AU606620B2 - Liquid cleaning products - Google Patents
Liquid cleaning products Download PDFInfo
- Publication number
- AU606620B2 AU606620B2 AU80167/87A AU8016787A AU606620B2 AU 606620 B2 AU606620 B2 AU 606620B2 AU 80167/87 A AU80167/87 A AU 80167/87A AU 8016787 A AU8016787 A AU 8016787A AU 606620 B2 AU606620 B2 AU 606620B2
- Authority
- AU
- Australia
- Prior art keywords
- product according
- cleaning product
- acid
- structurant
- solids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000007788 liquid Substances 0.000 title claims description 69
- 238000004140 cleaning Methods 0.000 title claims description 61
- 239000007787 solid Substances 0.000 claims description 107
- 239000002253 acid Substances 0.000 claims description 91
- 239000000203 mixture Substances 0.000 claims description 89
- 239000002904 solvent Substances 0.000 claims description 82
- 239000002245 particle Substances 0.000 claims description 65
- 239000004094 surface-active agent Substances 0.000 claims description 52
- -1 alkali-metal tripolyphosphate Chemical class 0.000 claims description 47
- 239000000463 material Substances 0.000 claims description 44
- 239000004615 ingredient Substances 0.000 claims description 36
- 125000000217 alkyl group Chemical group 0.000 claims description 33
- 150000007513 acids Chemical class 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- 239000004744 fabric Substances 0.000 claims description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 239000007844 bleaching agent Substances 0.000 claims description 20
- 239000012190 activator Substances 0.000 claims description 18
- 229910052783 alkali metal Inorganic materials 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 239000002736 nonionic surfactant Substances 0.000 claims description 16
- 238000003860 storage Methods 0.000 claims description 14
- 102000004190 Enzymes Human genes 0.000 claims description 12
- 108090000790 Enzymes Proteins 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 239000004927 clay Substances 0.000 claims description 10
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- 239000012876 carrier material Substances 0.000 claims description 9
- 230000003750 conditioning effect Effects 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 150000004965 peroxy acids Chemical class 0.000 claims description 7
- 238000005191 phase separation Methods 0.000 claims description 7
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 6
- 229910021532 Calcite Inorganic materials 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical group CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 239000000787 lecithin Substances 0.000 claims description 6
- 235000010445 lecithin Nutrition 0.000 claims description 6
- 229940067606 lecithin Drugs 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000002304 perfume Substances 0.000 claims description 5
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 5
- 235000011149 sulphuric acid Nutrition 0.000 claims description 5
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 230000007797 corrosion Effects 0.000 claims description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 3
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical group CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 150000003973 alkyl amines Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 239000004150 EU approved colour Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 125000003302 alkenyloxy group Chemical group 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 230000003641 microbiacidal effect Effects 0.000 claims description 2
- 239000011356 non-aqueous organic solvent Substances 0.000 claims description 2
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 claims description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 239000011343 solid material Substances 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims 1
- 239000000047 product Substances 0.000 description 62
- 150000003839 salts Chemical class 0.000 description 30
- 230000000694 effects Effects 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 28
- 238000004062 sedimentation Methods 0.000 description 26
- 239000003599 detergent Substances 0.000 description 24
- 238000001935 peptisation Methods 0.000 description 20
- 239000011734 sodium Substances 0.000 description 20
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 18
- 238000005259 measurement Methods 0.000 description 15
- 108010059892 Cellulase Proteins 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 229940106157 cellulase Drugs 0.000 description 13
- 235000014113 dietary fatty acids Nutrition 0.000 description 13
- 239000000194 fatty acid Substances 0.000 description 13
- 229930195729 fatty acid Natural products 0.000 description 13
- 239000000126 substance Substances 0.000 description 12
- 229920002257 Plurafac® Polymers 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- 229940088598 enzyme Drugs 0.000 description 10
- 230000009467 reduction Effects 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 150000001340 alkali metals Chemical class 0.000 description 9
- 239000000344 soap Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 7
- 230000007423 decrease Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003082 abrasive agent Substances 0.000 description 6
- 229940022682 acetone Drugs 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 239000007850 fluorescent dye Substances 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000003801 milling Methods 0.000 description 6
- 150000004682 monohydrates Chemical class 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 229920001983 poloxamer Polymers 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 108010084185 Cellulases Proteins 0.000 description 5
- 102000005575 Cellulases Human genes 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000002979 fabric softener Substances 0.000 description 5
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 241000894007 species Species 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 238000005273 aeration Methods 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 150000004967 organic peroxy acids Chemical class 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 238000002203 pretreatment Methods 0.000 description 4
- 230000002035 prolonged effect Effects 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 239000002841 Lewis acid Substances 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 108091005804 Peptidases Proteins 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 150000007517 lewis acids Chemical class 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
- 229960001922 sodium perborate Drugs 0.000 description 3
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 3
- 239000001117 sulphuric acid Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 150000003626 triacylglycerols Chemical class 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 235000019483 Peanut oil Nutrition 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000006177 alkyl benzyl group Chemical group 0.000 description 2
- 150000005215 alkyl ethers Chemical group 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 159000000013 aluminium salts Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 230000003625 amylolytic effect Effects 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052752 metalloid Inorganic materials 0.000 description 2
- 150000002738 metalloids Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 108010020132 microbial serine proteinases Proteins 0.000 description 2
- 239000002052 molecular layer Substances 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
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- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000003319 supportive effect Effects 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/60—Sulfonium or phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8625974 | 1986-10-30 | ||
| GB868625974A GB8625974D0 (en) | 1986-10-30 | 1986-10-30 | Non-aqueous liquid detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU8016787A AU8016787A (en) | 1988-05-05 |
| AU606620B2 true AU606620B2 (en) | 1991-02-14 |
Family
ID=10606550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU80167/87A Ceased AU606620B2 (en) | 1986-10-30 | 1987-10-27 | Liquid cleaning products |
Country Status (17)
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ225316A (en) * | 1987-07-15 | 1990-10-26 | Colgate Palmolive Co | Low density filler stabilised laundry compositions |
| US4931195A (en) * | 1987-07-15 | 1990-06-05 | Colgate-Palmolive Company | Low viscosity stable non-aqueous suspension containing organophilic clay and low density filler |
| US4830782A (en) * | 1987-08-31 | 1989-05-16 | Colgate-Palmolive Company | Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant and method of use |
| NZ226288A (en) * | 1987-09-30 | 1991-02-26 | Colgate Palmolive Co | Stable non-aqueous suspensions for fabrics |
| GB8810195D0 (en) * | 1988-04-29 | 1988-06-02 | Unilever Plc | Liquid cleaning products |
| US4988462A (en) * | 1988-04-29 | 1991-01-29 | Lever Brothers Company, Division Of Conopco, Inc. | Non-aqueous cleaning compositions containing bleach and capped nonionic surfactant |
| GB8810191D0 (en) * | 1988-04-29 | 1988-06-02 | Unilever Plc | Liquid cleaning products |
| CA1314186C (en) * | 1988-04-29 | 1993-03-09 | Frederik Jan Schepers | Liquid cleaning products |
| US5292448A (en) * | 1988-05-10 | 1994-03-08 | Lever Brothers Company, Division Of Conopco, Inc. | Enzymatic detergent composition |
| US4874537A (en) * | 1988-09-28 | 1989-10-17 | The Clorox Company | Stable liquid nonaqueous detergent compositions |
| GB8823705D0 (en) * | 1988-10-10 | 1988-11-16 | Unilever Plc | Liquid detergent products |
| GB8824110D0 (en) * | 1988-10-14 | 1988-11-23 | Unilever Plc | Liquid cleaning products |
| GB2228944A (en) * | 1989-03-08 | 1990-09-12 | Unilever Plc | Non-aqueous liquid cleaning composition |
| GB8909253D0 (en) * | 1989-04-24 | 1989-06-07 | Unilever Plc | Packaged liquid cleaning product |
| WO1991012313A1 (en) * | 1990-02-16 | 1991-08-22 | Unilever N.V. | Liquid cleaning products |
| DE69100402T2 (de) * | 1990-02-16 | 1994-01-13 | Unilever Nv | Flüssige reinigungsprodukte. |
| US5714449A (en) * | 1990-02-16 | 1998-02-03 | Unilever Patent Holdings B.V. | Non-aqueous liquid cleaning products which contain modified silica |
| DE4024531A1 (de) * | 1990-08-02 | 1992-02-06 | Henkel Kgaa | Fluessigwaschmittel |
| GB9020360D0 (en) * | 1990-09-18 | 1990-10-31 | Unilever Plc | Process and device for dosing detergent compositions |
| EP0490436A1 (en) * | 1990-12-10 | 1992-06-17 | Unilever N.V. | Use of non-aqueous detergent compositions |
| GB9123219D0 (en) * | 1991-11-01 | 1991-12-18 | Unilever Plc | Liquid cleaning products |
| US5516511A (en) * | 1994-05-06 | 1996-05-14 | The Procter & Gamble Company | Antiperspirant gel compositions comprising chelators |
| HUP9802501A3 (en) * | 1995-06-20 | 1999-08-30 | Procter And Gamble Company Cin | Nonaqueous, particulate-containing liquid detergent compositions with alkyl benzene sulfonate surfactant |
| US6225277B1 (en) * | 1995-10-09 | 2001-05-01 | The Procter & Gamble Company | Hard surface cleaning compositions |
| BR9710079A (pt) * | 1996-06-28 | 1999-08-10 | Procter & Gamble | Preparação de composições de detergente líquido não-aquoso que contêm partículado com fase líquida estruturada com tensoativo |
| US6576602B1 (en) * | 1996-06-28 | 2003-06-10 | The Procter & Gamble Company | Nonaqueous, particulate-containing liquid detergent compositions with surfactant-structured liquid phase |
| US5814592A (en) * | 1996-06-28 | 1998-09-29 | The Procter & Gamble Company | Non-aqueous, particulate-containing liquid detergent compositions with elasticized, surfactant-structured liquid phase |
| US5773405A (en) * | 1997-03-13 | 1998-06-30 | Milliken Research Corporation | Cleaner compositions containing surfactant and poly (oxyalkylene)-substituted reactive dye colorant |
| BR9810482A (pt) * | 1997-06-27 | 2000-09-12 | Procter & Gamble | Composições detergentes lìquidas, não aquosas, contendo salpicos |
| GB9803770D0 (en) * | 1998-02-23 | 1998-04-15 | Unilever Plc | Detergent compositions |
| US6461623B2 (en) * | 1998-04-13 | 2002-10-08 | Kao Corporation | Cosmetic composition |
| US5998358A (en) * | 1999-03-23 | 1999-12-07 | Ecolab Inc. | Antimicrobial acid cleaner for use on organic or food soil |
| US6565613B1 (en) * | 1999-04-29 | 2003-05-20 | Genencor International, Inc. | Cellulase detergent matrix |
| US6995125B2 (en) * | 2000-02-17 | 2006-02-07 | The Procter & Gamble Company | Detergent product |
| US6812199B2 (en) * | 2000-04-28 | 2004-11-02 | The Procter & Gamble Company | Method for treating stained materials |
| WO2001085892A1 (en) * | 2000-05-11 | 2001-11-15 | The Procter & Gamble Company | Highly concentrated fabric softener compositions and articles containing such compositions |
| AU7050301A (en) * | 2000-05-15 | 2001-11-26 | James Dawson Cropper | Liquid detergent composition |
| AU7971201A (en) * | 2000-07-06 | 2002-01-14 | Huntsman Int Llc | Solid-suspending systems |
| MXPA03000488A (es) * | 2000-07-19 | 2003-06-24 | Procter & Gamble | Composiciones para el lavado automatico de trastes en forma de gel, metodos de preparacion y uso de las mismas. |
| US7074748B2 (en) * | 2001-01-19 | 2006-07-11 | The Procter & Gamble Company | Liquid composition |
| US6492312B1 (en) | 2001-03-16 | 2002-12-10 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Water soluble sachet with a dishwashing enhancing particle |
| GB0114850D0 (en) * | 2001-06-18 | 2001-08-08 | Unilever Plc | Water soluble package and liquid contents thereof |
| US20050119150A1 (en) * | 2002-07-04 | 2005-06-02 | Ulrich Pegelow | Portioned detergent composition |
| US20050187137A1 (en) * | 2002-08-14 | 2005-08-25 | Ulrich Pegelow | Portioned cleaning agents or detergents containing phosphate |
| DE10237200A1 (de) * | 2002-08-14 | 2004-03-04 | Henkel Kgaa | Portionierte Wasch- oder Reinigungsmittelzusammensetzung |
| US20050187136A1 (en) * | 2002-08-14 | 2005-08-25 | Ulrich Pegelow | Portioned detergent compositions comprising phosphate II |
| CN101223312B (zh) * | 2005-09-23 | 2011-07-20 | 东洋制铁化学株式会社 | 非水液体氧漂白组合物 |
| US8394752B2 (en) * | 2008-12-18 | 2013-03-12 | The Procter & Gamble Company | Pearlescent agent slurry for liquid treatment composition |
| UA111166C2 (uk) * | 2010-08-27 | 2016-04-11 | Анітокс Корпорейшн | Композиція проти salmonella typhimurium та спосіб обробки корму для тварин |
| US8114344B1 (en) | 2010-12-21 | 2012-02-14 | Ecolab Usa Inc. | Corrosion inhibition of hypochlorite solutions using sugar acids and Ca |
| US8603392B2 (en) | 2010-12-21 | 2013-12-10 | Ecolab Usa Inc. | Electrolyzed water system |
| US8557178B2 (en) | 2010-12-21 | 2013-10-15 | Ecolab Usa Inc. | Corrosion inhibition of hypochlorite solutions in saturated wipes |
| US8114343B1 (en) | 2010-12-21 | 2012-02-14 | Ecolab USA, Inc. | Corrosion inhibition of hypochlorite solutions using Zn and Ca |
| US8729006B2 (en) * | 2011-06-28 | 2014-05-20 | Ecolab Usa Inc. | Methods and compositions using sodium carboxymethyl cellulose as scale control agent |
| ES2618638T5 (en) | 2011-10-20 | 2025-02-17 | Anitox Corp | Antimicrobial formulations with pelargonic acid |
| JP2015516486A (ja) * | 2012-04-12 | 2015-06-11 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 食器洗い用洗浄組成物 |
| DE102014202223A1 (de) | 2014-02-06 | 2015-08-06 | Henkel Ag & Co. Kgaa | Verwendung von Aminocarbonsäuren zur Stabilisierung von wasserarmen flüssigen Wasch- oder Reinigungsmittelkomponenten |
| JP2015199941A (ja) * | 2014-04-02 | 2015-11-12 | 花王株式会社 | 液体洗浄剤組成物 |
| US10030216B2 (en) | 2015-06-12 | 2018-07-24 | Crossford International, Llc | Systems and methods for cooling tower fill cleaning with a chemical gel |
| US9404069B1 (en) | 2015-06-12 | 2016-08-02 | Crossford International, Llc | Systems and methods for cooling tower fill cleaning with a chemical gel |
| MX2021014590A (es) | 2019-05-30 | 2022-01-11 | Ecolab Usa Inc | Sistema de dispensacion para transferir productos quimicos a un ensamblaje de cesta coladora. |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2178753A (en) * | 1985-08-05 | 1987-02-18 | Colgate Palmolive Co | Low phosphate, built, laundry detergent |
| GB2180551A (en) * | 1985-08-05 | 1987-04-01 | Colgate Palmolive Co | Phosphate free or low phosphate laundry detergent |
| GB2187199A (en) * | 1986-02-21 | 1987-09-03 | Colgate Palmolive Co | Built non-aqueous liquid laundry detergent compositions |
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| CA729145A (en) * | 1962-03-20 | 1966-03-01 | The Procter & Gamble Company | Built liquid detergent |
| LU52892A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1967-01-27 | 1968-08-28 | ||
| AT291414B (de) * | 1967-01-27 | 1971-07-12 | Unilever Nv | Wasch- und Reinigungsmitell |
| DK129804A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1969-01-17 | |||
| BE758553A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1969-11-11 | 1971-05-05 | Unilever Nv | |
| US3960742A (en) * | 1973-06-29 | 1976-06-01 | Chemical Cleaning Composition Trust | Water-dispersable solvent emulsion type cleaner concentrate |
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| GB1600981A (en) * | 1977-06-09 | 1981-10-21 | Ici Ltd | Detergent composition |
| NO781898L (no) * | 1977-06-09 | 1978-12-12 | Ici Ltd | Flytende vaskemiddelblanding. |
| DE3065073D1 (en) * | 1979-11-09 | 1983-11-03 | Unilever Nv | Non-aqueous, built liquid detergent composition and method for preparing same |
| DE3065199D1 (en) * | 1979-12-04 | 1983-11-10 | Ici Plc | Detergent composition |
| US4264466A (en) * | 1980-02-14 | 1981-04-28 | The Procter & Gamble Company | Mulls containing chain structure clay suspension aids |
| GB8308508D0 (en) * | 1983-03-28 | 1983-05-05 | Ici Plc | Detergent compositions |
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| EG16786A (en) * | 1984-03-23 | 1991-08-30 | Clorox Co | Low-temperature effective composition and delivery systems therefor |
| US4743394A (en) * | 1984-03-23 | 1988-05-10 | Kaufmann Edward J | Concentrated non-phosphate detergent paste compositions |
| GB2158838B (en) * | 1984-04-06 | 1987-10-28 | Colgate Palmolive Co | Liquid bleaching laundry detergent composition |
| ZA852197B (en) * | 1984-04-06 | 1986-11-26 | Colgate Palmolive Co | Liquid laundry detergent composition containing polyphosphate |
| GB2158454B (en) * | 1984-04-06 | 1988-05-18 | Colgate Palmolive Co | Liquid laundry detergent composition |
| FR2564318B1 (fr) * | 1984-05-15 | 1987-04-17 | Oreal | Composition anhydre pour le nettoyage de la peau |
| JPS6142597A (ja) * | 1984-08-06 | 1986-03-01 | 花王株式会社 | 非水系ペ−スト状洗浄剤組成物 |
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| MX162823B (es) * | 1985-03-29 | 1991-06-28 | Colgate Palmolive Co | Mejoras a composicion de detergente blanqueadora liquida para lavar ropa |
| JPS61227831A (ja) * | 1985-04-01 | 1986-10-09 | Nippon Oil & Fats Co Ltd | 非水系の固体分散剤 |
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| IN165978B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1985-08-20 | 1990-02-17 | Colgate Palmolive Co | |
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| US4753748A (en) * | 1986-08-28 | 1988-06-28 | Colgate-Palmolive Company | Nonaqueous liquid automatic dishwashing detergent composition with improved rinse properties and method of use |
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| US4797225A (en) * | 1986-09-08 | 1989-01-10 | Colgate-Palmolive Company | Nonaqueous liquid nonionic laundry detergent composition containing an alkali metal dithionite or sulfite reduction bleaching agent and method of use |
| NZ221505A (en) * | 1986-09-09 | 1989-08-29 | Colgate Palmolive Co | Liquid detergent compositions with peroxygen bleach and calcium cyanamide activator |
| NZ221555A (en) * | 1986-09-09 | 1989-08-29 | Colgate Palmolive Co | Detergent composition containing inorganic bleach and a liquid activator |
| AU602362B2 (en) * | 1986-10-29 | 1990-10-11 | Colgate-Palmolive Company, The | Built nonaqueous liquid nonionic laundry detergent composition containing hexylene glycol and method of use |
| US4830782A (en) * | 1987-08-31 | 1989-05-16 | Colgate-Palmolive Company | Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant and method of use |
-
1986
- 1986-10-30 GB GB868625974A patent/GB8625974D0/en active Pending
-
1987
- 1987-10-23 NZ NZ222288A patent/NZ222288A/xx unknown
- 1987-10-23 CA CA000550083A patent/CA1317182C/en not_active Expired - Fee Related
- 1987-10-27 CH CH4205/87A patent/CH678191A5/de not_active IP Right Cessation
- 1987-10-27 AU AU80167/87A patent/AU606620B2/en not_active Ceased
- 1987-10-28 IT IT8767903A patent/IT1211494B/it active
- 1987-10-28 NO NO874494A patent/NO170690C/no unknown
- 1987-10-29 EP EP87309568A patent/EP0266199B2/en not_active Expired - Lifetime
- 1987-10-29 ZA ZA878119A patent/ZA878119B/xx unknown
- 1987-10-29 GB GB8725339A patent/GB2197339B/en not_active Expired - Fee Related
- 1987-10-29 DE DE3751814T patent/DE3751814T3/de not_active Expired - Fee Related
- 1987-10-29 FR FR8714998A patent/FR2606026B2/fr not_active Expired - Fee Related
- 1987-10-29 ES ES87309568T patent/ES2086288T5/es not_active Expired - Lifetime
- 1987-10-29 BR BR8705776A patent/BR8705776A/pt not_active IP Right Cessation
- 1987-10-30 JP JP62275557A patent/JP2543726B2/ja not_active Expired - Fee Related
- 1987-10-30 TR TR87/0741A patent/TR25523A/xx unknown
- 1987-10-30 KR KR1019870012128A patent/KR920000899B1/ko not_active Expired
-
1988
- 1988-02-23 FR FR8802138A patent/FR2609042B1/fr not_active Expired - Fee Related
- 1988-02-23 FR FR888802137A patent/FR2609041B1/fr not_active Expired - Fee Related
-
1990
- 1990-12-21 US US07/631,761 patent/US5389284A/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2178753A (en) * | 1985-08-05 | 1987-02-18 | Colgate Palmolive Co | Low phosphate, built, laundry detergent |
| GB2180551A (en) * | 1985-08-05 | 1987-04-01 | Colgate Palmolive Co | Phosphate free or low phosphate laundry detergent |
| GB2187199A (en) * | 1986-02-21 | 1987-09-03 | Colgate Palmolive Co | Built non-aqueous liquid laundry detergent compositions |
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