BR112018012332A2 - process for producing a solid catalyst component and an alpha-olefin polymer - Google Patents

process for producing a solid catalyst component and an alpha-olefin polymer

Info

Publication number
BR112018012332A2
BR112018012332A2 BR112018012332-3A BR112018012332A BR112018012332A2 BR 112018012332 A2 BR112018012332 A2 BR 112018012332A2 BR 112018012332 A BR112018012332 A BR 112018012332A BR 112018012332 A2 BR112018012332 A2 BR 112018012332A2
Authority
BR
Brazil
Prior art keywords
component
contact
alpha
producing
solid catalyst
Prior art date
Application number
BR112018012332-3A
Other languages
Japanese (ja)
Portuguese (pt)
Other versions
BR112018012332B1 (en
Inventor
Fukuda Keiji
Ida Shouichi
Tanna Akio
Mizukami Shigeo
Original Assignee
Japan Polypropylene Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Polypropylene Corporation filed Critical Japan Polypropylene Corporation
Publication of BR112018012332A2 publication Critical patent/BR112018012332A2/en
Publication of BR112018012332B1 publication Critical patent/BR112018012332B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/607—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/609—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6093—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6498—Catalysts containing a specific non-metal or metal-free compound organic containing another heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

a presente invenção refere-se a um método para produzir um componente de catalisador sólido para polimerização de alfa-olefinas, colocando os componentes (a1) em (a4) em contato um com o outro em um solvente inerte e, sem lavar tal produto de contato com o solvente inerte, permitindo que o produto de contato permaneça e envelheça por um tempo de retenção de 3-180 dias a partir do momento em que todos os componentes (a1) a (a4) primeiro entram em contato um com o outro. componente (a1): um componente sólido contendo titânio, magnésio, um halogênio e um composto doador de elétrons como componentes essenciais. componente (a2): um composto de silano contendo um grupo alquenil. componente (a3): um composto de alcoxissilano. componente (a4): um composto de alumínio orgânico.the present invention relates to a method for producing a solid catalyst component for the polymerization of alpha-olefins, placing the components (a1) in (a4) in contact with each other in an inert solvent and, without washing such product of contact with the inert solvent, allowing the contact product to remain and age for a retention time of 3-180 days from the time when all components (a1) to (a4) first come into contact with each other. component (a1): a solid component containing titanium, magnesium, a halogen and an electron donating compound as essential components. component (a2): a silane compound containing an alkenyl group. component (a3): an alkoxysilane compound. component (a4): an organic aluminum compound.

BR112018012332-3A 2015-12-18 2016-12-16 METHODS FOR PRODUCTION OF A SOLID CATALYST COMPONENT AND AN A-OLEFIN POLYMER BR112018012332B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2015247337 2015-12-18
JP2015-247337 2015-12-18
PCT/JP2016/087595 WO2017104817A1 (en) 2015-12-18 2016-12-16 METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR α-OLEFIN POLYMERIZATION, AND METHOD FOR PRODUCING α-OLEFIN POLYMER USING SAME

Publications (2)

Publication Number Publication Date
BR112018012332A2 true BR112018012332A2 (en) 2018-12-04
BR112018012332B1 BR112018012332B1 (en) 2022-04-05

Family

ID=59056657

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018012332-3A BR112018012332B1 (en) 2015-12-18 2016-12-16 METHODS FOR PRODUCTION OF A SOLID CATALYST COMPONENT AND AN A-OLEFIN POLYMER

Country Status (7)

Country Link
US (1) US10526427B2 (en)
EP (1) EP3392277B1 (en)
JP (1) JP6714869B2 (en)
CN (1) CN108368192B (en)
BR (1) BR112018012332B1 (en)
TW (1) TWI686410B (en)
WO (1) WO2017104817A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107207645B (en) * 2015-01-30 2020-01-17 东邦钛株式会社 Process for producing olefin polymerization catalyst and process for producing olefin polymer
JP6809374B2 (en) * 2016-05-23 2021-01-06 日本ポリプロ株式会社 A method for producing a solid catalyst component for α-olefin polymerization, and a method for producing an α-olefin polymer using the same.
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization

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US4342856A (en) * 1980-11-14 1982-08-03 El Paso Polyolefins Company Propylene polymerization process and product
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JPS61171715A (en) 1985-01-24 1986-08-02 Mitsubishi Petrochem Co Ltd Production of propylene copolymer
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EP0439622A4 (en) * 1989-08-18 1993-05-26 Tonen Corporation Catalytic component for alpha-olefin polymerization
JP2709634B2 (en) * 1989-08-18 1998-02-04 東燃株式会社 Catalyst component for α-olefin polymerization
JP2709633B2 (en) * 1989-08-18 1998-02-04 東燃株式会社 Catalyst component for α-olefin polymerization
JP2874934B2 (en) 1990-02-08 1999-03-24 三菱化学株式会社 Production of .ALPHA.-olefin polymer
JP2945066B2 (en) 1990-04-13 1999-09-06 三井化学株式会社 Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst and olefin polymerization method
JPH072923A (en) 1993-06-15 1995-01-06 Mitsubishi Chem Corp Method for polymerizing olefin
JP3409263B2 (en) * 1993-09-07 2003-05-26 東邦チタニウム株式会社 Solid catalyst component for producing ethylene-propylene copolymer rubber
JP3258226B2 (en) 1995-02-13 2002-02-18 東邦チタニウム株式会社 Solid catalyst component and catalyst for olefin polymerization
KR100347078B1 (en) 1995-02-13 2002-11-30 도호 티타늄 가부시키가이샤 Solid catalyst component and catalyst for polymerization of olefins
IT1274250B (en) 1995-02-21 1997-07-15 Himont Inc DIETTERS THAT CAN BE USED IN THE PREPARATION OF ZIEGLER-NATTA CATALYSTS
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Also Published As

Publication number Publication date
EP3392277A1 (en) 2018-10-24
CN108368192B (en) 2020-09-11
EP3392277B1 (en) 2024-04-24
TW201741351A (en) 2017-12-01
EP3392277A4 (en) 2019-01-16
CN108368192A (en) 2018-08-03
US20180362673A1 (en) 2018-12-20
JP6714869B2 (en) 2020-07-01
US10526427B2 (en) 2020-01-07
TWI686410B (en) 2020-03-01
WO2017104817A1 (en) 2017-06-22
BR112018012332B1 (en) 2022-04-05
JP2017115142A (en) 2017-06-29

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Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/12/2016, OBSERVADAS AS CONDICOES LEGAIS.