BR0303674A - Adutos de dicloreto de magnésio e etanol e componentes catalìticos obtidos a partir deles - Google Patents

Adutos de dicloreto de magnésio e etanol e componentes catalìticos obtidos a partir deles

Info

Publication number
BR0303674A
BR0303674A BR0303674-0A BR0303674A BR0303674A BR 0303674 A BR0303674 A BR 0303674A BR 0303674 A BR0303674 A BR 0303674A BR 0303674 A BR0303674 A BR 0303674A
Authority
BR
Brazil
Prior art keywords
components obtained
adducts
obtained therefrom
catalytic components
magnesium dichloride
Prior art date
Application number
BR0303674-0A
Other languages
English (en)
Other versions
BR0303674B1 (pt
Inventor
Daniele Evangelisti
Gianni Collina
Original Assignee
Basell Poliolefine Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Spa filed Critical Basell Poliolefine Spa
Publication of BR0303674A publication Critical patent/BR0303674A/pt
Publication of BR0303674B1 publication Critical patent/BR0303674B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"ADUTOS DE DICLORETO DE MAGNéSIO E ETANOL E COMPONENTES CATALìTICOS OBTIDOS A PARTIR DELES". Refere-se o presente invento a um aduto de MgCl~ 2~ mEtOH em que m é de 2,5 a 3,2, opcionalmente contendo água até um máximo de 1 % em peso com base no peso total do aduto, caracterizado pelo fato de ter um diagrama DSC em que o pico mais alto de temperatura de fusão (Tm) é maior que 109<198>C e tem uma entalpia de fusão (AH) associada de 103 J/g ou menos. Os componentes catalíticos obtidos a partir dos adutos do presente invento são capazes de produzir catalisadores para a polimerização de olefinas caracterizados por uma atividade aperfeiçoada com relação aos catalisadores preparados a partir dos adutos do estado da técnica.
BRPI0303674-0A 2002-03-29 2003-03-17 aduto de dicloreto de magnésio e etanol, processo para a preparação de um componente catalìtico para a polimerização de olefinas e processo para a polimerização de olefinas. BR0303674B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02076256 2002-03-29
PCT/EP2003/002819 WO2003082930A2 (en) 2002-03-29 2003-03-17 Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom

Publications (2)

Publication Number Publication Date
BR0303674A true BR0303674A (pt) 2004-07-13
BR0303674B1 BR0303674B1 (pt) 2012-09-04

Family

ID=28459533

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0303674-0A BR0303674B1 (pt) 2002-03-29 2003-03-17 aduto de dicloreto de magnésio e etanol, processo para a preparação de um componente catalìtico para a polimerização de olefinas e processo para a polimerização de olefinas.

Country Status (11)

Country Link
US (1) US7060763B2 (pt)
EP (1) EP1490416B1 (pt)
JP (1) JP2005521730A (pt)
KR (1) KR100973457B1 (pt)
CN (1) CN100415782C (pt)
AT (1) ATE420121T1 (pt)
AU (1) AU2003232188A1 (pt)
BR (1) BR0303674B1 (pt)
DE (1) DE60325706D1 (pt)
ES (1) ES2318150T3 (pt)
WO (1) WO2003082930A2 (pt)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2003238067A1 (en) * 2002-07-23 2004-02-09 Basell Poliolefine Italia S.P.A. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
EP1539839B1 (en) * 2002-09-17 2017-08-16 Basell Poliolefine Italia S.r.l. Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom
BRPI0416436B1 (pt) * 2003-12-23 2016-06-07 Basell Poliolefine Srl componente catalítico, catalisador e processo para a polimerização de olefinas
CN100519597C (zh) * 2003-12-23 2009-07-29 巴塞尔聚烯烃意大利有限责任公司 二氯化镁-乙醇加合物和由此得到的催化剂组分
JP5580301B2 (ja) * 2008-06-11 2014-08-27 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 高活性のチーグラー・ナッタ触媒、触媒を生成するための方法およびその使用
SA3686B1 (ar) * 2009-10-16 2014-10-22 China Petroleum& Chemical Corp مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه
WO2012041944A1 (en) * 2010-09-30 2012-04-05 Basell Poliolefine Italia S.R.L. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
JP6062372B2 (ja) * 2010-12-24 2017-01-18 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 二塩化マグネシウム・エタノール付加物とそれから得られる触媒成分
JP2014522804A (ja) * 2011-08-08 2014-09-08 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 二塩化マグネシウムエタノール付加物とそれから得られる触媒成分
EP2692743A1 (en) 2012-08-03 2014-02-05 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
CN104558282B (zh) 2013-10-18 2017-02-15 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用
JP6397908B2 (ja) 2013-10-18 2018-09-26 中国石油化工股▲ふん▼有限公司 オレフィン重合触媒用球状担体、触媒成分、触媒、及びそれらの調製方法
MX2016008105A (es) * 2013-12-18 2016-10-03 Braskem Sa Soporte de catalizador y procesos relacionados.
US10407518B2 (en) * 2013-12-18 2019-09-10 Braskem S.A. Catalyst support and related processes
EP3676300A4 (en) * 2017-08-29 2021-05-26 W. R. Grace & Co. - Conn. OLEFIN POLYMERIZATION CATALYST

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US612730A (en) * 1898-10-18 Knob attachment
NL7711974A (nl) 1977-11-01 1979-05-03 Stamicarbon Werkwijze voor het polymeriseren van alkenen-1.
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS59210906A (ja) 1983-05-17 1984-11-29 Mitsui Toatsu Chem Inc α−オレフインの重合方法
IT1230133B (it) * 1989-04-28 1991-10-14 Himont Inc Composizioni polipropileniche plasto-elastiche
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
AU736901B2 (en) * 1997-03-29 2001-08-02 Montell Technology Company B.V. "Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom"

Also Published As

Publication number Publication date
DE60325706D1 (de) 2009-02-26
EP1490416B1 (en) 2009-01-07
BR0303674B1 (pt) 2012-09-04
EP1490416A2 (en) 2004-12-29
JP2005521730A (ja) 2005-07-21
AU2003232188A1 (en) 2003-10-13
ES2318150T3 (es) 2009-05-01
CN1551893A (zh) 2004-12-01
AU2003232188A8 (en) 2003-10-13
US20050014632A1 (en) 2005-01-20
CN100415782C (zh) 2008-09-03
WO2003082930A3 (en) 2004-07-29
KR20040095605A (ko) 2004-11-15
WO2003082930A2 (en) 2003-10-09
US7060763B2 (en) 2006-06-13
ATE420121T1 (de) 2009-01-15
KR100973457B1 (ko) 2010-08-02

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Legal Events

Date Code Title Description
B25D Requested change of name of applicant approved

Owner name: BASELL POLIOLEFINE ITALIA S.R.L. (IT)

Free format text: ALTERADO DE: BASELL POLIOLEFINE ITALIA S.P.A.

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/03/2003, OBSERVADAS AS CONDICOES LEGAIS.