BR112012027294A2 - polímero útil como aperfeiçoador de índice de viscosidade - Google Patents
polímero útil como aperfeiçoador de índice de viscosidadeInfo
- Publication number
- BR112012027294A2 BR112012027294A2 BR112012027294A BR112012027294A BR112012027294A2 BR 112012027294 A2 BR112012027294 A2 BR 112012027294A2 BR 112012027294 A BR112012027294 A BR 112012027294A BR 112012027294 A BR112012027294 A BR 112012027294A BR 112012027294 A2 BR112012027294 A2 BR 112012027294A2
- Authority
- BR
- Brazil
- Prior art keywords
- formula
- hydrogen
- polymer
- ethylenically unsaturated
- ester compounds
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
- C10M145/14—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/16—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/68—Shear stability
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/045—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for continuous variable transmission [CVT]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Abstract
polímero útil como aperfeiçoador de índice de viscosidade. a presente invenção refere-se a um polímero útil como aperfeiçoador de índice de viscosidade que compreende unidades derivadas de um ou mais compostos ésteres etilenicamente insaturados de fórmula (i) em que r é hidrogênio ou metila, r^ 1^ significa um resíduo alquila linear, ramificado ou cíclico com 1-6 átomos de carbono, r^ 2^ e r^ 3^, independentemente, representa hidrogênio ou um grupo de fórmula - coor<39>, em que r<39> significa hidrogênio ou um grupo alquila com 1-6 átomos de carbono, unidades de um ou mais compostos ésteres etilenicamente insaturados de fórmula (ii) em que r é hidrogênio ou metila, r^ 4^ significa um resíduo alquila ramificado 2-alquila com 12-18 átomo de carbono, r^ 5^ e r^ 6^ , independentemente são, hidrogênio ou um grupo de fórmula - coor", em que r" significa hidrogênio ou um grupo alquila com 12-18 átomos de carbono, e unidades de um ou mais compostos ésteres etilenicamente insaturados de fórmula (iii) em que r é hidrogênio ou metila, r^ 7^ significa um resíduo alquila linear com 12-24 átomos de carbono, r^ 8^ e r^ 9^ , independentemente são, hidrogênio ou um grupo de fórmula -coor", em que r" significa hidrogênio ou um grupo alquila com 12-24 átomos de carbono, no qual o polímero compreende pelo menos 10% em peso de unidades derivadas de um ou mais compostos ésteres etilenicamente insaturados de fórmula (i), com base no peso total do polímero, o polímero compreende pelo menos 10% em peso de unidades derivadas de um ou mais compostos ésteres etilenicamente insaturados de fórmula (ii), com base no peso total do polímero, e o polímero compreende pelo menos 10% em peso de unidades derivadas de um ou mais compostos ésteres etilenicamente insaturados de fórmula (iii), com base no peso total do polímero.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US32791710P | 2010-04-26 | 2010-04-26 | |
PCT/EP2011/052710 WO2011134694A1 (en) | 2010-04-26 | 2011-02-24 | A polymer useful as viscosity index improver |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112012027294A2 true BR112012027294A2 (pt) | 2017-12-26 |
BR112012027294B1 BR112012027294B1 (pt) | 2020-01-28 |
Family
ID=43920309
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012027294A BR112012027294B1 (pt) | 2010-04-26 | 2011-02-24 | polímero útil como aperfeiçoador de índice de viscosidade, composição lubrificante e seu uso |
Country Status (9)
Country | Link |
---|---|
US (1) | US9481849B2 (pt) |
EP (1) | EP2571907B1 (pt) |
JP (1) | JP5748841B2 (pt) |
KR (1) | KR101828098B1 (pt) |
CN (1) | CN102770470B (pt) |
BR (1) | BR112012027294B1 (pt) |
RU (1) | RU2572620C2 (pt) |
SG (1) | SG183825A1 (pt) |
WO (1) | WO2011134694A1 (pt) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010028195A1 (de) * | 2010-04-26 | 2011-10-27 | Evonik Rohmax Additives Gmbh | Schmiermittel für Getriebe |
WO2012076285A1 (en) * | 2010-12-10 | 2012-06-14 | Evonik Rohmax Additives Gmbh | A lubricant composition |
EP2878656B1 (en) | 2012-07-24 | 2018-01-10 | JX Nippon Oil & Energy Corporation | Poly(meth)acrylate-based viscosity index improver, lubricant additive and lubricant composition containing viscosity index improver |
EP2878658B1 (en) * | 2012-07-24 | 2018-09-05 | JX Nippon Oil & Energy Corporation | Lubricating oil composition |
JP6498084B2 (ja) * | 2014-09-10 | 2019-04-10 | 株式会社日本触媒 | 粘度指数向上剤、並びに潤滑油組成物 |
US20160168504A1 (en) * | 2014-12-10 | 2016-06-16 | Hyundai Motor Company | Low viscosity gear oil composition providing enhanced fuel efficiency |
EP3192857A1 (en) * | 2016-01-13 | 2017-07-19 | Basf Se | Use of poly(meth)acrylate copolymers with branched c17 alkyl chains in lubricant oil compositions |
JP6871977B2 (ja) * | 2018-08-09 | 2021-05-19 | 三洋化成工業株式会社 | 粘度指数向上剤及び潤滑油組成物 |
FR3096985B1 (fr) * | 2019-06-05 | 2021-05-14 | S N F Sa | Procede de preparation de polymeres structures sous forme de poudre par voie gel |
JP2022537696A (ja) * | 2019-06-14 | 2022-08-29 | ビーエーエスエフ ソシエタス・ヨーロピア | C13/15アクリレートをベースとするポリアクリレートを含む潤滑剤 |
US11085006B2 (en) * | 2019-07-12 | 2021-08-10 | Afton Chemical Corporation | Lubricants for electric and hybrid vehicle applications |
EP3851507B1 (en) * | 2020-01-15 | 2023-01-18 | Infineum International Limited | Polymers and lubricating compositions containing polymers |
US20220176361A1 (en) * | 2020-06-05 | 2022-06-09 | SCION Holdings LLC | Branched Products |
Family Cites Families (30)
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US940487A (en) | 1906-06-07 | 1909-11-16 | Gardner L Stanbro | Electromagnetic traction system. |
DE3339103A1 (de) | 1983-10-28 | 1985-05-09 | Röhm GmbH, 6100 Darmstadt | Additive fuer schmieroele |
DE3544061A1 (de) | 1985-12-13 | 1987-06-19 | Roehm Gmbh | Hochscherstabile mehrbereichsschmieroele mit verbessertem viskositaetsindex |
DE3613992C2 (de) | 1986-04-25 | 2000-05-04 | Roehm Gmbh | Additive für paraffinische Schmieröle |
IT1270673B (it) * | 1994-10-19 | 1997-05-07 | Euron Spa | Additivo multifunzionale per olii lubrificanti compatibili con fluoroelastomeri |
US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
US5807937A (en) | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
WO1997047661A1 (en) | 1996-06-12 | 1997-12-18 | University Of Warwick | Polymerisation catalyst and process |
DE69709110T2 (de) | 1996-07-10 | 2002-04-25 | Du Pont | Polymerisation mit "living" kennzeichen |
TW593347B (en) | 1997-03-11 | 2004-06-21 | Univ Carnegie Mellon | Improvements in atom or group transfer radical polymerization |
US6071980A (en) | 1997-08-27 | 2000-06-06 | E. I. Du Pont De Nemours And Company | Atom transfer radical polymerization |
US6124249A (en) * | 1998-12-22 | 2000-09-26 | The Lubrizol Corporation | Viscosity improvers for lubricating oil compositions |
US6391996B1 (en) * | 1999-11-30 | 2002-05-21 | Rohmax Additives Gmbh | Copolymers obtainable by the ATRP method and a method for their preparation and their use |
US6746993B2 (en) | 2001-04-06 | 2004-06-08 | Sanyo Chemical Industries, Ltd. | Viscosity index improver and lube oil containing the same |
JP3816847B2 (ja) * | 2001-08-29 | 2006-08-30 | 三洋化成工業株式会社 | 粘度指数向上剤および潤滑油組成物 |
JP4414123B2 (ja) | 2002-03-29 | 2010-02-10 | 三洋化成工業株式会社 | 単量体及びそれからなる共重合体 |
US20040077509A1 (en) | 2002-08-02 | 2004-04-22 | Tsuyoshi Yuki | Viscosity index improver and lube oil containing the same |
RU2280652C1 (ru) * | 2004-12-21 | 2006-07-27 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт химии и технологии полимеров им. академика В.А. Каргина с опытным заводом" (ФГУП "НИИ полимеров") | Способ получения полиалкилметакрилатной присадки (варианты). полиалкилметакрилатная присадка (варианты) |
JP5032029B2 (ja) | 2005-01-28 | 2012-09-26 | 三洋化成工業株式会社 | 粘度指数向上剤および潤滑油組成物 |
KR20070116672A (ko) * | 2005-03-30 | 2007-12-10 | 후지필름 가부시키가이샤 | 윤활제 조성물 |
US7648950B2 (en) * | 2005-04-22 | 2010-01-19 | Rohmax Additives Gmbh | Use of a polyalkylmethacrylate polymer |
JP2007172420A (ja) | 2005-12-23 | 2007-07-05 | Sobal Kk | Rfidタグを媒介としたr/w間通信プロトコル |
JP3987555B1 (ja) | 2006-03-28 | 2007-10-10 | 三洋化成工業株式会社 | 粘度指数向上剤および潤滑油組成物 |
JP2008024908A (ja) | 2006-06-19 | 2008-02-07 | Sanyo Chem Ind Ltd | 粘度指数向上剤および潤滑油組成物 |
JP5122875B2 (ja) | 2006-06-30 | 2013-01-16 | 三洋化成工業株式会社 | 粘度指数向上剤および潤滑油組成物 |
JP2008088215A (ja) | 2006-09-29 | 2008-04-17 | Sanyo Chem Ind Ltd | 粘度指数向上剤および潤滑油組成物 |
JP2009074068A (ja) | 2007-08-29 | 2009-04-09 | Sanyo Chem Ind Ltd | 粘度指数向上剤および潤滑油組成物 |
CA2765300A1 (en) | 2009-06-12 | 2010-12-16 | Evonik Rohmax Additives Gmbh | A fluid having improved viscosity index |
WO2012076676A1 (en) | 2010-12-10 | 2012-06-14 | Evonik Rohmax Additives Gmbh | A viscosity index improver comprising a polyalkyl(meth)acrylate polymer |
WO2012076285A1 (en) | 2010-12-10 | 2012-06-14 | Evonik Rohmax Additives Gmbh | A lubricant composition |
-
2011
- 2011-02-24 KR KR1020127027835A patent/KR101828098B1/ko active IP Right Grant
- 2011-02-24 US US13/576,098 patent/US9481849B2/en active Active
- 2011-02-24 WO PCT/EP2011/052710 patent/WO2011134694A1/en active Application Filing
- 2011-02-24 BR BR112012027294A patent/BR112012027294B1/pt active IP Right Grant
- 2011-02-24 RU RU2012150069/04A patent/RU2572620C2/ru active
- 2011-02-24 EP EP11707141.5A patent/EP2571907B1/en active Active
- 2011-02-24 SG SG2012064051A patent/SG183825A1/en unknown
- 2011-02-24 CN CN201180011205.4A patent/CN102770470B/zh active Active
- 2011-02-24 JP JP2013506552A patent/JP5748841B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
WO2011134694A1 (en) | 2011-11-03 |
EP2571907A1 (en) | 2013-03-27 |
SG183825A1 (en) | 2012-11-29 |
KR20130096146A (ko) | 2013-08-29 |
US20120302477A1 (en) | 2012-11-29 |
JP5748841B2 (ja) | 2015-07-15 |
CN102770470B (zh) | 2015-04-01 |
JP2013529231A (ja) | 2013-07-18 |
BR112012027294B1 (pt) | 2020-01-28 |
KR101828098B1 (ko) | 2018-02-09 |
EP2571907B1 (en) | 2015-04-08 |
US9481849B2 (en) | 2016-11-01 |
RU2012150069A (ru) | 2014-06-10 |
CN102770470A (zh) | 2012-11-07 |
RU2572620C2 (ru) | 2016-01-20 |
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