BE607424A

BE607424A -

Info

Publication number: BE607424A
Authority: BE; Belgium
Prior art keywords: sep; developing; alkaline solution; compound; quaternary ammonium
Prior art date

Application number

Other languages

English (en)

French (fr)

Publication of BE607424A publication Critical patent/BE607424A/fr

Links

239000000975 dye Substances 0.000 claims description 164
-1 silver halide Chemical class 0.000 claims description 127
229910052709 silver Inorganic materials 0.000 claims description 94
239000004332 silver Substances 0.000 claims description 94
239000000839 emulsion Substances 0.000 claims description 77
239000002904 solvent Substances 0.000 claims description 52
150000001875 compounds Chemical class 0.000 claims description 49
238000011161 development Methods 0.000 claims description 41
238000000034 method Methods 0.000 claims description 41
150000004010 onium ions Chemical class 0.000 claims description 39
239000000243 solution Substances 0.000 claims description 39
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 37
230000008569 process Effects 0.000 claims description 34
239000012670 alkaline solution Substances 0.000 claims description 27
238000012546 transfer Methods 0.000 claims description 26
239000000463 material Substances 0.000 claims description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 16
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 13
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
239000003086 colorant Substances 0.000 claims description 11
238000009792 diffusion process Methods 0.000 claims description 11
230000035945 sensitivity Effects 0.000 claims description 10
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 9
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 8
239000003513 alkali Substances 0.000 claims description 6
150000004820 halides Chemical class 0.000 claims description 6
125000001453 quaternary ammonium group Chemical group 0.000 claims description 5
XCZKKZXWDBOGPA-UHFFFAOYSA-N 2-phenylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C=2C=CC=CC=2)=C1 XCZKKZXWDBOGPA-UHFFFAOYSA-N 0.000 claims description 4
JNRLEMMIVRBKJE-UHFFFAOYSA-N 4,4'-Methylenebis(N,N-dimethylaniline) Chemical compound C1=CC(N(C)C)=CC=C1CC1=CC=C(N(C)C)C=C1 JNRLEMMIVRBKJE-UHFFFAOYSA-N 0.000 claims description 4
230000000295 complement effect Effects 0.000 claims description 4
125000005496 phosphonium group Chemical group 0.000 claims description 4
150000004023 quaternary phosphonium compounds Chemical class 0.000 claims description 4
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims description 4
GZUXJHMPEANEGY-UHFFFAOYSA-N methyl bromide Substances BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 claims description 3
LKGFNNSOZPTLSS-UHFFFAOYSA-M 1-benzyl-2-methylpyridin-1-ium;bromide Chemical compound [Br-].CC1=CC=CC=[N+]1CC1=CC=CC=C1 LKGFNNSOZPTLSS-UHFFFAOYSA-M 0.000 claims description 2
SNWSZCGYPHRJEY-UHFFFAOYSA-N 2-cyclohexylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C2CCCCC2)=C1 SNWSZCGYPHRJEY-UHFFFAOYSA-N 0.000 claims description 2
YSUUCHVSWMMYLY-UHFFFAOYSA-M 2-methyl-1-(1-phenylpropyl)pyridin-1-ium bromide Chemical compound [Br-].CCC(C1=CC=CC=C1)[N+]1=CC=CC=C1C YSUUCHVSWMMYLY-UHFFFAOYSA-M 0.000 claims description 2
NTKLFSYUWYPMCJ-UHFFFAOYSA-N 2-phenoxybenzene-1,4-diol Chemical compound OC1=CC=C(O)C(OC=2C=CC=CC=2)=C1 NTKLFSYUWYPMCJ-UHFFFAOYSA-N 0.000 claims description 2
229940102396 methyl bromide Drugs 0.000 claims description 2
QRWZCJXEAOZAAW-UHFFFAOYSA-N n,n,2-trimethylprop-2-enamide Chemical compound CN(C)C(=O)C(C)=C QRWZCJXEAOZAAW-UHFFFAOYSA-N 0.000 claims description 2
STOSPPMGXZPHKP-UHFFFAOYSA-N tetrachlorohydroquinone Chemical compound OC1=C(Cl)C(Cl)=C(O)C(Cl)=C1Cl STOSPPMGXZPHKP-UHFFFAOYSA-N 0.000 claims description 2
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 2
SGWZVZZVXOJRAQ-UHFFFAOYSA-N 2,6-Dimethyl-1,4-benzenediol Chemical compound CC1=CC(O)=CC(C)=C1O SGWZVZZVXOJRAQ-UHFFFAOYSA-N 0.000 claims 2
IYAREOPOQBFJLU-UHFFFAOYSA-M 1,2-dimethylpyridin-1-ium;4-methylbenzenesulfonate Chemical compound CC1=CC=CC=[N+]1C.CC1=CC=C(S([O-])(=O)=O)C=C1 IYAREOPOQBFJLU-UHFFFAOYSA-M 0.000 claims 1
FFMQPEWAOYKLIB-UHFFFAOYSA-M 1-(3-bromopropyl)-2-methylpyridin-1-ium;4-methylbenzenesulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CC1=CC=CC=[N+]1CCCBr FFMQPEWAOYKLIB-UHFFFAOYSA-M 0.000 claims 1
DPNHYAUITGEXCI-UHFFFAOYSA-M 1-heptyl-2-methylpyridin-1-ium;bromide Chemical compound [Br-].CCCCCCC[N+]1=CC=CC=C1C DPNHYAUITGEXCI-UHFFFAOYSA-M 0.000 claims 1
SAORNRFCWXEYSW-UHFFFAOYSA-M 1-propylpyridin-1-ium;bromide Chemical compound [Br-].CCC[N+]1=CC=CC=C1 SAORNRFCWXEYSW-UHFFFAOYSA-M 0.000 claims 1
AMKFXDUNGJKVDE-UHFFFAOYSA-N 2,5-di(propan-2-yl)benzene-1,4-diol Chemical compound CC(C)C1=CC(O)=C(C(C)C)C=C1O AMKFXDUNGJKVDE-UHFFFAOYSA-N 0.000 claims 1
AYNPIRVEWMUJDE-UHFFFAOYSA-N 2,5-dichlorohydroquinone Chemical compound OC1=CC(Cl)=C(O)C=C1Cl AYNPIRVEWMUJDE-UHFFFAOYSA-N 0.000 claims 1
BVVCBZSERKSMIE-UHFFFAOYSA-N 2,5-diphenylbenzene-1,4-diol Chemical compound OC1=CC(C=2C=CC=CC=2)=C(O)C=C1C1=CC=CC=C1 BVVCBZSERKSMIE-UHFFFAOYSA-N 0.000 claims 1
VFDVXJPXKQVMEU-UHFFFAOYSA-N 2-[2-(4-aminophenyl)ethyl]-5-methylbenzene-1,4-diol Chemical compound C1=C(O)C(C)=CC(O)=C1CCC1=CC=C(N)C=C1 VFDVXJPXKQVMEU-UHFFFAOYSA-N 0.000 claims 1
REFDOIWRJDGBHY-UHFFFAOYSA-N 2-bromobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Br)=C1 REFDOIWRJDGBHY-UHFFFAOYSA-N 0.000 claims 1
VXBBBPPOEADZAR-UHFFFAOYSA-N 2-butylbenzene-1,4-diol 2,5-dichlorobenzene-1,4-diol Chemical compound ClC1=C(O)C=C(C(=C1)O)Cl.C(CCC)C1=C(O)C=CC(=C1)O VXBBBPPOEADZAR-UHFFFAOYSA-N 0.000 claims 1
HFVATZRDXYQGBX-UHFFFAOYSA-M 2-methyl-1-(3-phenylpropyl)pyridin-1-ium;bromide Chemical compound [Br-].CC1=CC=CC=[N+]1CCCC1=CC=CC=C1 HFVATZRDXYQGBX-UHFFFAOYSA-M 0.000 claims 1
HXISUMFKRXBYND-UHFFFAOYSA-M 3-[1-(1-phenylethyl)pyridin-1-ium-4-yl]propan-1-ol bromide Chemical compound [Br-].OCCCC1=CC=[N+](C=C1)C(C)C1=CC=CC=C1 HXISUMFKRXBYND-UHFFFAOYSA-M 0.000 claims 1
OEUQGLWRUDITOO-UHFFFAOYSA-M [Br-].C(C)C=1C=CC=[N+](C=1)C(CC)C1=CC=CC=C1 Chemical compound [Br-].C(C)C=1C=CC=[N+](C=1)C(CC)C1=CC=CC=C1 OEUQGLWRUDITOO-UHFFFAOYSA-M 0.000 claims 1
XJAKVTUWCOGXNJ-UHFFFAOYSA-M [Br-].C(C)CC(C1=CC=CC=C1)[N+]1=CC=CC=C1 Chemical compound [Br-].C(C)CC(C1=CC=CC=C1)[N+]1=CC=CC=C1 XJAKVTUWCOGXNJ-UHFFFAOYSA-M 0.000 claims 1
230000000977 initiatory effect Effects 0.000 claims 1
239000003760 tallow Substances 0.000 claims 1
239000010410 layer Substances 0.000 description 154
239000000047 product Substances 0.000 description 78
239000012190 activator Substances 0.000 description 39
239000007788 liquid Substances 0.000 description 38
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 36
108010010803 Gelatin Proteins 0.000 description 32
239000008273 gelatin Substances 0.000 description 31
229920000159 gelatin Polymers 0.000 description 31
235000019322 gelatine Nutrition 0.000 description 31
235000011852 gelatine desserts Nutrition 0.000 description 31
238000012545 processing Methods 0.000 description 27
238000012360 testing method Methods 0.000 description 25
239000000203 mixture Substances 0.000 description 18
150000003839 salts Chemical class 0.000 description 17
239000000084 colloidal system Substances 0.000 description 15
230000000694 effects Effects 0.000 description 15
125000000217 alkyl group Chemical group 0.000 description 13
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
230000009471 action Effects 0.000 description 12
150000003254 radicals Chemical class 0.000 description 12
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
125000003118 aryl group Chemical group 0.000 description 9
238000009835 boiling Methods 0.000 description 9
239000006185 dispersion Substances 0.000 description 9
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 9
239000007864 aqueous solution Substances 0.000 description 8
239000011230 binding agent Substances 0.000 description 8
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
230000006872 improvement Effects 0.000 description 8
239000002585 base Substances 0.000 description 7
238000011109 contamination Methods 0.000 description 7
230000002829 reductive effect Effects 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
150000001450 anions Chemical class 0.000 description 6
125000004429 atom Chemical group 0.000 description 6
238000004040 coloring Methods 0.000 description 6
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 6
PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 5
239000004372 Polyvinyl alcohol Substances 0.000 description 5
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 5
125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
230000003647 oxidation Effects 0.000 description 5
238000007254 oxidation reaction Methods 0.000 description 5
229920002451 polyvinyl alcohol Polymers 0.000 description 5
239000000126 substance Substances 0.000 description 5
125000001424 substituent group Chemical group 0.000 description 5
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical class N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
230000010933 acylation Effects 0.000 description 4
238000005917 acylation reaction Methods 0.000 description 4
125000002947 alkylene group Chemical group 0.000 description 4
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
229920002678 cellulose Polymers 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
125000000623 heterocyclic group Chemical group 0.000 description 4
239000003960 organic solvent Substances 0.000 description 4
230000009467 reduction Effects 0.000 description 4
238000006722 reduction reaction Methods 0.000 description 4
JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 4
GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 3
VGVHNLRUAMRIEW-UHFFFAOYSA-N 4-methylcyclohexan-1-one Chemical class CC1CCC(=O)CC1 VGVHNLRUAMRIEW-UHFFFAOYSA-N 0.000 description 3
229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 3
DEBAJJOWBOLVCM-UHFFFAOYSA-M [Br-].C1(=CC=CC=C1)C(C)[N+]1=CC(=CC=C1)C Chemical compound [Br-].C1(=CC=CC=C1)C(C)[N+]1=CC(=CC=C1)C DEBAJJOWBOLVCM-UHFFFAOYSA-M 0.000 description 3
125000003545 alkoxy group Chemical group 0.000 description 3
239000001768 carboxy methyl cellulose Substances 0.000 description 3
235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
239000008112 carboxymethyl-cellulose Substances 0.000 description 3
239000001913 cellulose Substances 0.000 description 3
235000010980 cellulose Nutrition 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
125000001309 chloro group Chemical group Cl* 0.000 description 3
238000010586 diagram Methods 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000001035 drying Methods 0.000 description 3
XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 3
235000019345 sodium thiosulphate Nutrition 0.000 description 3
150000004026 tertiary sulfonium compounds Chemical class 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 2
OIDIRWZVUWCCCO-UHFFFAOYSA-N 1-ethylpyridin-1-ium Chemical compound CC[N+]1=CC=CC=C1 OIDIRWZVUWCCCO-UHFFFAOYSA-N 0.000 description 2
HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 2
WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 2
VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 2
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
CUZKCNWZBXLAJX-UHFFFAOYSA-N 2-phenylmethoxyethanol Chemical compound OCCOCC1=CC=CC=C1 CUZKCNWZBXLAJX-UHFFFAOYSA-N 0.000 description 2
KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 2
WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 2
DRSHXJFUUPIBHX-UHFFFAOYSA-N COc1ccc(cc1)N1N=CC2C=NC(Nc3cc(OC)c(OC)c(OCCCN4CCN(C)CC4)c3)=NC12 Chemical compound COc1ccc(cc1)N1N=CC2C=NC(Nc3cc(OC)c(OC)c(OCCCN4CCN(C)CC4)c3)=NC12 DRSHXJFUUPIBHX-UHFFFAOYSA-N 0.000 description 2
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
BHJHPYFAYGAPLS-UHFFFAOYSA-N Guaicyl acetate Chemical compound COC1=CC=CC=C1OC(C)=O BHJHPYFAYGAPLS-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
125000003277 amino group Chemical group 0.000 description 2
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
150000004056 anthraquinones Chemical class 0.000 description 2
125000003710 aryl alkyl group Chemical group 0.000 description 2
125000004104 aryloxy group Chemical group 0.000 description 2
CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
WZJYKHNJTSNBHV-UHFFFAOYSA-N benzo[h]quinoline Chemical class C1=CN=C2C3=CC=CC=C3C=CC2=C1 WZJYKHNJTSNBHV-UHFFFAOYSA-N 0.000 description 2
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
239000012964 benzotriazole Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
AFWARTLPQGAFMN-UHFFFAOYSA-M butyl(dimethyl)sulfanium;bromide Chemical compound [Br-].CCCC[S+](C)C AFWARTLPQGAFMN-UHFFFAOYSA-M 0.000 description 2
239000002775 capsule Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
229960002380 dibutyl phthalate Drugs 0.000 description 2
NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
IGMNYECMUMZDDF-UHFFFAOYSA-N homogentisic acid Chemical compound OC(=O)CC1=CC(O)=CC=C1O IGMNYECMUMZDDF-UHFFFAOYSA-N 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical class C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
150000002596 lactones Chemical class 0.000 description 2
HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 2
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
125000004433 nitrogen atom Chemical group N* 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 2
229920002689 polyvinyl acetate Polymers 0.000 description 2
239000011118 polyvinyl acetate Substances 0.000 description 2
229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
230000002441 reversible effect Effects 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
230000003595 spectral effect Effects 0.000 description 2
239000000758 substrate Substances 0.000 description 2
125000005420 sulfonamido group Chemical group S(=O)(=O)(N*)* 0.000 description 2
LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical group C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 2
LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
UJAWSGMWMKXZMP-UHFFFAOYSA-M 1,1-diethylpiperidin-1-ium;bromide Chemical compound [Br-].CC[N+]1(CC)CCCCC1 UJAWSGMWMKXZMP-UHFFFAOYSA-M 0.000 description 1
SGWDPXMORNZDKZ-UHFFFAOYSA-N 1,2-dibenzylpyridin-1-ium Chemical compound C=1C=CC=[N+](CC=2C=CC=CC=2)C=1CC1=CC=CC=C1 SGWDPXMORNZDKZ-UHFFFAOYSA-N 0.000 description 1
AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical class C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 description 1
BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
TYAFJEUCVKTKSL-UHFFFAOYSA-N 1,4-bis(2,5-dihydroxyanilino)anthracene-9,10-dione Chemical compound OC1=CC=C(O)C(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(NC=3C(=CC=C(O)C=3)O)=CC=2)=C1 TYAFJEUCVKTKSL-UHFFFAOYSA-N 0.000 description 1
PWMWNFMRSKOCEY-UHFFFAOYSA-N 1-Phenyl-1,2-ethanediol Chemical compound OCC(O)C1=CC=CC=C1 PWMWNFMRSKOCEY-UHFFFAOYSA-N 0.000 description 1
JHPZVPVIEQJNSU-UHFFFAOYSA-M 1-ethyl-2-methyl-3-(2-phenylethyl)benzimidazol-3-ium;bromide Chemical compound [Br-].C12=CC=CC=C2N(CC)C(C)=[N+]1CCC1=CC=CC=C1 JHPZVPVIEQJNSU-UHFFFAOYSA-M 0.000 description 1
ABFDKXBSQCTIKH-UHFFFAOYSA-M 1-ethylpyridin-1-ium;bromide Chemical compound [Br-].CC[N+]1=CC=CC=C1 ABFDKXBSQCTIKH-UHFFFAOYSA-M 0.000 description 1
FGQSEPCQVURWHV-UHFFFAOYSA-N 1-piperidin-1-yldodecan-1-one Chemical compound CCCCCCCCCCCC(=O)N1CCCCC1 FGQSEPCQVURWHV-UHFFFAOYSA-N 0.000 description 1
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
CARFETJZUQORNQ-UHFFFAOYSA-N 1h-pyrrole-2-thiol Chemical class SC1=CC=CN1 CARFETJZUQORNQ-UHFFFAOYSA-N 0.000 description 1
VQORRTFNAVANSO-UHFFFAOYSA-N 2,2-dibutyldodecanamide Chemical compound CCCCCCCCCCC(CCCC)(CCCC)C(N)=O VQORRTFNAVANSO-UHFFFAOYSA-N 0.000 description 1
QCIRZNMDADAION-UHFFFAOYSA-N 2,5-dibutoxybenzene-1,4-diol Chemical compound CCCCOC1=CC(O)=C(OCCCC)C=C1O QCIRZNMDADAION-UHFFFAOYSA-N 0.000 description 1
QVLXDGDLLZYJAM-UHFFFAOYSA-N 2,5-dioctylbenzene-1,4-diol Chemical compound CCCCCCCCC1=CC(O)=C(CCCCCCCC)C=C1O QVLXDGDLLZYJAM-UHFFFAOYSA-N 0.000 description 1
BRDIEXWCAJNNQS-UHFFFAOYSA-N 2-(4-methylphenyl)benzene-1,4-diol Chemical compound C1=CC(C)=CC=C1C1=CC(O)=CC=C1O BRDIEXWCAJNNQS-UHFFFAOYSA-N 0.000 description 1
GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 description 1
RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical compound O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
FVVXWRGARUACNW-UHFFFAOYSA-N 3-methylisoquinoline Chemical compound C1=CC=C2C=NC(C)=CC2=C1 FVVXWRGARUACNW-UHFFFAOYSA-N 0.000 description 1
PWYWSXCXTOFBSN-UHFFFAOYSA-M 4-methylbenzenesulfonate;1-nonylpyridin-1-ium Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CCCCCCCCC[N+]1=CC=CC=C1 PWYWSXCXTOFBSN-UHFFFAOYSA-M 0.000 description 1
MYAALGBQWWRACC-UHFFFAOYSA-N 6-oxo-6-(oxolan-2-ylmethoxy)hexanoic acid Chemical compound OC(=O)CCCCC(=O)OCC1CCCO1 MYAALGBQWWRACC-UHFFFAOYSA-N 0.000 description 1
RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical group C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
PQQMCCVAOLBQLR-UHFFFAOYSA-N Br[N+]1=CC=CC=C1 Chemical compound Br[N+]1=CC=CC=C1 PQQMCCVAOLBQLR-UHFFFAOYSA-N 0.000 description 1
IYPWHXGGZZQMMR-UHFFFAOYSA-N C(C)(C)C1=C(O)C=C(C(=C1)O)C(C)C.ClC1=C(O)C=C(C(=C1)O)Cl.C(CCC)C1=C(O)C=CC(=C1)O Chemical compound C(C)(C)C1=C(O)C=C(C(=C1)O)C(C)C.ClC1=C(O)C=C(C(=C1)O)Cl.C(CCC)C1=C(O)C=CC(=C1)O IYPWHXGGZZQMMR-UHFFFAOYSA-N 0.000 description 1
XZNRQJVLHKPLIY-UHFFFAOYSA-N C(C=1C(C(=O)O)=CC=CC1)(=O)O.CC(=O)C Chemical compound C(C=1C(C(=O)O)=CC=CC1)(=O)O.CC(=O)C XZNRQJVLHKPLIY-UHFFFAOYSA-N 0.000 description 1
AFIVGHHPMDXBSD-UHFFFAOYSA-N C(CC1=CC=CC=C1)C(C1=CC=CC=C1)[N+]1=CC=CC=C1 Chemical compound C(CC1=CC=CC=C1)C(C1=CC=CC=C1)[N+]1=CC=CC=C1 AFIVGHHPMDXBSD-UHFFFAOYSA-N 0.000 description 1
QLLMDCKLHXEACT-UHFFFAOYSA-O CC(C1=CC=CC=C1)[N+]1=C(C)C=CC=C1N Chemical compound CC(C1=CC=CC=C1)[N+]1=C(C)C=CC=C1N QLLMDCKLHXEACT-UHFFFAOYSA-O 0.000 description 1
FYIRISDJNQYVRQ-UHFFFAOYSA-N CC(C1=CC=CC=C1)[N+]1=CC=C(CC2=CC=CC=C2)C=C1 Chemical compound CC(C1=CC=CC=C1)[N+]1=CC=C(CC2=CC=CC=C2)C=C1 FYIRISDJNQYVRQ-UHFFFAOYSA-N 0.000 description 1
ZZLIAIQRRSGWDH-UHFFFAOYSA-N CC1=CC=[N+](C(CN)C2=CC=CC=C2)C=C1 Chemical compound CC1=CC=[N+](C(CN)C2=CC=CC=C2)C=C1 ZZLIAIQRRSGWDH-UHFFFAOYSA-N 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
206010010071 Coma Diseases 0.000 description 1
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
101100448208 Human herpesvirus 6B (strain Z29) U69 gene Proteins 0.000 description 1
229930194542 Keto Natural products 0.000 description 1
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
FMKCDSXOYLTWBR-UHFFFAOYSA-N Tetrahydrofurfuryl propionate Chemical compound CCC(=O)OCC1CCCO1 FMKCDSXOYLTWBR-UHFFFAOYSA-N 0.000 description 1
FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical class C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical group CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
MLFHJEHSLIIPHL-UHFFFAOYSA-N acetic acid isopentyl ester Natural products CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 1
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
KJCVRFUGPWSIIH-UHFFFAOYSA-N alpha-naphthol Natural products C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical class [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
125000001769 aryl amino group Chemical group 0.000 description 1
150000003851 azoles Chemical class 0.000 description 1
150000007514 bases Chemical class 0.000 description 1
239000003637 basic solution Substances 0.000 description 1
239000011324 bead Substances 0.000 description 1
150000001555 benzenes Chemical class 0.000 description 1
KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical class C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
DMNQTEVDCGAATA-UHFFFAOYSA-N bis(oxolan-2-ylmethyl) hexanedioate Chemical compound C1CCOC1COC(=O)CCCCC(=O)OCC1CCCO1 DMNQTEVDCGAATA-UHFFFAOYSA-N 0.000 description 1
150000001649 bromium compounds Chemical class 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
125000005518 carboxamido group Chemical group 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
238000010531 catalytic reduction reaction Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
230000008859 change Effects 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
239000002361 compost Substances 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
KDPRXSDKCJVMGN-UHFFFAOYSA-N decyl(dimethyl)sulfanium Chemical compound CCCCCCCCCC[S+](C)C KDPRXSDKCJVMGN-UHFFFAOYSA-N 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000004925 denaturation Methods 0.000 description 1
230000036425 denaturation Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
FQRPXALREFKNJX-UHFFFAOYSA-M dimethyl(nonyl)sulfanium;4-methylbenzenesulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CCCCCCCCC[S+](C)C FQRPXALREFKNJX-UHFFFAOYSA-M 0.000 description 1
LDZRYLOIIHCBQP-UHFFFAOYSA-N dimethyl(tetradecyl)sulfanium Chemical compound CCCCCCCCCCCCCC[S+](C)C LDZRYLOIIHCBQP-UHFFFAOYSA-N 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
NCZFYMIPOHPCCG-UHFFFAOYSA-N dodecyl(dimethyl)sulfanium Chemical compound CCCCCCCCCCCC[S+](C)C NCZFYMIPOHPCCG-UHFFFAOYSA-N 0.000 description 1
XPROKLGQTCGPDN-UHFFFAOYSA-M dodecyl(dimethyl)sulfanium;4-methylbenzenesulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CCCCCCCCCCCC[S+](C)C XPROKLGQTCGPDN-UHFFFAOYSA-M 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
DSICTTBMRSZYJL-UHFFFAOYSA-N ethyl n,n-dibutylcarbamate Chemical compound CCCCN(CCCC)C(=O)OCC DSICTTBMRSZYJL-UHFFFAOYSA-N 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000012530 fluid Substances 0.000 description 1
229960002737 fructose Drugs 0.000 description 1
239000000499 gel Substances 0.000 description 1
229960005219 gentisic acid Drugs 0.000 description 1
125000001188 haloalkyl group Chemical group 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
239000004312 hexamethylene tetramine Substances 0.000 description 1
235000010299 hexamethylene tetramine Nutrition 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 description 1
238000003384 imaging method Methods 0.000 description 1
230000003100 immobilizing effect Effects 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000011229 interlayer Substances 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
125000000468 ketone group Chemical group 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
229960003671 mercuric iodide Drugs 0.000 description 1
150000002730 mercury Chemical class 0.000 description 1
YFDLHELOZYVNJE-UHFFFAOYSA-L mercury diiodide Chemical compound I[Hg]I YFDLHELOZYVNJE-UHFFFAOYSA-L 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
MQWCXKGKQLNYQG-UHFFFAOYSA-N methyl cyclohexan-4-ol Natural products CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
MWCGLTCRJJFXKR-UHFFFAOYSA-N n-phenylethanethioamide Chemical compound CC(=S)NC1=CC=CC=C1 MWCGLTCRJJFXKR-UHFFFAOYSA-N 0.000 description 1
PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
150000002790 naphthalenes Chemical class 0.000 description 1
231100000989 no adverse effect Toxicity 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
UGKBTVICKIUXJF-UHFFFAOYSA-N oxolan-2-yl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1CCCO1 UGKBTVICKIUXJF-UHFFFAOYSA-N 0.000 description 1
230000003071 parasitic effect Effects 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
230000019612 pigmentation Effects 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000233 poly(alkylene oxides) Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
BBFCIBZLAVOLCF-UHFFFAOYSA-N pyridin-1-ium;bromide Chemical compound Br.C1=CC=NC=C1 BBFCIBZLAVOLCF-UHFFFAOYSA-N 0.000 description 1
RRTTWJWQIJJPDG-UHFFFAOYSA-N pyridin-1-ium;diperchlorate Chemical compound [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.C1=CC=[NH+]C=C1.C1=CC=[NH+]C=C1 RRTTWJWQIJJPDG-UHFFFAOYSA-N 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
150000003222 pyridines Chemical class 0.000 description 1
239000004627 regenerated cellulose Substances 0.000 description 1
230000001235 sensitizing effect Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
229960002317 succinimide Drugs 0.000 description 1
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
LRBQNJMCXXYXIU-YIILYMKVSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)C(OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-YIILYMKVSA-N 0.000 description 1
150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
LIXPXSXEKKHIRR-UHFFFAOYSA-M tetraethylphosphanium;bromide Chemical compound [Br-].CC[P+](CC)(CC)CC LIXPXSXEKKHIRR-UHFFFAOYSA-M 0.000 description 1
OPTBBAGXQYOFTL-UHFFFAOYSA-N tetraethylphthalamide Chemical compound CCN(CC)C(=O)C1=CC=CC=C1C(=O)N(CC)CC OPTBBAGXQYOFTL-UHFFFAOYSA-N 0.000 description 1
229950007617 tetraethylphthalamide Drugs 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
150000003567 thiocyanates Chemical class 0.000 description 1
125000003396 thiol group Chemical group [H]S* 0.000 description 1
WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 description 1
WCZKTXKOKMXREO-UHFFFAOYSA-N triethylsulfanium Chemical compound CC[S+](CC)CC WCZKTXKOKMXREO-UHFFFAOYSA-N 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical class C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
238000009736 wetting Methods 0.000 description 1
238000004804 winding Methods 0.000 description 1