BE517686A - - Google Patents

Info

Publication number

BE517686A

BE517686A BE517686DA BE517686A BE 517686 A BE517686 A BE 517686A BE 517686D A BE517686D A BE 517686DA BE 517686 A BE517686 A BE 517686A

Authority

BE

Belgium

Prior art keywords

hexachlorobenzene

hours

catalyst

oxygen

reaction

Prior art date

Links

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• Global Dossier
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• 238000006243 chemical reaction Methods 0.000 claims description 42
• 239000003054 catalyst Substances 0.000 claims description 25
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 23
• 239000001301 oxygen Substances 0.000 claims description 23
• 229910052760 oxygen Inorganic materials 0.000 claims description 23
• CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 claims description 20
• 238000000034 method Methods 0.000 claims description 16
• JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 claims description 16
• 239000007789 gas Substances 0.000 claims description 12
• 238000004519 manufacturing process Methods 0.000 claims description 10
• 229910001868 water Inorganic materials 0.000 claims description 6
• 239000000725 suspension Substances 0.000 claims description 5
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
• ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 3
• 239000000126 substance Substances 0.000 claims 1
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 18
• 239000000047 product Substances 0.000 description 14
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
• 239000000460 chlorine Substances 0.000 description 9
• 229910052801 chlorine Inorganic materials 0.000 description 9
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
• 150000001875 compounds Chemical class 0.000 description 4
• 229910052802 copper Inorganic materials 0.000 description 4
• 239000010949 copper Substances 0.000 description 4
• 239000000463 material Substances 0.000 description 4
• 239000000203 mixture Substances 0.000 description 4
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• 150000001555 benzenes Chemical class 0.000 description 3
• 230000015572 biosynthetic process Effects 0.000 description 3
• 238000002360 preparation method Methods 0.000 description 3
• RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 2
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
• KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
• 238000007138 Deacon process reaction Methods 0.000 description 2
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
• WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
• 150000001805 chlorine compounds Chemical group 0.000 description 2
• 230000007423 decrease Effects 0.000 description 2
• 239000010419 fine particle Substances 0.000 description 2
• 239000004615 ingredient Substances 0.000 description 2
• 229910052751 metal Inorganic materials 0.000 description 2
• 239000002184 metal Substances 0.000 description 2
• 229910052759 nickel Inorganic materials 0.000 description 2
• -1 oxides Chemical class 0.000 description 2
• CEOCDNVZRAIOQZ-UHFFFAOYSA-N pentachlorobenzene Chemical class ClC1=CC(Cl)=C(Cl)C(Cl)=C1Cl CEOCDNVZRAIOQZ-UHFFFAOYSA-N 0.000 description 2
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
• MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
• 229910000831 Steel Inorganic materials 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• 239000011449 brick Substances 0.000 description 1
• 239000006227 byproduct Substances 0.000 description 1
• 239000001569 carbon dioxide Substances 0.000 description 1
• 229910002092 carbon dioxide Inorganic materials 0.000 description 1
• 230000003197 catalytic effect Effects 0.000 description 1
• 238000001311 chemical methods and process Methods 0.000 description 1
• 239000007795 chemical reaction product Substances 0.000 description 1
• 238000005660 chlorination reaction Methods 0.000 description 1
• 229910052804 chromium Inorganic materials 0.000 description 1
• 239000011651 chromium Substances 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 230000008025 crystallization Effects 0.000 description 1
• 238000007033 dehydrochlorination reaction Methods 0.000 description 1
• 238000000605 extraction Methods 0.000 description 1
• 238000001640 fractional crystallisation Methods 0.000 description 1
• 238000004508 fractional distillation Methods 0.000 description 1
• JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
• 229910001026 inconel Inorganic materials 0.000 description 1
• 239000011261 inert gas Substances 0.000 description 1
• 230000000749 insecticidal effect Effects 0.000 description 1
• 229910052742 iron Inorganic materials 0.000 description 1
• 229960002809 lindane Drugs 0.000 description 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
• 150000002739 metals Chemical class 0.000 description 1
• 239000012768 molten material Substances 0.000 description 1
• 150000002823 nitrates Chemical class 0.000 description 1
• 239000005416 organic matter Substances 0.000 description 1
• 230000003647 oxidation Effects 0.000 description 1
• 238000007254 oxidation reaction Methods 0.000 description 1
• 230000001590 oxidative effect Effects 0.000 description 1
• 239000002245 particle Substances 0.000 description 1
• 239000001103 potassium chloride Substances 0.000 description 1
• 235000011164 potassium chloride Nutrition 0.000 description 1
• 239000000843 powder Substances 0.000 description 1
• 238000000197 pyrolysis Methods 0.000 description 1
• 239000002994 raw material Substances 0.000 description 1
• 230000000717 retained effect Effects 0.000 description 1
• 239000000741 silica gel Substances 0.000 description 1
• 229910002027 silica gel Inorganic materials 0.000 description 1
• 235000011121 sodium hydroxide Nutrition 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000010959 steel Substances 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1