AU2011330718B2 - Additive and method for removal of calcium from crude oils containing calcium naphthenate. - Google Patents
Additive and method for removal of calcium from crude oils containing calcium naphthenate. Download PDFInfo
- Publication number
- AU2011330718B2 AU2011330718B2 AU2011330718A AU2011330718A AU2011330718B2 AU 2011330718 B2 AU2011330718 B2 AU 2011330718B2 AU 2011330718 A AU2011330718 A AU 2011330718A AU 2011330718 A AU2011330718 A AU 2011330718A AU 2011330718 B2 AU2011330718 B2 AU 2011330718B2
- Authority
- AU
- Australia
- Prior art keywords
- crude oil
- calcium
- additive
- glyoxylic acid
- wash water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000010779 crude oil Substances 0.000 title claims abstract description 116
- 239000011575 calcium Substances 0.000 title claims abstract description 106
- 239000000654 additive Substances 0.000 title claims abstract description 104
- 230000000996 additive effect Effects 0.000 title claims abstract description 76
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 73
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 83
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 claims description 123
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 66
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 34
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 30
- 229910052717 sulfur Inorganic materials 0.000 claims description 30
- 239000011593 sulfur Substances 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 25
- 229910021529 ammonia Inorganic materials 0.000 claims description 17
- 239000000908 ammonium hydroxide Substances 0.000 claims description 16
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 15
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 15
- 150000002830 nitrogen compounds Chemical class 0.000 claims description 15
- 150000007514 bases Chemical class 0.000 claims description 14
- 125000005609 naphthenate group Chemical group 0.000 claims description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 58
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 32
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 31
- 239000001630 malic acid Substances 0.000 description 31
- 235000011090 malic acid Nutrition 0.000 description 31
- 239000010410 layer Substances 0.000 description 27
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 238000002474 experimental method Methods 0.000 description 20
- 239000002253 acid Substances 0.000 description 18
- 238000010979 pH adjustment Methods 0.000 description 17
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 9
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 9
- 235000012208 gluconic acid Nutrition 0.000 description 9
- 229950006191 gluconic acid Drugs 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- IFQUWYZCAGRUJN-UHFFFAOYSA-N ethylenediaminediacetic acid Chemical compound OC(=O)CNCCNCC(O)=O IFQUWYZCAGRUJN-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- -1 amine compounds Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
- C10G17/02—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acids or acid-containing liquids, e.g. acid sludge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/08—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by treating with water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN3111/MUM/2010 | 2010-11-15 | ||
| IN3111MU2010 | 2010-11-15 | ||
| PCT/IN2011/000786 WO2012066566A1 (en) | 2010-11-15 | 2011-11-14 | Additive and method for removal of calcium from crude oils containing calcium naphthenate. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2011330718A1 AU2011330718A1 (en) | 2013-06-06 |
| AU2011330718B2 true AU2011330718B2 (en) | 2016-02-25 |
Family
ID=45607323
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2011330718A Ceased AU2011330718B2 (en) | 2010-11-15 | 2011-11-14 | Additive and method for removal of calcium from crude oils containing calcium naphthenate. |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US9434889B2 (enExample) |
| EP (1) | EP2640809B1 (enExample) |
| JP (1) | JP5852125B2 (enExample) |
| KR (1) | KR101748417B1 (enExample) |
| CN (1) | CN103210064B (enExample) |
| AU (1) | AU2011330718B2 (enExample) |
| BR (1) | BR112013012007B1 (enExample) |
| CA (1) | CA2817040C (enExample) |
| CL (1) | CL2013001337A1 (enExample) |
| CO (1) | CO6721015A2 (enExample) |
| ES (1) | ES2882131T3 (enExample) |
| HR (1) | HRP20211301T1 (enExample) |
| MX (1) | MX342558B (enExample) |
| MY (1) | MY163743A (enExample) |
| PE (1) | PE20140394A1 (enExample) |
| PH (1) | PH12013500887A1 (enExample) |
| PL (1) | PL2640809T3 (enExample) |
| RS (1) | RS62223B1 (enExample) |
| SG (1) | SG190706A1 (enExample) |
| WO (1) | WO2012066566A1 (enExample) |
| ZA (1) | ZA201304365B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2761942T3 (es) * | 2009-04-15 | 2020-05-21 | Dorf Ketal Chemicals I Private Ltd | Procedimiento de uso de un aditivo no polimérico y antiincrustante efectivo para inhibir la corrosión por ácido nafténico a alta temperatura |
| ES2882131T3 (es) | 2010-11-15 | 2021-12-01 | Dorf Ketal Chemicals India Private Ltd | Eliminación del calcio del petróleo crudo que contiene naftenato de calcio |
| EP3316982B1 (en) * | 2015-07-01 | 2020-02-19 | Dorf Ketal Chemicals (India) Private Limited | Additive composition for demulsification of water-in-oil emulsion, and method of use thereof, and method of demulsification |
| CN109790472B (zh) * | 2016-09-22 | 2021-06-01 | Bp北美公司 | 从原油除去污染物 |
| US20200239785A1 (en) * | 2019-01-24 | 2020-07-30 | Exxonmobil Research And Engineering Company | Organic acid removal from liquid hydrocarbon product streams |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4476930A (en) * | 1982-08-23 | 1984-10-16 | Union Oil Company Of California | Inhibition of scale deposition from steam generation fluids |
| US5284635A (en) * | 1989-09-05 | 1994-02-08 | Societe Francaise Hoechst | Process for the elimination of hydrogen sulfide by using water-in-oil emulsions |
| US6068056A (en) * | 1999-10-13 | 2000-05-30 | Schlumberger Technology Corporation | Well treatment fluids comprising mixed aldehydes |
| WO2010128523A2 (en) * | 2009-05-05 | 2010-11-11 | Dorf Ketal Chemicals (India) Private Limited | Method of scavenging hydrogen sulfide from hydrocarbon stream |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6361087A (ja) * | 1986-08-28 | 1988-03-17 | シエブロン リサ−チ カンパニ− | 炭化水素供給原料の脱金属方法 |
| FR2651500A1 (fr) * | 1989-09-05 | 1991-03-08 | Hoechst France | Nouvelles emulsions eau dans huile et leur application a l'elimination du sulfure d'hydrogene. |
| JPH03277691A (ja) * | 1990-03-27 | 1991-12-09 | Chevron Res Co | 炭化水素原料からの金属除去方法 |
| MY160536A (en) * | 2008-01-24 | 2017-03-15 | Dorf Ketal Chemicals (I) Private Ltd | Method of removing metals from hydrocarbon feedstock using esters of carboxylic acids |
| ES2882131T3 (es) | 2010-11-15 | 2021-12-01 | Dorf Ketal Chemicals India Private Ltd | Eliminación del calcio del petróleo crudo que contiene naftenato de calcio |
-
2011
- 2011-11-14 ES ES11817538T patent/ES2882131T3/es active Active
- 2011-11-14 JP JP2013538334A patent/JP5852125B2/ja not_active Expired - Fee Related
- 2011-11-14 RS RS20211017A patent/RS62223B1/sr unknown
- 2011-11-14 PL PL11817538T patent/PL2640809T3/pl unknown
- 2011-11-14 US US13/885,216 patent/US9434889B2/en active Active
- 2011-11-14 AU AU2011330718A patent/AU2011330718B2/en not_active Ceased
- 2011-11-14 BR BR112013012007-0A patent/BR112013012007B1/pt not_active IP Right Cessation
- 2011-11-14 HR HRP20211301TT patent/HRP20211301T1/hr unknown
- 2011-11-14 EP EP11817538.9A patent/EP2640809B1/en active Active
- 2011-11-14 PE PE2013001081A patent/PE20140394A1/es active IP Right Grant
- 2011-11-14 PH PH1/2013/500887A patent/PH12013500887A1/en unknown
- 2011-11-14 CN CN201180055049.1A patent/CN103210064B/zh not_active Expired - Fee Related
- 2011-11-14 WO PCT/IN2011/000786 patent/WO2012066566A1/en not_active Ceased
- 2011-11-14 MX MX2013005404A patent/MX342558B/es active IP Right Grant
- 2011-11-14 SG SG2013037429A patent/SG190706A1/en unknown
- 2011-11-14 MY MYPI2013700797A patent/MY163743A/en unknown
- 2011-11-14 CA CA2817040A patent/CA2817040C/en active Active
- 2011-11-14 KR KR1020137015222A patent/KR101748417B1/ko active Active
-
2013
- 2013-05-14 CL CL2013001337A patent/CL2013001337A1/es unknown
- 2013-06-13 ZA ZA2013/04365A patent/ZA201304365B/en unknown
- 2013-06-14 CO CO13142402A patent/CO6721015A2/es unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4476930A (en) * | 1982-08-23 | 1984-10-16 | Union Oil Company Of California | Inhibition of scale deposition from steam generation fluids |
| US5284635A (en) * | 1989-09-05 | 1994-02-08 | Societe Francaise Hoechst | Process for the elimination of hydrogen sulfide by using water-in-oil emulsions |
| US6068056A (en) * | 1999-10-13 | 2000-05-30 | Schlumberger Technology Corporation | Well treatment fluids comprising mixed aldehydes |
| WO2010128523A2 (en) * | 2009-05-05 | 2010-11-11 | Dorf Ketal Chemicals (India) Private Limited | Method of scavenging hydrogen sulfide from hydrocarbon stream |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2640809B1 (en) | 2021-05-19 |
| ES2882131T3 (es) | 2021-12-01 |
| JP2013542306A (ja) | 2013-11-21 |
| KR20130106863A (ko) | 2013-09-30 |
| SG190706A1 (en) | 2013-07-31 |
| WO2012066566A1 (en) | 2012-05-24 |
| KR101748417B1 (ko) | 2017-06-16 |
| CL2013001337A1 (es) | 2013-08-09 |
| US9434889B2 (en) | 2016-09-06 |
| BR112013012007B1 (pt) | 2018-12-26 |
| CN103210064A (zh) | 2013-07-17 |
| PE20140394A1 (es) | 2014-04-03 |
| PL2640809T3 (pl) | 2021-11-22 |
| US20130233770A1 (en) | 2013-09-12 |
| MY163743A (en) | 2017-10-31 |
| CO6721015A2 (es) | 2013-07-31 |
| HRP20211301T1 (hr) | 2021-11-12 |
| CA2817040A1 (en) | 2012-05-24 |
| MX2013005404A (es) | 2013-08-01 |
| AU2011330718A1 (en) | 2013-06-06 |
| ZA201304365B (en) | 2014-09-25 |
| CA2817040C (en) | 2016-07-12 |
| BR112013012007A2 (pt) | 2016-09-06 |
| RS62223B1 (sr) | 2021-09-30 |
| CN103210064B (zh) | 2016-03-16 |
| PH12013500887A1 (en) | 2022-10-24 |
| JP5852125B2 (ja) | 2016-02-03 |
| EP2640809A1 (en) | 2013-09-25 |
| MX342558B (es) | 2016-10-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |