AU2012359201A1 - Tobacco-containing article - Google Patents

Tobacco-containing article Download PDF

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Publication number
AU2012359201A1
AU2012359201A1 AU2012359201A AU2012359201A AU2012359201A1 AU 2012359201 A1 AU2012359201 A1 AU 2012359201A1 AU 2012359201 A AU2012359201 A AU 2012359201A AU 2012359201 A AU2012359201 A AU 2012359201A AU 2012359201 A1 AU2012359201 A1 AU 2012359201A1
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AU
Australia
Prior art keywords
tobacco
plant parts
aromatic plant
containing article
article according
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Granted
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AU2012359201A
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AU2012359201B2 (en
Inventor
Jan Fuhrmann
Gitta Junemann
Regine Wolfgramm
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Reemtsma Cigarettenfabriken GmbH
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Reemtsma Cigarettenfabriken GmbH
HF and PhF Reemtsma GmbH and Co
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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B13/00Tobacco for pipes, for cigars, e.g. cigar inserts, or for cigarettes; Chewing tobacco; Snuff
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/302Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
    • A24B15/303Plant extracts other than tobacco
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/002Cigars; Cigarettes with additives, e.g. for flavouring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Botany (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Breeding Of Plants And Reproduction By Means Of Culturing (AREA)

Abstract

A tobacco-containing article (like a cigarette or other smokable products) comprises tobacco and aromatic plant parts, which do not derive from the tobacco plant, wherein the amount of the aromatic plant parts is in the range of from 0.5% by weight to 25% by weight, related to the total weight of the tobacco and the aromatic plant parts. The aromatic plant parts can have a size, defined by a screening method, in the range of from 0.1 mm to 10 mm or of from 0.2 mm to 6 mm. Suitable substances for the aromatic plant parts are, e.g., spearmint, peppermint, anise, rosemary, wintergreen, ginger, lemon myrtle, lavender, mate, avocado, ground coffee beans.

Description

WO 2013/091844 PCT/EP2012/005252 Tobacco-containing article The invention relates to a tobacco-containing article and to a 5 method of manufacturing a tobacco-containing article. Tobacco-containing articles, like cigarettes, cigarillos, ci gars or fine-cut products for self-made cigarettes and snus products, are often aromatised by means of flavourants, as LO e.g. menthol. Generally, such flavourants provide an intense flavour and are added in relatively small amounts, preferably as a liquid, e.g. during the preparation and saucing of the tobacco. L5 A disadvantage of this kind of conventional flavouring is the volatility and tendency to loss of many flavourants. It is also known to insert at least one flavour capsule into a tobacco-containing article, which can be broken by the con .0 sumer in order to release on demand the flavourant contained in the capsule. In this way, it is possible to use volatile flavourants, but the tobacco-containing article in question is more expensive. 15 It is an object of the invention to provide a tobacco containing article which can offer to the consumer new taste and flavour experiences but, nevertheless, involves moderate manufacturing expenses only. 0 This object is achieved by a tobacco-containing article having the features of claim 1. Claim 19 relates to a method of manu facturing such a tobacco-containing article. Advantageous ver sions of the invention follow from the dependant claims.
WO 2013/091844 PCT/EP2012/005252 -2 The tobacco-containing article according to the invention com prises tobacco and aromatic plant parts which do not derive from the tobacco plant. The amount of the aromatic plant parts is in the range of from 0.5% by weight to 25% by weight, re 5 lated to the total weight of the tobacco and the aromatic plant parts. In advantageous embodiments of the invention, the aromatic plant parts have a size in the range of from 0.1 mm to 10 mm 10 or in the range of from 0.2 mm to 6 mm. The size of the aro matic plant parts is defined by a screening method, which is described in detail further below. Shortly, the aromatic plant parts are submitted to a series of vibrating screens according to DIN ISO 3310-1 having generally square meshes of decreasing 15 sizes. If the aromatic plant parts have a size in a given range, virtually all of them will pass a screen having the up per' limit of the range as the nominal mesh size, whereas the aromatic plant parts will not pass a screen having the lower limit of the range as the nominal mesh size. Aromatic plant 20 parts passing a mesh diagonally may have a greater length than the nominal mesh size, but they are included by definition. On the other hand, the material used for the aromatic plant parts may include some dust which even passes the smallest mesh size. This dust, by definition, is considered as not being a 25 constituent of the aromatic plant parts. Its contribution is generally small. For a given advantageous embodiment, the to tal size range of the aromatic plant parts is embedded in one of the above ranges, but may have a smaller or even much smaller extension (spread of sizes). All lower limits of 30 greater than 0.1 mm and all upper limits of less than 10 mm of such spread are expressly disclosed herewith. The amount of the aromatic plant parts is provided as a weight related to the total weight of the tobacco and the aromatic 35 plant. parts. Therefore, any major dependency on the actual WO 2013/091844 PCT/EP2012/005252 -3 moisture of the aromatic plant parts or of the tobacco cancels out. In case the amount of the aromatic plant parts is to be measured with a high precision, the weight ratio shall be de termined after equilibration of the aromatic plant parts and 5 of the tobacco for 2 days- at 22 0 C and at a relative humidity of 58-60%. The tobacco-containing article according to the invention is an aromatised tobacco product, in which the aromatic. plant 10 parts are natural constituents and not artificial or concen trated aromas. This provides for a natural, maybe somewhat subliminal taste. experience. The addition of artificial fla vours, which otherwise would have to be added as alcoholic ex tracts, is not required, thus avoiding alcoholic constituents. 15 Generally, the relative amount of the aromatic plant parts is greater than that of a conventional concentrated aroma sub stance, but not so great as to provide an obtrusive taste. Since the aromatic plant parts are relatively large, e.g. in 20 the range of from 0.1 mm to 10 mm or from 0.2 mm to 6 mm, they generally contain material in addition to any flavourants, e.g. in a plant cell structure, which is able to keep the fla vourants and to reduce flavour loosening effects. This may re sult in a slightly increased flavour shelf life of the respec 25 tive tobacco-containing article, compared to a conventional tobacco-containing article treated with a liquid aroma concen trate. Due to the presence of a significant amount of aromatic plant 30 parts in addition to the tobacco, the relative amount of to bacco is smaller than in a conventional tobacco product. In a cigarette, cigarillo or cigar, this results in a dilution ef fect regarding tobacco nicotine and other constituents as, e.g., ammonia or nitrate. Examples are provided further below. 35 When the pH is increased because of the aromatic plant parts, WO 2013/091844 PCT/EP2012/005252 -4 the taste is generally stronger, although less nicotine is present. The aroma of the side-stream smoke of, e.g., a cigarette can 5 also be positively influenced and optimised, depending on the selection of the aromatic plant parts. The visual appearance of the aromatic plant parts, which in many applications are leaves or leaf parts, implies a natural 10 product and a natural aromatisation. The tobacco-containing article in question can generate a pleasant smell, even before consumption. In advantageous embodiments of the tobacco-containing article 15 according to the invention, the- aromatic plant parts comprise, e.g., spearmint, peppermint, anise, rosemary, wintergreen, ginger, lemon myrtle, lavender, mate, avocado, ground coffee beans, sage, herbs, teas, or any mixtures thereof. For exam ple, spearmint or peppermint causes a pleasant aroma. A de 20 tailed (but not exclusive) list of plants delivering suitable aromatic plant parts is given further below. In the tobacco-containing article, at least part of the to bacco and of the aromatic plant parts can be included in a 25 combined mixture. That means, e.g. cut tobacco parts and aro matic plant parts (e.g., in the size range of from 0.2 mm to 6 mm or of from 0.1 mm to 10 mm) are mixed together to form a combined and preferably generally homogeneous mixture. 30 It is also possible that at least part of the tobacco com prises reconstituted tobacco. Sheets of reconstituted tobacco can be cut to form cut reconstituted tobacco, which can be mixed, e.g., with aromatic plant parts and also with natural cut tobacco. 35 WO 2013/091844 PCT/EP2012/005252 -5 Moreover, it is conceivable to make a reconstituted product from aromatic plant parts, e.g. in a way similar to one of the known processes of manufacturing reconstituted tobacco, so that at least part of the aromatic plant parts in the tobacco 5 containing article comprises a reconstituted product. A sheet of this reconstituted product can be cut to the desired size of the aromatic plant parts, e.g., in the range of from 0.2 mm to 6 mm or of from 0.1 mm to 10 mm. 10 In another embodiment, a reconstituted product is used which contains a mixture of tobacco parts and of aromatic plant parts. Such reconstituted product can also be produced in a manner analogous to conventional reconstituted tobacco. In this way, at least part of the tobacco and at least part of 15 the aromatic plant parts are included in a combined reconsti tuted product, which can be cut to the desired size. In an advantageous embodiment of the invention, at least part of the aromatic plant parts is provided in the form of gran 20 ules, preferably of a size in the range of from 0.2 mm to 5 mm or from 0.5 mm to 2.5 mm. Such granules can be made of pressed aromatic plant parts and optionally additional water, without further additives. Granules comprising aromatic plant parts as well as tobacco are also conceivable. 25 In another advantageous embodiment of the invention, the to bacco-containing article includes a cut top-loaded sheet prod uct, in which a base layer comprises or is made of reconsti tuted tobacco, wherein the base layer is provided on one side 30 with aromatic plant parts. WO 03/082030 A discloses a method of manufacturing a top-loaded sheet product, in this case a top-loaded cigarette filler, in which a base layer on a basis of a fine fraction of tobacco and cellulose fibres is provided on one side with a fraction of course tobacco, wherein the as 35 sembly is subjected to a drying treatment. In an analogous WO 2013/091844 PCT/EP2012/005252 -6 manner, a base layer comprising reconstituted tobacco can be provided on one side with aromatic plant parts, and after dry ing this top-loaded sheet product is cut to pieces of the de sired size. 5 It is also conceivable that the tobacco-containing article in cludes a cut top-loaded sheet product,. in which a base layer comprises reconstituted aromatic plant parts, wherein the base layer is provided on one side with aromatic plant parts. This 10 cut top-loaded sheet product constitutes at least part of the aromatic plant parts. It can be mixed with tobacco and/or re constituted tobacco and optionally with additional aromatic plant parts. 15 If the aromatic plant parts are included in a reconstituted sheet product, the size of the aromatic plant parts in the range of from 0.1 mm to 10 mm or of from 0.2 mm to 6 mm is to be understood as the size of the aromatic plant part pieces used in the manufacturing process of the reconstituted sheet 20 product. A reconstituted product is produced as generally known in the art. In case the amount of natural aromas present in the aromatic plant parts is not sufficient for a specific design of a to 25 bacco-containing article, at least one flavourant in addition to the aromatic plant parts can be added, preferably as a liq uid. An example is the addition of menthol to achieve a super aromatisation. 30 Typically, the aromatic plant parts can have a moisture of from 5% to 35%, preferably of from 5% to 20% or of from 7% to 12%, related to the total of the dry weight of the respective aromatic plant parts plus the moisture. After admixture to to bacco, moisture generally equilibrates between the aromatic 35 plant parts and the tobacco, e.g. within a closed packaging.
WO 2013/091844 PCT/EP2012/005252 -7 Cigarettes typically have a moisture of from 7% to 14%. Snus typically has a moisture in the order of 35%. Concerning the tobacco in the tobacco-containing article, all 5 kinds of conventional tobaccos and tobacco blends, optionally including reconstituted tobacco, can be used. Examples are an American blend or a Virginia blend. The tobacco-containing article according to the invention is 10 provided as a cigarette, e.g., as a full-flavour cigarette having a tar level depending on regulatory ceilings, as a light cigarette having a tar level of up to 7 mg or as an ul tralight cigarette having a tar level of up to 2 mg, or as a cigarillo or as a cigar. In such embodiments, the tobacco and 15 the aromatic plant parts are contained in the rod of the ciga rette, cigarillo or cigar, respectively. This does not ex clude, however, that a filter also includes tobacco and/or aromatic plant parts. 20 In different embodiments of the invention, the tobacco containing article is provided in the form of pipe tobacco or in the form of fine-cut for self-made cigarettes, packaged in a suitable enclosure. Self-made cigarettes are known as "RYO" (roll-your-own), which means that the consumer takes a portion 25 of fine-cut comprising tobacco and aromatic plant parts from a package, puts it on a cigarette paper (optionally with an ad ditional filter) , rolls the cigarette paper about the fine-cut and glues the seam of the cigarette paper. Another type of self-made cigarettes is "MYO" (make-your-own), wherein fine 30 cut is taken from a package and filled into some apparatus which, upon operation by the consumer, automatically or semi automatically forms a finished smoking article. If the tobacco-containing article is provided as a cigarette, 35 cigarillo or cigar and comprises a rod, e.g. the rod of a WO 2013/091844 PCT/EP2012/005252 -8 cigarette, the rod (which comprises tobacco and aromatic plant parts) can be wrapped by a low-sidestream cigarette paper hav ing a base weight in the range of 'from 35 g/m2 to 60 g/m2, having a porosity of less than 15 CU and including a filler. 5 The filler comprises CaCO 3 of at least 30% and/or MgO of at least 3% and/or Mg(OH) 2 of at least 3%, the percentages being percent per weight of the respective compound, related to the total weight of the low-sidestream cigarette paper. 1 CU = 1 Coresta unit = 1 ml/(cm2-min-kPa). 10 The tobacco-containing article could also. be provided in -the form -of snus, a product consumed by placing it under the lip for some period of time. Preferably, the snus comprising to bacco and aromatic plant parts is prepared in a grinded and 15 sieved form. The snus parts can have a size range of, e.g., from 0.1 mm to 1.5 mm or from 0.1 mm to 0.8 mm. In many applications, including embodiments already explained above, the tobacco-containing article comprises cut tobacco 20 and/or cut sheet products. Generally, the cut width of the to bacco or the respective sheet product can be that of cut to bacco in conventional tobacco-containing articles, e.g., 0.2 mm to 0.75 mm for fine cut tobacco, greater than 1.5 mm for pipe tobacco, or 0.6 mm to 0.9 mm for typical cigarettes. Such 25 widths can also be suitable to the aromatic plant parts, when used in cut leaf form or cut sheet form. In an advantageous method of manufacturing a tobacco containing article according to the invention, after cutting 30 tobacco, aromatic plant parts, which do not derive from the tobacco plant and which have a size in the desired range, e.g., in the range of from 0.1 mm to 10 mm or in the range of from 0.2 mm to 6 mm, are added to the tobacco in an amount in the range of from 0.5% by weight to 25% by weight, related to 35 the total weight of the tobacco and the aromatic plant parts.
WO 2013/091844 PCT/EP2012/005252 -9 That means that the tobacco or at least part of the tobacco is cut independently of the aromatic plant parts. Generally, it is conceivable that uncut, large aromatic plant parts are al ready added to tobacco parts like leaves, ribs or stems or to 5 a reconstituted tobacco sheet before the cutting step is per formed. It is advantageous, however, when the aromatic plant parts are admixed relatively late in the process because they might release a strong aroma which tends to contaminate the manufacturing equipment. 10 For example, aromatic plant parts (preferably cut ones) can be added during treatment of the cut tobacco, e.g., during blend ing or flavouring.. 15 In the following,- the invention is described in more detail, also by means of examples. Screening method 20 In order to define reproducible sizes of the aromatic plant parts, a screening method is used. This method is performed in analogy to DIN V 10376 of February 2005 ("Analysis of tobacco and tobacco products - Determination of size of the fillers of 25 cigars and cigarillosby means of sieve analysis"). To this end, the aromatic plant parts to be examined are mois ture-conditioned at a relative humidity of (70 + 2)% and at a temperature of (22 ± 1)*C for 48 h. If the particles were too 30 dry, they would break during sieving, which would deliver er roneous results. The moisture-conditioned aromatic plant parts are submitted to a stack of vibrating screens according to DIN ISO 3310-1 hav 35 ing meshes of decreasing sizes. If the aromatic plant parts WO 2013/091844 PCT/EP2012/005252 - 10 have a size distribution in a given range, virtually all of them will pass a screen having the upper limit of the range as the nominal mesh size, whereas the aromatic plant parts will not pass a screen having the lower limit of the range as the 5 nominal mesh size. Individual aromatic plant parts passing a mesh diagonally may have a greater length than the nominal mesh size, but- they are included by definition. On the other hand, the material used for the aromatic plant parts may in clude some dust which even passes the smallest mesh size. This 10 dust, by definition, is considered as not being a constituent of the aromatic plant parts. Its contribution is generally small. Further details of the method follow from DIN V 10376. As al 15 ready mentioned, the present screening method is performed in analogy thereto, with the following differences. For screening leaves, the screening machine performs horizon tal vibrations of 15 mm with a frequency of 270/min for 5 min 20 utes (instead of 10 minutes). Mesh sizes of 1.18 mm, 2.36 mm and 4 mm are used. For screening granulates, the screening ma chine runs for 1 minute, and mesh sizes of 1.6 mm, 1.4 mm, 1.2 mm, 1.0 mm, 0.8 mm, 0.5 mm, 0.25 mm and 0 mm are used. 25 If a size distribution is to be determined with a higher accu racy, a stack of several screens can be used. In case the num ber of screens exceeds the capability of the screening ma chine, the size distribution can be determined sequentially. 30 Examples for aromatic plant parts Generally, a large variety of plant species can be used as sources for the aromatic plant parts according to the inven 35 tion. Spearmint, peppermint, anise, rosemary, wintergreen, WO 2013/091844 PCT/EP2012/005252 - 11 ginger, lemon myrtle, lavender, mate, avocado, ground coffee beans, sage as well as herbs and teas in general have already been mentioned above. Depending on the plant species, the ap propriate plant parts may derive from leaves., blossoms, 5 fruits, roots, bark, etc. Mixtures of aromatic plant parts from different species are conceivable as well. The following Table 1 includes a plurality of plant species which may be particularly useful for the purposes of the in 10 vention: Table 1 Examples for plant species as source for aromatic plant parts English Name Latin Name Anise Pimpinella anisum Apple Malus sylvestris Avocado Persea americana Bearberry Arctostaphylos uva ursi Black current (folia) Ribes nigrum Cinnamon (cortex) Cinnamomum spec. Coltsfoot Tussilago farfara Damask rose (flores) Rosa centifolia Damiana leaves (folia) Turnera diffusa Dandelion blooms Taraxacum officinalis Elder (flores) Sanbucus nigra Eucalyptus Eucalyptus globulus German chamomile (flores) Matricaria chamomilla Ginger Zin giber officinale Gingko biloba Gingko biloba Hazelnut Corylus avellana Honeysuckle Lonicera spec. Hop blooms (glandulae) Humulus lupulus Jasmine (flores) Jasminum officinale Lady's mantle Alchemilla vulgaris WO 2013/091844 PCT/EP2012/005252 - 12 Lavender (flores) Lavandula officinalis Lemon myrtle Backhousia citriodora Marshmallow herb (folia) Althaeae officinalis Mat6 (folia) Ilex paraguariensis Melissa (folia) Melissa officinalis Mint leaves Mentha crispata Mullein (folia) Verbascum densiflorum Orange blossom (flores) Citrus aurantium Papaya Carica papaya Passionf lower (herba) Passiflora incarnata Peppermint Mentha piperita Red clover (flores) Trifolium pratense Red willow Cornus amomum Robinia blossom (flores) Robinia pseudoacacia Rose petals Rosa spec. Rosemary (folia) Rosmarinus officinalis Sage Salvia officinalis, S. triloba Sculicap Scutellaria spec. Spearmint Mentha spicata Summer savory (herba) Satureja hortensis Teas e.g., from Camellia sinensis Valerian root (radix) Valeriana officinalis Vervain (herba) Verbena odorata. Wine leaves Vitis vinifera wintergreen Gaultheria procumbens Yerba buena Clinopodium douglasii Yerba santa Eriodictyon californica Example 1: Spearmint 5 Spearmint (Mentha spicata) contains some (but not much) men thol, as well as carvone, pulegone, limonene and esters.
WO 2013/091844 PCT/EP2012/005252 - 13 After equilibration at 22C and 60% relative humidity, a sam ple of spearmint leaves had a relative moisture of 10.0%. Here and in the following, all relative moisture contents are re lated to the total of the dry weight (determined after oven 5 treatment at 82 0 C for 3 h; "Horo" method) and the moisture. From this sample, a mixture with American blend tobacco was prepared, which contained 10% by weight of spearmint leaves and 90%. by weight of tobacco. After equilibration at 30 0 C and 10 75% relative humidity, the mixture had a relative moisture of 18.5%. Under the same equilibration conditions, the pure to bacco had a relative moisture of 19.1% and the pure spearmint sample a relative moisture of 13.7%. 15 The size distribution of the leaves of two' different samples of spearmint leaves was determined by means of the screening method described above, using mesh sizes of 1.18 mm, 2.36 mm and 4 mm. In the first sample, about 2.6% by weight of the leaves did not pass the 4 mm mesh screen, about 27.3% by weig 20 ht did not pass the 2.36 mm mesh screen, about 57.2% by.weight did not pass the 1.18 mm mesh screen, and about 12.9% by weight passed the 1.18 mm mesh screen, the peak size being slightly more than 1.18 mm. In the second sample, the corre sponding numbers were 10.2%, 63.1%, 24.8% and 2.0%, respec 25 tively, and the peak. was at a leaf size of about 2 mm. Example 2: Peppermint 30 Peppermint (Mentha piperita) contains menthol, menthone, cineol, tanning agents and flavonoids. A sample of granulated peppermint, after equilibration at 220C and 60% relative humidity, had a relative moisture of 8.6%. 35 WO 2013/091844 PCT/EP2012/005252 - 14 The size distribution of the granules of this sample was de termined by the screening method described above. Table 2 pre sents the fraction of the total sample of 402.34 g retained by a screen of a given mesh size (mesh sizes of 1.6 mm, 1.4 mm, 5 1.2 mm, 1.0 mm, 0.8 mm, 0.5 mm, 0.25 mm and 0 mm). Table 2 Size distribution in a sample of granulated pepper mint Mesh size [mm] Retained mass [g] Fraction [1%] 1.6 0.05 0.01 1.4 0.35 0.09 1.2 19.79 4.92 1.0 67.75 16.84 0.8 98.50 24.48 0.5 163.15 40.55 0.25 51.20 12.73 0 1.55 0.39 1402.34 100.00 10 Table 2 shows that essentially all of the granules have a size in the range of from 0.25 mm to 1.2 mm. The contribution of the particles passing the 0.25 mm mesh (dust) is negligible. The distribution peaks at about 0.5 mm. 15 Example 3: Spearmint, peppermint As Example 3, two other samples of spearmint and peppermint 20 were investigated. In both samples, the aromatic plant parts had a granular form. After equilibration at 22 0 C and 60% rela tive humidity, the spearmint sample had a relative moisture of 7.5% and the peppermint sample of 8.5%.
WO 2013/091844 PCT/EP2012/005252 - 15 The size distributions of the granules, obtained as described above, are shown in Table 3. Table 3 Size distributions in a sample of granulated spear 5 mint and in a sample of granulated peppermint Mesh size [mm] Spearmint Peppermint Fraction (% Fraction [%] 1.6 0.04 0.02 1.4 0.02 0.08 1.2 0.12 0.28 1.0 10.00 15.56 0.8 43.78 39.94 0.5 43.69 41.06 0.25 2.31 3.04 0 0.04 0.04 100.00 100.00 In. both samples, the granules essentially have sizes in the range of from 0.25 mm to 1.2 mm, peaking somewhere between 0.5 10 mm and 0.8 mm. Example 4: Mixture of tobacco and spearmint 15 In Example 4, one of the spearmint samples of Example 1 (that with the peak size of about 2 mm) was used to prepare virtu ally homogeneous mixtures of spearmint leaves and American blend tobacco. From mixtures containing 2%, 5%, 10% and 20% spearmint by weight (related to the total weight of spearmint 20 and tobacco; designated by MS1, MS2, MS3, and MS4, respec tively), filter cigarettes of 7.8 mm diameter with a cellulose acetate filter plug of 21 mm length and a tobacco/spearmint rod of 62 mm length were made. Some constituents of the to bacco/spearmint mixtures were analyzed. Moreover, properties WO 2013/091844 PCT/EP2012/005252 - 16 of the cigarettes including smoke data (according to DIN ISO 4387/A) were measured. The results for the samples MS1, MS2, MS3, and MS4 as well as for a control sample CS (American blend tobacco without spearmint) are summarised in Table 4. 5 The abbreviations used in Table 4 are' explained at the end of Table 5 below. It is evident from Table 4 that the tobacco nicotine (i.e. the relative amount of nicotine in the mixture of tobacco and 10 spearmint) decreases with increasing amount of spearmint in the -mixture. There is also the tendency that smoke nicotine decreases when the contribution of spearmint increases. Moreover, with increasing amount of spearmint, the hardness of 15 the cigarette decreases somewhat (not shown in Table 4).
WO 2013/091844 PCT/EP2012/005252 - 17 Table 4 Data for. cigarettes made from mixtures of American blend tobacco and spearmint I I I TIT Sample CS MS1 MS2 MS3 MS4 Physical Data Units AB+2% AB+5% AB+1O% AB+20% Blend AB mint mint mint mint 7.8 x 7.8 x 7.8 x 7.8 x 7.8 x Format(mm 62+21) (62+21) (62+21) (62+21) (62+21) Cigarette weight mg 844 845 847 842 825 Oven Horo moisture % 12.0 12.1 11.9 11.7 11.4 Diameter mm 7.80 7.80 7.82 7.83 7.83 Pressure drop filter mmWG 67.9 67.9 68.5 68.9 67.9 Pressure drop open Pdo* mmWG 82 80 79 81 82 Press. drop closed Pdc** mmWG 129 124 123 126 129 Ventilation % .46.1 46.7 47.0 46.8 46.1 Tobacco Data Units Tobacco nicotine % d.b. 2.30 2.29 2.19 1.98 1.80 Ammonia % d.b. 0.17 0.17 0.17 0.16 0.15 Nitrate % d.b. 1.02 1.09 0.99 0.94 0.92 Chloride % d.b. 0.77 0.81 0.77 0.80 0.77 Sacchrose (HPLC) % d.b. 1.6 1.7 1.7 1.7 1.8 Glucose (HPLC) % d.b. 2.9 2.8 2.6 2.6 2.4 Fructose (HPLC) % d.b. 4.2 4.2 3.9 3.9 3.6 Ash % d.b. 15.6 15.6 15.5 15.5 15.1 Tobacco pH 5.43 5.40 5.47 5.53 5.60 Acid equivalents 11.7 11.5 10.9 10.0 9.0 Propylene glycol % d.b. 1.1 1.1 1.1 1.1 0.9 Smoke Data (DIN ISO 4387/A) Units Smoke nicotine mg/Cig. 0.65 0.65 0.64 0.63 0.58 WTPM mg/Cig. 8.0 8.0 8.0 8.1 8.0 NFDPM mg/Cig. 6.5 6.5 6.6 6.8 6.6 Puff number 7.3 7.3 7.3 7.3 7.0 CO mg/Cig. 7.2 6.9 6.9 7.4 7.1 WO 2013/091844 PCT/EP2012/005252 - 18 Table 5 Data for cigarettes made from mixtures of American blend tobacco and black tea Sample CS TSI TS2 TS3 TS4 Physical Data Units ABI+2% AB+5% AB+10% AB+20% Blend AB black tea black tea black tea black tea 7.8 x 7.8 x 7.8 x 7.8 x 7.8 x Format mm (62+21) (62+21) (62+21) (62+21) (62+21) Cigarette weight mg 844 847 846 847 842 Oven Horo moisture % 12.0 11.8 11.7 11.5 10.9 Pressure drop open Pdo* mmWG 82 79 -79 78 75 Press. drop closed Pdc** mmWG 129 125 122 119 111 Ventilation % 46.1 47.3 46.7 45.9 44.6 Tobacco Data Units Tobacco nicotine % d.b. 2.30 2.20 2.24 2.11 1.89 Ammonia % d.b. 0.17 0.17 0.16 0.16 0.15 Nitrate % d.b. 1.02 1.02 1.13 0.96 0.95 Chloride % d.b. 0.77 0.76 0.75 0.70 0.68 Sacchrose (HPLC) % d.b. 1.6 1.7 1.7 1.6 1.5 Glucose (HPLC) % d.b. 2.9 2.6 2.6 2.7 2.4 Fructose (HPLC) % d.b. 4.2 3.9 3.9 3.9 3.5 Tobacco pH 5.43 5.47 5.48 5.46 5.45 Acid equivalents 11.3 11.3 11.0 11.0 10.5 Propylene glycol % d.b. 1.1 1.1 1.2 1.1 0.9 Smoke Data (DIN ISO 4387/A) Units Smoke nicotine mg/Cig. 0.65 0.63 0.65 0.68 0.70 WTPM mg/Cig. 8.0 8.1 8.2 8.4 9.1 NFDPM mg/Cig. 6.5 6.7 6.8 7.1 7.7 Puff number 7.3 7.2 7.3 7.4 7.6 CO mg/Cig. 7.2 7.1 6.9 7.0 6.9 WO 2013/091844 PCT/EP2012/005252 - 19 Explanations to Tables 4 and 5 CS: Control sample MSI-MS4: Spearmint samples 1-4 TS1-TS4: Black tea samples 5 Cigarette format: Standard King Size Cigarette with a cigarette paper of 60 Coresta * Pressure drop measured with open filter wrapper perforation ** Pressure drop measured with closed filter wrapper perforation in mg KOH/g tobacco d.b. AB: American Blend 10 d.b.: dry base mmWG: millimeter Water Gauge (ISO 10185) HPLC: High Performance Liquid Chromatography WTPM: Wet Total Particulate Matter (ISO 10185) NFDPM: Nicotine Free Dry Particulate Matter (ISO 10185) 15 Cig.: Cigarette Example 5: Mixture of tobacco and black tea 20 In Example 5, virtually homogeneous mixtures of American blend tobacco and black tea (loose leaves) were prepared. From mix tures containing 2%, 5%, 10% and 20% black tea by weight (re lated to the total weight of black tea and tobacco; designated by TS1, TS2, TS3, and TS4, respectively), filter cigarettes of 25 7.8 mm diameter with a cellulose acetate filter plug of 21 mm length and a tobacco/black tea rod of 62 mm length were made. Some constituents of the tobacco/black tea mixtures were ana lyzed. Moreover, properties of the cigarettes including smoke data (according to DIN ISO 4387/A) were measured. The results 30 for the samples TS1, TS2, TS3, and TS4 as well as for a con trol sample CS (American blend tobacco without black tea) are summarised in Table 5. The abbreviations used in Table 5 are explained at the end of the table.
WO 2013/091844 PCT/EP2012/005252 - 20 Table 5 shows that the tobacco nicotine (i.e. the relative amount of nicotine in the mixture of tobacco- and black tea) decreases with increasing amount of black tea in the mixture. 5 Example 6: Storage behaviour The relative losses of flavour constituents from filter ciga rettes made from mixtures of American blend tobacco and spear 10 mint according to Example 4 were investigated. To this end, cigarette boxes containing cigarettes comprising the mixtures MS1 and MS3 were stored for six months under different condi tions, i.e. as -a closed box in a refrigerator, as a closed box at room temperature and as an opened box at room temperature. 15 Spearmint aroma constituents were determined by gas chromato graphy before and after six months of storage. Table 6 shows, for both mixtures MS1 and MS3, averages of the absolute amounts of the spearmint aroma constituents before 20 storage and of the relative losses (related to the initial amounts) after six months of storage. Table 6 Aroma constituents in cigarettes containing American blend tobacco and spearmint according to Example 4, 25 initially and relative loss after 6 months of storage Spearmint Initial 6 m. 6 m. 6 m. Initial 6 m. 6 m. 6 m. constituent amount refrig. room room amount refrig. room room pg/Cig. clos. clos. open pg/Cig. clos. clos. open loss%, loss% loss% loss%, loss% loss% MS1 - MS3 Pulegone 23.7 16.5 18.3 43.0 150.0 19.2 13.6 41.2 Carvone 103.1 24.8 22.0 31.0 555.6 23.8 18.1 45.6 WO 2013/091844 PCT/EP2012/005252 - 21 The results in Table 6 exhibit the following trends: The rela tive losses of spearmint constituents from closed boxes stored at room temperature and from closed boxes stored in a refrig erator are similar. In case of opened packs stored at room 5 temperature, the relative losses are significantly higher. For cigarettes with a greater spearmint contribution, the relative losses tend to be somewhat higher. Moreover, migration of the spearmint constituents during the storage period resulted in some aroma accumulation in the cigarette filters (data not 10 shown in Table 6). Example 7: Mixture of tobacco and lemon myrtle 15 In Example 7, lemon myrtle (Backhousia citriodora) was used to prepare virtually homogeneous mixtures of lemon myrtle leaves and American blend tobacco. From mixtures containing 2%, 5%, 10% and 20% lemon myrtle by weight (related to the total weight of lemon myrtle and tobacco), designated by LM1, LM2, 20 LM3 and LM4, respectively, filter cigarettes of 7.8 mm diame ter with a cellulose acetate filter plug of 25 mm length and a tobacco/lemon myrtle rod of 58 mm in length were made. Some constituents of the tobacco/lemon myrtle mixtures were ana lysed. Moreover, properties of the cigarettes including smoke 25 data (according to DIN ISO 4387/A) were measured. The results for the samples LM1, LM2, LM3 and LM4 as well as for a control sample CS (American blend tobacco without lemon myrtle) are summarised in Table 7. The abbreviations used in Table 7 are explained at the end of Table 7. 30 It is evident from Table 7 that the tobacco nicotine (i.e. the relative amount of nicotine in the mixture of tobacco and lemon myrtle) decreases with increasing amount of lemon myrtle in the mixture. Any decrease of smoke nicotine was not ob 5 served.
WO 2013/091844 PCT/EP2012/005252 - 22 Table 7 Data for cigarettes made from mixtures of American blend tobacco and-lemon myrtle Sample CS LM1 LM2 LM3 LM4 Physical Data Units Blend AB AB+ AB+ AB+ AB+ 2%LM 5%LM 10%LM 20%LM 7.8 x 7.8 x 7.8 x 7.8 x 7.8 x Format mm 58+25) (58+25) (58+25) (58+25) (58+25) Cigarette weight mg 823 832 838 855 853 Oven Horo moisture % 11.5 10.8 11.1 11.0 10.3 Pressure drop open Pdo* mmWG 71 73 74 72 68 Pressure drop closed Pdc** mmWG 118 121 121 119 110 Ventilation % 51.7 50.6 50.2 51.5 51.4 Tobacco Data Units Tobacco nicotine % d.b. 2.33 2.28 2.07 1.95 1.75 Ammonia % d.b. 0.16 0.16 0.15 0.14 0.13 Nitrate % d.b. 1.04 1.0 1.04 1.00 0.85 Chloride % d.b. 0.93 0.90 0.96 0.93 0.89 Sacchrose (HPLC) % d.b. 1.4 1.4 1.4 1.4 1.4 Glucose (HPLC) % d.b. 2.1 2.0 2.0 1.9 1.9 Fructose (HPLC) % d.b. 3.0 3.0 3.1 2.9 3.1 Tobacco pH 5.54 5.56 5.59 5.57 5.54 Acid equivalents 11.0 10.6 10.1 9.8 9.4 Propylene Glycol % d.b. 1.2 1.2 1.2 1.2 1.1 Smoke Data (DIN ISO 4387/A) Smoke nicotine mg/Cig. 0.48 0.52 0.53 0.54 0.54 WTPM mg/Cig. 6.5 6.9 7.1 7.2 7.7 NFDPM mg/Cig. 5.3 5.9 6.0 6.2 6.6 Puff Number 6.1 6.3 6.6 6.7 6.8 CO mg/Cig. 5.3 5.7 5.8 5.9 6.2 5 -Explanations to Tables 7 and 8 CS: Control Sample LM1-LM4: Lemon Myrtle samples 1-4 WO 2013/091844 PCT/EP2012/005252 - 23 G1-G3: Ginger samples 1-3 * Pressure drop measured with open filter wrapper perforation ** Pressure drop measured with closed filter wrapper perforation in mg KOH/g tobacco d.b. s AB: American Blend d.b.: dry base mmWG: millimeter Water Gauge (ISO 10185) HPLC: High Performance Liquid Chromatography WTPM: Wet Total Particulate Matter (ISO 10185) lo NFDPM: Nicotine Free Dry Particulate Matter (ISO 10185) Cig.: Cigarette Example 8: Mixture of tobacco and ginger 15 In Example 8, ginger (Zingiber officinale) was used to prepare virtually homogeneous mixtures of dried ginger rhizome parti cles and American blend tobacco. From mixtures containing 2%, 5%, and 10% ginger by weight (related to the total weight of 20 ginger and tobacco), designated by G1, G2 and G3, respec .tively, filter cigarettes of 7.9 mm diameter with a cellulose acetate filter plug of 27 mm length and a tobacco/ginger rod of 56 mm in length were made. Some constituents of the to bacco/ginger mixtures were analysed. Moreover, properties of 25 the cigarettes including smoke data (according to DIN ISO 4387/A) were measured. The results for the samples G1, G2 and G3 as well as for a control sample CS (American blend tobacco without ginger) are summarised in Table 8. The abbreviations used in Table 8 are explained at the end of Table 7 above. 30 It is evident from Table 8 that the tobacco nicotine (i.e. the relative amount of nicotine in the mixture of tobacco-and gin ger) decreases with increasing amount of ginger in the mix ture. Any decrease of smoke nicotine was not observed.
WO 2013/091844 PCT/EP2012/005252 - 24 Table 8 Data for cigarettes made from mixtures of American blend tobacco and ginger Sample CS G1 G2 G3 Physical Data. Units Blend AB AB+2% AB+5% AB+10% Ginger Ginger Ginger 7.9 x 7.9 x 7.9 x 7.9 x Format mm (56+27) (56+27) (56+27) (56+27) Cgarette weight mg 907 858 842 905 Pessure drop closed Pdc** mmWG 169 165 158 172 Ventilation % 0.0 0.0 0.0 0.0 Tobacco Data Units Tobacco nicotine % d.b. 2.36 2.23 2.08 2.05 Ammonia % d.b. 0.18 0.17 0.17 0.16 Nitrate % d.b. 1.05 1.00 0.97 0.95 Chloride % d.b. 0.95 0.86 0.79 0.86 Sacchrose (HPLC) % d.b. 1.6 1.6 1.1 1.7 Glucose (HPLC) % d.b. 2.0 2.0 1.9 2.0 Fructose (HPLC) % d.b. 3.0 3.0 3.0 3.0 Tobacco pH 5.58 5.59 5.53 5.60 Acid equivalents * 10.7 10.6 10.9 10.0 Propylene Glycol % d.b. 1.2 1.2 0.7 1.1 Smoke Data DIN ISO 4387/A Smoke nicotine mg/Cig. 0.62 0.62 0.60 0.67 WTPM mg/Cig. 10.1 10.2 10.0 10.8 NFDPM mg/Cig. 8.1 8.4 8.2 8.8 Puff Number 5.9 6.1 5.9 6.8 CO mg/Cig. 11.7 12.3 12.1 12.5 5 Example 9: Mixture of tobacco and lavender Cigarettes containing 2% and 5% of lavender (Lavandula offici 10 nalis) blossoms (related to the total weight of lavender and tobacco) were produced according to Example 4. The cigarettes WO 2013/091844 PCT/EP2012/005252 - 25 were smoked by an expert panel to evaluate their taste proper ties. While the 2%-lavender sample was judged to have a slightly soapy and perfume-like taste, lavender taste was clearly identified in the 5%-sample. 5 Both versions were also machine-smoked in an. experimental stainless-steel chamber. After smoking was finished, the air in the closed chamber was thoroughly mixed by fans. A trained smell panel was asked to evaluate the smoke in the chamber us 10 ing a standard questionnaire. It was found that smoke inten sity remained unchanged compared to a standard cigarette while the smoke smell was judged to be less intense and more pleas ant for the 2%-lavender sample. A similar effect was noted for the 5%-sample, but in contrast to the 2%-sample, a distinct 15 lavender smell was also recognized. Example 10: Tobacco/lavender with low-sidestream paper 20 Cigarettes containing 2% lavender blossoms (related to.the to tal weight of lavender and tobacco) were produced according to Examples 4 and 5, but instead of a conventional cigarette pa per, a low-sidestream (LSS) cigarette paper was used. The pa per had a porosity of 6 CU, a base weight of 45 g/m2 and a 25 filler content of 45% calcite. 1 CU = 1 Coresta unit = 1 ml/(cm 2 -min-kPa). The smoke smell in an experimental chamber was evaluated as in Example 9. The panel found that not only smoke intensity was 30 reduced compared to a conventional cigarette but also the smoke smell was more pleasant and less irritating.

Claims (20)

1. Tobacco-containing article, comprising - tobacco and 5 - aromatic plant parts, which do not derive from the to bacco plant, - wherein the amount of the aromatic plant parts is in the range of from 0.5% by weight to 25% by weight, related to the total weight of the tobacco and the aromatic plant. 10 parts, and - wherein the tobacco-containing article is provided as one of the following tobacco-containing articles: a ciga rette, a cigarillo, a cigar, pipe tobacco, fine-cut for self-made cigarettes. 15
2. Tobacco-containing article according to claim 1, charac terised in that the aromatic plant parts have a size, de fined by a screening method, in the range of from 0.1 mm to 10 mm. 20
3. Tobacco-containing article according to claim 2, charac terised in that the aromatic plant parts have a size in the range of from 0.2 mm to 6 mm. 25
4. Tobacco-containing article according to anyone of claims 1 to 3, characterised in that the aromatic plant parts com prise at least one of the substances selected from the following list: spearmint, peppermint, anise, rosemary, wintergreen, avocado, ground coffee beans. 30
5. Tobacco-containing article according to anyone of claims 1 to 4, characterised in that at least part of the tobacco and of the aromatic plant parts are included in a combined mixture. 3 5 WO 2013/091844 PCT/EP2012/005252 - 27
6. Tobacco-containing article according to anyone of claims 1 to 5, characterised in that at least part of the tobacco comprises reconstituted tobacco. 5
7. Tobacco-containing article according to anyone of claims 1 to 6, characterised in that at least part of the aromatic plant parts comprises a reconstituted product.
8. Tobacco-containing article according to anyone of claims 1 10 to 5, characterised in that at least part of the tobacco and of the aromatic plant parts are included in a combined reconstituted product.
9. Tobacco-containing article according to anyone of claims 1 15 to 8, characterised in that at least part of the aromatic plant parts is provided in the form of granules, prefera bly of a size in the range of from 0.2 mm to 5 mm or from 0.5 mm to 2.5'mm. 20
10. Tobacco-containing article according to claim 9, charac terised in that at least part of the granules consists of pressed aromatic plant parts and optionally additional wa ter, without further additives. 25
11. Tobacco-containing article according to anyone of claims 1 to 10, characterised by a cut top-loaded sheet product, in which a base layer comprises reconstituted tobacco, wherein the base layer is provided on one side with aro matic plant parts. 30
12. Tobacco-containing article according to anyone of claims 1 to 11, characterised by a cut top-loaded sheet product, in which a base layer comprises reconstituted aromatic plant parts, wherein the base layer is provided on one side with 35 aromatic plant parts. WO 2013/091844 PCT/EP2012/005252 - 28
13. Tobacco-containing article according to anyone of claims 1 to 12, characterised by at least one flavourant in addi tion to the aromatic plant parts, preferably added as a 5 liquid.
14. Tobacco-containing article according to anyone of claims 1 to 13, characterised in that the tobacco comprises an American blend or a Virginia blend. 10
15. Tobacco-containing article according to anyone of claims 1 to 14, characterised in that the aromatic plant parts have a moisture of from 5% to 35%, preferably of from 5% to 20% or from 7% to 12%, related to the dry weight of the re 15 spective aromatic plant parts plus the moisture.
16. Tobacco-containing article according to anyone of claims 1 to 15, characterised in that the aromatic plant parts com prise at least one of the substances selected from the 20 following list: lavender, mate.
17. Tobacco-containing article according to anyone of claims 1 to 16, characterised in that the aromatic plant parts com prise at least one of the substances selected from the 25 following list: ginger, lemon myrtle.
18. Tobacco-containing article according to anyone of claims 1 to 17, characterised in that the tobacco-containing arti cle comprises a rod, which is wrapped by a low-sidestream 30 cigarette paper having a base weight in the range of from 35 g/m2 to 60 g/m2, having a porosity of less than 15 CU and comprising a filler, wherein the filler comprises at least one of the compounds selected from the following list: CaCO 3 of at least 30%, MgO of at least 3%, Mg(OH) 2 Of '5 at least 3%, the percentages being percent per weight of WO 2013/091844 PCT/EP2012/005252 - 29 the respective compound, related to the total weight of the low-sidestream.cigarette paper.
19. Method of manufacturing a tobacco-containing article ac 5 cording to claim 1, wherein, after cutting tobacco, aro matic plant parts, which do not derive from the tobacco plant and which, preferably, have a size defined by a screening method in the range of from 0.1 mm to 10 mm or in the range of from 0.2 mm to 6 mm, are added to the to 10 bacco in an amount in the range of from 0.5% by weight to 25% by weight, related to the total weight of the tobacco and the aromatic plant parts.
20. Method according to claim 19, characterised in that aro 15 matic plant parts are added during treatment of the cut tobacco.
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MA35848B1 (en) 2014-12-01
TWI578920B (en) 2017-04-21
AU2012359201B2 (en) 2015-09-17
EP2606751A1 (en) 2013-06-26
TN2014000231A1 (en) 2015-09-30
RU2604460C2 (en) 2016-12-10
TW201332459A (en) 2013-08-16
UA114307C2 (en) 2017-05-25
WO2013091844A1 (en) 2013-06-27
PL2793623T3 (en) 2017-06-30
JP2015502161A (en) 2015-01-22
ES2610212T3 (en) 2017-04-26
EP2793623B1 (en) 2016-10-19
NZ625665A (en) 2015-11-27
RU2014129553A (en) 2016-02-10
EP2793623A1 (en) 2014-10-29

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