AU669684B2 - Catalyst and process for the polymerization and copolymerization of olefins - Google Patents

Catalyst and process for the polymerization and copolymerization of olefins Download PDF

Info

Publication number
AU669684B2
AU669684B2 AU31996/93A AU3199693A AU669684B2 AU 669684 B2 AU669684 B2 AU 669684B2 AU 31996/93 A AU31996/93 A AU 31996/93A AU 3199693 A AU3199693 A AU 3199693A AU 669684 B2 AU669684 B2 AU 669684B2
Authority
AU
Australia
Prior art keywords
group
formula
compound
polymerization
metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU31996/93A
Other languages
English (en)
Other versions
AU3199693A (en
Inventor
Volker Dolle
Walter Spaleck
Andreas Winter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6450335&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AU669684(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of AU3199693A publication Critical patent/AU3199693A/en
Application granted granted Critical
Publication of AU669684B2 publication Critical patent/AU669684B2/en
Assigned to BASELL POLYOLEFINE GMBH reassignment BASELL POLYOLEFINE GMBH Alteration of Name(s) in Register under S187 Assignors: HOECHST AKTIENGESELLSCHAFT
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AU31996/93A 1992-01-27 1993-01-25 Catalyst and process for the polymerization and copolymerization of olefins Ceased AU669684B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4202163 1992-01-27
DE4202163 1992-01-27

Publications (2)

Publication Number Publication Date
AU3199693A AU3199693A (en) 1993-07-29
AU669684B2 true AU669684B2 (en) 1996-06-20

Family

ID=6450335

Family Applications (1)

Application Number Title Priority Date Filing Date
AU31996/93A Ceased AU669684B2 (en) 1992-01-27 1993-01-25 Catalyst and process for the polymerization and copolymerization of olefins

Country Status (11)

Country Link
US (1) US5985784A (US06818585-20041116-C00001.png)
EP (1) EP0553757B1 (US06818585-20041116-C00001.png)
JP (1) JP3459272B2 (US06818585-20041116-C00001.png)
KR (1) KR100268539B1 (US06818585-20041116-C00001.png)
AT (1) ATE143384T1 (US06818585-20041116-C00001.png)
AU (1) AU669684B2 (US06818585-20041116-C00001.png)
CA (1) CA2088114A1 (US06818585-20041116-C00001.png)
DE (1) DE59303908D1 (US06818585-20041116-C00001.png)
ES (1) ES2093287T3 (US06818585-20041116-C00001.png)
TW (1) TW304963B (US06818585-20041116-C00001.png)
ZA (1) ZA93548B (US06818585-20041116-C00001.png)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06100614A (ja) * 1992-08-06 1994-04-12 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
TW298593B (US06818585-20041116-C00001.png) * 1993-02-12 1997-02-21 Hoechst Ag
US6166153A (en) * 1995-07-18 2000-12-26 Fina Technology, Inc. Process for the syndiotactic propagation of olefins
US6818585B2 (en) 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US6034192A (en) * 1998-12-30 2000-03-07 Univation Technologies, Llc Germanium bridged metallocenes producing polymers with increased melt strength
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6444765B1 (en) * 2000-06-14 2002-09-03 Equistar Chemicals, Lp Olefin polymerization process for producing broad MWD polymers
WO2003014166A1 (en) * 2001-08-07 2003-02-20 Denki Kagaku Kogyo Kabushiki Kaisha Process for producing polymer
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
EP1620479B1 (en) 2002-10-15 2013-07-24 ExxonMobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
BR0317318A (pt) 2002-12-16 2005-11-08 Basell Polyolefine Gmbh Preparação de sistemas catalisadores suportados contendo quantidades reduzidas de aluminoxanos
JP5695419B2 (ja) 2007-08-29 2015-04-08 アルベマール・コーポレーシヨン ジアルキルアルミニウム陽イオンの前駆剤から生じるアルミノキサン触媒活性剤、同物質の製造方法、ならびにオレフィンの触媒および重合におけるその用途
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
US20230110235A1 (en) * 2020-08-12 2023-04-13 Lg Chem, Ltd. Method for preparing supported metallocene catalyst, supported metallocene catalyst, and method for preparing polyolefin using the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0314797A1 (en) * 1987-04-20 1989-05-10 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for polymerizing olefin
EP0459264A2 (en) * 1990-05-24 1991-12-04 MITSUI TOATSU CHEMICALS, Inc. Method for preparing syndiotactic poly (alpha-olefin)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
DE3907965A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
ES2087145T3 (es) * 1989-10-10 1996-07-16 Fina Technology Catalizadores metalocenos con acidos de lewis y alkilo-aluminios.
EP0513380B2 (en) * 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Process for producing olefinic polymer
EP0516458B2 (en) * 1991-05-31 2007-12-19 Mitsui Chemicals, Inc. Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
US5308817A (en) * 1992-05-18 1994-05-03 Fina Technology, Inc. Metallocene catalyst component with good catalyst efficiency after aging
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0314797A1 (en) * 1987-04-20 1989-05-10 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for polymerizing olefin
EP0459264A2 (en) * 1990-05-24 1991-12-04 MITSUI TOATSU CHEMICALS, Inc. Method for preparing syndiotactic poly (alpha-olefin)

Also Published As

Publication number Publication date
DE59303908D1 (de) 1996-10-31
JPH06122706A (ja) 1994-05-06
ATE143384T1 (de) 1996-10-15
TW304963B (US06818585-20041116-C00001.png) 1997-05-11
JP3459272B2 (ja) 2003-10-20
ZA93548B (en) 1993-08-05
CA2088114A1 (en) 1993-07-28
EP0553757B1 (de) 1996-09-25
KR930016446A (ko) 1993-08-26
AU3199693A (en) 1993-07-29
EP0553757A1 (de) 1993-08-04
ES2093287T3 (es) 1996-12-16
KR100268539B1 (ko) 2000-10-16
US5985784A (en) 1999-11-16

Similar Documents

Publication Publication Date Title
AU648172B2 (en) Process for the preparation of syndiotactic polyolefins having a broad molecular weight distribution
AU656968B2 (en) Process for the preparation of polyolefins having a broad molecular weight distribution
AU630451B2 (en) Process for the preparation of ethylene polymers
US5696045A (en) Process for the preparation of polyolefins
US6197902B1 (en) Syndio-isoblock polymer and process for its preparation
EP0956308B1 (en) New homogeneous olefin polymerization catalyst composition
EP0664304B1 (en) Olefin polymerization catalyst and process for olefin polymerization
KR100244381B1 (ko) α-올레핀 중합체의 제조방법
EP0528041B1 (en) Novel transition metal compound and process for polymerizing olefin by using the same
JPH0632830A (ja) 触媒系の調製法、オレフィンの単独重合及び共重合法並びに少なくとも一種のオレフィンのポリマー及びコポリマー
MXPA97005210A (en) Catalyst system and process for the production of a polim
JPH07224079A (ja) メタロセン化合物
AU669684B2 (en) Catalyst and process for the polymerization and copolymerization of olefins
JPH06100613A (ja) α‐オレフィン重合体の製造法
JP4153062B2 (ja) 部分的に水素化されたπリガンドを含有するメタロセン
JPH08217816A (ja) 立体規則性ポリプロピレンの製造方法
JP3117257B2 (ja) ポリオレフィン製造用固体触媒およびポリオレフィンの製造方法
JPH06345817A (ja) 固体触媒成分およびこれを用いたオレフィンの重合方法
JPH06345816A (ja) 固体触媒成分およびこれを用いたオレフィンの重合方法
JP3408594B2 (ja) ポリオレフィンの製造方法
KR20030085390A (ko) 비대칭성 비가교형 메탈로센 화합물 및 이를 포함하는촉매 조성물
JP3160042B2 (ja) オレフィン重合用触媒およびオレフィンの重合方法
JP3144851B2 (ja) オレフィンの重合方法
JP3639865B2 (ja) オレフィンの重合方法
JPH0551411A (ja) オレフインの重合方法