AU2015336234A1 - Forward osmosis process for concentration of lithium containing solutions - Google Patents
Forward osmosis process for concentration of lithium containing solutions Download PDFInfo
- Publication number
- AU2015336234A1 AU2015336234A1 AU2015336234A AU2015336234A AU2015336234A1 AU 2015336234 A1 AU2015336234 A1 AU 2015336234A1 AU 2015336234 A AU2015336234 A AU 2015336234A AU 2015336234 A AU2015336234 A AU 2015336234A AU 2015336234 A1 AU2015336234 A1 AU 2015336234A1
- Authority
- AU
- Australia
- Prior art keywords
- solution
- membrane
- lithium
- flow
- forward osmosis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 165
- 230000008569 process Effects 0.000 title claims abstract description 159
- 238000009292 forward osmosis Methods 0.000 title claims abstract description 139
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 79
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 239000012528 membrane Substances 0.000 claims abstract description 196
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 92
- 230000003204 osmotic effect Effects 0.000 claims abstract description 65
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 47
- 239000000654 additive Substances 0.000 claims abstract description 10
- 239000000243 solution Substances 0.000 claims description 349
- 239000012267 brine Substances 0.000 claims description 122
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 122
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 38
- 230000004907 flux Effects 0.000 claims description 33
- 150000003839 salts Chemical class 0.000 claims description 28
- 229910003002 lithium salt Inorganic materials 0.000 claims description 25
- 159000000002 lithium salts Chemical class 0.000 claims description 25
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 22
- 239000011780 sodium chloride Substances 0.000 claims description 10
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000001110 calcium chloride Substances 0.000 claims description 8
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 8
- 229920002301 cellulose acetate Polymers 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 6
- 239000010409 thin film Substances 0.000 claims description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- 239000011630 iodine Substances 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Chemical class 0.000 claims description 3
- 229910052791 calcium Chemical class 0.000 claims description 3
- 239000010408 film Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical class [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 239000011777 magnesium Chemical class 0.000 claims description 2
- 229910052749 magnesium Chemical class 0.000 claims description 2
- 239000011591 potassium Chemical class 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 36
- 239000012266 salt solution Substances 0.000 abstract description 19
- 239000012141 concentrate Substances 0.000 abstract description 3
- 235000002639 sodium chloride Nutrition 0.000 description 34
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 14
- 239000000306 component Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- 229910001416 lithium ion Inorganic materials 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 7
- 235000011148 calcium chloride Nutrition 0.000 description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 description 7
- 235000011147 magnesium chloride Nutrition 0.000 description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000032258 transport Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000010612 desalination reaction Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000009616 inductively coupled plasma Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000012206 bottled water Nutrition 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 230000037427 ion transport Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000002572 peristaltic effect Effects 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- WHXSMMKQMYFTQS-BJUDXGSMSA-N (6Li)Lithium Chemical compound [6Li] WHXSMMKQMYFTQS-BJUDXGSMSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012527 feed solution Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- -1 lithium halide salts Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000009285 membrane fouling Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical group CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/58—Multistep processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/002—Forward osmosis or direct osmosis
- B01D61/0021—Forward osmosis or direct osmosis comprising multiple forward osmosis steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/04—Halides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/445—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by forward osmosis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/25—Recirculation, recycling or bypass, e.g. recirculation of concentrate into the feed
- B01D2311/252—Recirculation of concentrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2315/00—Details relating to the membrane module operation
- B01D2315/10—Cross-flow filtration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/001—Upstream control, i.e. monitoring for predictive control
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462065965P | 2014-10-20 | 2014-10-20 | |
| US62/065,965 | 2014-10-20 | ||
| PCT/US2015/056090 WO2016064689A2 (en) | 2014-10-20 | 2015-10-16 | Process for concentration of lithium containing solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2015336234A1 true AU2015336234A1 (en) | 2017-04-20 |
Family
ID=55310889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2015336234A Abandoned AU2015336234A1 (en) | 2014-10-20 | 2015-10-16 | Forward osmosis process for concentration of lithium containing solutions |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20180147532A1 (https=) |
| JP (1) | JP2017532197A (https=) |
| KR (1) | KR20170071502A (https=) |
| AR (1) | AR102363A1 (https=) |
| AU (1) | AU2015336234A1 (https=) |
| CA (1) | CA2963565A1 (https=) |
| CL (2) | CL2017000964A1 (https=) |
| WO (1) | WO2016064689A2 (https=) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4438749A3 (en) | 2016-11-14 | 2025-01-08 | Lilac Solutions, Inc. | Lithium extraction with coated ion exchange particles |
| US11839853B2 (en) * | 2017-01-20 | 2023-12-12 | Trevi Systems, Inc. | Osmotic pressure assisted reverse osmosis membrane and module |
| JP2018118186A (ja) * | 2017-01-23 | 2018-08-02 | 株式会社東芝 | 正浸透膜および水処理システム |
| AR112663A1 (es) | 2017-08-02 | 2019-11-27 | Lilac Solutions Inc | Extracción de litio con perlas porosas de intercambio iónico |
| US10439200B2 (en) | 2017-08-02 | 2019-10-08 | Lilac Solutions, Inc. | Ion exchange system for lithium extraction |
| US10648090B2 (en) | 2018-02-17 | 2020-05-12 | Lilac Solutions, Inc. | Integrated system for lithium extraction and conversion |
| KR102667270B1 (ko) * | 2018-02-17 | 2024-05-17 | 리락 솔루션즈, 인크. | 리튬 추출 및 전환을 위한 통합 시스템 |
| KR20200116526A (ko) | 2018-02-28 | 2020-10-12 | 리락 솔루션즈, 인크. | 리튬 추출을 위한 입자 트랩을 가진 이온 교환 반응기 |
| US11235282B2 (en) * | 2018-03-09 | 2022-02-01 | Terralithium Llc | Processes for producing lithium compounds using forward osmosis |
| US11174532B1 (en) | 2018-03-09 | 2021-11-16 | Terralithium Llc | Processes for producing lithium compounds using reverse osmosis |
| WO2020033668A1 (en) * | 2018-08-09 | 2020-02-13 | Ut-Battelle, Llc | Forward osmosis composite membranes for concentration of lithium containing solutions |
| JP7186557B2 (ja) * | 2018-09-14 | 2022-12-09 | 旭化成株式会社 | 溶媒含有物品の濃縮システム |
| CL2020001650A1 (es) | 2019-06-18 | 2021-01-29 | Schlumberger Technology Bv | Extracción de litio |
| CN112108001B (zh) * | 2019-06-20 | 2022-09-13 | 国家能源投资集团有限责任公司 | 一种反渗透系统及其浓缩含锂盐水的方法 |
| US12297519B2 (en) | 2019-09-25 | 2025-05-13 | Veolia Water Solutions & Technologies Support | Energy efficient process for concentrating and recovering lithium from a lithium containing brine |
| KR20220119166A (ko) | 2020-01-09 | 2022-08-26 | 리락 솔루션즈, 인크. | 바람직하지 않은 금속의 분리 방법 |
| GB202003685D0 (en) * | 2020-03-13 | 2020-04-29 | Ide Projects Ltd | Forward osmotic separation system and method |
| CA3178825A1 (en) | 2020-06-09 | 2021-12-16 | David Henry SNYDACKER | Lithium extraction in the presence of scalants |
| US12391566B2 (en) | 2020-08-21 | 2025-08-19 | Schlumberger Technology Corporation | Lithium extraction improvements |
| CA3199218A1 (en) | 2020-11-20 | 2022-05-27 | David Henry SNYDACKER | Lithium production with volatile acid |
| KR20240014047A (ko) | 2021-04-23 | 2024-01-31 | 리락 솔루션즈, 인크. | 리튬 추출을 위한 이온 교환 장치 |
| AU2022317068A1 (en) | 2021-07-30 | 2024-02-15 | Schlumberger Technology B.V. | Lithium recovery thermal management |
| US20230032153A1 (en) * | 2021-07-30 | 2023-02-02 | Schlumberger Technology Corporation | Lithium purification and conversion |
| US12215035B2 (en) * | 2021-07-30 | 2025-02-04 | Schlumberger Technology Corporation | Lithium purification and conversion |
| US20250128211A1 (en) * | 2021-08-26 | 2025-04-24 | Massachusetts Institute Of Technology | Harnessing Metal Ions from Brines |
| US12590539B2 (en) | 2022-03-14 | 2026-03-31 | Schlumberger Technology Corporation | Systems and methods for analysis of drilling fluid |
| EP4499260A4 (en) | 2022-03-28 | 2026-04-01 | Lilac Solutions Inc | DEVICES FOR THE EFFICIENT USE OF SORBANTS IN LITHIUM EXTRACTION |
| AR128953A1 (es) | 2022-04-01 | 2024-06-26 | Lilac Solutions Inc | Extracción de litio con aditivos químicos |
| EP4519471A1 (en) | 2022-05-04 | 2025-03-12 | Services Pétroliers Schlumberger | Lithium recovery using aqueous sources |
| US11502323B1 (en) | 2022-05-09 | 2022-11-15 | Rahul S Nana | Reverse electrodialysis cell and methods of use thereof |
| US11502322B1 (en) | 2022-05-09 | 2022-11-15 | Rahul S Nana | Reverse electrodialysis cell with heat pump |
| US12421137B2 (en) | 2022-12-07 | 2025-09-23 | Schlumberger Technology Corporation | Hydrocarbon and sulfide removal in direct aqueous extraction |
| WO2024123398A1 (en) | 2022-12-07 | 2024-06-13 | Schlumberger Technology Corporation | Hydrocarbon and sulfide removal in direct aqueous extraction |
| US11855324B1 (en) | 2022-11-15 | 2023-12-26 | Rahul S. Nana | Reverse electrodialysis or pressure-retarded osmosis cell with heat pump |
| US12040517B2 (en) | 2022-11-15 | 2024-07-16 | Rahul S. Nana | Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof |
| JP2025538227A (ja) | 2022-11-15 | 2025-11-26 | エス ナナ，ラフル | 逆電気透析または圧力遅延浸透セルおよびその使用方法 |
| WO2025012681A1 (es) * | 2023-07-11 | 2025-01-16 | Universidad Católica De La Santísima Concepción | Sistema y método para concentración de salmueras de litio y purificación de agua |
| US12491476B2 (en) | 2023-12-01 | 2025-12-09 | Schlumberger Technology Corporation | Method of recovering lithium from a lithium source |
| WO2025155342A1 (en) * | 2024-01-19 | 2025-07-24 | Albemarle Corporation | Processes for recovering lithium values from lithium-containing brines |
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| US3130156A (en) | 1960-12-13 | 1964-04-21 | Ray A Neff | Solvent extractor |
| US5158683A (en) * | 1991-09-03 | 1992-10-27 | Ethyl Corporation | Bromide separation and concentration using semipermeable membranes |
| AU2005299387A1 (en) * | 2004-10-25 | 2006-05-04 | Cascade Designs, Inc. | Forward osmosis utilizing a controllable osmotic agent |
| US7445712B2 (en) | 2005-04-07 | 2008-11-04 | Hydration Technologies Inc. | Asymmetric forward osmosis membranes |
| WO2009151709A2 (en) * | 2008-03-20 | 2009-12-17 | Yale University | Spiral wound membrane module for forward osmotic use |
| JP2011525147A (ja) * | 2008-06-20 | 2011-09-15 | イェール ユニバーシティー | 正浸透分離法 |
| US8354026B2 (en) | 2009-03-09 | 2013-01-15 | Hydration Systems, Llc | Center tube configuration for a multiple spiral wound forward osmosis element |
| EA027334B1 (ru) | 2009-10-28 | 2017-07-31 | Оасис Уотер, Инк. | Способы прямого осмотического разделения |
| US9044711B2 (en) * | 2009-10-28 | 2015-06-02 | Oasys Water, Inc. | Osmotically driven membrane processes and systems and methods for draw solute recovery |
| KR101272868B1 (ko) * | 2010-11-11 | 2013-06-11 | 한국과학기술원 | 정삼투압을 이용한 저농도 발효액의 농축 방법 |
| PE20142465A1 (es) | 2011-04-25 | 2015-01-22 | Oasys Water Inc | Sistemas y metodos de separacion osmotica |
| US20130048564A1 (en) * | 2011-08-26 | 2013-02-28 | Battelle Energy Alliance, Llc | Draw solutes, methods of forming draw solutes, and methods of using draw solutes to treat an aqueous liquid |
| CN103182246A (zh) * | 2011-12-28 | 2013-07-03 | 新加坡三泰水技术有限公司 | 一种溶液的膜分离工艺方法及系统 |
| US20130341272A1 (en) * | 2012-06-26 | 2013-12-26 | Algae Systems, LLC | Dewatering Systems and Methods for Biomass Concentration |
| BR112015011092A2 (pt) * | 2012-11-16 | 2017-07-11 | Oasys Water Inc | recuperação de soluto de extração e soluções de extração para processos de membrana direcionada osmoticamente |
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- 2015-10-16 US US15/520,519 patent/US20180147532A1/en not_active Abandoned
- 2015-10-16 AU AU2015336234A patent/AU2015336234A1/en not_active Abandoned
- 2015-10-16 JP JP2017521134A patent/JP2017532197A/ja active Pending
- 2015-10-16 CA CA2963565A patent/CA2963565A1/en not_active Abandoned
- 2015-10-16 KR KR1020177010484A patent/KR20170071502A/ko not_active Withdrawn
- 2015-10-19 AR ARP150103383A patent/AR102363A1/es unknown
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2017
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2019
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| WO2016064689A3 (en) | 2016-07-28 |
| CA2963565A1 (en) | 2016-04-28 |
| US20180147532A1 (en) | 2018-05-31 |
| CL2017000964A1 (es) | 2017-11-03 |
| WO2016064689A2 (en) | 2016-04-28 |
| JP2017532197A (ja) | 2017-11-02 |
| CL2019002546A1 (es) | 2019-11-15 |
| KR20170071502A (ko) | 2017-06-23 |
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