BR112012020131A2 - method to metallize objects that have at least two different plastics on the surface - Google Patents

method to metallize objects that have at least two different plastics on the surface

Info

Publication number
BR112012020131A2
BR112012020131A2 BR112012020131A BR112012020131A BR112012020131A2 BR 112012020131 A2 BR112012020131 A2 BR 112012020131A2 BR 112012020131 A BR112012020131 A BR 112012020131A BR 112012020131 A BR112012020131 A BR 112012020131A BR 112012020131 A2 BR112012020131 A2 BR 112012020131A2
Authority
BR
Brazil
Prior art keywords
objects
metallized
metallization
different plastics
solution
Prior art date
Application number
BR112012020131A
Other languages
Portuguese (pt)
Inventor
Pereira Arnaldo
Ewald Heinz
Original Assignee
Atotech Deutschland Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atotech Deutschland Gmbh filed Critical Atotech Deutschland Gmbh
Publication of BR112012020131A2 publication Critical patent/BR112012020131A2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02—Electroplating of selected surface areas
    • C25D5/022—Electroplating of selected surface areas using masking means
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1603—Process or apparatus coating on selected surface areas
    • C23C18/1607—Process or apparatus coating on selected surface areas by direct patterning
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
    • C23C18/2046—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
    • C23C18/2073—Multistep pretreatment
    • C23C18/2086—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/28—Sensitising or activating
    • C23C18/30—Activating or accelerating or sensitising with palladium or other noble metal
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
    • C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/38—Coating with copper
    • C23C18/40—Coating with copper using reducing agents
    • C23C18/405—Formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/20—Electroplating using ultrasonics, vibrations
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/54—Electroplating of non-metallic surfaces
    • C25D5/56—Electroplating of non-metallic surfaces of plastics
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemically Coating (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

método para metalizar objetos que têm pelo menos dois plásticos diferentes sobre a superfície. a presente invenção refere-se a um método para melhorar a seletividade durante a metalização de áreas superficiais a serem metalizadas sobre objetos 7 que têm plásticos diferentes, e ao mesmo tempo, não permitindo que áreas que não devem ser metalizadas sejam metalizadas: (a) decapagem dos objetos 7 com uma solução decapante; (b) tratamento dos objetos 7 com uma solução de um coloide ou com um composto metálico, sendo o metal um metal do grupo viiib ou ib da tabela periódica dos elementos; e (c) metalização eletrlítica dos objetos 7 com uma solução de metalização. de acordo com a presente invenção, os objetos 7 são submetidos ao tratamento ultrassônico durante o tratamento em uma outra etapa do método depois da etapa (b) do método e antes de etapa (c) do método, para evitar a metalização de pelo menos um primeiro plástico exposto sobre a superfície dos objetos 7, e ao mesmo tempo, pelo menos um segundo plástico exposto sobre a superfície dos objetos 7 é metalizado.Method for metallising objects that have at least two different plastics on the surface. The present invention relates to a method for improving selectivity during metallization of surface areas to be metallized over objects having different plastics, while at the same time not allowing areas that should not be metallized to be metallized: (a) stripping objects 7 with a stripping solution; (b) treating the objects 7 with a solution of a colloid or with a metallic compound, the metal being a metal of group viiib or ib of the periodic table of elements; and (c) electrolytic metallization of objects 7 with a metallization solution. According to the present invention, objects 7 are subjected to ultrasonic treatment during treatment in another method step after method step (b) and before method step (c), to avoid metallization of at least one first plastic exposed on the surface of objects 7, and at the same time at least one second plastic exposed on the surface of objects 7 is metallized.

BR112012020131A 2010-02-12 2011-02-07 method to metallize objects that have at least two different plastics on the surface BR112012020131A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10001464.6A EP2360294B1 (en) 2010-02-12 2010-02-12 Method for metallising objects with at least two different plastics on their surface
PCT/EP2011/051757 WO2011098428A1 (en) 2010-02-12 2011-02-07 Method for metallising objects which have at least two different plastics on the surface

Publications (1)

Publication Number Publication Date
BR112012020131A2 true BR112012020131A2 (en) 2018-03-06

Family

ID=42270001

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012020131A BR112012020131A2 (en) 2010-02-12 2011-02-07 method to metallize objects that have at least two different plastics on the surface

Country Status (10)

Country Link
US (1) US20120305406A1 (en)
EP (1) EP2360294B1 (en)
JP (1) JP2013519786A (en)
KR (1) KR20120115993A (en)
CN (1) CN102791907B (en)
BR (1) BR112012020131A2 (en)
ES (1) ES2416982T3 (en)
PL (1) PL2360294T3 (en)
PT (1) PT2360294E (en)
WO (1) WO2011098428A1 (en)

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CN103220884A (en) * 2012-01-18 2013-07-24 光宏精密股份有限公司 Line substrate structure and manufacturing method thereof
EP2639333A1 (en) * 2012-03-15 2013-09-18 Atotech Deutschland GmbH Method for metallising non-conductive plastic surfaces
LT6070B (en) * 2012-12-07 2014-09-25 Atotech Deutschland Gmbh Preparation of plastic surface for chemical metallization process
KR20170008309A (en) * 2014-07-10 2017-01-23 오꾸노 케미칼 인더스트리즈 컴파니,리미티드 Resin plating method
US10895015B1 (en) * 2014-12-16 2021-01-19 Hrl Laboratories, Llc Thin-walled high temperature alloy structures via multi-material additive manufacturing
DE102015204912A1 (en) 2015-03-18 2016-09-22 Coventya Gmbh Process for the selective metallization of butadiene-containing plastic areas in a component and kit for carrying out the method
JP6750293B2 (en) * 2016-04-28 2020-09-02 栗田工業株式会社 How to treat plastic surface
US10525919B2 (en) 2016-05-27 2020-01-07 Srg Global Inc. Vehicle exterior components having discontinuous plated features
US9914404B2 (en) 2016-08-08 2018-03-13 Srg Global Inc. Vehicle components having deep mesh plated features
EP3339481A1 (en) * 2016-12-21 2018-06-27 Dr. M. Kampschulte GmbH & Co. KG Method and kit of parts for the pretreatment of objects to be chromed
DE102021117567A1 (en) 2021-07-07 2023-01-12 Leibniz-Institut Für Polymerforschung Dresden E.V. Process for the selective coating of multi-component plastic composites and components made of selectively coated multi-component plastic composites

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Also Published As

Publication number Publication date
CN102791907B (en) 2015-08-05
EP2360294B1 (en) 2013-05-15
JP2013519786A (en) 2013-05-30
KR20120115993A (en) 2012-10-19
CN102791907A (en) 2012-11-21
WO2011098428A1 (en) 2011-08-18
EP2360294A1 (en) 2011-08-24
ES2416982T3 (en) 2013-08-05
US20120305406A1 (en) 2012-12-06
PT2360294E (en) 2013-06-28
PL2360294T3 (en) 2013-09-30

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Legal Events

Date Code Title Description
B08F Application fees: application dismissed [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]