BR112013022014A2 - catalisador, artigo catalítico, e, método para reduzir a emissão de nox a partir de uma turbina de gás estacionária - Google Patents

catalisador, artigo catalítico, e, método para reduzir a emissão de nox a partir de uma turbina de gás estacionária

Info

Publication number
BR112013022014A2
BR112013022014A2 BR112013022014A BR112013022014A BR112013022014A2 BR 112013022014 A2 BR112013022014 A2 BR 112013022014A2 BR 112013022014 A BR112013022014 A BR 112013022014A BR 112013022014 A BR112013022014 A BR 112013022014A BR 112013022014 A2 BR112013022014 A2 BR 112013022014A2
Authority
BR
Brazil
Prior art keywords
catalyst
gas turbine
stationary gas
catalytic article
nox emission
Prior art date
Application number
BR112013022014A
Other languages
English (en)
Inventor
J Reining Arthur
Chen Hai-Ying
M Fedeyko Joseph
J Andersen Paul
Original Assignee
Johnson Matthey Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey Inc filed Critical Johnson Matthey Inc
Publication of BR112013022014A2 publication Critical patent/BR112013022014A2/pt

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85Silicoaluminophosphates (SAPO compounds)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8628Processes characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/723CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74Noble metals
    • B01J29/743CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions

Abstract

catalisador, artigo catalítico, e, método para reduzir a emissão de nox a partir de uma turbina de gás estacionária um catalisador que compreende: (a) peneira molecular cristalina microporosa que compreende o mínimo de silício, alumínio e fósforo e tendo um tamanho de poro de anel 8; e (b) um metal de transição carregado na peneira molecular, a carga de metal de transição é menor do que cerca de 1% em peso. um método de usar o catalisador na redução catalítica seletiva (scr).
BR112013022014A 2011-02-28 2012-02-28 catalisador, artigo catalítico, e, método para reduzir a emissão de nox a partir de uma turbina de gás estacionária BR112013022014A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/036,823 US20120134916A1 (en) 2011-02-28 2011-02-28 High-temperature scr catalyst
PCT/US2012/026925 WO2012158239A1 (en) 2011-02-28 2012-02-28 High-temperature scr catalyst

Publications (1)

Publication Number Publication Date
BR112013022014A2 true BR112013022014A2 (pt) 2017-08-01

Family

ID=46000337

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013022014A BR112013022014A2 (pt) 2011-02-28 2012-02-28 catalisador, artigo catalítico, e, método para reduzir a emissão de nox a partir de uma turbina de gás estacionária

Country Status (8)

Country Link
US (1) US20120134916A1 (pt)
EP (1) EP2680966A1 (pt)
JP (1) JP6066932B2 (pt)
KR (1) KR20140011350A (pt)
CN (1) CN103619478A (pt)
BR (1) BR112013022014A2 (pt)
RU (1) RU2013143789A (pt)
WO (1) WO2012158239A1 (pt)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2555853A4 (en) * 2010-03-11 2014-04-16 Johnson Matthey Plc UNLOCATED MOLECULAR SCREENS FOR SELECTIVE CATALYTIC NOX REDUCTION
JP5936995B2 (ja) * 2012-11-26 2016-06-22 一般財団法人電力中央研究所 Co2回収型ガス化ガス発電プラント
DE112015001008T5 (de) * 2014-02-28 2017-04-20 Johnson Matthey Public Limited Company SCR-Katalysatoren mit verbesserter Niedertemperaturleistung und Verfahren zur Herstellung und Verwendung derselben
DE102014205783A1 (de) * 2014-03-27 2015-10-01 Johnson Matthey Public Limited Company Katalysator sowie Verfahren zum Herstellen eines Katalysator
CN104475152B (zh) * 2014-10-09 2017-12-22 南开大学 用于氮氧化物氢气选择催化还原的催化剂及其应用
JP2016222505A (ja) * 2015-06-01 2016-12-28 イビデン株式会社 ゼオライトの製造方法
CN105688921A (zh) * 2016-02-06 2016-06-22 慈溪市梦园果蔬专业合作社 烟气脱NOx催化剂及制备方法
US10343925B2 (en) * 2016-02-12 2019-07-09 Hyundai Motor Company Method for preparing zeolite catalyst
EP3205398A1 (en) 2016-02-12 2017-08-16 Hyundai Motor Company Method for preparing zeolite catalyst
CN105688980A (zh) * 2016-03-10 2016-06-22 镇江翰宏新材料科技有限公司 一种分子筛负载scr催化剂的制备方法
KR101846914B1 (ko) * 2016-10-21 2018-04-09 현대자동차 주식회사 촉매 및 촉매의 제조 방법
GB2571039A (en) * 2016-10-31 2019-08-14 Johnson Matthey Plc LTA catalysts having extra-framework iron and/or manganese for treating exhaust gas
JP6792264B2 (ja) * 2016-11-25 2020-11-25 国立大学法人広島大学 ガリウムを含有する結晶性アルミノシリケートおよびその製造方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US5024981A (en) * 1989-04-20 1991-06-18 Engelhard Corporation Staged metal-promoted zeolite catalysts and method for catalytic reduction of nitrogen oxides using the same
JP2645614B2 (ja) * 1991-01-08 1997-08-25 財団法人石油産業活性化センター 窒素酸化物を含む排ガスの浄化方法
JPH07155614A (ja) * 1993-12-07 1995-06-20 Toyota Motor Corp 排気ガス浄化用触媒の製造方法
US5589147A (en) * 1994-07-07 1996-12-31 Mobil Oil Corporation Catalytic system for the reducton of nitrogen oxides
GB9805815D0 (en) 1998-03-19 1998-05-13 Johnson Matthey Plc Manufacturing process
JP2001038216A (ja) * 1999-08-04 2001-02-13 Mitsubishi Gas Chem Co Inc 触媒寿命の改善方法
US8580216B2 (en) * 2005-02-28 2013-11-12 Ecs Holdings, Inc. Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols
KR100765413B1 (ko) * 2005-07-06 2007-10-09 희성촉매 주식회사 암모니아 산화촉매 및 이를 이용한 슬립 암모니아 또는폐암모니아 처리장치
US20070297975A1 (en) * 2006-06-23 2007-12-27 Janssen Marcel J Metal loading of molecular sieves using organic carriers with limited water content
MY146586A (en) * 2007-03-26 2012-08-30 Pq Corp Novel microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure and methods of making and using same
JP5777339B2 (ja) 2007-04-26 2015-09-09 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Publiclimited Company 遷移金属/ゼオライトscr触媒
JP2009018287A (ja) * 2007-07-13 2009-01-29 Mitsubishi Chemicals Corp 排ガス浄化用酸化触媒
US9863297B2 (en) * 2007-12-12 2018-01-09 Basf Corporation Emission treatment system
US7695703B2 (en) * 2008-02-01 2010-04-13 Siemens Energy, Inc. High temperature catalyst and process for selective catalytic reduction of NOx in exhaust gases of fossil fuel combustion
WO2010121257A1 (en) * 2009-04-17 2010-10-21 Johnson Matthey Public Limited Company Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
EP2687284A1 (en) * 2009-06-08 2014-01-22 Basf Se Cu containing silicoaluminophosphate (Cu-SAPO-34)
US8017097B1 (en) * 2010-03-26 2011-09-13 Umicore Ag & Co. Kg ZrOx, Ce-ZrOx, Ce-Zr-REOx as host matrices for redox active cations for low temperature, hydrothermally durable and poison resistant SCR catalysts
CN103118780B (zh) * 2010-09-15 2016-06-01 庄信万丰股份有限公司 组合的逸失催化剂和烃放热催化剂
US9174849B2 (en) * 2011-08-25 2015-11-03 Basf Corporation Molecular sieve precursors and synthesis of molecular sieves

Also Published As

Publication number Publication date
CN103619478A (zh) 2014-03-05
KR20140011350A (ko) 2014-01-28
US20120134916A1 (en) 2012-05-31
RU2013143789A (ru) 2015-04-10
WO2012158239A1 (en) 2012-11-22
JP6066932B2 (ja) 2017-01-25
EP2680966A1 (en) 2014-01-08
JP2014509935A (ja) 2014-04-24

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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