BR0303674A - Adutos de dicloreto de magnésio e etanol e componentes catalìticos obtidos a partir deles - Google Patents
Adutos de dicloreto de magnésio e etanol e componentes catalìticos obtidos a partir delesInfo
- Publication number
- BR0303674A BR0303674A BR0303674-0A BR0303674A BR0303674A BR 0303674 A BR0303674 A BR 0303674A BR 0303674 A BR0303674 A BR 0303674A BR 0303674 A BR0303674 A BR 0303674A
- Authority
- BR
- Brazil
- Prior art keywords
- components obtained
- adducts
- obtained therefrom
- catalytic components
- magnesium dichloride
- Prior art date
Links
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 title 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 235000011147 magnesium chloride Nutrition 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"ADUTOS DE DICLORETO DE MAGNéSIO E ETANOL E COMPONENTES CATALìTICOS OBTIDOS A PARTIR DELES". Refere-se o presente invento a um aduto de MgCl~ 2~ mEtOH em que m é de 2,5 a 3,2, opcionalmente contendo água até um máximo de 1 % em peso com base no peso total do aduto, caracterizado pelo fato de ter um diagrama DSC em que o pico mais alto de temperatura de fusão (Tm) é maior que 109<198>C e tem uma entalpia de fusão (AH) associada de 103 J/g ou menos. Os componentes catalíticos obtidos a partir dos adutos do presente invento são capazes de produzir catalisadores para a polimerização de olefinas caracterizados por uma atividade aperfeiçoada com relação aos catalisadores preparados a partir dos adutos do estado da técnica.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02076256 | 2002-03-29 | ||
PCT/EP2003/002819 WO2003082930A2 (en) | 2002-03-29 | 2003-03-17 | Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0303674A true BR0303674A (pt) | 2004-07-13 |
BR0303674B1 BR0303674B1 (pt) | 2012-09-04 |
Family
ID=28459533
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0303674-0A BR0303674B1 (pt) | 2002-03-29 | 2003-03-17 | aduto de dicloreto de magnésio e etanol, processo para a preparação de um componente catalìtico para a polimerização de olefinas e processo para a polimerização de olefinas. |
Country Status (11)
Country | Link |
---|---|
US (1) | US7060763B2 (pt) |
EP (1) | EP1490416B1 (pt) |
JP (1) | JP2005521730A (pt) |
KR (1) | KR100973457B1 (pt) |
CN (1) | CN100415782C (pt) |
AT (1) | ATE420121T1 (pt) |
AU (1) | AU2003232188A1 (pt) |
BR (1) | BR0303674B1 (pt) |
DE (1) | DE60325706D1 (pt) |
ES (1) | ES2318150T3 (pt) |
WO (1) | WO2003082930A2 (pt) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2003238067A1 (en) * | 2002-07-23 | 2004-02-09 | Basell Poliolefine Italia S.P.A. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
EP1539839B1 (en) * | 2002-09-17 | 2017-08-16 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom |
BRPI0416436B1 (pt) * | 2003-12-23 | 2016-06-07 | Basell Poliolefine Srl | componente catalítico, catalisador e processo para a polimerização de olefinas |
CN100519597C (zh) * | 2003-12-23 | 2009-07-29 | 巴塞尔聚烯烃意大利有限责任公司 | 二氯化镁-乙醇加合物和由此得到的催化剂组分 |
JP5580301B2 (ja) * | 2008-06-11 | 2014-08-27 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | 高活性のチーグラー・ナッタ触媒、触媒を生成するための方法およびその使用 |
SA3686B1 (ar) * | 2009-10-16 | 2014-10-22 | China Petroleum& Chemical Corp | مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه |
WO2012041944A1 (en) * | 2010-09-30 | 2012-04-05 | Basell Poliolefine Italia S.R.L. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
JP6062372B2 (ja) * | 2010-12-24 | 2017-01-18 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 二塩化マグネシウム・エタノール付加物とそれから得られる触媒成分 |
JP2014522804A (ja) * | 2011-08-08 | 2014-09-08 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 二塩化マグネシウムエタノール付加物とそれから得られる触媒成分 |
EP2692743A1 (en) | 2012-08-03 | 2014-02-05 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
CN104558282B (zh) | 2013-10-18 | 2017-02-15 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用 |
JP6397908B2 (ja) | 2013-10-18 | 2018-09-26 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合触媒用球状担体、触媒成分、触媒、及びそれらの調製方法 |
MX2016008105A (es) * | 2013-12-18 | 2016-10-03 | Braskem Sa | Soporte de catalizador y procesos relacionados. |
US10407518B2 (en) * | 2013-12-18 | 2019-09-10 | Braskem S.A. | Catalyst support and related processes |
EP3676300A4 (en) * | 2017-08-29 | 2021-05-26 | W. R. Grace & Co. - Conn. | OLEFIN POLYMERIZATION CATALYST |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US612730A (en) * | 1898-10-18 | Knob attachment | ||
NL7711974A (nl) | 1977-11-01 | 1979-05-03 | Stamicarbon | Werkwijze voor het polymeriseren van alkenen-1. |
IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
JPS59210906A (ja) | 1983-05-17 | 1984-11-29 | Mitsui Toatsu Chem Inc | α−オレフインの重合方法 |
IT1230133B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Composizioni polipropileniche plasto-elastiche |
IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
AU736901B2 (en) * | 1997-03-29 | 2001-08-02 | Montell Technology Company B.V. | "Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom" |
-
2003
- 2003-03-17 CN CNB038005522A patent/CN100415782C/zh not_active Expired - Lifetime
- 2003-03-17 US US10/486,877 patent/US7060763B2/en not_active Expired - Lifetime
- 2003-03-17 ES ES03745265T patent/ES2318150T3/es not_active Expired - Lifetime
- 2003-03-17 WO PCT/EP2003/002819 patent/WO2003082930A2/en active Application Filing
- 2003-03-17 AT AT03745265T patent/ATE420121T1/de active
- 2003-03-17 EP EP03745265A patent/EP1490416B1/en not_active Expired - Lifetime
- 2003-03-17 DE DE60325706T patent/DE60325706D1/de not_active Expired - Lifetime
- 2003-03-17 KR KR1020037014862A patent/KR100973457B1/ko not_active IP Right Cessation
- 2003-03-17 BR BRPI0303674-0A patent/BR0303674B1/pt active IP Right Grant
- 2003-03-17 AU AU2003232188A patent/AU2003232188A1/en not_active Abandoned
- 2003-03-17 JP JP2003580391A patent/JP2005521730A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
DE60325706D1 (de) | 2009-02-26 |
EP1490416B1 (en) | 2009-01-07 |
BR0303674B1 (pt) | 2012-09-04 |
EP1490416A2 (en) | 2004-12-29 |
JP2005521730A (ja) | 2005-07-21 |
AU2003232188A1 (en) | 2003-10-13 |
ES2318150T3 (es) | 2009-05-01 |
CN1551893A (zh) | 2004-12-01 |
AU2003232188A8 (en) | 2003-10-13 |
US20050014632A1 (en) | 2005-01-20 |
CN100415782C (zh) | 2008-09-03 |
WO2003082930A3 (en) | 2004-07-29 |
KR20040095605A (ko) | 2004-11-15 |
WO2003082930A2 (en) | 2003-10-09 |
US7060763B2 (en) | 2006-06-13 |
ATE420121T1 (de) | 2009-01-15 |
KR100973457B1 (ko) | 2010-08-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B25D | Requested change of name of applicant approved |
Owner name: BASELL POLIOLEFINE ITALIA S.R.L. (IT) Free format text: ALTERADO DE: BASELL POLIOLEFINE ITALIA S.P.A. |
|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/03/2003, OBSERVADAS AS CONDICOES LEGAIS. |