BR112012001941A8 - Método para regeneração de catalisador para tratamento de gás de exaustão, e catalisador para tratamento de gás de exaustão produzido por esse método - Google Patents

Método para regeneração de catalisador para tratamento de gás de exaustão, e catalisador para tratamento de gás de exaustão produzido por esse método

Info

Publication number
BR112012001941A8
BR112012001941A8 BR112012001941A BR112012001941A BR112012001941A8 BR 112012001941 A8 BR112012001941 A8 BR 112012001941A8 BR 112012001941 A BR112012001941 A BR 112012001941A BR 112012001941 A BR112012001941 A BR 112012001941A BR 112012001941 A8 BR112012001941 A8 BR 112012001941A8
Authority
BR
Brazil
Prior art keywords
catalyst
gas treatment
exhaust gas
grinding
base material
Prior art date
Application number
BR112012001941A
Other languages
English (en)
Other versions
BR112012001941A2 (pt
Inventor
Obayashi Yoshiaki
Kiyosawa Masashi
Demoto Masanori
Original Assignee
Mitsubishi Heavy Ind Ltd
Mitsubishi Hitachi Power Sys Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Ind Ltd, Mitsubishi Hitachi Power Sys Ltd filed Critical Mitsubishi Heavy Ind Ltd
Publication of BR112012001941A2 publication Critical patent/BR112012001941A2/pt
Publication of BR112012001941A8 publication Critical patent/BR112012001941A8/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/92—Dimensions
    • B01D2255/9202—Linear dimensions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

MÉTODO PARA REGENERAÇÃO DE CATALISADOR PARA TRATAMENTO DE GÁS DE EXAUSTÃO, E CATALISADOR PARA TRATAMENTO DE GÁS DE EXAUSTÃO PRODUZIDO POR ESSE MÉTODO. Um catalisador para tratamento de gás de exaustão regenerado (17) pode ser produzido realizando-se as etapas: uma etapa de trituração grosseira do catalisador usado (S1) para triturar grosseiramente um catalisador para tratamento de gás de exaustão usado (11), uma etapa de separação (S2) para separar um material grosseiramente triturado em pedaços grandes (12) e um pó fino (13); uma etapa de trituração fina do catalisador usado (S3) para triturar os pedaços grosseiros bem finos (12); as etapas (S4 a (S7) para amassar o pó fino juntamente com outros materiais brutos, moldagem de um material amassado, e secagem e queima de um material moldado para produzir um material de base (14); uma etapa de trituração do catalisador novo (S8) para tritrurar um catalisador para tratamento de gás de exaustão recente (15); uma etapa de suspensão (s9) para formar uma solução aquosa de suspensão do produto triturado do catalisador para tratamento de gás de exaustão recentemente produzido (15); uma etapa de revestimento com a suspensão (S10) para revestir a superfície do material de base (14) com a solução de suspensão (16)ç e uma etapa de secagem do revestimento (S11) e uma etapa de queima do revestimento (S12) para secar o material de base (14) que foi revestido com a solução aquosa de suspensão (16); e a queima do material de base (14) a uma temperatura maior do que a temperatura de queima empregada na produção do catalisador para tratamento de gás de exaustão (15).
BR112012001941A 2010-06-02 2011-01-28 Método para regeneração de catalisador para tratamento de gás de exaustão, e catalisador para tratamento de gás de exaustão produzido por esse método BR112012001941A8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2010126513A JP5535769B2 (ja) 2010-06-02 2010-06-02 排ガス処理触媒の再生方法及びこの方法を使用した排ガス処理触媒
PCT/JP2011/051690 WO2011152080A1 (ja) 2010-06-02 2011-01-28 排ガス処理触媒の再生方法及びこの方法を使用した排ガス処理触媒

Publications (2)

Publication Number Publication Date
BR112012001941A2 BR112012001941A2 (pt) 2017-10-03
BR112012001941A8 true BR112012001941A8 (pt) 2018-02-06

Family

ID=45066469

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012001941A BR112012001941A8 (pt) 2010-06-02 2011-01-28 Método para regeneração de catalisador para tratamento de gás de exaustão, e catalisador para tratamento de gás de exaustão produzido por esse método

Country Status (10)

Country Link
US (2) US8835340B2 (pt)
EP (1) EP2578314B1 (pt)
JP (1) JP5535769B2 (pt)
KR (1) KR101398317B1 (pt)
CN (1) CN102470364A (pt)
BR (1) BR112012001941A8 (pt)
CA (1) CA2768961C (pt)
PL (1) PL2578314T3 (pt)
RU (1) RU2505358C2 (pt)
WO (1) WO2011152080A1 (pt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5812768B2 (ja) 2011-08-31 2015-11-17 三菱日立パワーシステムズ株式会社 脱硝触媒の再生方法及び重質油焚き燃焼装置の運転方法
JP6441140B2 (ja) * 2014-03-28 2018-12-19 日揮触媒化成株式会社 使用済み触媒を用いた酸化チタン系微粉末の製造方法および該粉末を用いた排ガス処理触媒の製造方法
JP6391397B2 (ja) * 2014-09-30 2018-09-19 株式会社日本触媒 排ガス処理触媒の製造方法
KR101581613B1 (ko) * 2015-01-14 2015-12-31 성균관대학교산학협력단 원자층 증착법으로 제조된 저온 일산화탄소 산화용 니켈계 촉매 및 이의 활용
WO2023248967A1 (ja) * 2022-06-20 2023-12-28 日本碍子株式会社 酸性ガス吸着装置の再生方法、および、酸性ガス吸着装置の製造方法

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JPS5780433A (en) * 1980-11-10 1982-05-20 Yoshino Kogyosho Co Ltd Method for treatment of bottle made of saturated polyester
JPS57180433A (en) * 1981-04-28 1982-11-06 Mitsubishi Heavy Ind Ltd Regeneration of used denitration catalyst
JPH03127630A (ja) 1989-10-09 1991-05-30 Hitachi Ltd 脱硝触媒と脱硝触媒用被覆ガラス
US5763352A (en) * 1994-05-30 1998-06-09 Yukong Ltd. Catalyst composition for the purification of the exhaust of diesel vehicles, catalyst using the same and preparing methods thereof
JP3495475B2 (ja) * 1995-10-17 2004-02-09 三菱重工業株式会社 窒素酸化物除去触媒
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JP4264643B2 (ja) 2003-09-18 2009-05-20 日立造船株式会社 劣化触媒の再生方法
KR20060129391A (ko) * 2004-01-20 2006-12-15 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 소모된 수소처리 촉매의 촉매 활성을 복원하는 방법, 촉매활성이 복원된 소모된 수소처리 촉매 및 수소처리 방법
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Also Published As

Publication number Publication date
PL2578314T3 (pl) 2021-12-20
EP2578314A4 (en) 2014-04-02
EP2578314B1 (en) 2021-08-18
RU2505358C2 (ru) 2014-01-27
JP5535769B2 (ja) 2014-07-02
JP2011251245A (ja) 2011-12-15
CN102470364A (zh) 2012-05-23
KR20120040219A (ko) 2012-04-26
US20120204543A1 (en) 2012-08-16
CA2768961A1 (en) 2011-12-08
US8835340B2 (en) 2014-09-16
US20140349838A1 (en) 2014-11-27
EP2578314A1 (en) 2013-04-10
BR112012001941A2 (pt) 2017-10-03
WO2011152080A1 (ja) 2011-12-08
CA2768961C (en) 2015-03-10
KR101398317B1 (ko) 2014-05-23

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B25A Requested transfer of rights approved

Owner name: MITSUBISHI HITACHI POWER SYSTEMS, LTD. (JP)

B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements
B350 Update of information on the portal [chapter 15.35 patent gazette]