BR112014005460A2 - complexo oxo-nitrogenado de lantanídeos, sistema catalítico compreendendo referido complexo oxo-nitrogenado e processo para a (co)polimerização de dienos conjungados - Google Patents

complexo oxo-nitrogenado de lantanídeos, sistema catalítico compreendendo referido complexo oxo-nitrogenado e processo para a (co)polimerização de dienos conjungados

Info

Publication number
BR112014005460A2
BR112014005460A2 BR112014005460A BR112014005460A BR112014005460A2 BR 112014005460 A2 BR112014005460 A2 BR 112014005460A2 BR 112014005460 A BR112014005460 A BR 112014005460A BR 112014005460 A BR112014005460 A BR 112014005460A BR 112014005460 A2 BR112014005460 A2 BR 112014005460A2
Authority
BR
Brazil
Prior art keywords
oxo
nitrogenous
complex
polymerization
conjugated dienes
Prior art date
Application number
BR112014005460A
Other languages
English (en)
Other versions
BR112014005460B1 (pt
Inventor
Boglia Aldo
Sommazzi Anna
Masi Francesco
Ricci Giovanni
Leone Giuseppe
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of BR112014005460A2 publication Critical patent/BR112014005460A2/pt
Publication of BR112014005460B1 publication Critical patent/BR112014005460B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

resumo complexo oxo-nitrogenado de lantanídeos, sistema catalítico compreendendo referido complexo oxo-nitrogenado e processo para a (co)polimerização de dienos conjungados um complexo de piridina bis-imina de lantanídeos tendo a fórmula geral (i). o referido complexo de piridina bis-imina de lantanídeos tendo a fórmula geral (i) podem ser usados vantajosamente em um sistema catalítico para a (co)polimerização de dienos conjugados.
BR112014005460-6A 2011-09-14 2012-09-13 complexos oxo-nitrogenados de lantanídeos, sistema catalítico compreendendo os referidos complexos oxo-nitrogenados e processo para a (co)polimerização de dienos conjungados BR112014005460B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2011A001652 2011-09-14
IT001652A ITMI20111652A1 (it) 2011-09-14 2011-09-14 Complesso oss-azotato di lantanidi, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati
PCT/EP2012/067990 WO2013037911A1 (en) 2011-09-14 2012-09-13 Oxo-nitrogenated complex of lanthanides, catalytic system comprising said oxo-nitrogenated complex and process for the (co)polymerization of conjugated dienes

Publications (2)

Publication Number Publication Date
BR112014005460A2 true BR112014005460A2 (pt) 2017-03-21
BR112014005460B1 BR112014005460B1 (pt) 2020-10-27

Family

ID=44907950

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014005460-6A BR112014005460B1 (pt) 2011-09-14 2012-09-13 complexos oxo-nitrogenados de lantanídeos, sistema catalítico compreendendo os referidos complexos oxo-nitrogenados e processo para a (co)polimerização de dienos conjungados

Country Status (18)

Country Link
US (1) US9200101B2 (pt)
EP (1) EP2756009B1 (pt)
KR (1) KR101944141B1 (pt)
CN (1) CN103797035B (pt)
BR (1) BR112014005460B1 (pt)
CA (1) CA2845871C (pt)
ES (1) ES2735538T3 (pt)
HU (1) HUE045643T2 (pt)
IN (1) IN2014DN01828A (pt)
IT (1) ITMI20111652A1 (pt)
MY (1) MY185082A (pt)
PL (1) PL2756009T3 (pt)
PT (1) PT2756009T (pt)
RU (1) RU2615780C2 (pt)
TR (1) TR201911225T4 (pt)
TW (1) TWI577686B (pt)
WO (1) WO2013037911A1 (pt)
ZA (1) ZA201400268B (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITUB20159429A1 (it) * 2015-12-24 2017-06-24 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di vanadio.
IT201700006307A1 (it) * 2017-01-20 2018-07-20 Versalis Spa Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE551851A (pt) 1955-10-17
US4206132A (en) * 1971-09-24 1980-06-03 The United States Of America As Represented By The Secretary Of The Air Force Lanthanide chelate of a fluorinated ligand
DE2830080A1 (de) 1978-07-08 1980-01-17 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
IT1140452B (it) 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
IT1197465B (it) 1986-08-25 1988-11-30 Consiglio Nazionale Ricerche Catalizzatori migliorati a base di neodimio per la polimerizzazione di diolefine coniugate
US4950790A (en) * 1988-11-14 1990-08-21 Air Products And Chemicals, Inc. Volatile fluorinated β-ketoimines and associated metal complexes
IT1228442B (it) 1989-02-21 1991-06-19 Consiglio Nazionale Ricerche Nuovi catalizzatori a base di neodimio per la polimerizzazione di diolefine coniugate.
US5782986A (en) * 1996-01-11 1998-07-21 Fsi International Process for metals removal using beta-diketone or beta-ketoimine ligand forming compounds
IT1313599B1 (it) 1999-08-05 2002-09-09 Enichem Spa Complessi metallici utilizzabili nella catalisi per la (co)polimerizzazione delle alfa-olefine
US6544919B1 (en) * 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
ATE416203T1 (de) * 2000-11-09 2008-12-15 Michelin Soc Tech Katalytisches system und verfahren zur herstellung von elastomeren unter verwendung dieses systems
US6943224B2 (en) * 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
US6919467B2 (en) 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
EP1367069A1 (en) * 2002-05-28 2003-12-03 Dow Global Technologies Inc. Process for homo-or copolymerization of conjugated diens
US7091150B2 (en) * 2003-12-19 2006-08-15 The Goodyear Tire & Rubber Company Synthetic polyisoprene rubber
JP4925297B2 (ja) * 2005-01-21 2012-04-25 独立行政法人理化学研究所 三座配位子を含む金属錯体、およびそれを含む重合用触媒
CN1931839A (zh) * 2006-09-27 2007-03-21 温州大学 一种n－取代吡咯的合成方法
CN101260164B (zh) * 2008-04-29 2010-12-22 中国科学院长春应用化学研究所 异戊二烯或丁二烯顺1,4-选择性聚合的催化体系及制法和用法
EP2289949B1 (en) * 2008-04-29 2013-09-04 Changchun Institute Of Applied Chemistry Chinese Academy Of Sciences Isoprene or butadiene cis 1,4-polymeric bi-component catalyst system and polymerization process
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers

Also Published As

Publication number Publication date
EP2756009A1 (en) 2014-07-23
ES2735538T3 (es) 2019-12-19
RU2014113637A (ru) 2015-10-20
ITMI20111652A1 (it) 2013-03-15
WO2013037911A1 (en) 2013-03-21
PL2756009T3 (pl) 2019-10-31
TWI577686B (zh) 2017-04-11
TW201323431A (zh) 2013-06-16
CN103797035B (zh) 2017-07-28
MY185082A (en) 2021-04-30
PT2756009T (pt) 2019-07-09
TR201911225T4 (tr) 2019-08-21
KR20140069086A (ko) 2014-06-09
RU2615780C2 (ru) 2017-04-11
ZA201400268B (en) 2014-10-29
IN2014DN01828A (pt) 2015-05-15
CA2845871C (en) 2019-08-06
US20140221592A1 (en) 2014-08-07
US9200101B2 (en) 2015-12-01
CA2845871A1 (en) 2013-03-21
KR101944141B1 (ko) 2019-04-17
HUE045643T2 (hu) 2020-01-28
EP2756009B1 (en) 2019-05-15
BR112014005460B1 (pt) 2020-10-27
CN103797035A (zh) 2014-05-14

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 13/09/2012, OBSERVADAS AS CONDICOES LEGAIS.