BR0214693A - Processo para realizar a reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta - Google Patents

Processo para realizar a reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta

Info

Publication number
BR0214693A
BR0214693A BR0214693-2A BR0214693A BR0214693A BR 0214693 A BR0214693 A BR 0214693A BR 0214693 A BR0214693 A BR 0214693A BR 0214693 A BR0214693 A BR 0214693A
Authority
BR
Brazil
Prior art keywords
carbon monoxide
hydrogen
steam
methane
reforming
Prior art date
Application number
BR0214693-2A
Other languages
English (en)
Inventor
Michael Joseph Bowe
Clive Derek Lee-Tuffnell
Jason Andrew Maude
Ian Frederick Zimmerman
Original Assignee
Gtl Microsystems Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gtl Microsystems Ag filed Critical Gtl Microsystems Ag
Publication of BR0214693A publication Critical patent/BR0214693A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2495—Net-type reactors
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00117—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00132—Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135—Electric resistance heaters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2453—Plates arranged in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2459—Corrugated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2465—Two reactions in indirect heat exchange with each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2466—The same reactant stream undergoing different reactions, endothermic or exothermic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2479—Catalysts coated on the surface of plates or inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2482—Catalytically active foils; Plates having catalytically activity on their own
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2483—Construction materials of the plates
    • B01J2219/2485—Metals or alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2492—Assembling means
    • B01J2219/2493—Means for assembling plates together, e.g. sealing means, screws, bolts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2497—Size aspects, i.e. concrete sizes are being mentioned in the classified document
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2498—Additional structures inserted in the channels, e.g. plates, catalyst holding meshes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/3221—Corrugated sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32408—Metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B01J2219/32475—Composition or microstructure of the elements comprising catalytically active material involving heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"PROCESSO PARA REALIZAR A REFORMA DE VAPOR/METANO PARA GERAR MONóXIDO DE CARBONO E HIDROGêNIO, E, PLANTA". Metano é reagido com vapor para gerar monóxido de carbono e hidrogênio em um primeiro reator catalítico, a mistura de gás resultante podendo ser então usada para realizar a síntese de Fisher-Tropsch em um segundo reator catalítico. Ao realizar a reforma de vapor/metano, a mistura de gás é passada através de um canal de fluxo estreito contendo uma estrutura de catalisador em um substrato de metal; e adjacente a uma fonte de calor, em um tempo menor do que 0,5 s, de modo que somente irão ocorrer estas reações que tem uma cinética comparativamente rápida. Tanto a temperatura média como a temperatura de saída do canal estão na faixa de 750<198> a 900<198>C. A relação de vapor para metano deve ser preferivelmente de 1,4 a 1,6, por exemplo cerca de 1,5. Quase todo o metano irá sofrer a reação de reforma, formando quase que completamente monóxido de carbono. Após reformar a síntese de Fischer-Tropsch, o hidrogênio restante é preferivelmente usado para fornecer calor para a reação de reforma.
BR0214693-2A 2001-12-05 2002-12-02 Processo para realizar a reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta BR0214693A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0129054.3A GB0129054D0 (en) 2001-12-05 2001-12-05 Catalytic reactor and process
PCT/GB2002/005443 WO2003048035A1 (en) 2001-12-05 2002-12-02 Process and apparatus for steam-methane reforming

Publications (1)

Publication Number Publication Date
BR0214693A true BR0214693A (pt) 2004-11-03

Family

ID=9927001

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0214693-2A BR0214693A (pt) 2001-12-05 2002-12-02 Processo para realizar a reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta

Country Status (9)

Country Link
US (1) US7087651B2 (pt)
EP (1) EP1451098A1 (pt)
AU (1) AU2002365663B2 (pt)
BR (1) BR0214693A (pt)
GB (1) GB0129054D0 (pt)
MY (1) MY131482A (pt)
NO (1) NO20042280L (pt)
TW (1) TW592832B (pt)
WO (1) WO2003048035A1 (pt)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003048034A1 (en) * 2001-12-05 2003-06-12 Gtl Microsystems Ag Process an apparatus for steam-methane reforming
US8603430B2 (en) * 2002-02-05 2013-12-10 The Regents Of The University Of California Controlling the synthesis gas composition of a steam methane reformer
US8349288B2 (en) * 2006-12-06 2013-01-08 The Regents Of The University Of California Process for enhancing the operability of hot gas cleanup for the production of synthesis gas from steam-hydrogasification producer gas
KR101053040B1 (ko) † 2002-12-02 2011-08-01 컴팩트지티엘 피엘씨 촉매 반응기 및 프로세스
GB0314790D0 (en) * 2003-06-25 2003-07-30 Accentus Plc Catalytic reactor and process
US7326394B2 (en) * 2003-03-07 2008-02-05 Velocys Catalysts, methods of making catalysts, and methods of combustion
WO2005113426A1 (en) * 2004-05-20 2005-12-01 The Petroleum Oil And Gas Corporation Of South Africa (Pty) Ltd Recovery of water originating from low temperature fischer-tropsch synthesis processes
WO2005113425A1 (en) * 2004-05-20 2005-12-01 The Petroleum Oil And Gas Corporation Of South Africa (Pty) Ltd. Recovery of waste water originating from synthesis processes
GB0413400D0 (en) * 2004-06-16 2004-07-21 Accentus Plc Catalytic plant and process
GB0501731D0 (en) * 2005-01-31 2005-03-02 Accentus Plc Catalytic reactor
GB0504622D0 (en) * 2005-03-05 2005-04-13 Accentus Plc Catalytic reactors
GB0513484D0 (en) * 2005-07-01 2005-08-10 Accentus Plc Producing liquid hydrocarbons
GB0608927D0 (en) * 2006-05-08 2006-06-14 Accentus Plc Catalytic Reactor
EA200970443A1 (ru) * 2006-11-02 2009-12-30 Рко2 Ас Способ получения диоксида углерода и метана по каталитической газовой реакции
JP5383508B2 (ja) * 2007-01-19 2014-01-08 ヴェロシス，インク． マイクロチャネルプロセス技術を用いて天然ガスを分子量の高くなった炭化水素に変換するためのプロセスおよび装置
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
US8100996B2 (en) * 2008-04-09 2012-01-24 Velocys, Inc. Process for upgrading a carbonaceous material using microchannel process technology
EP2282828A2 (en) 2008-04-09 2011-02-16 Velocys, Inc. Process for converting a carbonaceous material to methane, methanol and/or dimethyl ether using microchannel process technology
US20090277441A1 (en) * 2008-05-10 2009-11-12 Reed Jensen Low entropy heat exchanger especially for use with solar gas processors
CA2739325C (en) 2008-10-10 2018-11-27 Velocys Inc. Process and apparatus employing microchannel process technology
GB0822544D0 (en) * 2008-12-11 2009-01-14 Compactgtl Plc Chemical reactor operation
WO2011021944A1 (en) 2009-08-19 2011-02-24 Eicproc As Combined processes for utilizing synthesis gas at low co2 emission and high energy output
US20110083997A1 (en) * 2009-10-09 2011-04-14 Silva Laura J Process for treating heavy oil
US8535448B2 (en) * 2011-07-11 2013-09-17 Chevron Phillips Chemical Company Lp Methods of removing a protective layer
US9199888B2 (en) 2012-01-24 2015-12-01 Sge Scandgreen Energy Ab Combined processes for utilizing synthesis gas with low CO2 emission and high energy output
US9676623B2 (en) 2013-03-14 2017-06-13 Velocys, Inc. Process and apparatus for conducting simultaneous endothermic and exothermic reactions
DE102013226126A1 (de) 2013-12-16 2015-06-18 Technische Universität Bergakademie Freiberg Allotherme Methan-Reformierung mit physikalischer Energierückgewinnung
CA2950288C (en) 2014-05-30 2019-05-14 Sgc Energia Co Llc Methods, systems, and apparatuses for recycling fischer-tropsch water and fischer-tropsch tail gas
US11452981B2 (en) 2017-11-16 2022-09-27 Societe de Commercialisation des Produits de la Recherche Appliquée Socpra Sciences et Génie S.E.C. Integrated solar micro-reactors for hydrogen synthesis via steam methane reforming
UA127416C2 (uk) 2017-12-08 2023-08-16 Хальдор Топсьое А/С Спосіб і система для виробництва синтез-газу
WO2019110265A1 (en) 2017-12-08 2019-06-13 Haldor Topsøe A/S A process and system for reforming a hydrocarbon gas
FI3720812T3 (fi) 2017-12-08 2023-08-11 Topsoe As Laitos ja prosessi synteesikaasun tuottamiseksi
CN114249299B (zh) * 2021-11-09 2023-06-23 浙江思欣通氢能科技有限公司 一种富甲烷气等离子多重整反应催化剂预处理方法
CN116002617A (zh) * 2023-01-15 2023-04-25 中国石油大学(华东) 一种适用于气井井下工况的甲烷原地重整制氢方法和系统

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1662870A (en) * 1924-10-09 1928-03-20 Stancliffe Engineering Corp Grooved-plate heat interchanger
US4214867A (en) * 1978-07-18 1980-07-29 Matthey Bishop, Inc. Method and apparatus for catalytic heat exchange
EP0212878A1 (en) 1985-08-08 1987-03-04 Heatric Pty. Limited Plate-type cross-flow heat exchanger
EP0292245A1 (en) 1987-05-21 1988-11-23 Heatric Pty. Limited Flat-plate heat exchanger
US4945116A (en) 1988-12-29 1990-07-31 Uop Fischer-Tropsch synthesis process employing a moderated ruthenium catalyst
DE3926466C2 (de) 1989-08-10 1996-12-19 Christoph Dipl Ing Caesar Mikroreaktor zur Durchführung chemischer Reaktionen von zwei chemischen Stoffen mit starker Wärmetönung
NL8902250A (nl) 1989-09-08 1991-04-02 Veg Gasinstituut Nv Werkwijze voor het uitvoeren van een chemische reactie en daarbij te gebruiken reactor.
JPH085644B2 (ja) 1989-11-27 1996-01-24 石川島播磨重工業株式会社 プレート型改質器
US5534328A (en) * 1993-12-02 1996-07-09 E. I. Du Pont De Nemours And Company Integrated chemical processing apparatus and processes for the preparation thereof
JPH0812303A (ja) * 1994-07-05 1996-01-16 Ishikawajima Harima Heavy Ind Co Ltd プレートリフォーマ
US5811062A (en) * 1994-07-29 1998-09-22 Battelle Memorial Institute Microcomponent chemical process sheet architecture
FR2736650B1 (fr) * 1995-07-13 1997-09-05 Inst Francais Du Petrole Procede de conversion du gaz de synthese en phase liquide
DE19654361A1 (de) * 1996-12-24 1998-06-25 Behr Gmbh & Co Reaktor in Stapelbauweise
GB2322633A (en) 1997-02-28 1998-09-02 Norske Stats Oljeselskap Fischer-Tropsch reactor
US6200536B1 (en) * 1997-06-26 2001-03-13 Battelle Memorial Institute Active microchannel heat exchanger
US6440895B1 (en) * 1998-07-27 2002-08-27 Battelle Memorial Institute Catalyst, method of making, and reactions using the catalyst
US6180846B1 (en) * 1998-09-08 2001-01-30 Uop Llc Process and apparatus using plate arrangement for combustive reactant heating
GB9918586D0 (en) 1999-08-07 1999-10-06 British Gas Plc Compact reactor
US6451864B1 (en) * 1999-08-17 2002-09-17 Battelle Memorial Institute Catalyst structure and method of Fischer-Tropsch synthesis
US7335346B2 (en) 1999-08-17 2008-02-26 Battelle Memorial Institute Catalyst and method of steam reforming
AU778040B2 (en) 1999-08-17 2004-11-11 Battelle Memorial Institute Catalyst structure and method of fischer-tropsch synthesis
WO2001012753A1 (en) 1999-08-17 2001-02-22 Battelle Memorial Institute Catalyst structure and method of fischer-tropsch synthesis
US6969506B2 (en) 1999-08-17 2005-11-29 Battelle Memorial Institute Methods of conducting simultaneous exothermic and endothermic reactions
EP1206316B1 (en) 1999-08-17 2005-06-29 Battelle Memorial Institute Chemical reactor and method for catalytic gas phase reactions
US6488838B1 (en) * 1999-08-17 2002-12-03 Battelle Memorial Institute Chemical reactor and method for gas phase reactant catalytic reactions
US6284217B1 (en) * 1999-08-17 2001-09-04 Battelle Memorial Institute Method and catalyst structure for steam reforming of a hydrocarbon
BR0107557B1 (pt) * 2000-01-11 2011-08-09 reator catalìtico, método para realizar reações quìmicas entre gases e processamento de metano.
US6495610B1 (en) * 2000-06-19 2002-12-17 Imperial Chemical Industries Plc Methanol and hydrocarbons

Also Published As

Publication number Publication date
WO2003048035A1 (en) 2003-06-12
AU2002365663A1 (en) 2003-06-17
AU2002365663B2 (en) 2007-03-22
MY131482A (en) 2007-08-30
US20050054737A1 (en) 2005-03-10
NO20042280L (no) 2004-09-03
EP1451098A1 (en) 2004-09-01
GB0129054D0 (en) 2002-01-23
TW200301160A (en) 2003-07-01
US7087651B2 (en) 2006-08-08
TW592832B (en) 2004-06-21

Similar Documents

Publication Publication Date Title
BR0214693A (pt) Processo para realizar a reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta
BR0206966A (pt) Processo para realizar reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta para processar metano
Choudhary et al. Production of COx-free hydrogen for fuel cells via step-wise hydrocarbon reforming and catalytic dehydrogenation of ammonia
CA1084435A (en) Parallel steam reformers to provide low energy process
Ersoz et al. Autothermal reforming as a hydrocarbon fuel processing option for PEM fuel cell
Palm et al. Small-scale testing of a precious metal catalyst in the autothermal reforming of various hydrocarbon feeds
Wang et al. Thermodynamic analysis of hydrogen production via partial oxidation of ethanol
Authayanun et al. Hydrogen production from glycerol steam reforming for low-and high-temperature PEMFCs
ZA996123B (en) Process for the autothermal reforming of a hydrocarbon feedstock containing higher hydrocarbons.
AU2005306866B2 (en) Steam methane reforming method
RU2003128600A (ru) Способ получения синтез-газа
Xu et al. Temperature-staged methanation: an alternative method to purify hydrogen-rich fuel gas for PEFC
CA2641183A1 (en) Oxygen removal
Zhang et al. Process development of hydrogenous gas production for PEFC from biogas
DK0738235T3 (da) Fremgangsmåde til fremstilling af hydrogen/carbonmonoxidblandinger eller af hydrogen ud fra methan
Polman et al. Novel compact steam reformer for fuel cells with heat generation by catalytic combustion augmented by induction heating
Cao et al. Methanol-steam reforming over a ZnO–Cr2O3/CeO2–ZrO2/Al2O3 catalyst
AU2004218207B2 (en) Method for producing long-chain hydrocarbons from natural gas
Chen et al. Simulation for steam reforming of natural gas with oxygen input in a novel membrane reformer
MY138154A (en) Process to prepare a hydrogen and carbon monoxide containing gas
MX168297B (es) Procedimiento para la preparacion de un gas reductor
Su et al. System integration of multi-grade exploitation of biogas chemical energy driven by solar energy
JP2002319416A (ja) 複合熱及び電力プラント、並びにその操作方法
MXPA05010538A (es) Proceso para la preparacion de una corriente rica en hidrogeno.
Pashchenko et al. Thermodynamic analysis of carbon formation conditions in a steam methane reforming process

Legal Events

Date Code Title Description
B25A Requested transfer of rights approved

Owner name: COMPACTGTL PLC (GB)

Free format text: TRANSFERIDO DE: GTL MICROSYSTEMS AG

B25G Requested change of headquarter approved

Owner name: COMPACTGTL PLC (GB)

Free format text: SEDE ALTERADA CONFORME SOLICITADO NA PETICAO NO 020070184947/RJ DE 28/12/2007.

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PEDIDO DE ACORDO COM ART .8O COMBINADO COM ART. 13 DA LPI.

B12B Appeal against refusal [chapter 12.2 patent gazette]
B25D Requested change of name of applicant approved

Owner name: COMPACTGTL LIMITED (GB)

B25G Requested change of headquarter approved

Owner name: COMPACTGTL LIMITED (GB)

B11D Dismissal acc. art. 38, par 2 of ipl - failure to pay fee after grant in time