BR0110483A - Processo para a preparação de caprolactama - Google Patents
Processo para a preparação de caprolactamaInfo
- Publication number
- BR0110483A BR0110483A BR0110483-7A BR0110483A BR0110483A BR 0110483 A BR0110483 A BR 0110483A BR 0110483 A BR0110483 A BR 0110483A BR 0110483 A BR0110483 A BR 0110483A
- Authority
- BR
- Brazil
- Prior art keywords
- mixture
- caprolactam
- water
- high boiling
- low boiling
- Prior art date
Links
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 title abstract 14
- 239000000203 mixture Substances 0.000 abstract 8
- 238000009835 boiling Methods 0.000 abstract 6
- 239000000126 substance Substances 0.000 abstract 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- KBMSFJFLSXLIDJ-UHFFFAOYSA-N 6-aminohexanenitrile Chemical compound NCCCCCC#N KBMSFJFLSXLIDJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"PROCESSO PARA A PREPARAçãO DE CAPROLACTAMA". A invenção, refere-se a um método para produzir caprolactama, que é caracterizado pelas etapas de: a) reagir, na presença de um catalisador uma mistura (I) que contém 6-amino-capronitrila e água na fase gasosa para dar uma mistura (II) que contém caprolactama, amónia, água, substâncias de baixo ponto de ebulição e de elevado ponto de ebulição, subseq³entemente b) remover a amónia da mistura (II), para produzir deste modo uma mistura (III) que contém caprolactama, água, substâncias de baixo ponto de ebulição e de elevado ponto de ebulição, c) remover a água da mistura (III), para produzir deste modo uma mistura (IV) que contém caprolactama, substâncias de baixo ponto de ebulição e de elevado ponto de ebulição, e finalmente d) obter por cristalização uma substância sólida contendo caprolactama (V) da mistura (IV), a percentagem em peso de caprolactama na substância sólida (V) sendo maior do que na mistura (IV).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10021192A DE10021192A1 (de) | 2000-05-03 | 2000-05-03 | Verfahren zur Herstellung von Caprolactam |
| PCT/EP2001/004837 WO2001083443A1 (de) | 2000-05-03 | 2001-04-30 | Verfahren zur herstellung von caprolactam aus 6-aminocapronitril und nachträgliche reinigung durch kristallisation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0110483A true BR0110483A (pt) | 2003-04-08 |
Family
ID=7640431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0110483-7A BR0110483A (pt) | 2000-05-03 | 2001-04-30 | Processo para a preparação de caprolactama |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6683179B2 (pt) |
| EP (1) | EP1280767A1 (pt) |
| JP (1) | JP2003531893A (pt) |
| KR (1) | KR20030013398A (pt) |
| CN (1) | CN1174965C (pt) |
| AU (1) | AU5482001A (pt) |
| BR (1) | BR0110483A (pt) |
| CA (1) | CA2407728A1 (pt) |
| DE (1) | DE10021192A1 (pt) |
| MX (1) | MXPA02009714A (pt) |
| MY (1) | MY122991A (pt) |
| TW (1) | TWI239329B (pt) |
| WO (1) | WO2001083443A1 (pt) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1405846A1 (en) * | 2002-10-01 | 2004-04-07 | DSM IP Assets B.V. | Process for the preparation of epsilon-caprolactam from a mixture comprising 6-aminocaproamide and/or oligomers |
| DE10253094A1 (de) | 2002-11-13 | 2004-05-27 | Basf Ag | Verfahren zur Reinigung von Caprolactam |
| DE10253095A1 (de) * | 2002-11-13 | 2004-06-17 | Basf Ag | Verfahren zur Reinigung von Caprolactam |
| TWI520944B (zh) * | 2015-02-13 | 2016-02-11 | 中國石油化學工業開發股份有限公司 | 己內醯胺之製造方法及其系統 |
| WO2018074598A1 (ja) * | 2016-10-21 | 2018-04-26 | 国立大学法人 岡山大学 | 赤色顔料用酸化鉄及びその製造方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU75083A1 (ru) | 1948-05-19 | 1948-11-30 | Л.В. Зильперт | Способ повышени светостойкости пластических масс или лакокрасочных покрытий на основе полихлорвинила, содержащих в качестве пластификатора диметилфталат |
| DE1253716B (de) | 1961-09-28 | 1967-11-09 | Basf Ag | Verfahren zur Reinigung von Lactamen |
| DE3925575A1 (de) | 1989-08-02 | 1991-02-07 | Basf Ag | Verfahren zur kontinuierlichen reinigung von caprolactam |
| FR2714379B1 (fr) | 1993-12-23 | 1996-02-02 | Rhone Poulenc Chimie | Procédé de préparation de lactame. |
| DE19500041A1 (de) | 1995-01-03 | 1996-07-04 | Basf Ag | Verfahren zur kontinuierlichen Reinigung von aus 6-Aminocapronitril hergestelltem Roh-Caprolactam |
| FR2729949A1 (fr) | 1995-01-27 | 1996-08-02 | Rhone Poulenc Chimie | Procede de preparation de lactame |
| AU6244496A (en) | 1995-07-04 | 1997-02-05 | Dsm N.V. | Process to prepare 5-formylvaleric acid |
| DE19529239A1 (de) | 1995-08-09 | 1997-02-13 | Basf Ag | Verfahren zur kontinuierlichen Reindarstellung von 5-Formylvaleriansäureestern |
| EP0860431A1 (en) | 1997-02-19 | 1998-08-26 | Dsm N.V. | Process to prepare e-caprolactam |
| DE19753301A1 (de) * | 1997-12-01 | 1999-06-02 | Basf Ag | Verfahren zur Herstellung von Lactamen |
| DE19811880A1 (de) | 1998-03-18 | 1999-09-23 | Basf Ag | Verfahren zur Herstellung von Lactamen |
| EP0943608A1 (en) | 1998-03-20 | 1999-09-22 | Dsm N.V. | Process for the continuous purification of crude epsilon--caprolactam |
| CA2335114A1 (en) * | 1998-06-15 | 1999-12-23 | George Ernest Ii Keller | Separation of epsilon caprolactam from isomers |
-
2000
- 2000-05-03 DE DE10021192A patent/DE10021192A1/de not_active Withdrawn
-
2001
- 2001-04-20 MY MYPI20011884A patent/MY122991A/en unknown
- 2001-04-27 TW TW090110169A patent/TWI239329B/zh not_active IP Right Cessation
- 2001-04-30 AU AU54820/01A patent/AU5482001A/en not_active Abandoned
- 2001-04-30 CA CA002407728A patent/CA2407728A1/en not_active Abandoned
- 2001-04-30 CN CNB018089526A patent/CN1174965C/zh not_active Expired - Fee Related
- 2001-04-30 KR KR1020027014740A patent/KR20030013398A/ko not_active Application Discontinuation
- 2001-04-30 US US10/258,941 patent/US6683179B2/en not_active Expired - Lifetime
- 2001-04-30 BR BR0110483-7A patent/BR0110483A/pt not_active IP Right Cessation
- 2001-04-30 WO PCT/EP2001/004837 patent/WO2001083443A1/de active Application Filing
- 2001-04-30 MX MXPA02009714A patent/MXPA02009714A/es unknown
- 2001-04-30 EP EP01927930A patent/EP1280767A1/de not_active Withdrawn
- 2001-04-30 JP JP2001580872A patent/JP2003531893A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001083443A1 (de) | 2001-11-08 |
| KR20030013398A (ko) | 2003-02-14 |
| MXPA02009714A (es) | 2003-04-22 |
| CN1174965C (zh) | 2004-11-10 |
| CN1427820A (zh) | 2003-07-02 |
| CA2407728A1 (en) | 2002-10-29 |
| EP1280767A1 (de) | 2003-02-05 |
| DE10021192A1 (de) | 2001-11-08 |
| AU5482001A (en) | 2001-11-12 |
| US20030105322A1 (en) | 2003-06-05 |
| JP2003531893A (ja) | 2003-10-28 |
| US6683179B2 (en) | 2004-01-27 |
| TWI239329B (en) | 2005-09-11 |
| MY122991A (en) | 2006-05-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 6A , 7A E 8A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO DA RPI 2016 DE 25/08/2009. |