BG29130A3 - Method and apparatus for partially oxidation with oxygene of organic compounds in gas phase - Google Patents
Method and apparatus for partially oxidation with oxygene of organic compounds in gas phaseInfo
- Publication number
- BG29130A3 BG29130A3 BG026576A BG2657674A BG29130A3 BG 29130 A3 BG29130 A3 BG 29130A3 BG 026576 A BG026576 A BG 026576A BG 2657674 A BG2657674 A BG 2657674A BG 29130 A3 BG29130 A3 BG 29130A3
- Authority
- BG
- Bulgaria
- Prior art keywords
- zone
- filled
- oxygen
- gas phase
- heating
- Prior art date
Links
- 150000002894 organic compounds Chemical class 0.000 title abstract 5
- 230000003647 oxidation Effects 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 4
- 238000001816 cooling Methods 0.000 abstract 4
- 238000010438 heat treatment Methods 0.000 abstract 4
- 239000001301 oxygen Substances 0.000 abstract 4
- 229910052760 oxygen Inorganic materials 0.000 abstract 4
- 239000007789 gas Substances 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000011874 heated mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Метод за частично окисляване с кислород на органични съединения в газова фаза, по-специално окисляване на етилен до етиленов окис, характеризиращ се с това, че сместта на органичното съединение и кислорода или газа, съдържащ кислород, се подава в нагревателна зона, пълна с инертни материали, и там се нагрява до крайна температура на сместа от 100'с до 300'с, по-специално от 180'с до 220'с, след което нагрятата смес минава през съседна реакционна зона, напълнена с катализатор, където органичното съединение се окислява и накрая получените реакционни продукти се охлаждат под 150'с в трета зона, която в даден случай може да е съседна на предхождащата зона и да има пълнеж от инертни материали, като топлината, извлечена от охладителната зона, се оползотворява в нагревателната зона. Апаратура за частично окисляване с кислород на органични съединения в газова фаза, по-специално на етилен до етиленов окис, характеризираща се с това, че включва реактор, състоящ се от сноп тръби и обвивка, разделени от две прегради върху обвивката на три зони, като тръбите са свързани в краищата към плочи, към които са съединени дъната на реактора и охладителен кръг на междинната реакционна зона и един или повече кръга за нагряване на една от крайната зона за сметка на топлината, извлечена при охлаждане на другата зона, като междинната тръбна зона е пълна с катализатор докато тръбната нагревателна, в даден случай охладителна зона е пълна с инертни материали. Патентните претенции са формулирани в 14 точки.A method for the partial oxidation of organic compounds with oxygen in the gas phase, in particular the oxidation of ethylene to ethylene oxide, characterized in that the mixture of the organic compound and the oxygen or the gas containing oxygen is fed into a heating zone filled with inert materials, and there is heated to a final mixture temperature of 100'C to 300'C, particularly 180'C to 220'C, after which the heated mixture passes through an adjacent catalyst-filled reaction zone where the organic compound oxidizes and finally the reaction products obtained are cooled below 150°C in a third zone, which in some cases may be adjacent to the preceding zone and have a filling of inert materials, the heat extracted from the cooling zone being utilized in the heating zone. Apparatus for the partial oxidation with oxygen of organic compounds in the gas phase, in particular of ethylene to ethylene oxide, characterized in that it comprises a reactor consisting of a bundle of tubes and a shell divided by two baffles on the shell into three zones, as the tubes are connected at the ends to plates to which are connected the bottoms of the reactor and a cooling circuit of the intermediate reaction zone and one or more circuits for heating one of the end zones at the expense of the heat extracted by cooling the other zone, such as the intermediate tube zone is filled with catalyst while the tubular heating, in some cases cooling zone is filled with inert materials. The patent claims are formulated in 14 points.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT23558/73A IT986732B (en) | 1973-04-30 | 1973-04-30 | PROCEDURE FOR CONDUCTING PARTIAL OXIDATION REACTIONS WITH OXY GENO OF ORGANIC COMPOUNDS IN THE STEAM PHASE AND EQUIPMENT SUITABLE TO CARRY OUT THIS PROCEDURE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BG29130A3 true BG29130A3 (en) | 1980-09-15 |
Family
ID=11208123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG026576A BG29130A3 (en) | 1973-04-30 | 1974-04-30 | Method and apparatus for partially oxidation with oxygene of organic compounds in gas phase |
Country Status (24)
| Country | Link |
|---|---|
| AR (1) | AR201766A1 (en) |
| AT (1) | AT358600B (en) |
| BE (1) | BE814030A (en) |
| BG (1) | BG29130A3 (en) |
| BR (1) | BR7403404D0 (en) |
| CA (1) | CA1022178A (en) |
| CH (1) | CH609691A5 (en) |
| CS (2) | CS191912B2 (en) |
| DD (1) | DD111373A5 (en) |
| DE (1) | DE2420949C3 (en) |
| ES (1) | ES426072A1 (en) |
| FR (1) | FR2227268B1 (en) |
| GB (2) | GB1449091A (en) |
| HU (1) | HU176866B (en) |
| IT (1) | IT986732B (en) |
| LU (1) | LU69956A1 (en) |
| NL (1) | NL7405777A (en) |
| NO (1) | NO143532C (en) |
| RO (1) | RO70183A (en) |
| SE (1) | SE412231B (en) |
| SU (1) | SU1205750A3 (en) |
| TR (1) | TR17979A (en) |
| YU (1) | YU36169B (en) |
| ZA (1) | ZA742714B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6045637B2 (en) | 1978-07-26 | 1985-10-11 | 株式会社日本触媒 | Method for producing ethylene oxide |
| DE3028646A1 (en) * | 1980-07-29 | 1982-03-04 | Metallgesellschaft Ag, 6000 Frankfurt | METHOD FOR IMPROVING BALANCE AND SIMULTANEOUSLY GENERATING HIGH-PRESSURE STEAM IN THE PRODUCTION OF METHANOL |
| JPS59190983A (en) * | 1983-04-12 | 1984-10-29 | Mitsubishi Petrochem Co Ltd | Filler for using in reactor for preparation of ethylene oxide |
| IN161263B (en) * | 1983-06-30 | 1987-10-31 | Halcon Sd Group Inc | |
| DE3631642A1 (en) * | 1986-09-17 | 1988-04-07 | Linde Ag | METHOD FOR CARRYING OUT CATALYTIC REACTIONS |
| US4921681A (en) * | 1987-07-17 | 1990-05-01 | Scientific Design Company, Inc. | Ethylene oxide reactor |
| JP2778878B2 (en) * | 1991-09-12 | 1998-07-23 | 株式会社日本触媒 | Method for producing ethylene oxide |
| US7294317B2 (en) * | 2001-02-08 | 2007-11-13 | Sd Lizenzverwertungsgesellschaft Mbh & Co. | Exothermic reaction system |
| MX246250B (en) | 2001-02-08 | 2007-06-07 | Scient Design Co | Exothermic reaction system. |
| US7750170B2 (en) | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
| DE102007024934B4 (en) | 2007-05-29 | 2010-04-29 | Man Dwe Gmbh | Tube bundle reactors with pressure fluid cooling |
| US8343433B2 (en) | 2007-12-18 | 2013-01-01 | Dow Technology Investments Llc | Tube reactor |
| CN101284904B (en) * | 2008-06-06 | 2011-04-13 | 王加国 | Highly effective, energy-conserving and steam-free type ethoxylation reactor |
| US20100185001A1 (en) * | 2009-01-19 | 2010-07-22 | Van Maaren Wouter | Process and apparatus for the production of ethylene oxide |
-
1973
- 1973-04-30 IT IT23558/73A patent/IT986732B/en active
-
1974
- 1974-04-17 YU YU1079/74A patent/YU36169B/en unknown
- 1974-04-19 FR FR7413729A patent/FR2227268B1/fr not_active Expired
- 1974-04-22 BE BE143477A patent/BE814030A/en not_active IP Right Cessation
- 1974-04-25 BR BR3404/74A patent/BR7403404D0/en unknown
- 1974-04-25 RO RO7478557A patent/RO70183A/en unknown
- 1974-04-26 HU HU74SA2632A patent/HU176866B/en unknown
- 1974-04-26 DD DD178149A patent/DD111373A5/xx unknown
- 1974-04-26 AR AR253485A patent/AR201766A1/en active
- 1974-04-29 AT AT353774A patent/AT358600B/en not_active IP Right Cessation
- 1974-04-29 NO NO741536A patent/NO143532C/en unknown
- 1974-04-29 CH CH586674A patent/CH609691A5/en not_active IP Right Cessation
- 1974-04-29 SU SU742023942A patent/SU1205750A3/en active
- 1974-04-29 NL NL7405777A patent/NL7405777A/xx active Search and Examination
- 1974-04-29 LU LU69956A patent/LU69956A1/xx unknown
- 1974-04-29 CA CA198,623A patent/CA1022178A/en not_active Expired
- 1974-04-30 ZA ZA00742714A patent/ZA742714B/en unknown
- 1974-04-30 BG BG026576A patent/BG29130A3/en unknown
- 1974-04-30 DE DE2420949A patent/DE2420949C3/en not_active Expired
- 1974-04-30 GB GB1895474A patent/GB1449091A/en not_active Expired
- 1974-04-30 SE SE7405813A patent/SE412231B/en unknown
- 1974-04-30 TR TR17979A patent/TR17979A/en unknown
- 1974-04-30 GB GB522276A patent/GB1449092A/en not_active Expired
- 1974-04-30 ES ES426072A patent/ES426072A1/en not_active Expired
- 1974-04-30 CS CS743108A patent/CS191912B2/en unknown
-
1977
- 1977-01-25 CS CS77501A patent/CS191949B2/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO70183A (en) | 1981-06-22 |
| CS191912B2 (en) | 1979-07-31 |
| SU1205750A3 (en) | 1986-01-15 |
| NL7405777A (en) | 1974-11-01 |
| AU6779674A (en) | 1975-10-16 |
| NO143532C (en) | 1981-03-04 |
| DE2420949A1 (en) | 1974-11-14 |
| AT358600B (en) | 1980-09-25 |
| GB1449092A (en) | 1976-09-08 |
| BR7403404D0 (en) | 1974-11-19 |
| FR2227268B1 (en) | 1978-07-07 |
| BE814030A (en) | 1974-08-16 |
| AR201766A1 (en) | 1975-04-15 |
| FR2227268A1 (en) | 1974-11-22 |
| HU176866B (en) | 1981-05-28 |
| TR17979A (en) | 1976-09-01 |
| ZA742714B (en) | 1975-05-28 |
| NO143532B (en) | 1980-11-24 |
| DE2420949B2 (en) | 1979-07-12 |
| DE2420949C3 (en) | 1980-03-27 |
| IT986732B (en) | 1975-01-30 |
| DD111373A5 (en) | 1975-02-12 |
| SE412231B (en) | 1980-02-25 |
| ATA353774A (en) | 1980-02-15 |
| CS191949B2 (en) | 1979-07-31 |
| LU69956A1 (en) | 1974-08-06 |
| ES426072A1 (en) | 1976-07-01 |
| YU107974A (en) | 1981-06-30 |
| NO741536L (en) | 1974-10-31 |
| YU36169B (en) | 1982-02-25 |
| CA1022178A (en) | 1977-12-06 |
| CH609691A5 (en) | 1979-03-15 |
| GB1449091A (en) | 1976-09-08 |
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