AU2006227654A1 - Anti-blocking compositions comprising interpolymers of ethylene/alpha-olefins - Google Patents
Anti-blocking compositions comprising interpolymers of ethylene/alpha-olefins Download PDFInfo
- Publication number
- AU2006227654A1 AU2006227654A1 AU2006227654A AU2006227654A AU2006227654A1 AU 2006227654 A1 AU2006227654 A1 AU 2006227654A1 AU 2006227654 A AU2006227654 A AU 2006227654A AU 2006227654 A AU2006227654 A AU 2006227654A AU 2006227654 A1 AU2006227654 A1 AU 2006227654A1
- Authority
- AU
- Australia
- Prior art keywords
- ethylene
- polymer
- percent
- interpolymer
- peak
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 147
- 239000005977 Ethylene Substances 0.000 title claims description 147
- 239000000203 mixture Substances 0.000 title claims description 147
- 239000004711 α-olefin Substances 0.000 title description 4
- 229920000642 polymer Polymers 0.000 claims description 379
- -1 propylene-ethylene Chemical group 0.000 claims description 89
- 238000002844 melting Methods 0.000 claims description 52
- 230000008018 melting Effects 0.000 claims description 52
- 239000002981 blocking agent Substances 0.000 claims description 41
- 230000004927 fusion Effects 0.000 claims description 38
- 229920001577 copolymer Polymers 0.000 claims description 32
- 238000009826 distribution Methods 0.000 claims description 27
- 238000003860 storage Methods 0.000 claims description 22
- 238000011084 recovery Methods 0.000 claims description 19
- 229920005604 random copolymer Polymers 0.000 claims description 18
- 150000001408 amides Chemical class 0.000 claims description 15
- 239000000155 melt Substances 0.000 claims description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 230000001186 cumulative effect Effects 0.000 claims description 8
- 229910052702 rhenium Inorganic materials 0.000 claims description 5
- 229910052775 Thulium Inorganic materials 0.000 claims description 4
- 229920005653 propylene-ethylene copolymer Polymers 0.000 claims 6
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims 1
- 239000011342 resin composition Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 64
- 239000003054 catalyst Substances 0.000 description 46
- 239000000523 sample Substances 0.000 description 45
- 238000000113 differential scanning calorimetry Methods 0.000 description 44
- 239000000178 monomer Substances 0.000 description 39
- 230000000052 comparative effect Effects 0.000 description 38
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 32
- 150000001336 alkenes Chemical class 0.000 description 27
- 230000000903 blocking effect Effects 0.000 description 27
- 230000006835 compression Effects 0.000 description 27
- 238000007906 compression Methods 0.000 description 27
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 27
- 229920001400 block copolymer Polymers 0.000 description 25
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 24
- 239000008188 pellet Substances 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 23
- 239000000243 solution Substances 0.000 description 23
- 239000000654 additive Substances 0.000 description 22
- 230000008569 process Effects 0.000 description 22
- 239000002904 solvent Substances 0.000 description 22
- 125000004432 carbon atom Chemical group C* 0.000 description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 20
- 150000001993 dienes Chemical class 0.000 description 20
- 239000010408 film Substances 0.000 description 20
- 239000002245 particle Substances 0.000 description 20
- 239000000126 substance Substances 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 229920000098 polyolefin Polymers 0.000 description 18
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 17
- 238000010828 elution Methods 0.000 description 17
- 238000006116 polymerization reaction Methods 0.000 description 17
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 16
- 229920003023 plastic Polymers 0.000 description 16
- 239000004033 plastic Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 125000000217 alkyl group Chemical group 0.000 description 15
- 238000002156 mixing Methods 0.000 description 14
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 14
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 13
- 125000003342 alkenyl group Chemical group 0.000 description 13
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical group CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 13
- 238000001125 extrusion Methods 0.000 description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 13
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 12
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 12
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000005481 NMR spectroscopy Methods 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 12
- 230000035515 penetration Effects 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 239000000945 filler Substances 0.000 description 11
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000004014 plasticizer Substances 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 9
- 238000004364 calculation method Methods 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 8
- 239000002216 antistatic agent Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000000314 lubricant Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 239000012963 UV stabilizer Substances 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 7
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 7
- 238000011088 calibration curve Methods 0.000 description 7
- 239000003086 colorant Substances 0.000 description 7
- 239000003431 cross linking reagent Substances 0.000 description 7
- 125000000392 cycloalkenyl group Chemical group 0.000 description 7
- 238000005194 fractionation Methods 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000000454 talc Substances 0.000 description 7
- 229910052623 talc Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical class C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 6
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical class C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 6
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000071 blow moulding Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 125000000753 cycloalkyl group Chemical group 0.000 description 6
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 6
- 150000002466 imines Chemical class 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 6
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 6
- SOEVKJXMZBAALG-UHFFFAOYSA-N octylalumane Chemical compound CCCCCCCC[AlH2] SOEVKJXMZBAALG-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 229920002223 polystyrene Polymers 0.000 description 6
- 150000003141 primary amines Chemical class 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 230000004044 response Effects 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 5
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 5
- 229920013665 Ampacet Polymers 0.000 description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 5
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
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- 125000004122 cyclic group Chemical group 0.000 description 5
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- 235000014113 dietary fatty acids Nutrition 0.000 description 5
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- 238000000605 extraction Methods 0.000 description 5
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- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
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- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 5
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- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 description 4
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- 238000005299 abrasion Methods 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000010410 dusting Methods 0.000 description 4
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 4
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 4
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- 238000002347 injection Methods 0.000 description 4
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- 150000002576 ketones Chemical class 0.000 description 4
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- 150000003335 secondary amines Chemical class 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
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- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
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- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 3
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- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 2
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- JUOCTSZRGAFSKS-UHFFFAOYSA-N CCCCCC[Zn]CCCCCC Chemical compound CCCCCC[Zn]CCCCCC JUOCTSZRGAFSKS-UHFFFAOYSA-N 0.000 description 2
- RDRSMXYUSKJLIZ-UHFFFAOYSA-M CC[Zn+].[O-]C1=C(C=2C=CC=CC=2)C=CC=C1C1=CC=CC=C1 Chemical compound CC[Zn+].[O-]C1=C(C=2C=CC=CC=2)C=CC=C1C1=CC=CC=C1 RDRSMXYUSKJLIZ-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
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- 229910052759 nickel Inorganic materials 0.000 description 1
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- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002848 norbornenes Chemical class 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- PRKFEDZJXPHATD-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)prop-2-enoate Chemical class CCCCCCCCCCCCCCCCCCOC(=O)C=CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 PRKFEDZJXPHATD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 1
- 150000004989 p-phenylenediamines Chemical class 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- 150000002979 perylenes Chemical class 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229910003446 platinum oxide Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000005932 reductive alkylation reaction Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- BEOOHQFXGBMRKU-UHFFFAOYSA-N sodium cyanoborohydride Chemical compound [Na+].[B-]C#N BEOOHQFXGBMRKU-UHFFFAOYSA-N 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000005472 straight-chain saturated fatty acid group Chemical group 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229910002029 synthetic silica gel Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- CWXZMNMLGZGDSW-UHFFFAOYSA-N tetracontanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O CWXZMNMLGZGDSW-UHFFFAOYSA-N 0.000 description 1
- QZZGJDVWLFXDLK-UHFFFAOYSA-N tetracosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(O)=O QZZGJDVWLFXDLK-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- BITHHVVYSMSWAG-MDZDMXLPSA-N trans-gondoic acid Chemical compound CCCCCCCC\C=C\CCCCCCCCCC(O)=O BITHHVVYSMSWAG-MDZDMXLPSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- QEPDENOFSCCDEA-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl)alumane;2-undecyl-1h-imidazole Chemical compound CCCCCCCCCCCC1=NC=CN1.FC1=C(F)C(F)=C(F)C(F)=C1[Al](C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F.FC1=C(F)C(F)=C(F)C(F)=C1[Al](C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F QEPDENOFSCCDEA-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- CZPRKINNVBONSF-UHFFFAOYSA-M zinc;dioxido(oxo)phosphanium Chemical compound [Zn+2].[O-][P+]([O-])=O CZPRKINNVBONSF-UHFFFAOYSA-M 0.000 description 1
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPCT/US2005/008917 | 2005-03-17 | ||
| PCT/US2005/008917 WO2005090427A2 (en) | 2004-03-17 | 2005-03-17 | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| US71758805P | 2005-09-16 | 2005-09-16 | |
| US60/717,588 | 2005-09-16 | ||
| PCT/US2006/009378 WO2006101915A2 (en) | 2005-03-17 | 2006-03-15 | Anti-blocking compositions comprising interpolymers of ethylene/alpha-olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2006227654A1 true AU2006227654A1 (en) | 2006-09-28 |
Family
ID=36593137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2006227654A Abandoned AU2006227654A1 (en) | 2005-03-17 | 2006-03-15 | Anti-blocking compositions comprising interpolymers of ethylene/alpha-olefins |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1858941B1 (https=) |
| JP (1) | JP5199064B2 (https=) |
| KR (1) | KR101399691B1 (https=) |
| AR (1) | AR053695A1 (https=) |
| AT (1) | ATE495207T1 (https=) |
| AU (1) | AU2006227654A1 (https=) |
| BR (1) | BRPI0609815B1 (https=) |
| CA (1) | CA2601233A1 (https=) |
| DE (1) | DE602006019556D1 (https=) |
| MX (1) | MX2007011314A (https=) |
| RU (1) | RU2007134347A (https=) |
| TW (1) | TWI373476B (https=) |
| WO (1) | WO2006101915A2 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7786216B2 (en) * | 2005-03-17 | 2010-08-31 | Dow Global Technologies Inc. | Oil based blends of interpolymers of ethylene/α-olefins |
| BRPI0816523B1 (pt) | 2007-10-22 | 2018-12-11 | Dow Global Technologies Inc | composição polimérica e processo para fabricar um artigo moldado |
| WO2010025342A2 (en) * | 2008-08-28 | 2010-03-04 | Dow Global Technologies Inc. | Process and compositions for injections blow molding |
| CN102725345B (zh) * | 2009-09-18 | 2014-12-10 | 陶氏环球技术有限责任公司 | 用于凝塑成形工艺的粉末热塑性聚烯烃弹性体组合物 |
| EP2580278B1 (en) * | 2010-06-08 | 2014-10-29 | Dow Global Technologies LLC | Polyolefin elastomer composition for artificial leather applications |
| EP2961795B1 (en) * | 2013-02-28 | 2017-04-12 | Dow Global Technologies LLC | Improved powdered thermoplastic polyolefin elastomer composition for slush molding |
| KR101388194B1 (ko) * | 2013-09-13 | 2014-04-23 | 화인케미칼 주식회사 | 냉장고 가스켓용 조성물 |
| US10428229B2 (en) | 2017-12-28 | 2019-10-01 | Industrial Technology Research Institute | Aqueous coating material and method for manufacturing the same |
| WO2019188338A1 (ja) * | 2018-03-28 | 2019-10-03 | Nok株式会社 | ゴム組成物 |
| CN112090518B (zh) * | 2020-08-20 | 2021-12-31 | 南京美星鹏科技实业有限公司 | 用于智能设备显示屏基材的混合材料的制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4762890A (en) * | 1986-09-05 | 1988-08-09 | The Dow Chemical Company | Method of grafting maleic anhydride to polymers |
| US4927888A (en) * | 1986-09-05 | 1990-05-22 | The Dow Chemical Company | Maleic anhydride graft copolymers having low yellowness index and films containing the same |
| US4950541A (en) * | 1984-08-15 | 1990-08-21 | The Dow Chemical Company | Maleic anhydride grafts of olefin polymers |
| JPH0827305A (ja) * | 1994-07-13 | 1996-01-30 | Fuji Photo Film Co Ltd | 写真感光材料の包装材料用着色マスターバッチ樹脂組成物及びその製造方法並びに写真感光材料用包装材料及びその製造方法 |
| JP4688247B2 (ja) * | 1998-08-25 | 2011-05-25 | 株式会社プライムポリマー | プロピレン系樹脂組成物、その製造方法および用途 |
| DE69909689T2 (de) * | 1998-08-25 | 2004-04-15 | Idemitsu Petrochemical Co., Ltd. | Propylenharzzusammensetzungen, Verfahren zur Herstellung und Verwendung |
| US6287705B1 (en) * | 1998-09-01 | 2001-09-11 | Idemitsu Petrochemical Co., Ltd. | Propylene random copolymer, propylene resin composition, film of these, and multilayered propylene resin laminate |
| JP2000313777A (ja) * | 1999-04-28 | 2000-11-14 | Idemitsu Petrochem Co Ltd | プロピレン系共重合体及び該共重合体を成形してなる成形体 |
| JP4384782B2 (ja) * | 2000-04-07 | 2009-12-16 | 日本ポリプロ株式会社 | プロピレン系樹脂組成物 |
| DE60106219T2 (de) * | 2001-06-27 | 2006-03-09 | Borealis Technology Oy | Propylen-Copolymer mit zufälliger Comonomerverteilung und Verfahren zu seiner Herstellung |
| JP2004204058A (ja) * | 2002-12-25 | 2004-07-22 | Mitsui Chemicals Inc | オレフィン系ブロック共重合体 |
| JP4068953B2 (ja) * | 2002-12-25 | 2008-03-26 | 三井化学株式会社 | プロピレン系樹脂組成物 |
| JP4907062B2 (ja) * | 2004-04-20 | 2012-03-28 | 日本ポリプロ株式会社 | ポリプロピレン系二軸延伸複層フィルム |
| NZ549262A (en) * | 2004-03-17 | 2010-08-27 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| JP5159302B2 (ja) * | 2004-03-17 | 2013-03-06 | ダウ グローバル テクノロジーズ エルエルシー | エチレンコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| AU2005224259B2 (en) * | 2004-03-17 | 2010-09-09 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| JP4512411B2 (ja) * | 2004-04-30 | 2010-07-28 | 日本ポリプロ株式会社 | 新規なプロピレン−エチレンランダムブロック共重合体 |
-
2006
- 2006-03-15 MX MX2007011314A patent/MX2007011314A/es active IP Right Grant
- 2006-03-15 RU RU2007134347/04A patent/RU2007134347A/ru not_active Application Discontinuation
- 2006-03-15 KR KR1020077021232A patent/KR101399691B1/ko not_active Expired - Lifetime
- 2006-03-15 EP EP06738441A patent/EP1858941B1/en not_active Expired - Lifetime
- 2006-03-15 TW TW095108736A patent/TWI373476B/zh not_active IP Right Cessation
- 2006-03-15 JP JP2008502012A patent/JP5199064B2/ja not_active Expired - Lifetime
- 2006-03-15 AT AT06738441T patent/ATE495207T1/de not_active IP Right Cessation
- 2006-03-15 WO PCT/US2006/009378 patent/WO2006101915A2/en not_active Ceased
- 2006-03-15 DE DE602006019556T patent/DE602006019556D1/de not_active Expired - Lifetime
- 2006-03-15 AU AU2006227654A patent/AU2006227654A1/en not_active Abandoned
- 2006-03-15 CA CA002601233A patent/CA2601233A1/en not_active Abandoned
- 2006-03-15 BR BRPI0609815A patent/BRPI0609815B1/pt active IP Right Grant
- 2006-03-15 AR ARP060101004A patent/AR053695A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006101915A3 (en) | 2007-06-14 |
| ATE495207T1 (de) | 2011-01-15 |
| KR101399691B1 (ko) | 2014-05-27 |
| BRPI0609815B1 (pt) | 2018-11-06 |
| DE602006019556D1 (de) | 2011-02-24 |
| EP1858941A2 (en) | 2007-11-28 |
| TWI373476B (en) | 2012-10-01 |
| CA2601233A1 (en) | 2006-09-28 |
| WO2006101915A2 (en) | 2006-09-28 |
| RU2007134347A (ru) | 2009-03-20 |
| WO2006101915B1 (en) | 2007-08-02 |
| EP1858941B1 (en) | 2011-01-12 |
| TW200640959A (en) | 2006-12-01 |
| MX2007011314A (es) | 2007-11-08 |
| JP5199064B2 (ja) | 2013-05-15 |
| AR053695A1 (es) | 2007-05-16 |
| BRPI0609815A2 (pt) | 2010-04-27 |
| JP2008540694A (ja) | 2008-11-20 |
| KR20070119647A (ko) | 2007-12-20 |
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