2022-09-27 中国科学院青岛生物能源与过程研究所 一种聚共轭二烯液体橡胶及其制备方法和应用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL211454A (pt) 1955-10-17
DE2830080A1 (de) 1978-07-08 1980-01-17 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
IT1140452B (it) 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
IT1197465B (it) 1986-08-25 1988-11-30 Consiglio Nazionale Ricerche Catalizzatori migliorati a base di neodimio per la polimerizzazione di diolefine coniugate
IT1228442B (it) 1989-02-21 1991-06-19 Consiglio Nazionale Ricerche Nuovi catalizzatori a base di neodimio per la polimerizzazione di diolefine coniugate.
IT1318653B1 (it) 2000-07-28 2003-08-27 Enichem Spa Leganti tridentati e loro complessi con metalli di transizione.
IT1319240B1 (it) 2000-10-26 2003-09-26 Enichem Spa Procedimento per la oligomerizzazione selettiva dell'etilene.
ES2317952T3 (es) * 2000-11-09 2009-05-01 Societe De Technologie Michelin Sistema catalitico y procedimiento de preparacion de elastomeros mediante este sistema.
EP1367069A1 (en) * 2002-05-28 2003-12-03 Dow Global Technologies Inc. Process for homo-or copolymerization of conjugated diens
EP1376069A1 (de) 2002-06-13 2004-01-02 Krohne AG Ultraschalldurchflussmessverfahren
WO2004074333A2 (en) * 2003-02-18 2004-09-02 Dow Global Technologies Inc. Process for homo- or copolymerizationof conjugated olefines
JP5001000B2 (ja) * 2003-02-21 2012-08-15 スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング 共役オレフィンのホモ重合又は共重合方法
EP1840130B1 (en) * 2005-01-21 2012-12-26 Riken Metal complex containing tridentate ligand, and polymerization catalyst comprising the same
CN101260164B (zh) * 2008-04-29 2010-12-22 中国科学院长春应用化学研究所 异戊二烯或丁二烯顺1,4-选择性聚合的催化体系及制法和用法
US8394901B2 (en) * 2008-04-29 2013-03-12 Changchun Institute Of Applied Chemistry Chinese Academy Of Sciences Bi-component catalyst system for isoprene or butadiene cis 1, 4-polymerization and polymerization process
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers

Also Published As

Publication number Publication date
BR112014005383A2 (pt) 2017-03-28
CN103842392A (zh) 2014-06-04
EP2756011B1 (en) 2019-02-13
ES2722227T3 (es) 2019-08-08
ZA201400664B (en) 2014-10-29
TW201329119A (zh) 2013-07-16
BR112014005383C8 (pt) 2021-07-13
EP2756011A1 (en) 2014-07-23
ITMI20111651A1 (it) 2013-03-15
KR20140069107A (ko) 2014-06-09
US20170166666A1 (en) 2017-06-15
HUE044903T2 (hu) 2019-11-28
PL2756011T3 (pl) 2019-07-31
KR102080427B1 (ko) 2020-02-21
TR201906505T4 (tr) 2019-05-21
MY193205A (en) 2022-09-26
CA2845874A1 (en) 2013-03-21
RU2014114162A (ru) 2015-10-20
BR112014005383B1 (pt) 2020-11-03
WO2013037913A1 (en) 2013-03-21
PT2756011T (pt) 2019-05-28
US20140213433A1 (en) 2014-07-31
KR20180093085A (ko) 2018-08-20
RU2616005C2 (ru) 2017-04-12
US10766979B2 (en) 2020-09-08
TWI548660B (zh) 2016-09-11
CA2845874C (en) 2019-10-08
CN103842392B (zh) 2016-10-12

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B16C Correction of notification of the grant [chapter 16.3 patent gazette]

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