AU739809B2 - Treatment method for cork material and corks - Google Patents
Treatment method for cork material and corks Download PDFInfo
- Publication number
- AU739809B2 AU739809B2 AU27167/99A AU2716799A AU739809B2 AU 739809 B2 AU739809 B2 AU 739809B2 AU 27167/99 A AU27167/99 A AU 27167/99A AU 2716799 A AU2716799 A AU 2716799A AU 739809 B2 AU739809 B2 AU 739809B2
- Authority
- AU
- Australia
- Prior art keywords
- cork
- corks
- irradiation
- microwaves
- per
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/003—Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
- B27K5/0055—Radio-waves, e.g. microwaves
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/08—Radiation
- A61L2/12—Microwaves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K7/00—Chemical or physical treatment of cork
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67B—APPLYING CLOSURE MEMBERS TO BOTTLES JARS, OR SIMILAR CONTAINERS; OPENING CLOSED CONTAINERS
- B67B1/00—Closing bottles, jars or similar containers by applying stoppers
- B67B1/03—Pretreatment of stoppers, e.g. cleaning, steaming, heating, impregnating or coating; Applying resilient rings to stoppers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/10—Extraction of components naturally occurring in wood, cork, straw, cane or reed
Description
17482.3 PCT/EP99/00174. Translation of application as amended on March 27, 2000.
Treatment Method for Cork Material and Corks The present invention concerns a treatment method, in particular, for the sterilization and for the reduction of chemical contamination in cork material and corks.
Natural cork from the bark of the cork tree (Quercus suber) has been utilized since antiquity in large quantities for the sealing of bottles, tubes and the like. Bottle corks for high quality products, e.g. wine and sparkling wine, can be produced in differing manners and have different compositions. One can stamp the corks out of the cork bark of ~the cork oak to obtain a single piece of cork (natural cork).
Alternatively, conventional agglomerate corks can be made from ground cork material with the addition of a binding agent either as individual or extruded products. Natural cork sheets and agglomerate bodies can also be combined into corks.
The harvested and stored plates of cork bark (cork wood) are prepared for further processing via a boiling process during which a change in the cell structure effects the high *2O j elasticity of the cork. Contaminants can thereby gain access to the cork material due to impurities in the water. Air 2 drying is normally used to adjust the water content of the cork plates to the desired value throughout the subsequent storage period (stabilization) of normally up to 21 days.
During this period, bacteria or mold can develop in and on the cork material.
The natural cork is subsequently stamped out of the cork bark using a suitable device and subjected to a chemical bleaching process preferentially based on peroxide or on chlorine bleach. Further processing then follows using differing oO. external processing agents. Natural cork sheets for sparkling wine corks or composite wine corks made from a combination of 0@ S natural cork sheet and agglomerate bodies are stamped out of thin layers of natural cork, the outer layers of which are previously removed.
S Agglomerate corks are produced from ground unused residue in @065 natural cork production (ca. 60% of a cork plate). The
S.
granulated material is, in dependence on the quality of the agglomerate cork material to be produced, cleaned to a greater or lesser degree, mixed with bonding agents (e.g.
polyurethane glue) and shaped in an extrusion procedure or in a single piece processing procedure. For the case of combined corks, agglomerate bodies and natural cork sheets are joined using various glues.
-d.ixng the course of these differing production processes, a rQ increase in the microorganism content on or in the 3 cork or corks can occur for various reasons, either due to new external contamination or due to an improvement in environmental conditions associated with the increase in internal temperature and moisture. Modern gluing techniques require long stabilizing periods during the course of which a large increase in the number of microorganisms can occur.
In addition, a degree of chemical contamination can also occur in the cork material for differing reasons. Cooperation between microbiological metabolism selectivity in the presence of chemical contaminants can lead to a strong enrichment in metabolism products, such as the conventional 00 2,4,6-trichloroanisol causing the characteristic cork flavor.
The production of this latter material, according to the current state of knowledge, is only due to microbiological metabolization of chemical precursors. Two other metabolizing o products are l-octen-3-ol, causing the strong wild mushroom
OOSS
aroma and guaiacol, causing a medical/or burnt taste discoloration. In addition, a plurality of chemical contaminants can lead directly, i.e. without intermediate metabolization, to tainting accents.
To solve or to reduce the above mentioned problems in conventional industrial cork production, the cork material or the corks are treated with peroxides. However, this does not lead to deep-acting sterilization, since the solutions do not penetrate into the cork or only to a very insignificant <gRamount due to the poor permeability of cork with regard to liquids. In addition, a reduction in chemical contaminants is not thereby achieved. Adjustment of the water content using the currently applied hot air treatment is associated with wide fluctuations, since cork is an extraordinarily good heat insulator.
It is thereby the underlying purpose of the present invention to create a treatment method for cork materials and cork by means of which not only the surface but also the inner portions of the respective cork are reached with the desired sterilization without damaging the cork material itself and which can be carried out under economical conditions, wherein contamination of the cork is also reduced. In addition, agglomerate corks and combined corks should be improved with regard to the curing of the glue.
0005 This purpose is achieved through the treatment method @0er articulated by the features in the main claim and enhanced by the features of the dependent claims.
In order to guarantee an event treatment, in dependence on the manufacturing phase in which microwaves are applied, cork wood plates following the cooking procedure) or previously stamped-out cork, cork sheets, cork granulated material, freshly glued cork or other intermediate and end products are appropriately dispensed onto a conveyor belt and transported though a microwave installation to be irradiated fTn with microwaves.
Since the materials being treated have differing compositions, quality and water content, the energy used as well as the irradiation time for the microwaves has to be adjusted to the respective initial conditions (cork type or types, cork quality and water content) and to the desired result.
The energy and the processing time are thereby determined in dependence on need and checked by suitable analytic methods.
These quantities depend on additional boundary conditions @000 such as the moisture and the temperature of the ambient air 0@ as well as on the size and configuration of the microwave S. installation used.
In order to guarantee a homogeneous irradiation of the cork being processed, the corks are either irradiated in a closed 0ee* microwave oven or preferentially in a continuous conveyor 0e belt microwave oven. An irradiation dose of 15 to 1000 W per kg of cork during an irradiation time of 2.5 to 30 minutes has turned out to be particularly appropriate. A microwave seg oven power of 0.1 to 4 kW/h per kg of cork, preferentially approximately 0.5 kW/h per kg, normally leads to very good sterility for the cork material. Lower power levels only lead to a partial drying of the cork but not to sterilization. In fact, lower irradiation doses have led to increased contamination compared to cork which has not been treated i' ith microwaves. This is due to the production of temperatures within the cork of 30 to 40 0 C which are advantageous for an amplified replication of microorganisms.
Irradiation exceeding the power levels indicated above leads to an overheating of the cork material and thereby to excessive drying out and decomposition so that such treatment should be avoided. Complete sterilization is normally achieved. The risk of microbiological production of chemical compounds in cork which can be sensed and which are the primary causes of subsequent negative aromatic and taste changes in wine, sparkling wine and other beverages sealed with corks, is thereby substantially reduced.
free*: As a positive side effect of the sterilization, corks having
C-
relatively strong initial moisturization with water contents of approximately 6 to 20%, as are obtained following bleaching and subsequent washing processes, are homogeneously OB O a a dried to an even moisture of approximately 4 to 10%, which is 0509 a a optimal for processing.
S o 0 a A reduction in chemical contamination is also effected under these conditions. The risk of direct taste discoloration due aaa.ao to the migration of contaminants, which can lead to aromatic a or taste changes without an intermediate microbiological metabolization, are significantly reduced by the processing as is the risk of taste discoloration due to the migration of contaminants which are first transformed into compounds which can be sensed after microbiological metabolization.
With regard to the production of agglomerate corks or of combined corks comprising agglomerate corks and natural cork sheets sparkling wine corks, so-called 1+1 corks), the method leads to a more rapid polymerization and curing of the polyurethane binding agent currently used. A particular improvement is achieved in the presently used "sheet glue" (binding the agglomerate blank of the sparkling wine cork or of the 1+1 cork to the natural cork sheet) with which the socalled "stabilization phase" subsequent to gluing and prior to further processing can be substantially reduced.
By means of the thoroughly precise adjustment of the water content of the cork and of the intermediate cork product with the assistance of the new method, a significantly higher S. quality is achieved with regard to the application and binding of external processing agents which determine the sealing behavior of the cork and, moreover, guarantee a Sproper closing and opening of the bottles.
oooo •vii The substantial advantage of the microwave treatment compared to the thermal method is due to a fundamental shortcoming common to all types of thermal cork treatment: its substantially low heat conductivity. Using a thermal treatment applied externally, the required temperature increase is limited to the outer region of the cork or corks and decreases continuously towards the inner portion of the cork.
In contrast thereto, the microwaves excite, with the speed of light and with associated very high penetration depths, water and other molecules which can be excited by microwaves and which are located in the material being processed to thereby lead to a very rapid and homogeneous warming-up or heating of the material being processed without formation of temperature gradients. The higher the water content of the material being treated, the more effective the transformation of the microwaves into heat. This explains the bacterial reduction and sterilizing effect of the microwaves, which is due to a very effective transformation of the microwaves into heat in the cell water of the microorganisms to kill-off same.
oooo Seos..
So. The water content of the microwave-treated material can be S continuously monitored under production conditions using appropriate sensor technology (contactless IR-measurement techniques, pyrometers, etc.), since the reduction in water 555.
content is associated with a reduced transformation of sees •go• microwave energy into heat permitting a precisely calculable and predictable temperature dependence in the material being processed.
The reduction in chemical contamination is due: to direct excitation of the compounds to be removed and thereby to a heating up and increased vapor pressure of the corresponding components, leading to a rapid out-gassing of the cork material, and/or to a co-distillation effect occurring during evaporation of water out of the cork material being processed and/or to an increased out-gassing due to the increased temperature in the cork materials associated with the excitation of the water.
In a preferred embodiment, the cork material is continuously transported through a continuous conveyor belt microwave installation to achieve the purposes delineated above.
S..
Clearly, it is also possible to use other conventional types of microwave continuous flow ovens or dryers which have been commercially available for several years.
0 The experimentally utilized microwave continuous flow oven permitted adjustments of the microwave power in a heating 0000 Szone of approximately 2000 mm up to 4.0 kW, wherein the @555 o product to be irradiated could be transported on a conveyor belt having a belt speed between 0 and 2 m/min with a conveyor belt width of 290 mm. In order to investigate sterilization, the cork was placed together on the conveyor belt and transported through the oven with a throughput velocity between 2 to 10 minutes. The microwave power was between 500 and 4000 Watt. As can be seen in table i, the microbiological activity of non-treated cork is increased by weak microwave irradiation, wherein up to a doubling of the /STNX tivity can occur which, with the subsequent higher irradiation density used in accordance with the invention, rapidly sinks to approximately zero.
Table 1: The Microwave Treatment of Cork for Purposes of Sterilization: Energy acceptance microbiological Activity per kg Cork in Watts (CORA Factor) non-treated 1.075 1.055 1.260 15 2.020 100 0.019 Table 2 shows the reduction of three exemplary chemical contaminants (trichloromethane, dichlorobenzole and 2,4,6trichloroanisol). The microwave treatment was thereby carried out at an irradiation of 4 kW with an oven flow through time of 10 minutes with a charge of 1 kg of cork, a reasonable irradiation for successful sterilization. It has turned out
B
that approximately 90% of both products are driven off. The out-gassing is thereby probably due both to an increase in the vapor pressure of the respective component through heating of the cork material as well as to a co-distillation evaporation together with the expelled water.
Table 2: The Microwave Treatment of Cork for PurDoses of Chemical Decontamination: Energy acceptance per kg cork in Watt Trichloromethane Ag/g cork 125 12.5 untreated 100 125 12.5 9.
9e t o o 0 9 a.
p.
Energy acceptance per kg cork in Watt Dichlorobenzole #g/g cork non-treated 100
I
8.9 0.89 *Ob.
0
C
00 a.
a..
0e 0 Energy acceptance per kg of cork in Watt untreated 100 2,4,6-trichloroanisol ng/g cork The manufacturing and treatment method is described more closely below for differing types of cork: In all cases, the bark of the cork oak is initially harvested, subsequently subjected to a curing process, and boiled. For purposes of sterilization and pre-sterilization >r decontamination, the cork bark pieces are then subjected to a microwave energy of 15 to 250 W/(kg cork), wherein the energy applied depends on the moisture of the cork bark pieces.
For production of single piece natural corks, same are subsequently punched out of the cork bark pieces and are then subjected to renewed irradiation with microwaves at a power of 50 to 200 W/(kg cork) to achieve substantial sterilization and decontamination. Natural cork sheets used for sparkling wine and champagne corks are produced and processed in a similar manner.
After scraping-off the natural corks, same are bleached with ooooo
H
2 0 2 (peroxide) and subsequently dried to a desired moisture content through renewed irradiation of microwave energy of to 150 W/(kg cork) .Ges. For the production of agglomerate corks or combined corks, a
S.C.
granulated material is produced from material residues
SC..
occurring during the punching-out of the natural cork, the o moisture of which is adjusted to a desired value through irradiation of microwave energies from 50 to 200 W/(kg cork)
CS
and thereby simultaneously sterilized and decontaminated.
A
cork blank is then produced from the granulated material with the addition of glue in a single piece production method or in extrusion process, which is glued to the previously produced natural cork sheet. The corks produced in this manner are subjected to irradiation with microwave energy of to 150 W/(kg cork) for stabilization of the glue, wherein an approximately complete sterilization and decontamination are thereby simultaneously achieved.
4 to 6 weeks of time can sometimes pass between production of the corks and delivery to customers, so that the cork may have an insufficient amount of moisture (less than in certain isolated cases. In this event, the corks are moistened by spraying on water and the moisture content is subsequently adjusted to the desired level using the microwave energy, wherein renewed sterilization and decontamination are effected.
0 0 0000 0000@@ 0
*S
0 0 *0
Claims (6)
1. Method for manufacturing single pieces of decontaminated and sterilized corks from cork material, wherein the corks are stamped out of pieces of cork bark and subsequently subjected to irradiation with microwaves with a power of to 200 W per kg of cork for a duration of 2.5 to 30 minutes to decontaminate and sterilize, the cork subsequently being ground and bleached and/or washed and then subjected to renewed irradiation with microwaves with a power between to 150 W per kg of cork.
2. The method of claim 1, characterized in that the corks are disposed next to one another on a conveyor belt and transported therewith through a continuous flow-through microwave oven.
3. The method of claim 1 or 2, characterized in that the corks are moistened 4 to 6 weeks after manufacture by spraying water, wherein the moisture content is adjusted to a desired level through the influence of microwave energy. method of claim 3, characterized in that the moisture content is adjusted to 4 to 10 by weight. Method for manufacturing decontaminated and sterilized cork from a combination of agglomerate and cork sheets, wherein the cork sheets are stamped out of pieces of cork bark and subsequently subjected to an irradiation with microwaves with a power of 250 W per kg of cork for a duration of to 30 minutes for decontamination and sterilization, wherein a cork granulate is produced from residual cork and, for sterilization and decontamination, is subjected to *irradiation with microwaves with a power of 50 to 200 W per kg of cork for a duration of 2.5 to 30 minutes, wherein a cork blank is subsequently produced from the cork granulate S" by the addition of a glue, the cork blank then being joined with and glued to the independently produced cork sheets. *o
6. The method of claim 5, characterized in that the cork o• granulate and/or cork sheets are disposed next to one another on a conveyor belt and transported therewith through a continuous flow-through microwave oven.
7. The method of claim 5 or 6, characterized in that the moisture content of the cork granulate and/or cork sheets is adjusted to 4 to 10 by weight through irradiation of microwave energy.
8. The method of any one of the claims 5 through 7, characterized in that the glued cork is subjected to 16 renewed irradiation with microwaves of power between 20 to 150 W per kg of cork to stabilize the glue. DATED THIS 23rd day of August 2001 RUDOLF OHLINGER GMBH CO. KG; FRANCISCO OLLER, S.A.; JUVENAL FERREIRA DA SILVA, LDA. Patent Attorneys for the Applicants:- F B RICE CO S. S.. 5 S 5* 5 S 5* S. S. S 555555 S S S 55 S S 5 S. S 55 S S S. S S. S N9 -o
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19802297A DE19802297C5 (en) | 1998-01-22 | 1998-01-22 | Treatment methods for cork and cork |
DE19802297 | 1998-01-22 | ||
PCT/EP1999/000174 WO1999037334A2 (en) | 1998-01-22 | 1999-01-14 | Treatment method for cork material and corks |
Publications (2)
Publication Number | Publication Date |
---|---|
AU2716799A AU2716799A (en) | 1999-08-09 |
AU739809B2 true AU739809B2 (en) | 2001-10-18 |
Family
ID=7855335
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU27167/99A Ceased AU739809B2 (en) | 1998-01-22 | 1999-01-14 | Treatment method for cork material and corks |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP1049492B8 (en) |
CN (1) | CN1288389A (en) |
AR (1) | AR014447A1 (en) |
AT (1) | ATE370751T1 (en) |
AU (1) | AU739809B2 (en) |
CA (1) | CA2319351C (en) |
DE (1) | DE19802297C5 (en) |
ES (1) | ES2310030T3 (en) |
HU (1) | HUP0101133A3 (en) |
NZ (1) | NZ505790A (en) |
PT (1) | PT1049492E (en) |
WO (1) | WO1999037334A2 (en) |
ZA (1) | ZA99396B (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10008512C2 (en) * | 2000-02-24 | 2003-06-18 | Linn High Therm Gmbh | Device for treating bottle corks |
FR2805995B1 (en) * | 2000-03-10 | 2003-04-18 | Thales Sa | METHOD AND INSTALLATION FOR DISINFECTING WOODEN ELEMENTS IN CONTACT WITH FOODSTUFFS |
DE10101981B4 (en) * | 2001-01-18 | 2006-06-01 | Linn High Therm Gmbh | Apparatus for producing agglomerate bodies |
DE10101980B4 (en) * | 2001-01-18 | 2005-02-24 | Linn High Therm Gmbh | Device for treating a bulk material, in particular cork granules |
FR2821287B1 (en) | 2001-02-27 | 2003-05-02 | Jean Paul Obrecht | MACHINE FOR TREATING CORK PLUG |
WO2006021225A1 (en) * | 2004-08-24 | 2006-03-02 | Hartwig Pollinger | Method and device for the treatment of cork oaks |
PT103697A (en) * | 2007-03-21 | 2008-09-30 | Amorim Isolamentos S A | PRE-EXPANSION PROCESS OF CORK BY SUBMISSION TO MICROWAVE RADIATIONS AND RESULTING PRODUCT THEREOF |
ITTO20090226A1 (en) * | 2009-03-24 | 2010-09-25 | Mar Co Martini Costruzioni Di Mart Ini Marco | UNIT AND METHOD OF HEATING OF PORTIONS OF BOTTLE CAPS |
ITBA20120015A1 (en) * | 2012-03-01 | 2013-09-02 | Emitech S R L | METHOD TO EXTRACT ANOMALOUS AROMATIC COMPOUNDS AND THE 2,4,6, TRICHLOROANISOL (TCA) FROM THE CAPS AND THE CORK OF NATURAL CORK THROUGH A CONTINUOUS THERMAL PROCESS ASSISTED BY ELECTROMAGNETIC ENERGY TO HYPERFREQUENCES. |
ES2423255B1 (en) | 2012-03-13 | 2014-10-01 | Universidad De Salamanca | Procedure for the elimination of haloanisols and halophenols present in the cork and installation to carry out said elimination |
Citations (2)
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---|---|---|---|---|
GB1126233A (en) * | 1964-09-02 | 1968-09-05 | Gerhard Greiner | An improved process for articles made wholly or partly from cork |
EP0360447A2 (en) * | 1988-09-19 | 1990-03-28 | Camland Products Limited | Bark treatment |
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AT281299B (en) * | 1964-10-09 | 1970-05-11 | Greiner & Soehne C A | Method for treating in a package, e.g. a foil packaging |
FR2478613A1 (en) * | 1980-03-18 | 1981-09-25 | Lemaire Freres Sa | Bottle cork heating device preceding corking point - uses microwave resonator for rapid heating without immersion, controlled by microprocessor and has pulverisation and removal devices |
US4456498A (en) * | 1982-08-10 | 1984-06-26 | Macmillan Bloedel Limited | Microwave applicator for continuous press |
AU572470B2 (en) * | 1982-09-03 | 1988-05-12 | Cork & Seals Pty. Limited | Process for treatment of natural cork |
ES8802283A1 (en) * | 1984-01-04 | 1986-12-01 | Cruz Plaja Jose | Cork agglomerate mfr. |
DE3430673A1 (en) * | 1984-08-21 | 1986-02-27 | Hermann Berstorff Maschinenbau Gmbh, 3000 Hannover | Device for the pasteurisation and sterilisation of free-flowing materials |
DE3639412A1 (en) * | 1986-11-18 | 1988-06-16 | Aro Lab | Pasteurisation and sterilisation of pulverulent and lumpy foods, spices and medicaments as well as stimulants by means of high frequency or ultrahigh frequency |
FR2645950A1 (en) * | 1989-04-18 | 1990-10-19 | Marzat Claude | Combined mechanical, electrical and electromagnetic device allowing optimised drying of corks or another product by the association of ventilation and the application of microwaves |
DE3934500A1 (en) * | 1989-10-16 | 1991-04-18 | Burkhard Prof Dr Ahlert | Sterilisation of foodstuffs, partic. spices and dried fruits - food particles are passed through chamber on conveyor belt and subjected to microwaves and ultrasonics |
ES2019514A6 (en) * | 1989-12-22 | 1991-06-16 | Saez Blas Serna | Method for manufacturing footwear insoles (inner soles, templates) |
ES2020371A6 (en) * | 1989-12-22 | 1991-08-01 | Saez Blas Serna | Installation for manufacturing insoles (inner soles, templates) for footwear |
DE4141976C2 (en) * | 1991-12-19 | 1993-12-16 | Lloyd Werft Bremerhaven Gmbh | Method and device for sanitizing pourable materials |
AT400691B (en) * | 1994-08-12 | 1996-02-26 | Schilcher Industrieanlagen Und | PRODUCTION PLANT FOR THE PRODUCTION OF A RAW PROFILE FROM ROD OR BOARD SHAPED SLATS |
AT410272B (en) * | 1994-08-12 | 2003-03-25 | M T T Maschinen Technik Thaler | HEATING DEVICE WITH A MICROWAVE GENERATOR |
-
1998
- 1998-01-22 DE DE19802297A patent/DE19802297C5/en not_active Expired - Fee Related
-
1999
- 1999-01-14 EP EP99907368A patent/EP1049492B8/en not_active Expired - Lifetime
- 1999-01-14 CA CA002319351A patent/CA2319351C/en not_active Expired - Fee Related
- 1999-01-14 NZ NZ505790A patent/NZ505790A/en unknown
- 1999-01-14 AU AU27167/99A patent/AU739809B2/en not_active Ceased
- 1999-01-14 AT AT99907368T patent/ATE370751T1/en not_active IP Right Cessation
- 1999-01-14 CN CN99802322A patent/CN1288389A/en active Pending
- 1999-01-14 ES ES99907368T patent/ES2310030T3/en not_active Expired - Lifetime
- 1999-01-14 PT PT99907368T patent/PT1049492E/en unknown
- 1999-01-14 WO PCT/EP1999/000174 patent/WO1999037334A2/en active IP Right Grant
- 1999-01-14 HU HU0101133A patent/HUP0101133A3/en unknown
- 1999-01-20 AR ARP990100225A patent/AR014447A1/en active IP Right Grant
- 1999-01-20 ZA ZA9900396A patent/ZA99396B/en unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1126233A (en) * | 1964-09-02 | 1968-09-05 | Gerhard Greiner | An improved process for articles made wholly or partly from cork |
EP0360447A2 (en) * | 1988-09-19 | 1990-03-28 | Camland Products Limited | Bark treatment |
Also Published As
Publication number | Publication date |
---|---|
HUP0101133A3 (en) | 2003-04-28 |
EP1049492B8 (en) | 2007-10-10 |
ES2310030T3 (en) | 2008-12-16 |
EP1049492A2 (en) | 2000-11-08 |
AR014447A1 (en) | 2001-02-28 |
HUP0101133A2 (en) | 2001-12-28 |
NZ505790A (en) | 2002-03-28 |
WO1999037334A3 (en) | 1999-09-23 |
CA2319351A1 (en) | 1999-07-29 |
ATE370751T1 (en) | 2007-09-15 |
PT1049492E (en) | 2007-10-23 |
DE19802297C1 (en) | 1999-07-22 |
CA2319351C (en) | 2006-09-12 |
DE19802297C5 (en) | 2004-05-27 |
CN1288389A (en) | 2001-03-21 |
ZA99396B (en) | 1999-07-20 |
AU2716799A (en) | 1999-08-09 |
WO1999037334A2 (en) | 1999-07-29 |
EP1049492B1 (en) | 2007-08-22 |
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