CA1276578C - Catalytic two-stage coal hydrogenation and hydroconversion process - Google Patents
Catalytic two-stage coal hydrogenation and hydroconversion processInfo
- Publication number
- CA1276578C CA1276578C CA000506634A CA506634A CA1276578C CA 1276578 C CA1276578 C CA 1276578C CA 000506634 A CA000506634 A CA 000506634A CA 506634 A CA506634 A CA 506634A CA 1276578 C CA1276578 C CA 1276578C
- Authority
- CA
- Canada
- Prior art keywords
- coal
- stage
- liquid
- reaction zone
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003245 coal Substances 0.000 title claims abstract description 139
- 238000000034 method Methods 0.000 title claims abstract description 78
- 230000008569 process Effects 0.000 title claims abstract description 77
- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 33
- 230000003197 catalytic effect Effects 0.000 title description 44
- 239000007788 liquid Substances 0.000 claims abstract description 69
- 238000006243 chemical reaction Methods 0.000 claims abstract description 66
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 53
- 239000001257 hydrogen Substances 0.000 claims abstract description 53
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 43
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 42
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 40
- 239000000463 material Substances 0.000 claims abstract description 40
- 239000003054 catalyst Substances 0.000 claims abstract description 39
- 238000009835 boiling Methods 0.000 claims abstract description 26
- 239000007789 gas Substances 0.000 claims abstract description 25
- 239000000047 product Substances 0.000 claims abstract description 19
- 239000012263 liquid product Substances 0.000 claims abstract description 18
- 239000003921 oil Substances 0.000 claims abstract description 15
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 14
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims abstract description 6
- 239000002002 slurry Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 239000010742 number 1 fuel oil Substances 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- 230000009969 flowable effect Effects 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 3
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000011135 tin Substances 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000002802 bituminous coal Substances 0.000 claims description 2
- 239000003250 coal slurry Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 26
- 238000004519 manufacturing process Methods 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 125000005842 heteroatom Chemical group 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000003077 lignite Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 239000003476 subbituminous coal Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- NLPVCCRZRNXTLT-UHFFFAOYSA-N dioxido(dioxo)molybdenum;nickel(2+) Chemical compound [Ni+2].[O-][Mo]([O-])(=O)=O NLPVCCRZRNXTLT-UHFFFAOYSA-N 0.000 description 1
- 239000000386 donor Substances 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000000852 hydrogen donor Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- -1 pyrene/hydropyrenes Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001373 regressive effect Effects 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72545885A | 1985-04-22 | 1985-04-22 | |
| US725,458 | 1991-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1276578C true CA1276578C (en) | 1990-11-20 |
Family
ID=24914646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000506634A Expired - Fee Related CA1276578C (en) | 1985-04-22 | 1986-04-15 | Catalytic two-stage coal hydrogenation and hydroconversion process |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPH0823020B2 (enrdf_load_stackoverflow) |
| AU (1) | AU579462B2 (enrdf_load_stackoverflow) |
| BE (1) | BE904634A (enrdf_load_stackoverflow) |
| CA (1) | CA1276578C (enrdf_load_stackoverflow) |
| DE (1) | DE3613445A1 (enrdf_load_stackoverflow) |
| ZA (1) | ZA862692B (enrdf_load_stackoverflow) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA862690B (en) * | 1985-04-22 | 1988-11-30 | Hri Inc | Catalytic two-stage co-processing of coal/oil feedstocks |
| US4874506A (en) * | 1986-06-18 | 1989-10-17 | Hri, Inc. | Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction |
| US4816141A (en) * | 1987-10-16 | 1989-03-28 | Hri, Inc. | Catalytic two-stage liquefaction of coal utilizing cascading of used ebullated-bed catalyst |
| US5045180A (en) * | 1990-04-16 | 1991-09-03 | Hri, Inc. | Catalytic two-stage coal liquefaction process having improved nitrogen removal |
| JP2018024732A (ja) * | 2016-08-08 | 2018-02-15 | 株式会社神戸製鋼所 | 無灰炭の製造方法及び無灰炭の製造装置 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5761082A (en) * | 1980-09-30 | 1982-04-13 | Kobe Steel Ltd | Liquefaction of coal |
| JPS5968391A (ja) * | 1982-10-12 | 1984-04-18 | Asahi Chem Ind Co Ltd | 石炭の液化方法 |
| ZA841630B (en) * | 1983-03-07 | 1984-10-31 | Hri Inc | Hydrogenation of undissolved coal and subsequent liquefaction of hydrogenated coal |
| ZA862690B (en) * | 1985-04-22 | 1988-11-30 | Hri Inc | Catalytic two-stage co-processing of coal/oil feedstocks |
-
1986
- 1986-04-10 AU AU55950/86A patent/AU579462B2/en not_active Ceased
- 1986-04-10 ZA ZA862692A patent/ZA862692B/xx unknown
- 1986-04-15 CA CA000506634A patent/CA1276578C/en not_active Expired - Fee Related
- 1986-04-21 DE DE19863613445 patent/DE3613445A1/de active Granted
- 1986-04-21 BE BE2/60963A patent/BE904634A/nl not_active IP Right Cessation
- 1986-04-22 JP JP61091400A patent/JPH0823020B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BE904634A (nl) | 1986-08-18 |
| DE3613445C2 (enrdf_load_stackoverflow) | 1989-06-08 |
| JPS61247791A (ja) | 1986-11-05 |
| AU579462B2 (en) | 1988-11-24 |
| DE3613445A1 (de) | 1986-10-23 |
| AU5595086A (en) | 1986-10-30 |
| ZA862692B (en) | 1987-03-25 |
| JPH0823020B2 (ja) | 1996-03-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |