AU2013284587A1 - Method for operating blast furnace - Google Patents

Method for operating blast furnace Download PDF

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AU2013284587A1
AU2013284587A1 AU2013284587A AU2013284587A AU2013284587A1 AU 2013284587 A1 AU2013284587 A1 AU 2013284587A1 AU 2013284587 A AU2013284587 A AU 2013284587A AU 2013284587 A AU2013284587 A AU 2013284587A AU 2013284587 A1 AU2013284587 A1 AU 2013284587A1
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pulverized coal
furnace
lance
combustion
volatile matter
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AU2013284587B2 (en
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Daiki Fujiwara
Akinori Murao
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JFE Steel Corp
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JFE Steel Corp
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/001Injecting additional fuel or reducing agents
    • C21B5/003Injection of pulverulent coal
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/16Tuyéres
    • C21B7/163Blowpipe assembly

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Iron (AREA)
  • Blast Furnaces (AREA)

Abstract

[Problem] To propose a method for operating a blast furnace, the method making it possible to improve the degree of combustion of pulverized coal blown into the furnace from the tuyeres and to reduce the reducing-material unit. [Solution] A method for operating a blast furnace into which a solid reducing material is blown also from the tuyeres through the lances, wherein when the amount of the solid reducing material to be blown from the tuyeres is 150 kg/t or larger per ton of the pig iron, double-pipe lances are used as the lances to blow the solid reducing material into the furnace through each inner pipe and blow 100ºC or lower oxygen into the furnace through the space between each inner pipe and the outer pipe and pulverized coal is used as the solid reducing material to be blown into, the pulverized coal having an average volatile content that is higher than 25 mass% but not higher than 50 mass%.

Description

- 1 DESCRIPTION METHOD FOR OPERATING BLAST FURNACE TECHNICAL FIELD 5 10001] This invention relates to a method for operating a blast furnace, and particularly to a method for operating a blast furnace that is effective in improving productivity and reducing a reducing material basic unit by blowing a solid reducing material such as pulverized coal from a tuyere of a blast furnace. BACKGROUND ART 10 [0002] In recent years, global warming due to an increase in carbon dioxide emission has become a problem, and this has also become an important issue in an iron manufacturing industry. In response to this problem, in the recent blast furnace, a low reduction agent ratio (low RAR: an abbreviation for Reduction Agent Ratio, a total amount of a reducing material blown from the tuyere and 15 coke charged from a furnace top per ton production of pig iron) operation has been promoted. The blast furnace primarily uses coke and pulverized coal as the reducing material. Therefore, in order to achieve suppression of the above-described low reduction agent ratio and carbon dioxide emission, a method for improving the combustion rate of the pulverized coal and improving air 20 permeability of the furnace by reducing an amount of powder occurring in the furnace has been considered to be effective. [0003] In this respect, Patent Document I suggests a method for improving the combustion rate of the pulverized coal by mixed-combustion of liquefied natural gas (LNG) and the pulverized coal. Further, Patent Document 2 suggests 25 a method for promoting the combustion of the pulverized coal by the volatile matter content by using the pulverized coal having a high volatile matter content. Patent Document 3 suggests a method for coping by providing a reduced-diameter portion in the tuyere. Patent Document 4 suggests a method for improving combustibility of the pulverized coal by simultaneously blowing 30 the solid reducing material and oxygen from the tuyere lance. Furthermore, Patent Document 5 suggests a method for improving the combustion efficiency of the pulverized coal by increasing the temperature of oxygen, when oxygen is -2 used for the purpose of improving the combustion rate of the pulverized coal. PRIOR ART DOCUMENTS PATENT DOCUMENT [0004] Patent Document 1: JP 2006-233332 A 5 Patent Document 2: JP 2002-241815 A Patent Document 3: JP 3644856 BI Patent Document 4: JP 4074467 BI Patent Document 5: JP 8-260010 A DISCLOSURE OF THE INVENTION 10 PROBLEM TO BE SOLVED BY THE INVENTION [00051 However, in the method of using LNG as disclosed in Patent Document 1, there is a problem in that LNG is expensive and a large amount of LNG is necessary to improve the combustion rate of the pulverized coal. Furthermore, in the method disclosed in Patent Document 3, there is a need for 15 modification of the tuyere, which leads to an increase in equipment cost. [0006] The method for operating a blast furnace disclosed in Patent Document 2 is effective in reducing the reducing material basic unit by an improvement in combustion rate of pulverized coal, as compared to the method for blowing the pulverized coal having a low volatile matter content from the 20 tuyere. However, in this method, the combustion rate is improved, but since a combustion point moves to a furnace wall side by an increase in the combustion rate, heat removal from the furnace wall increases, and the thermal efficiency of the blast furnace decreases. Moreover, in this method, pressure loss of the tuyere due to rapid expansion of gas increases, the blast pressure increases, and 25 the running cost increases. [0007] An object of this invention is to provide a method for operating a blast furnace capable of improving a combustion rate of the solid reducing material without causing heat removal and pressure loss. MEANS FOR SOLVING THE PROBLEM 30 [0008] As a method for achieving the above-described object, this invention provides a method for operating a blast furnace in which a solid reducing material is charged from a furnace top and also blown from a tuyere via a lance, in which, -3 when a blowing amount of the solid reducing material blown from the tuyere is not less than 150 kg/t per ton of pig iron, a double tube lance is used as the lance to blow the solid reducing material from an inner tube and blow oxygen of not higher than 100*C from between the inner tube and an outer tube, and a material 5 having an average volatile matter content of more than 25 mass% and not more than 50 mass% is used as the blowing solid reducing material. 10009] Incidentally, as described above, Patent Document 4 suggests a method for simultaneously blowing the solid reducing material (pulverized coal) and oxygen into the blast furnace from the tuyere, thereby improving the 10 combustibility of the pulverized coal. However, in this method, the pulverized coal having a low volatile matter content is used. The reason is that since the pulverized coal having a low volatile matter content has high amount of heat, when using such a low volatile matter content coal, it is possible to improve the combustibility in the furnace bottom, and additionally, it is possible to reduce the 15 coke used for temperature maintenance of the furnace bottom. [0010] However, when the blowing amount (hereinafter, referred to as a "pulverized coal ratio") of the pulverized coal from the tuyere per ton of pig iron is not less than 150 kg/t, or when a coke strength [DI 5 0 15 ] is not more than 85%, since an increase in the furnace powder greatly contributes to the reduction agent 20 ratio compared to the heat generation using the blown pulverized coal, it is advantageous to use the pulverized coal of a high volatile matter content. [0011] Furthermore, the inventors have obtained the following knowledge in regard to the strength of the coke charged into the blast furnace from the blast furnace top. In the blast furnace operation, as the coke strength is low, it is easy 25 to generate the coke powder of not more than 5 mm under the influence of load and friction in the furnace. When the amount of the coke powder becomes greater than an amount consumed by a solution loss reaction (reaction in which solid carbon reacts with carbon dioxide to produce carbon monoxide), a part of the coke powder is deposited on a central region (hereinafter, referred to as a 30 "furnace core") of the furnace bottom. If the amount of deposition of the coke powder increases, hot air blown from the tuyere passes through a furnace wall side, without passing through the furnace core part (hereinafter, this phenomenon -4 is referred to as "drift"). When the flow of hot air is drifted to the furnace wall side in this way, an amount of heat removal from the furnace wall increases or the reaction efficiency between the reducing gas and ore decreases, which leads to an increase in the reduction agent ratio. 5 [00121 At this time, when the blown pulverized coal ratio from the tuyere increases, unburned char flowing into the furnace also increases. If the unburned char is predominantly consumed in the solution loss reaction, the amount of the coke powder deposited on the furnace core without being consumed in the solution loss increases. Thus, if the strength [DI 5 0 15 [%]] of 10 coke charged from the blast furnace top is not more than 85, and the blowing amount of pulverized coal from the tuyere is not less than150 kg/t (pig iron), it becomes possible to reduce an amount of inflow of unburned char into the furnace by improving the combustion rate of the pulverized coal, which is advantageous to reduce the reduction agent ratio. 15 [0013J In addition, Patent Document 5 discloses that raising the oxygen temperature is desirable for the combustion of pulverized coal. However, in the case of considering the durability of the lance, when raising the temperature of oxygen, as described below, the surface temperature of the lance also increases, and deformation or erosion of the lance occurs, which may cause trouble such as 20 blowing failure of the pulverized coal or the tuyere wear. For that reason, it is desirable that the temperature of the oxygen blown from the lance is adjusted to a temperature below the temperature at which the deformation of the lance occurs. [0014] From the above, it is preferred that the method for operating the blast furnace according to this invention is configured as follows: 25 (1) The solid reducing material charged from the furnace top is coke having strength: [DI 5 0 1 5 [%]] of not more than 85 measured by a test method described in JIS K2151; (2) As the blowing solid reducing material, a material, in which the solid reducing material having a volatile matter content of 30 mass% to 60 30 mass% is contained in amount of not less than 10 mass%, is used; and (3) The blowing solid reducing material is pulverized coal.
-5 EFFECTS OF THE INVENTION [0015] According to the method for operating a blast furnace of this invention, when the pulverized coal ratio is not less than 150 kg/t (pig iron: this will not be described below), and the strength [DI'S 0 15 [%]] of the coke charged 5 from the furnace top of the blast furnace is not more than 85, the double tube lance is used to blow the solid reducing material from the inner tube thereof and blow oxygen of not higher than 1 00 0 C from between the inner tube and the outer tube, and as the solid reducing material at this time, a material having an average volatile matter content of more than 25 mass% and not more than 50 mass% is 10 used. Accordingly, it is possible to improve a combustion rate of the solid reducing material, without causing heat removal from the furnace wall or pressure loss of the furnace bottom. As a result, when adopting the method of this invention, it is possible to achieve a reduction in the operating cost of the blast furnace, and a reduction in equipment cost. 15 BRIEF DESCRIPTION OF DRAWINGS [00161 [Fig. 1] is a longitudinal cross-sectional view illustrating an embodiment of a blast furnace to which a method for operating the blast furnace of this invention is applied. [FIG. 2] is an explanatory view of each combustion state when only 20 the pulverized coal is blown from a lance. [FIG. 3] is an explanatory view of a combustion mechanism at the time of blowing the pulverized coal. [FIG. 4] is an explanatory view of a combustion mechanism at the time of blowing the pulverized coal having a high volatile matter content. 25 [FIG. 5] is an explanatory view of a combustion mechanism when the pulverized coal having a high volatile matter content and cold oxygen are simultaneously blown. [FIG. 6] is an explanatory view of a combustion test device. [FIG. 7] is a graph illustrating a relation between a volatile matter 30 content of the pulverized coal and a combustion rate in a combustion test result. [FIG. 8] is a graph illustrating a relation between a volatile matter content of the pulverized coal and an amount of heat removal from the furnace -6 wall in a combustion test result. [FIG. 91 is a graph illustrating a relation between a volatile matter content of the pulverized coal and a pressure loss of the furnace bottom in a combustion test result. 5 [FIG. 10] is a graph illustrating a relation between a pulverized coal ratio and a coke replacement rate. [FIG. 11] is a graph illustrating a relation between a pulverized coal ratio and a coke replacement rate. [FIG. 12] is a graph illustrating a relation between an oxygen 10 temperature and a lance surface temperature. EMBODIMENTS FOR CARRYING OUT THE INVENTION [0017] Hereinafter, an embodiment of a method for operating a blast furnace according to this invention will be described with reference to the accompanying 15 drawings. FIG. 1 is an overall view of a blast furnace I to which the method for operating the blast furnace of this embodiment is applied. A tuyere 3 is disposed in a bosh part of the blast furnace 1, and a blast tube 2 for blowing hot air is connected to the tuyere 3. As illustrated in FIG. 2, a lance 4 for blowing the solid fuel or the like is attached to the blast tube 2. In a coke deposition 20 layer portion of the furnace in front of a hot-air blowing direction from the tuyere 3, a combustion space called a raceway 5 is formed. Molten iron is primarily generated in the combustion space. 10018] FIG. 2 is a diagram schematically illustrating a combustion state when only pulverized coal 6 as a solid reducing material is blown into the furnace from 25 the lance 4 through the tuyere 3. As illustrated in this figure, the volatile matter content and the fixed carbon of the pulverized coal 6 blown into the raceway 5 from the lance 4 through the tuyere 3 are combusted with a furnace deposition coke 7, and aggregation of carbon and ash that remains without being completely combusted, that is, char is discharged as unburned char 8 from the raceways 5. 30 In addition, the velocity of the hot wind in front of the hot-air blowing direction of the tuyere 3 is about 200 m/sec. Meanwhile, a distance reaching the raceway 5 from the front end portion of the lance 4, that is, a region where 02 is present is -7 about 0.3 to 0.5 m. Thus, there is a need to cause the temperature rise of the blown pulverized coal particles, and the contact (dispersibility) between the pulverized coal and 02 to react substantially in a short period of 1/1000 seconds. [00191 FIG. 3 illustrates a combustion mechanism in a case where only the 5 pulverized coal (PC (Pulverized Coal) in the figure) 6 is blown into the blast tube 2 via the lance 4. Particles of the pulverized coal 6 blown into the raceway 5 from the tuyere 3 are heated by radiation heat transfer from the flame of the raceway 5, the temperature of the particle sharply rises by the radiation heat transfer and the conduction heat transfer, thermal decomposition starts from a 10 point of time at which the temperature rises to not lower than 300*C, and the volatile matter content is ignited and combusted (flame is formed) and a temperature of 1400 to 17004C is achieved. The pulverized coal from which the volatile matter content is released becomes the char 8. Since the char 8 mainly consists of fixed carbon, carbon dissolution reaction also occurs together with the 15 combustion reaction. [0020] FIG. 4 illustrates a combustion mechanism in a case where the pulverized coal 6 having a high volatile matter content is blown into the blast tube 2 via the lance 4. In a case where the pulverized coal 6 having a high volatile matter content is blown in this way, ignition of the pulverized coal 6 is 20 promoted by an increase in the volatile matter content, and an increase in the amount of combustion due to the volatile matter content occurs. As a result, the temperature rising rate and the maximum temperature of the pulverized coal increase, dispersibility of the pulverized coal increases, and the reaction velocity of the char is enhanced by the elevation of temperature. At this time, the 25 pulverized coal 6 is dispersed by vaporization expansion of volatile matter content and causes the combustion of volatile matter content, and the pulverized coal itself is rapidly heated and the temperature rises by the combustion heat. Moreover, since the combustion of the pulverized coal in this case occurs at a position close to the furnace wall, the heat removal from the tuyere 3 and the 30 pressure loss in the furnace increase. [0021] FIG. 5 illustrates a combustion mechanism in a case where the pulverized coal 6 having a high volatile matter content and low-temperature -8 oxygen (hereinafter, referred to as "cold oxygen") of not higher than 1 00*C are simultaneously blown into the blast tube 2 from the lance 4. When the pulverized coal 6 having a high volatile matter content and the cold oxygen are simultaneously blown in this way, the temperature rising rate of the pulverized 5 coal drops by the effect of the cold oxygen, and the ignition is delayed. However, thereafter, the combustion velocity of the volatile matter content increases by the high oxygen concentration in the vicinity of the pulverized coal, at the same time, the temperature rise of the pulverized coal is also promoted, the temperature of pulverized coal rises, and thus, the reaction velocity of the char 10 increases. Thus, when blowing the cold oxygen, the temperature rising rate of the pulverized coal initially drops and the combustion is delayed, but since the oxygen concentration in the vicinity of the pulverized coal is high as described above, when the temperature of the pulverized coal becomes a certain level or higher, the pulverized coal is rapidly combusted soon, and finally, the 15 combustion rate of the pulverized coal rather improves. The improvement in the combustion rate, and the prevention of increases in the heat removal from the furnace wall and the furnace pressure loss caused by the combustion delay are achieved by such a mechanism. That is, by setting the temperature of oxygen blown from the lance 4 to not higher than 100 C, it is possible to prevent the 20 deformation or the erosion of the lance in the case of supplying high-temperature oxygen, and an increase in pressure loss of the blast tube 2 due to a rapid combustion, and it is possible to achieve both the effect of improving the combustion rate and the effect of preventing the heat removal from the furnace wall. 25 [0022] The inventors have performed a combustion test using a combustion test device simulating a blast furnace illustrated in FIG. 6, based on this knowledge. A test furnace 11 used in the test device is such that coke is filled inside and a viewing window is provided to be able to observe the interior of the raceway 15. Moreover, a blast tube 12 is also attached to the test furnace 11, 30 hot air generated in a combustion burner 13 externally installed can be blown into the test furnace 11 via the blast tube 12, and it is possible to adjust the amount of oxygen enrichment during the blast. In addition, the lance 14 is inserted into the -9 blast tube 12. The lance 14 is used to blow one or both of the pulverized coal and oxygen into the blast tube 12. Exhaust gas occurring within the test furnace 11 is separated into exhaust gas and dust via a separation device 16 called a cyclone, the exhaust gas is sent to an exhaust gas treatment apparatus such as a 5 combustion-assisting furnace, and the dust is collected to a collection box 17. [0023] Upon combustion test using the above-described device, a single tube lance and a double tube lance were used as the lance 14. In the test, the combustion rate, the tuyere heat removal, the furnace pressure loss and the like were measured, for each of a case where only the pulverized coal is blown using 10 the single tube lance and a case where the pulverized coal and oxygen are simultaneously blown using the double tube lance. The combustion rate was determined from a weight change by recovering the unburned char by a probe from the rear of the raceway 15. The used pulverized coal was fixed carbon (FC: Fixed Carbon) of 40 to 80 mass%, volatile matter content (VM: Volatile 15 Matter) of 10 to 50 vol.%, and an ash content (Ash) of 7 to 12 mass%, and blowing conditions were 50 kg/h (corresponding to 158 kg/t in the molten iron basic unit). In addition, blowing conditions of oxygen from the lance 14 were 12 Nm 3 /h (corresponding to 3% oxygen enrichment). Coke of [DI' 50 15 [%]] 83 in the test method described in JIS K2151 was used. Conditions of the blast 20 were the blast temperature: 1200'C, the flow rate: 350 Nm 3 /h, and the flow velocity: 80 m/s, and 02 enrichment was +3.7 (oxygen concentration 24.7%, enrichment of 3.7% with respect to oxygen concentration 21% in the air). [0024] As evaluation of the test results, by variously changing the volatile matter content of the pulverized coal, the combustion rate, the heat removal from 25 the tuyere, and the furnace pressure loss when blowing only the pulverized coal from the single tube lance (using N 2 as a medium), and the combustion rate, the heat removal from the tuyere, and the furnace pressure loss when simultaneously blowing the pulverized coal and oxygen using the double tube lance were evaluated. 30 [0025] FIG. 7 is a graph illustrating a relation between the volatile matter content of the blown pulverized coal and the combustion rate. As illustrated in this figure, when blowing only the pulverized coal (high volatile matter content - 10 coal) from the single tube lance, the combustion rate began to significantly rise from 25 mass% of the volatile matter content of the pulverized coal, it became maximum at 45 mass%, and an effect of combustion rate improvement was saturated at not less than 45 mass%. It is thought that this is because the heat 5 generated by the combustion of the volatile matter content escapes to the air blast in the range of the volatile matter content of not less than 45 mass%, heat used for raising the temperature of the pulverized coal reaches a peak, and the combustion velocity does not increase above the level. [0026] In contrast, in the relation between the pulverized coal and the 10 combustion rate, in the case of simultaneously blowing the pulverized coal (high volatility dispersion) and cold oxygen using the double tube lance, the combustion rate is generally improved, compared to the case of blowing only the pulverized coal from the single tube lance. The reason is that the combustion velocity of the pulverized coal increases by an increase in the oxygen 15 concentration in the vicinity of the pulverized coal. 100271 FIG. 8 is a diagram illustrating a relation between the volatile matter content of the pulverized coal and the tuyere heat removal. As illustrated in FIG. 8, when blowing only the pulverized coal from the single tube lance, heat removal from the furnace wall increases with an increase in volatile matter 20 content. It is thought that this is because the combustion velocity of the pulverized coal increases by an increase in volatile matter content, and combustion point is shifted to the furnace wall side. [0028] In contrast, in the relation between the volatile matter content of the pulverized coal and the tuyere heat removal, in the case of simultaneously 25 blowing the pulverized coal (high volatility dispersion) of a high volatile matter content and cold oxygen using the double tube lance, the heat removal from the furnace wall generally decreases, as compared to the case of blowing only the pulverized coal from the single tube lance. The reason is that the temperature rising rate of the pulverized coal decreases by cold oxygen, and the combustion 30 point is shifted to the furnace interior side. [0029] In addition, cold oxygen (oxygen of not higher than 1 00 0 C to be blown from the lance) used in the above-described test was prepared as follows.
- 11 That is, the cold oxygen blown from the lance was used such that the cold oxygen obtained by a cryogenic separation process becomes not higher than 20'C in the lance portion. In addition, since the front end portion of the lance is inserted into the high-temperature blast tube 2, the front end portion is affected by the hot 5 air in the blast tube 2 and heat from the wall surface of the blast tube 2. Therefore, the temperature of oxygen blown from the lance inevitably rises, but since oxygen obtained by the cryogenic separation is supplied to the lance while remaining in a low temperature, after all, the temperature of oxygen blown from the lance can be set to not higher than 100 C. Also, by adjusting the insertion 10 depth of the lance into the blast tube 2, it is also possible to adjust the temperature of oxygen supplied from the lance. When the temperature of oxygen blown from the lance can be adjusted to not higher than 100 C by adjustment of the insertion depth of the lance, there is no need to set the supply oxygen temperature to the lance to not higher than 20'C. 15 [0030] FIG. 9 is a diagram illustrating a relation between the volatile matter content of the blown pulverized coal and the furnace pressure loss. As illustrated in FIG. 9, in the case of blowing only the pulverized coal from the single tube lance, a pressure loss of the furnace bottom decreases with an increase in volatile matter content up to the volatile matter content of 29 mass%, and 20 increases with an increase in the volatile matter content in the range of not less than 29 mass%. This is because the air permeability of the furnace improves by a decrease in unburned content up to the volatile matter content of 29 mass%, whereas the combustion gas flows to be inclined to the furnace wall in the volatile matter content of not less than 29 mass%. 25 [0031] In contrast, in the relation between the volatile matter content of the pulverized coal and the furnace pressure, in the case of simultaneously blowing the pulverized coal having a high volatile matter content and cold oxygen using the double tube lance, as compared to the case of blowing only the pulverized coal using the single tube lance, the pressure loss of the furnace bottom is 30 generally lowered, thereby maintaining a low pressure loss, particularly when blowing the pulverized coal having the volatile matter content of not less than 30 mass%. This is because the temperature rising rate of the pulverized coal is - 12 lowered by cold oxygen, and the drift of the gas is suppressed by transition of the combustion point to the furnace interior side. From this fact, in the solid reducing material (pulverized coal) having an average volatile matter content of 25 to 50 mass, by mixing the solid reducing material (pulverized coal) having the 5 volatile matter content of 30 to 60 mass% in amount of not less than 10% in terms of weight percentage, the pressure loss reduction effect can be reliably obtained. [00321 FIGs. 10 and 11 are graphs illustrating a relation between the pulverized coal ratio and the coke replacement rate. Here, the coke replacement 10 rate is a coke ratio (kg/t) capable of being reduced in a case where the pulverized coal ratio increases by 1 kg/t in the blast furnace operation. The coke replacement rate decreases by an increase in the pulverized coal ratio, but this is because the amount of coke powder deposited on the furnace core increases by an increase in unburned content of the pulverized coal in the furnace, the furnace gas 15 flows to be inclined to the furnace wall side, and thus the reaction and the heat exchange efficiency of the furnace decrease. [0033] As illustrated in FIG. 10, in a case where the strength [DI 5 t 0 5 [%]] of the coke charged into the blast furnace is not more than 85, when the pulverized coal ratio blown from the tuyere is not more than 150 kg/t, the coke replacement 20 rate due to the pulverized coal is maintained at a high level, but when the pulverized coal ratio exceeds 150 kg/t, the replacement rate of coke due to the pulverized coal is lowered. That is, if the pulverized coal ratio exceeds 150 kg/t, when using the pulverized coal (solid reducing material) having an average volatile matter content exceeding 25 mass% referred to in this invention, a high 25 coke replacement rate can be maintained. This means that, under the condition that the pulverized coal ratio is small, that is, the furnace gas does not drift, combustion of the pulverized coal on the furnace wall side, that is, in the vicinity of the tuyere is not promoted, the amount of heat in the vicinity of the tuyere is small even if the volatile matter content of the pulverized coal increases, and thus, 30 the coke replacement rate is small. [0034] In contrast, the reason is that, under the condition that the pulverized coal ratio is large, that is, the furnace gas drifts, since the combustion of the -13 pulverized coal on the furnace wall side, that is, in the vicinity of the tuyere is promoted, the higher the volatile matter content of the pulverized coal is, the higher the combustion rate is, and thus, the pulverized coal reduces to consequentially suppress the drift of the furnace gas, and the reduction in coke 5 replacement rate is shifted to a high pulverized coal ratio side. t0035] Meanwhile, as illustrated in FIG. 11, in a case where the coke strength
[DI"
15 s [%]] is not less than 85, a case where the average volatile matter content of the pulverized coal exceeds 25 mass% always has a high coke replacement rate, compared to a case where the average volatile matter content is not more than 25 10 mass%. This is because the larger the coke strength [DI.
50 15 [%]] is, the smaller the proportion of coke powder in the furnace is, the drift in the furnace gas is suppressed, and thus, the effect of combustion rate improvement is lowered. In addition, FIGs. 10 and 11 illustrate a relation between the pulverized coal ratio and the coke replacement rate when using cold oxygen in this invention. 15 [0036] FIG. 12 is a graph illustrating a relation between the temperature of oxygen blown from the lance and the lance surface temperature. As can be seen from FIG. 12, the lance surface temperature also increases with an increase in temperature of oxygen. In this case, when using the double tube lance, if the surface temperature of the double tube lance exceeds 880*C, creep deformation 20 occurs and the tube is bent, or corrosion of the lance also occurs. In addition, when the supply temperature of oxygen blown from the lance exceeds 100 0 C, since the surface temperature of the lance exceeds 880*C, there is a risk of deformation or corrosion of the lance. For this reason, it is required to set the temperature of oxygen blown from the lance to not higher than 100'C. 25 [0037] As described above, in the method for operating the blast furnace according to this invention, when blowing the pulverized coal (solid reducing material) from the tuyere, the lance is used as a double tube to blow the pulverized coal (solid reducing material) from the inner tube, and blow oxygen of not higher than 100'C from between the inner tube and the outer tube, and the 30 pulverized coal (solid reducing material) having an average volatile matter content of more than 25 mass% and not more than 50 mass% blown through the lance is used. Thus, it is possible to improve the combustion rate of the - 14 pulverized coal (solid reducing material) without increasing the heat removal and the pressure loss, and thus, it is possible to improve the coke replacement rate. DESCRIPTION OF REFERENCE SYMBOLS [00381 1: blast furnace 5 2: blast tube 3: tuyere 4: lance 5: raceway 6: pulverized coal (solid reducing material) 10 7: coke 8: char

Claims (2)

  1. 2. The method for operating the blast furnace according to claim 1, wherein the solid reducing material charged from the furnace top is coke having strength: [DI1 50 15 [%]] of not more than 85 measured by a test method described 15 in JIS K2151.
  2. 3. The method for operating the blast furnace according to claim 2, wherein, as the blowing solid reducing material, a material, in which the solid reducing material having a volatile matter content of 30 mass% to 60 mass% is contained in amount of not less than 10 mass%, is used. 20 4. The method for operating the blast furnace according to claim 3, wherein the blowing solid reducing material is pulverized coal.
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JP2013077526 2013-04-03
JP2013-077526 2013-04-03
PCT/JP2013/067788 WO2014007152A1 (en) 2012-07-03 2013-06-28 Method for operating blast furnace

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EP2871247B1 (en) 2017-05-10
KR101608231B1 (en) 2016-04-01

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