AU770334B2 - Activation and regeneration of a hydro-oxidation catalyst - Google Patents
Activation and regeneration of a hydro-oxidation catalyst Download PDFInfo
- Publication number
- AU770334B2 AU770334B2 AU22567/01A AU2256701A AU770334B2 AU 770334 B2 AU770334 B2 AU 770334B2 AU 22567/01 A AU22567/01 A AU 22567/01A AU 2256701 A AU2256701 A AU 2256701A AU 770334 B2 AU770334 B2 AU 770334B2
- Authority
- AU
- Australia
- Prior art keywords
- hydro
- catalyst
- oxidation
- titanium
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 238000007254 oxidation reaction Methods 0.000 title claims description 118
- 238000011069 regeneration method Methods 0.000 title claims description 67
- 230000008929 regeneration Effects 0.000 title claims description 55
- 230000004913 activation Effects 0.000 title claims description 33
- 238000000034 method Methods 0.000 claims description 164
- 230000008569 process Effects 0.000 claims description 135
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- 229910052751 metal Inorganic materials 0.000 claims description 72
- 239000002184 metal Substances 0.000 claims description 72
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 66
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 66
- 229910052719 titanium Inorganic materials 0.000 claims description 66
- 239000010936 titanium Substances 0.000 claims description 66
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 56
- 239000001301 oxygen Substances 0.000 claims description 56
- 229910052760 oxygen Inorganic materials 0.000 claims description 56
- 239000010931 gold Substances 0.000 claims description 47
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 46
- 229910052737 gold Inorganic materials 0.000 claims description 46
- -1 argori Substances 0.000 claims description 41
- 239000001257 hydrogen Substances 0.000 claims description 41
- 229910052739 hydrogen Inorganic materials 0.000 claims description 41
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 40
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 24
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- IZLAVFWQHMDDGK-UHFFFAOYSA-N gold(1+);cyanide Chemical compound [Au+].N#[C-] IZLAVFWQHMDDGK-UHFFFAOYSA-N 0.000 description 1
- 229910021505 gold(III) hydroxide Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- JFZUABNDWZQLIJ-UHFFFAOYSA-N methyl 2-[(2-chloroacetyl)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1NC(=O)CCl JFZUABNDWZQLIJ-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000012457 nonaqueous media Substances 0.000 description 1
- JOBYUFJYCWUMQS-UHFFFAOYSA-N oxotitanium;pentane-2,4-dione Chemical compound [Ti]=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O JOBYUFJYCWUMQS-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- 229930015698 phenylpropene Natural products 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- XTFKWYDMKGAZKK-UHFFFAOYSA-N potassium;gold(1+);dicyanide Chemical compound [K+].[Au+].N#[C-].N#[C-] XTFKWYDMKGAZKK-UHFFFAOYSA-N 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 1
- POSICDHOUBKJKP-UHFFFAOYSA-N prop-2-enoxybenzene Chemical compound C=CCOC1=CC=CC=C1 POSICDHOUBKJKP-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000001055 reflectance spectroscopy Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/12—Oxidising
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16986299P | 1999-12-09 | 1999-12-09 | |
| US60/169862 | 1999-12-09 | ||
| PCT/US2000/033385 WO2001041926A1 (en) | 1999-12-09 | 2000-12-07 | Activation and regeneration of a hydro-oxidation catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2256701A AU2256701A (en) | 2001-06-18 |
| AU770334B2 true AU770334B2 (en) | 2004-02-19 |
Family
ID=22617503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU22567/01A Ceased AU770334B2 (en) | 1999-12-09 | 2000-12-07 | Activation and regeneration of a hydro-oxidation catalyst |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7018948B2 (enExample) |
| EP (1) | EP1283747B1 (enExample) |
| JP (1) | JP2003519560A (enExample) |
| KR (1) | KR20030003219A (enExample) |
| CN (1) | CN1151891C (enExample) |
| AT (1) | ATE261341T1 (enExample) |
| AU (1) | AU770334B2 (enExample) |
| BR (1) | BR0016486A (enExample) |
| DE (1) | DE60008933T2 (enExample) |
| ES (1) | ES2213064T3 (enExample) |
| WO (1) | WO2001041926A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6562986B2 (en) * | 1997-06-30 | 2003-05-13 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
| JP2002532482A (ja) | 1998-12-16 | 2002-10-02 | ザ ダウ ケミカル カンパニー | オレフィンのオレフィンオキシドへの直接酸化法 |
| US6821923B1 (en) | 1999-04-08 | 2004-11-23 | Dow Global Technologies Inc. | Method of preparing a catalyst containing gold and titanium |
| ES2260459T3 (es) | 2001-08-01 | 2006-11-01 | Dow Global Technologies Inc. | Metodo para aumentar la duracion de un catalizador de hidro-oxidacion. |
| WO2004090937A2 (en) * | 2003-04-10 | 2004-10-21 | Technion Research & Development Foundation Ltd | Copper cmp slurry composition |
| US7541012B2 (en) | 2004-07-07 | 2009-06-02 | The Hong Kong University Of Science And Technology | Catalytic material and method of production thereof |
| DE102004059375A1 (de) | 2004-12-09 | 2006-06-22 | Consortium für elektrochemische Industrie GmbH | Auf nanoskaligem Titandioxid geträgerte Platin-Katalysatoren, deren Verwendung in der Hydrosilylierung, ein Hydrosilylierungsverfahren mit solchen Katalysatoren und Zusammensetzungen enthaltend solche Katalysatoren |
| US7494610B2 (en) * | 2005-08-30 | 2009-02-24 | The Hong Kong University Of Science And Technology | Methods for fabricating zeolite micromembranes |
| US7704908B2 (en) | 2005-12-22 | 2010-04-27 | Shell Oil Company | Method for reusing rhenium from a donor spent epoxidation catalyst |
| US7459589B2 (en) | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| US8357812B2 (en) | 2005-12-22 | 2013-01-22 | Shell Oil Company | Process for preparing a rejuvenated epoxidation catalyst |
| US20090325783A1 (en) * | 2008-06-30 | 2009-12-31 | Myers Daniel N | Oto quench tower catalyst recovery system utilizing a low temperature fluidized drying chamber |
| KR101844084B1 (ko) * | 2009-11-27 | 2018-03-30 | 바스프 에스이 | 티탄 제올라이트 촉매의 제조 방법 |
| WO2012017452A1 (en) | 2010-08-03 | 2012-02-09 | Aditya Birla Science And Technology Co. Ltd. | A process for regeneration of τγγανο silicate catalyst |
| US8742147B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| US8742146B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| CN102133547B (zh) * | 2011-03-02 | 2013-03-20 | 华南理工大学 | 一种钒钛基烟气脱硝催化剂的臭氧处理再生方法及装置 |
| US10598599B2 (en) | 2015-11-03 | 2020-03-24 | Savannah River Nuclear Solutions, Llc | Methods and materials for determination of distribution coefficients for separation materials |
| US10744488B2 (en) * | 2016-01-20 | 2020-08-18 | President And Fellows Of Harvard College | Ozone-activated nanoporous gold and methods of its use |
| US10994268B2 (en) * | 2017-05-03 | 2021-05-04 | Exxonmobil Chemical Patents Inc. | Processes for rejuvenating catalysts |
| CN109174075A (zh) * | 2018-09-04 | 2019-01-11 | 中国科学院上海硅酸盐研究所 | 一种用于光催化降解VOCs的稀土元素改性二氧化钛纳米光催化材料及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1048660A1 (en) * | 1999-04-28 | 2000-11-02 | Agency of Industrial Science and Technology | Manufacturing method of epoxides |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2029719B (en) | 1978-09-01 | 1982-12-08 | Mitsubishi Rayon Co | Method of regenerating an oxidized catalyst |
| AU641571B2 (en) * | 1990-11-28 | 1993-09-23 | Sumitomo Seika Chemicals Co., Ltd. | Method for treating gas and apparatus used therefor |
| US5183789A (en) * | 1991-03-11 | 1993-02-02 | Exxon Research And Engineering Company | Ozone regeneration of platinum, and polymetallic platinum reforming catalysts |
| US5365009A (en) * | 1993-04-14 | 1994-11-15 | Exxon Research And Engineering Company | Heterogeneous alkylation and regeneration of alkylation catalysts |
| DE4425672A1 (de) * | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
| JP2615432B2 (ja) * | 1994-10-28 | 1997-05-28 | 工業技術院長 | 金−酸化チタン含有触媒による炭化水素の部分酸化方法 |
| US5753576A (en) | 1995-05-18 | 1998-05-19 | Arco Chemical Technology, L.P. | Regeneration of a titanium-containing molecular sieve |
| DE19528220C1 (de) * | 1995-08-01 | 1997-01-09 | Degussa | Verfahren zur Regenerierung eines Katalysators und Verfahren zur Herstellung eines Epoxids in Gegenwart des Katalysators |
| DE19600708A1 (de) | 1996-01-11 | 1997-07-17 | Basf Ag | Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
| US5681789A (en) * | 1996-02-12 | 1997-10-28 | Arco Chemical Technology, L.P. | Activation of as-synthesized titanium-containing zeolites |
| EP0827779A4 (en) | 1996-03-21 | 1999-06-30 | Agency Ind Science Techn | CATALYSTS AND METHOD FOR PARTIAL OXIDATION OF HYDROCARBONS |
| JP4135818B2 (ja) * | 1997-03-03 | 2008-08-20 | 株式会社日本触媒 | 炭化水素の部分酸化用触媒および炭化水素の部分酸化方法 |
| BR9710995A (pt) | 1996-07-01 | 2000-03-14 | Dow Chemical Co | Processo para preparar um óxido de olefina, processo para preparar óxido de propileno, composição de catalisador e processo para regenerar uma composição de catalisador |
| BE1010717A3 (fr) * | 1996-10-25 | 1998-12-01 | Solvay | Procede de regeneration de catalyseurs. |
| US5798313A (en) * | 1996-12-20 | 1998-08-25 | Arco Chemical Technology, L.P. | Heterogeneous catalyst regeneration |
| DE19723949A1 (de) * | 1997-06-06 | 1998-12-10 | Basf Ag | Verfahren zur Regenerierung eines Zeolith-Katalysators |
| DE19723950A1 (de) * | 1997-06-06 | 1998-12-10 | Basf Ag | Verfahren zur Oxidation einer mindestens eine C-C-Doppelbindung aufweisenden organischen Verbindung |
| JP4282096B2 (ja) | 1997-06-30 | 2009-06-17 | ダウ・グローバル・テクノロジーズ・インコーポレーテッド | オレフィンオキシドへのオレフィンの直接酸化法 |
| DE19804711A1 (de) | 1998-02-06 | 1999-08-12 | Bayer Ag | Verfahren zur Regenerierung von mit Goldteilchen belegten Trägerkatalysatoren für die Oxidation ungesättigter Kohlenwasserstoffe |
| DE19804712A1 (de) | 1998-02-06 | 1999-08-12 | Bayer Ag | Verfahren zur Standzeitverlängerung von mit Goldteilen belegten Trägerkatalysatoren für die Oxidation ungesättigter Kohlenwasserstoffe |
| US5939569A (en) * | 1998-03-10 | 1999-08-17 | Jones; C. Andrew | Epoxidation process |
| JP2002532482A (ja) | 1998-12-16 | 2002-10-02 | ザ ダウ ケミカル カンパニー | オレフィンのオレフィンオキシドへの直接酸化法 |
| AU4335100A (en) | 1999-04-08 | 2000-10-23 | Dow Chemical Company, The | Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst |
-
2000
- 2000-12-07 AT AT00986298T patent/ATE261341T1/de not_active IP Right Cessation
- 2000-12-07 AU AU22567/01A patent/AU770334B2/en not_active Ceased
- 2000-12-07 KR KR1020027007287A patent/KR20030003219A/ko not_active Withdrawn
- 2000-12-07 WO PCT/US2000/033385 patent/WO2001041926A1/en not_active Ceased
- 2000-12-07 US US10/148,804 patent/US7018948B2/en not_active Expired - Fee Related
- 2000-12-07 JP JP2001543261A patent/JP2003519560A/ja active Pending
- 2000-12-07 CN CNB008181780A patent/CN1151891C/zh not_active Expired - Fee Related
- 2000-12-07 BR BR0016486-0A patent/BR0016486A/pt active Search and Examination
- 2000-12-07 EP EP00986298A patent/EP1283747B1/en not_active Expired - Lifetime
- 2000-12-07 ES ES00986298T patent/ES2213064T3/es not_active Expired - Lifetime
- 2000-12-07 DE DE60008933T patent/DE60008933T2/de not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1048660A1 (en) * | 1999-04-28 | 2000-11-02 | Agency of Industrial Science and Technology | Manufacturing method of epoxides |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1283747B1 (en) | 2004-03-10 |
| CN1414884A (zh) | 2003-04-30 |
| KR20030003219A (ko) | 2003-01-09 |
| WO2001041926A1 (en) | 2001-06-14 |
| CN1151891C (zh) | 2004-06-02 |
| ATE261341T1 (de) | 2004-03-15 |
| AU2256701A (en) | 2001-06-18 |
| ES2213064T3 (es) | 2004-08-16 |
| EP1283747A1 (en) | 2003-02-19 |
| JP2003519560A (ja) | 2003-06-24 |
| DE60008933T2 (de) | 2005-01-05 |
| BR0016486A (pt) | 2002-11-26 |
| DE60008933D1 (de) | 2004-04-15 |
| US7018948B2 (en) | 2006-03-28 |
| US20030212283A1 (en) | 2003-11-13 |
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