BE904634A - Werkwijze voor de katalytische hydrogenering van kool in twee trappen. - Google Patents
Werkwijze voor de katalytische hydrogenering van kool in twee trappen. Download PDFInfo
- Publication number
- BE904634A BE904634A BE2/60963A BE2060963A BE904634A BE 904634 A BE904634 A BE 904634A BE 2/60963 A BE2/60963 A BE 2/60963A BE 2060963 A BE2060963 A BE 2060963A BE 904634 A BE904634 A BE 904634A
- Authority
- BE
- Belgium
- Prior art keywords
- sep
- liquid
- carbon
- stage
- reaction zone
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 77
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 68
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 238000009903 catalytic hydrogenation reaction Methods 0.000 title claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 72
- 239000007788 liquid Substances 0.000 claims abstract description 63
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 51
- 239000001257 hydrogen Substances 0.000 claims abstract description 51
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003054 catalyst Substances 0.000 claims abstract description 44
- 239000000047 product Substances 0.000 claims abstract description 37
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 34
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 33
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 30
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 25
- 239000007789 gas Substances 0.000 claims abstract description 20
- 238000009835 boiling Methods 0.000 claims abstract description 18
- 230000005587 bubbling Effects 0.000 claims abstract description 14
- 239000002002 slurry Substances 0.000 claims abstract description 11
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 9
- 239000012263 liquid product Substances 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims description 61
- 239000003245 coal Substances 0.000 claims description 34
- 239000000463 material Substances 0.000 claims description 22
- 239000003921 oil Substances 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 239000002802 bituminous coal Substances 0.000 claims description 5
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000003476 subbituminous coal Substances 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 230000009969 flowable effect Effects 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 239000007858 starting material Substances 0.000 claims 2
- 150000001721 carbon Chemical class 0.000 claims 1
- 239000000428 dust Substances 0.000 claims 1
- 239000011344 liquid material Substances 0.000 claims 1
- 238000005191 phase separation Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 description 28
- 239000002904 solvent Substances 0.000 description 23
- 240000007124 Brassica oleracea Species 0.000 description 11
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 11
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 11
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 11
- 125000005842 heteroatom Chemical group 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 230000006872 improvement Effects 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000003077 lignite Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- XRWSZZJLZRKHHD-WVWIJVSJSA-N asunaprevir Chemical compound O=C([C@@H]1C[C@H](CN1C(=O)[C@@H](NC(=O)OC(C)(C)C)C(C)(C)C)OC1=NC=C(C2=CC=C(Cl)C=C21)OC)N[C@]1(C(=O)NS(=O)(=O)C2CC2)C[C@H]1C=C XRWSZZJLZRKHHD-WVWIJVSJSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003250 coal slurry Substances 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
- 229940125961 compound 24 Drugs 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- NLPVCCRZRNXTLT-UHFFFAOYSA-N dioxido(dioxo)molybdenum;nickel(2+) Chemical compound [Ni+2].[O-][Mo]([O-])(=O)=O NLPVCCRZRNXTLT-UHFFFAOYSA-N 0.000 description 1
- 239000000386 donor Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000852 hydrogen donor Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001373 regressive effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72545885A | 1985-04-22 | 1985-04-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE904634A true BE904634A (nl) | 1986-08-18 |
Family
ID=24914646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE2/60963A BE904634A (nl) | 1985-04-22 | 1986-04-21 | Werkwijze voor de katalytische hydrogenering van kool in twee trappen. |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPH0823020B2 (enrdf_load_stackoverflow) |
| AU (1) | AU579462B2 (enrdf_load_stackoverflow) |
| BE (1) | BE904634A (enrdf_load_stackoverflow) |
| CA (1) | CA1276578C (enrdf_load_stackoverflow) |
| DE (1) | DE3613445A1 (enrdf_load_stackoverflow) |
| ZA (1) | ZA862692B (enrdf_load_stackoverflow) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA862690B (en) * | 1985-04-22 | 1988-11-30 | Hri Inc | Catalytic two-stage co-processing of coal/oil feedstocks |
| US4874506A (en) * | 1986-06-18 | 1989-10-17 | Hri, Inc. | Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction |
| US4816141A (en) * | 1987-10-16 | 1989-03-28 | Hri, Inc. | Catalytic two-stage liquefaction of coal utilizing cascading of used ebullated-bed catalyst |
| US5045180A (en) * | 1990-04-16 | 1991-09-03 | Hri, Inc. | Catalytic two-stage coal liquefaction process having improved nitrogen removal |
| JP2018024732A (ja) * | 2016-08-08 | 2018-02-15 | 株式会社神戸製鋼所 | 無灰炭の製造方法及び無灰炭の製造装置 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5761082A (en) * | 1980-09-30 | 1982-04-13 | Kobe Steel Ltd | Liquefaction of coal |
| JPS5968391A (ja) * | 1982-10-12 | 1984-04-18 | Asahi Chem Ind Co Ltd | 石炭の液化方法 |
| ZA841630B (en) * | 1983-03-07 | 1984-10-31 | Hri Inc | Hydrogenation of undissolved coal and subsequent liquefaction of hydrogenated coal |
| ZA862690B (en) * | 1985-04-22 | 1988-11-30 | Hri Inc | Catalytic two-stage co-processing of coal/oil feedstocks |
-
1986
- 1986-04-10 AU AU55950/86A patent/AU579462B2/en not_active Ceased
- 1986-04-10 ZA ZA862692A patent/ZA862692B/xx unknown
- 1986-04-15 CA CA000506634A patent/CA1276578C/en not_active Expired - Fee Related
- 1986-04-21 DE DE19863613445 patent/DE3613445A1/de active Granted
- 1986-04-21 BE BE2/60963A patent/BE904634A/nl not_active IP Right Cessation
- 1986-04-22 JP JP61091400A patent/JPH0823020B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3613445C2 (enrdf_load_stackoverflow) | 1989-06-08 |
| CA1276578C (en) | 1990-11-20 |
| JPS61247791A (ja) | 1986-11-05 |
| AU579462B2 (en) | 1988-11-24 |
| DE3613445A1 (de) | 1986-10-23 |
| AU5595086A (en) | 1986-10-30 |
| ZA862692B (en) | 1987-03-25 |
| JPH0823020B2 (ja) | 1996-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4842719A (en) | Catalytic two-stage coal hydrogenation and hydroconversion process | |
| US4839030A (en) | Coal liquefaction process utilizing coal/CO2 slurry feedstream | |
| US4222844A (en) | Use of once-through treat gas to remove the heat of reaction in solvent hydrogenation processes | |
| NO324214B1 (no) | Fremgangsmate for fremstilling av hydrokarboner fra syntesegass | |
| US4411767A (en) | Integrated process for the solvent refining of coal | |
| US4045329A (en) | Coal hydrogenation with selective recycle of liquid to reactor | |
| JPH08911B2 (ja) | 液体留分の超臨界蒸気抽出を用いる炭化水素液体の水素化転化方法 | |
| US4300996A (en) | Three-stage coal liquefaction process | |
| US4179352A (en) | Coal liquefaction process | |
| US4874506A (en) | Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction | |
| AU608654B2 (en) | Catalytic two-stage liquefaction of coal utilizing cascading of used ebullated-bed catalyst | |
| US4452688A (en) | Integrated coal liquefication process | |
| US8226821B2 (en) | Direct coal liquefaction with integrated product hydrotreating and catalyst cascading | |
| US4283267A (en) | Staged temperature hydrogen-donor coal liquefaction process | |
| BE904634A (nl) | Werkwijze voor de katalytische hydrogenering van kool in twee trappen. | |
| US4879021A (en) | Hydrogenation of coal and subsequent liquefaction of hydrogenated undissolved coal | |
| US4331531A (en) | Three-stage coal liquefaction process | |
| CA1128889A (en) | Coal liquefaction process with improved slurry recycle system | |
| CA1232220A (en) | Hydrogenation of undissolved coal and subsequent liquefaction of hydrogenated coal | |
| US5045180A (en) | Catalytic two-stage coal liquefaction process having improved nitrogen removal | |
| US3617474A (en) | Low sulfur fuel oil from coal | |
| US4541914A (en) | Process for converting coal | |
| WO1980001282A1 (en) | Coal liquefaction process employing extraneous minerals | |
| BE904635A (nl) | Tweetraps-werkwijze voor de continue katalytische hydroconversie van een mengsel van vast koolhoudend materiaal en zware vloeibare koolwaterstof. | |
| US4750991A (en) | Method for hydrogenating a solvent-refined coal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RE | Patent lapsed |
Owner name: HRI INC. Effective date: 19890430 |