BR0201368A - Processo para preparar um catalisador melhorado, catalisador, e, processos para produzir uma nitrila insaturada e para ppoduzir um ácido carboxìlico insaturado - Google Patents
Processo para preparar um catalisador melhorado, catalisador, e, processos para produzir uma nitrila insaturada e para ppoduzir um ácido carboxìlico insaturadoInfo
- Publication number
- BR0201368A BR0201368A BR0201368-1A BR0201368A BR0201368A BR 0201368 A BR0201368 A BR 0201368A BR 0201368 A BR0201368 A BR 0201368A BR 0201368 A BR0201368 A BR 0201368A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- producing
- preparing
- processes
- unsaturated carboxylic
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 150000002825 nitriles Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 239000002198 insoluble material Substances 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28621701P | 2001-04-25 | 2001-04-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0201368A true BR0201368A (pt) | 2003-06-10 |
Family
ID=23097603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0201368-1A BR0201368A (pt) | 2001-04-25 | 2002-04-22 | Processo para preparar um catalisador melhorado, catalisador, e, processos para produzir uma nitrila insaturada e para ppoduzir um ácido carboxìlico insaturado |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6841699B2 (enExample) |
| EP (1) | EP1254709A3 (enExample) |
| JP (1) | JP2003024789A (enExample) |
| KR (1) | KR100905955B1 (enExample) |
| CN (1) | CN1382522A (enExample) |
| BR (1) | BR0201368A (enExample) |
| MX (1) | MXPA02003868A (enExample) |
| TW (1) | TW574186B (enExample) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6740620B2 (en) * | 2001-04-25 | 2004-05-25 | Rohn And Haas Company | Single crystalline phase catalyst |
| US7038082B2 (en) | 2002-10-17 | 2006-05-02 | Basf Aktiengesellschaft | Preparation of a multimetal oxide material |
| JP4155034B2 (ja) * | 2003-01-21 | 2008-09-24 | 東亞合成株式会社 | 金属酸化物触媒の製造方法 |
| JPWO2004078344A1 (ja) * | 2003-03-05 | 2006-06-08 | 旭化成ケミカルズ株式会社 | 粒状多孔性アンモ酸化触媒 |
| DE10316465A1 (de) | 2003-04-09 | 2004-10-28 | Basf Ag | Verfahren der heterogen katalysierten partiellen direkten Oxidation von Propan und/oder iso-Butan |
| WO2004099081A1 (de) | 2003-05-12 | 2004-11-18 | Basf Aktiengesellschaft | In reiner i-phase vorliegende, mo, v und alkalimetall enthaltende multimetalloxidmassen |
| DE10321398A1 (de) * | 2003-05-12 | 2004-05-27 | Basf Ag | Mo und V enthaltende Multimetalloxidmassen |
| US7589046B2 (en) | 2003-06-04 | 2009-09-15 | Basf Aktiengesellschaft | Thermal treatment of the precursor material of a catalytically active material |
| EP1491253A1 (en) * | 2003-06-26 | 2004-12-29 | Urea Casale S.A. | Fluid bed granulation process and apparatus |
| US7253310B2 (en) | 2003-08-19 | 2007-08-07 | Basf Aktiengesellschaft | Preparation of (meth)acrylic acid |
| US7012157B2 (en) | 2003-09-23 | 2006-03-14 | Basf Aktiengesellschaft | Preparation of (meth)acrylic acid |
| US7019169B2 (en) | 2003-09-23 | 2006-03-28 | Basf Aktiengesellschaft | Preparation of (meth)acrylic acid |
| US20050107252A1 (en) * | 2003-11-17 | 2005-05-19 | Gaffney Anne M. | Process for preparing mixed metal oxide catalyst |
| BRPI0500609A (pt) * | 2004-03-10 | 2007-07-10 | Rohm & Haas | processos para preparar um ou mais catalisadores modificados, e, para a criotrituração de um ou mais catalisadores de óxido metálico |
| EP1598110A1 (en) * | 2004-04-22 | 2005-11-23 | Rohm and Haas Company | Structured oxidation catalysts |
| WO2006008177A1 (en) * | 2004-07-22 | 2006-01-26 | Fritz Haber Institut Der Max Planck Gesellschaft | Metal oxide catalyst and method for the preparation thereof |
| US7556793B2 (en) * | 2005-06-06 | 2009-07-07 | Saint-Gobain Ceramics & Plastics, Inc. | Rutile titania catalyst carrier |
| JP4902990B2 (ja) * | 2005-12-21 | 2012-03-21 | 三菱レイヨン株式会社 | メタクリル酸合成用触媒およびその製造方法、メタクリル酸の製造方法 |
| DE102007004961A1 (de) | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist |
| JP4858266B2 (ja) * | 2007-03-28 | 2012-01-18 | 三菱化学株式会社 | 複合酸化物触媒の製造法 |
| DE102007025869A1 (de) | 2007-06-01 | 2008-07-03 | Basf Se | Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett |
| DE102007029053A1 (de) | 2007-06-21 | 2008-01-03 | Basf Ag | Verfahren der heterogen katalysierten partiellen Direktoxidation von n-Propan zu Acrylsäure |
| KR100954045B1 (ko) * | 2007-08-13 | 2010-04-20 | 주식회사 엘지화학 | 개선된 아크릴산 제조용 촉매의 합성방법 |
| KR100954046B1 (ko) * | 2007-08-22 | 2010-04-20 | 주식회사 엘지화학 | 반응성 볼밀링을 이용한 아크릴산 제조용 촉매의 제조방법 |
| DE102008040093A1 (de) | 2008-07-02 | 2008-12-18 | Basf Se | Verfahren zur Herstellung eines ringähnlichen oxidischen Formkörpers |
| DE102008040094A1 (de) | 2008-07-02 | 2009-01-29 | Basf Se | Verfahren zur Herstellung eines oxidischen geometrischen Formkörpers |
| US8105971B2 (en) * | 2009-04-02 | 2012-01-31 | Lummus Technology Inc. | Process for making catalysts useful for the conversion of paraffins to olefins |
| US8519210B2 (en) * | 2009-04-02 | 2013-08-27 | Lummus Technology Inc. | Process for producing ethylene via oxidative dehydrogenation (ODH) of ethane |
| CN104684642B (zh) * | 2012-09-28 | 2017-10-31 | 罗门哈斯公司 | 丙烷氧化催化剂的制备 |
| SG11201502415UA (en) * | 2012-09-28 | 2015-04-29 | Rohm & Haas | Preparation of propane oxidation catalysts |
| CA2900775C (en) | 2015-08-20 | 2023-10-10 | Nova Chemicals Corporation | Improved oxidative dehydrogenation catalyst |
| CA2904477A1 (en) * | 2015-09-14 | 2017-03-14 | Nova Chemicals Corporation | Heat dissipating diluent in fixed bed reactors |
| CA2975144C (en) * | 2017-08-03 | 2025-07-08 | Nova Chemicals Corporation | AGGLOMERATED OXIDATIVE DEHYDROGENATION CATALYST |
| CA2999092A1 (en) | 2018-03-26 | 2019-09-26 | Nova Chemicals Corporation | Calcination process to produce enhanced odh catlyst |
| CN108745389B (zh) * | 2018-06-06 | 2021-04-23 | 辽宁格瑞凯特科技有限公司 | 一种用于合成对羟基苯甲腈的催化剂的制备方法 |
| CN110038588A (zh) * | 2019-05-17 | 2019-07-23 | 湖南夏朗环保科技有限公司 | 一种高浓度有机废水处理专用催化剂及废水处理方法 |
| CN113769664B (zh) * | 2021-08-31 | 2023-08-29 | 山东神驰石化有限公司 | 一种丙烷脱氢制丙烯反应产物的分离装置 |
| CN119303601B (zh) * | 2023-07-14 | 2025-10-31 | 中国石油化工股份有限公司 | 用于乙苯脱氢制苯乙烯的催化剂及其制备方法和应用 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4292203A (en) * | 1977-04-04 | 1981-09-29 | The Standard Oil Company | Oxidation catalysts |
| US4866195A (en) * | 1987-10-22 | 1989-09-12 | The Standard Oil Company | Method for ammoxidation of paraffins and catalyst system therefor |
| EP0529853B1 (en) * | 1991-08-08 | 1996-02-28 | Mitsubishi Chemical Corporation | Catalyst and process for producing nitriles |
| EP0608838B1 (en) * | 1993-01-28 | 1997-04-16 | Mitsubishi Chemical Corporation | Method for producing an unsaturated carboxylic acid |
| JP3500663B2 (ja) | 1993-08-18 | 2004-02-23 | 三菱化学株式会社 | アクリル酸の製造方法 |
| US5534650A (en) * | 1994-01-12 | 1996-07-09 | Mitsubishi Chemical Corporation | Method for producing a nitrile |
| KR100247524B1 (ko) * | 1994-05-31 | 2000-03-15 | 겐지 아이다 | 아크릴산 제조용 촉매 및 이 촉매를 이용한 아크릴산의 제조방법 |
| DE19620542A1 (de) * | 1996-05-22 | 1997-11-27 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
| DE19630832A1 (de) * | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
| EP0929511B1 (en) * | 1996-09-24 | 2002-12-04 | E.I. Du Pont De Nemours And Company | Molybdenum based oxidation catalysts |
| ID20670A (id) * | 1997-08-05 | 1999-02-11 | Asahi Chemical Ind | Katalis amoksidasi untuk digunakan dalam memproduksi akrilonitril atau metakrilonitril dari propana atau isobutana dengan amoksidasi |
| DE19745902A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| CA2271397A1 (en) * | 1998-05-21 | 1999-11-21 | Rohm And Haas Company | A process for preparing a catalyst |
| US6114278A (en) * | 1998-11-16 | 2000-09-05 | Saudi Basic Industries Corporation | Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same |
| GB9907704D0 (en) * | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| US6171571B1 (en) * | 1999-05-10 | 2001-01-09 | Uop Llc | Crystalline multinary metal oxide compositions, process for preparing and processes for using the composition |
| US6258992B1 (en) * | 1999-09-17 | 2001-07-10 | Saudi Basic Industries Corporation | Gas phase catalytic oxidation of hydrocarbons to carboxylic acids and dehydrogenated products |
| US6444845B1 (en) * | 2000-04-28 | 2002-09-03 | Saudia Basic Industries Corporation | Process for the oxidation of unsaturated aldehydes to produce carboxylic acids using Mo-V based catalysts |
| US6441227B1 (en) * | 2000-06-23 | 2002-08-27 | Saudi Basic Industries Corporation | Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons |
| US20020038052A1 (en) * | 2000-09-28 | 2002-03-28 | Bogan, Leonard Edward | Calcination |
| US6642173B2 (en) * | 2001-04-25 | 2003-11-04 | Rohm And Haas Company | Catalyst |
-
2002
- 2002-04-08 US US10/117,908 patent/US6841699B2/en not_active Expired - Lifetime
- 2002-04-16 TW TW91107753A patent/TW574186B/zh not_active IP Right Cessation
- 2002-04-18 MX MXPA02003868A patent/MXPA02003868A/es unknown
- 2002-04-22 KR KR1020020021918A patent/KR100905955B1/ko not_active Expired - Fee Related
- 2002-04-22 BR BR0201368-1A patent/BR0201368A/pt not_active Application Discontinuation
- 2002-04-23 EP EP02252866A patent/EP1254709A3/en not_active Withdrawn
- 2002-04-25 JP JP2002123817A patent/JP2003024789A/ja active Pending
- 2002-04-25 CN CN02118441A patent/CN1382522A/zh active Pending
-
2004
- 2004-03-24 US US10/808,861 patent/US20040181085A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003024789A (ja) | 2003-01-28 |
| US20040181085A1 (en) | 2004-09-16 |
| EP1254709A2 (en) | 2002-11-06 |
| US6841699B2 (en) | 2005-01-11 |
| EP1254709A3 (en) | 2003-04-02 |
| US20020188149A1 (en) | 2002-12-12 |
| KR20020082765A (ko) | 2002-10-31 |
| KR100905955B1 (ko) | 2009-07-06 |
| TW574186B (en) | 2004-02-01 |
| MXPA02003868A (es) | 2003-07-14 |
| CN1382522A (zh) | 2002-12-04 |
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