BR0318173A - projeto de reator multifase que incorpora um sistema de filtração para catalisadores de camada fixa - Google Patents
projeto de reator multifase que incorpora um sistema de filtração para catalisadores de camada fixaInfo
- Publication number
- BR0318173A BR0318173A BRPI0318173-1A BR0318173A BR0318173A BR 0318173 A BR0318173 A BR 0318173A BR 0318173 A BR0318173 A BR 0318173A BR 0318173 A BR0318173 A BR 0318173A
- Authority
- BR
- Brazil
- Prior art keywords
- reactor
- fixed layer
- design incorporating
- reactor design
- filtration system
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000001914 filtration Methods 0.000 title abstract 2
- 239000011949 solid catalyst Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/01—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with flat filtering elements
- B01D29/018—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with flat filtering elements ring shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/50—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition
- B01D29/56—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition in series connection
- B01D29/58—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition in series connection arranged concentrically or coaxially
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00805—Details of the particulate material
- B01J2208/00814—Details of the particulate material the particulate material being provides in prefilled containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00831—Stationary elements
- B01J2208/00849—Stationary elements outside the bed, e.g. baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00858—Moving elements
- B01J2208/00876—Moving elements outside the bed, e.g. rotary mixer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
"PROJETO DE REATOR MULTIFASE QUE INCORPORA UM SISTEMA DE FILTRAçãO PARA CATALISADORES DE CAMADA FIXA". A presente invenção refere-se a uma configuração de reator especialmente adequada para transferência de massa de interface e mistura de fases múltiplas, isto é, gases, líquidos e sólidos onde a reação é catalisada por um catalisador sólido que compreende um reator de tubo de aspiração em que as partículas do catalisador sólido são mantidas em um espaço anular (25) entre o tubo de aspiração (21) do reator e uma parede que define um anel tubular por meio de elementos de filtro (26, 27) posicionado a jusante e, opcionalmente, também a montante a partir da camada de catalisador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/385,180 US7279145B2 (en) | 2003-03-10 | 2003-03-10 | Multiphase reactor design incorporating filtration system for fixed--bed catalyst |
PCT/US2003/041215 WO2004080584A1 (en) | 2003-03-10 | 2003-12-19 | Reactor with a filter for fixed-bed catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0318173A true BR0318173A (pt) | 2006-02-21 |
Family
ID=32961450
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0318173-1A BR0318173A (pt) | 2003-03-10 | 2003-12-19 | projeto de reator multifase que incorpora um sistema de filtração para catalisadores de camada fixa |
Country Status (11)
Country | Link |
---|---|
US (2) | US7279145B2 (pt) |
EP (1) | EP1601453B1 (pt) |
JP (1) | JP2006513850A (pt) |
KR (1) | KR20050106068A (pt) |
CN (1) | CN100377772C (pt) |
AT (1) | ATE445456T1 (pt) |
AU (1) | AU2003300361A1 (pt) |
BR (1) | BR0318173A (pt) |
CA (1) | CA2514456A1 (pt) |
DE (1) | DE60329716D1 (pt) |
WO (1) | WO2004080584A1 (pt) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100798024B1 (ko) * | 2006-03-30 | 2008-01-28 | 한국생산기술연구원 | 다층 필름으로부터 알루미늄을 분리하기 위한 반응기 |
EP1852418A1 (en) | 2006-04-27 | 2007-11-07 | Arkema France | Process for synthesizing selected organic peroxides |
EP1849804A1 (en) * | 2006-04-27 | 2007-10-31 | Arkema France | Process of free-radical polymerization or crosslinking in the presence of an organic peroxide by an ex situ process |
US7748891B2 (en) * | 2007-02-27 | 2010-07-06 | Chicago Bridge & Iron Company | Liquid storage tank with draft tube mixing system |
US7550610B1 (en) | 2008-03-28 | 2009-06-23 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
US7649102B2 (en) * | 2008-03-28 | 2010-01-19 | Lyondell Chemical Technology, L.P. | Propylene oxide process |
US7541479B1 (en) | 2008-05-27 | 2009-06-02 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
BRPI0805341B1 (pt) * | 2008-12-05 | 2017-02-07 | Petroleo Brasileiro S A - Petrobras | reator multifásico multifuncional |
US20100174099A1 (en) * | 2009-01-05 | 2010-07-08 | Lyondell Chemical Technology, L.P. | Propylene oxide reactor gas distribution system |
US8167981B2 (en) * | 2009-04-21 | 2012-05-01 | Spx Corporation | Vacuum filter assembly |
US8207360B2 (en) * | 2010-01-29 | 2012-06-26 | Lyondell Chemical Technology, L.P. | Propylene oxide process |
FR2959677B1 (fr) * | 2010-05-06 | 2012-05-18 | Inst Francais Du Petrole | Paniers amovibles contenant des particules de filtration pour reacteur a lit fixe. |
FR2966752B1 (fr) * | 2010-11-03 | 2013-11-01 | IFP Energies Nouvelles | Dispositif de test de solides mis en forme fonctionnant en phase heterogene |
US9222924B1 (en) * | 2013-07-30 | 2015-12-29 | E3Tec Service, Llc | Differential kinetic test unit |
CN112159369A (zh) * | 2015-11-26 | 2021-01-01 | 赢创运营有限公司 | 用于烯烃环氧化的反应器 |
DE102016204717A1 (de) * | 2016-03-22 | 2017-09-28 | Siemens Aktiengesellschaft | Reaktor zur Durchführung von gleichgewichtslimitierten Reaktionen |
DE102016204718A1 (de) | 2016-03-22 | 2017-09-28 | Siemens Aktiengesellschaft | Reaktor |
DE102016210224A1 (de) * | 2016-06-09 | 2017-12-14 | Friedrich-Alexander-Universität Erlangen-Nürnberg | Reaktor und Verfahren zur Umsetzung von gleichgewichtslimitierten Reaktionen |
WO2018039155A1 (en) * | 2016-08-24 | 2018-03-01 | The Regents Of The University Of California | Selective solid catalyst for tail end of olefin-epoxidation flow reactor |
US10308568B2 (en) * | 2017-05-01 | 2019-06-04 | Chevron Phillips Chemical Company Lp | Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity |
US10241014B2 (en) * | 2017-07-10 | 2019-03-26 | Cem Corporation | Instrument for analytical sample preparation |
CN112004789B (zh) | 2018-04-25 | 2023-06-09 | 利安德化学技术有限公司 | 用于纯化粗丙烷的方法和装置 |
CN108940130B (zh) * | 2018-07-23 | 2020-04-24 | 新奥科技发展有限公司 | 一种固定床催化反应器 |
US20200108366A1 (en) * | 2018-10-05 | 2020-04-09 | Uop Llc | Apparatus for retaining solid material in a radial flow reactor and method of converting hydrocarbons |
CN111375353B (zh) * | 2018-12-30 | 2021-06-04 | 中国石油化工股份有限公司 | 固定床上流式反应器及其应用 |
CN109833832B (zh) * | 2019-04-08 | 2024-01-26 | 江苏扬农化工集团有限公司 | 一种轴径向hppo固定床反应器 |
CN110681319B (zh) * | 2019-10-10 | 2020-10-16 | 潍坊弘润新材料有限公司 | 引射循环甲醇芳烃甲基化反应生产均四甲苯的系统及工艺 |
CN110841349B (zh) * | 2019-11-26 | 2024-06-18 | 中国成达工程有限公司 | 一种新型byd废催化剂处理系统 |
CN111676058B (zh) * | 2020-06-19 | 2022-01-07 | 中耐工程科技有限公司 | 一种物料流向交替变化的渣油加氢反应器、含有该反应器的渣油加氢系统及其渣油加氢工艺 |
CN112958013A (zh) * | 2021-02-20 | 2021-06-15 | 国家能源集团宁夏煤业有限责任公司 | 固定床反应管和中试装置 |
CN112973581A (zh) * | 2021-02-24 | 2021-06-18 | 中国石油化工股份有限公司 | 一种积垢过滤器、积垢过滤设备和大型固定床反应器 |
Family Cites Families (17)
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US1765386A (en) * | 1925-01-17 | 1930-06-24 | Nat Aniline & Chem Co Inc | Producing nonturbulent circulation of liquids |
US2413153A (en) * | 1943-03-26 | 1946-12-24 | Commercial Solvents Corp | Process for catalytic hydrogenation of aliphatic nitrohydroxy compounds |
US3488280A (en) * | 1967-05-29 | 1970-01-06 | Exxon Research Engineering Co | Catalytic hydrogenation of coal with water recycle |
US3998932A (en) * | 1972-05-15 | 1974-12-21 | Montedison Fibre S.P.A. | Process for the catalytic synthesis of ammonia |
USRE32562E (en) * | 1982-07-08 | 1987-12-15 | Union Carbide Corporation | Process and apparatus for mixing a gas and a liquid |
US4594228A (en) * | 1984-05-21 | 1986-06-10 | The Standard Oil Company | Mixing apparatus |
IT1213504B (it) * | 1986-10-22 | 1989-12-20 | Eniricerche Spa | Zeoliti legate e procedimenye per la loro prosuzione. |
DK155979C (da) * | 1987-05-20 | 1989-10-30 | Haldor Topsoe As | Fordelingselement til fordeling af gas til en reaktor |
US5132472A (en) * | 1990-10-17 | 1992-07-21 | Sun Refining And Marketing Company | Catalytic oxidation of alkanes |
DE4109502A1 (de) * | 1991-03-22 | 1992-09-24 | Degussa | Katalysator zur haertung von fettsaeuren und verfahren zu seiner herstellung |
DE4425672A1 (de) * | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
US5856533A (en) * | 1995-12-28 | 1999-01-05 | Praxair Technology, Inc. | High efficiency heat and mass transfer for vapor phase heterogeneous reactions |
EP0918762B1 (en) * | 1996-07-01 | 2001-05-16 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
DE19731627A1 (de) * | 1997-07-23 | 1999-01-28 | Degussa | Granulate, enthaltend Titansilikalit-l |
US5972661A (en) * | 1998-09-28 | 1999-10-26 | Penn State Research Foundation | Mixing systems |
TW518609B (en) * | 2000-03-15 | 2003-01-21 | Hitachi Ltd | Chemical decontamination liquid decomposition device provided with catalyst tower and catalyst tower therefor |
US6376686B1 (en) * | 2001-09-05 | 2002-04-23 | Arco Chemical Technology, L.P. | Direct epoxidation process |
-
2003
- 2003-03-10 US US10/385,180 patent/US7279145B2/en not_active Expired - Fee Related
- 2003-12-19 AU AU2003300361A patent/AU2003300361A1/en not_active Abandoned
- 2003-12-19 JP JP2004569429A patent/JP2006513850A/ja active Pending
- 2003-12-19 AT AT03816285T patent/ATE445456T1/de not_active IP Right Cessation
- 2003-12-19 WO PCT/US2003/041215 patent/WO2004080584A1/en active Application Filing
- 2003-12-19 CA CA002514456A patent/CA2514456A1/en not_active Abandoned
- 2003-12-19 BR BRPI0318173-1A patent/BR0318173A/pt not_active IP Right Cessation
- 2003-12-19 CN CNB2003801101391A patent/CN100377772C/zh not_active Expired - Fee Related
- 2003-12-19 DE DE60329716T patent/DE60329716D1/de not_active Expired - Fee Related
- 2003-12-19 EP EP03816285A patent/EP1601453B1/en not_active Revoked
- 2003-12-19 KR KR1020057016307A patent/KR20050106068A/ko not_active Application Discontinuation
-
2007
- 2007-08-03 US US11/890,183 patent/US7642365B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20080009657A1 (en) | 2008-01-10 |
CA2514456A1 (en) | 2004-09-23 |
CN100377772C (zh) | 2008-04-02 |
KR20050106068A (ko) | 2005-11-08 |
US7642365B2 (en) | 2010-01-05 |
US7279145B2 (en) | 2007-10-09 |
CN1758954A (zh) | 2006-04-12 |
AU2003300361A1 (en) | 2004-09-30 |
US20040179983A1 (en) | 2004-09-16 |
DE60329716D1 (de) | 2009-11-26 |
EP1601453A1 (en) | 2005-12-07 |
JP2006513850A (ja) | 2006-04-27 |
ATE445456T1 (de) | 2009-10-15 |
EP1601453B1 (en) | 2009-10-14 |
WO2004080584A1 (en) | 2004-09-23 |
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