BE544743A - - Google Patents

Info

Publication number

BE544743A

BE544743A BE544743DA BE544743A BE 544743 A BE544743 A BE 544743A BE 544743D A BE544743D A BE 544743DA BE 544743 A BE544743 A BE 544743A

Authority

BE

Belgium

Prior art keywords

added

bis

product

chloride

nitrobenzene

Prior art date

Links

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• VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 16
• LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 16
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 10
• 239000000047 product Substances 0.000 description 9
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
• 239000002585 base Substances 0.000 description 8
• 229910052736 halogen Inorganic materials 0.000 description 7
• 238000000034 method Methods 0.000 description 7
• 238000002360 preparation method Methods 0.000 description 7
• 150000002367 halogens Chemical class 0.000 description 6
• 150000003839 salts Chemical class 0.000 description 6
• 239000002904 solvent Substances 0.000 description 6
• 238000003756 stirring Methods 0.000 description 5
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
• 238000009833 condensation Methods 0.000 description 4
• 230000005494 condensation Effects 0.000 description 4
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• 238000009835 boiling Methods 0.000 description 3
• 229910052801 chlorine Inorganic materials 0.000 description 3
• 239000000460 chlorine Substances 0.000 description 3
• 150000001875 compounds Chemical class 0.000 description 3
• 238000000926 separation method Methods 0.000 description 3
• 239000011780 sodium chloride Substances 0.000 description 3
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
• ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
• 239000007859 condensation product Substances 0.000 description 2
• 238000001816 cooling Methods 0.000 description 2
• 150000004820 halides Chemical class 0.000 description 2
• 238000010438 heat treatment Methods 0.000 description 2
• 238000002844 melting Methods 0.000 description 2
• 230000008018 melting Effects 0.000 description 2
• 239000000203 mixture Substances 0.000 description 2
• 239000011541 reaction mixture Substances 0.000 description 2
• 229910052708 sodium Inorganic materials 0.000 description 2
• 239000011734 sodium Substances 0.000 description 2
• 229910000679 solder Inorganic materials 0.000 description 2
• 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
• YMDNODNLFSHHCV-UHFFFAOYSA-N 2-chloro-n,n-diethylethanamine Chemical compound CCN(CC)CCCl YMDNODNLFSHHCV-UHFFFAOYSA-N 0.000 description 1
• ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
• 235000014066 European mistletoe Nutrition 0.000 description 1
• 235000012300 Rhipsalis cassutha Nutrition 0.000 description 1
• 244000028419 Styrax benzoin Species 0.000 description 1
• 235000000126 Styrax benzoin Nutrition 0.000 description 1
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
• 235000008411 Sumatra benzointree Nutrition 0.000 description 1
• 241000221012 Viscum Species 0.000 description 1
• 239000002253 acid Substances 0.000 description 1
• 239000003513 alkali Substances 0.000 description 1
• 229910052783 alkali metal Inorganic materials 0.000 description 1
• 150000001340 alkali metals Chemical class 0.000 description 1
• 229940037003 alum Drugs 0.000 description 1
• 239000007864 aqueous solution Substances 0.000 description 1
• 229960002130 benzoin Drugs 0.000 description 1
• 239000006227 byproduct Substances 0.000 description 1
• 239000012141 concentrate Substances 0.000 description 1
• -1 diethylaminoethyl halide Chemical class 0.000 description 1
• 239000003814 drug Substances 0.000 description 1
• 235000019382 gum benzoic Nutrition 0.000 description 1
• 229910052740 iodine Inorganic materials 0.000 description 1
• 239000011630 iodine Substances 0.000 description 1
• 229910052751 metal Inorganic materials 0.000 description 1
• 239000002184 metal Substances 0.000 description 1
• 230000020477 pH reduction Effects 0.000 description 1
• 235000008001 rakum palm Nutrition 0.000 description 1
• 238000010992 reflux Methods 0.000 description 1
• 229920006395 saturated elastomer Polymers 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 239000012265 solid product Substances 0.000 description 1
• 239000000243 solution Substances 0.000 description 1