BR0113916A - Processo para a isomerização de alcoóis alìlicos precursores, complexo de oxoperoxotungstênio, e, uso de compostos - Google Patents

Processo para a isomerização de alcoóis alìlicos precursores, complexo de oxoperoxotungstênio, e, uso de compostos

Info

Publication number
BR0113916A
BR0113916A BR0113916-9A BR0113916A BR0113916A BR 0113916 A BR0113916 A BR 0113916A BR 0113916 A BR0113916 A BR 0113916A BR 0113916 A BR0113916 A BR 0113916A
Authority
BR
Brazil
Prior art keywords
oxoperoxotungsten
complex
alcohols
isomerization
compounds
Prior art date
Application number
BR0113916-9A
Other languages
English (en)
Inventor
Frank Haese
Klaus Ebel
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BR0113916A publication Critical patent/BR0113916A/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

"PROCESSO PARA A ISOMERIZAçãO DE ALCOóIS ALìLICOS PRECURSORES, COMPLEXO DE OXOPEROXOTUNGSTêNIO, E, USO DE COMPOSTOS". A invenção refere-se a um método para a isomerização de extrato de álcoois alílicos da fórmula (I) nos álcoois alílicos produtos da fórmula geral (II) onde R^ 1^ a R^ 5^ representa hidrogênio ou um grupo alquila C~ 1~-C~ 12~ monoinsaturado ou poliinsaturado, o qual pode opcionalmente ser substituído, em ambas as direções do equilíbrio. O referido método é caracterizado em que a reação acontece na presença de um complexo de oxoperoxotungstênio (VI) da fórmula geral (III) onde L1 e L2 independentemente um do outro representam água ou um sítio de coordenação livre ou opcionalmente um ligando, escolhido do grupo contendo aminoálcoois, aminofenóis, ácidos aminocarboxílicos ou misturas dos mesmos, ou misturas de aminas e álcoois, ou aminas e fenóis, ou ácidos carboxílicos, m representa o número 1 ou 2, n representa um número entre 1 e 6, p representa um número entre 1 e 6, onde se p> 1, é formado um complexo binuclear ou polinuclear. A invenção também se refere a complexos novos de oxoperoxotungstênio (VI) e ao uso dos mesmos.
BR0113916-9A 2000-09-20 2001-09-18 Processo para a isomerização de alcoóis alìlicos precursores, complexo de oxoperoxotungstênio, e, uso de compostos BR0113916A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10046865A DE10046865A1 (de) 2000-09-20 2000-09-20 Verfahren zur Isomerisierung von Allylalkoholen
PCT/EP2001/010777 WO2002024617A1 (de) 2000-09-20 2001-09-18 Verfahren zur isomerisierung von allylalkoholen

Publications (1)

Publication Number Publication Date
BR0113916A true BR0113916A (pt) 2003-07-22

Family

ID=7657152

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0113916-9A BR0113916A (pt) 2000-09-20 2001-09-18 Processo para a isomerização de alcoóis alìlicos precursores, complexo de oxoperoxotungstênio, e, uso de compostos

Country Status (14)

Country Link
US (1) US6989468B2 (pt)
EP (1) EP1322583B1 (pt)
JP (1) JP4377128B2 (pt)
CN (1) CN1211331C (pt)
AR (1) AR030752A1 (pt)
AT (1) ATE315547T1 (pt)
AU (1) AU2001291871A1 (pt)
BR (1) BR0113916A (pt)
DE (2) DE10046865A1 (pt)
ES (1) ES2255569T3 (pt)
IL (1) IL154519A0 (pt)
MX (1) MXPA03001577A (pt)
WO (1) WO2002024617A1 (pt)
ZA (1) ZA200303030B (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10160146A1 (de) 2001-12-07 2003-06-18 Basf Ag Verfahren zur Isomerisierung von Allylalkoholen
DE10160147A1 (de) * 2001-12-07 2003-06-18 Basf Ag Verfahren zur Isomerisierung von Allylalkoholen
DE102004009311A1 (de) * 2004-02-26 2005-09-08 Basf Ag Verfahren zur Herstellung eines Propargylalkohols und eines Allylalkohols
CN101605748B (zh) * 2007-02-09 2013-04-03 帝斯曼知识产权资产管理有限公司 戊-1-烯-3-醇的异构化工艺
JP5801727B2 (ja) * 2012-01-16 2015-10-28 株式会社日本触媒 ペルオキソ錯体
EP2657216B1 (de) 2012-04-27 2014-06-25 Symrise AG Verfahren zum Umsetzen von Farnesol zu Nerolidol in Gegenwart von alpha-Bisabolol
CN105218312B (zh) * 2015-11-03 2017-04-26 山东新和成药业有限公司 一种烯丙基醇经异构化法连续制备芳樟醇的方法
CN105541544A (zh) * 2015-12-16 2016-05-04 绍兴明业化纤有限公司 一种3-甲基-3-丁烯-1-醇的生产方法
CN105967978B (zh) * 2016-07-15 2018-04-24 西南化工研究设计院有限公司 含水甲基丁烯醇异构化合成异戊烯醇
CN108892602A (zh) * 2018-09-18 2018-11-27 杭州更蓝生物科技有限公司 一种制备芳樟醇的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2516698A1 (de) * 1974-04-22 1975-10-30 Kuraray Co Neue wolframverbindungen
JPS5826730B2 (ja) * 1976-04-22 1983-06-04 株式会社クラレ シトロネロ−ルの分離方法
EP0860415B1 (de) 1997-02-25 2002-12-04 Basf Aktiengesellschaft Verfahren zur Isomerisierung von Allylalkoholen

Also Published As

Publication number Publication date
IL154519A0 (en) 2003-09-17
MXPA03001577A (es) 2003-06-04
DE50108693D1 (de) 2006-04-06
US6989468B2 (en) 2006-01-24
ES2255569T3 (es) 2006-07-01
JP2004509157A (ja) 2004-03-25
AU2001291871A1 (en) 2002-04-02
US20040097765A1 (en) 2004-05-20
CN1211331C (zh) 2005-07-20
ZA200303030B (en) 2004-04-19
JP4377128B2 (ja) 2009-12-02
WO2002024617A1 (de) 2002-03-28
DE10046865A1 (de) 2002-03-28
ATE315547T1 (de) 2006-02-15
EP1322583B1 (de) 2006-01-11
CN1461291A (zh) 2003-12-10
EP1322583A1 (de) 2003-07-02
AR030752A1 (es) 2003-09-03

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2116 DE 26/07/2011.