AU2006202179B2 - Lower-energy process for preparing passivated inorganic nanoparticles - Google Patents
Lower-energy process for preparing passivated inorganic nanoparticles Download PDFInfo
- Publication number
- AU2006202179B2 AU2006202179B2 AU2006202179A AU2006202179A AU2006202179B2 AU 2006202179 B2 AU2006202179 B2 AU 2006202179B2 AU 2006202179 A AU2006202179 A AU 2006202179A AU 2006202179 A AU2006202179 A AU 2006202179A AU 2006202179 B2 AU2006202179 B2 AU 2006202179B2
- Authority
- AU
- Australia
- Prior art keywords
- titanium dioxide
- alumina
- nanoparticles
- slurry
- dioxide particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000002105 nanoparticle Substances 0.000 title claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 title abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 196
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 91
- 239000000203 mixture Substances 0.000 claims abstract description 84
- 239000002245 particle Substances 0.000 claims abstract description 84
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000002002 slurry Substances 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 46
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000000576 coating method Methods 0.000 claims abstract description 23
- -1 citric acid Chemical class 0.000 claims abstract description 22
- 238000003801 milling Methods 0.000 claims abstract description 21
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 18
- 150000001450 anions Chemical class 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910001388 sodium aluminate Inorganic materials 0.000 claims abstract description 12
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- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims description 6
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- 235000003270 potassium fluoride Nutrition 0.000 claims description 5
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- 230000002776 aggregation Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
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- 239000004115 Sodium Silicate Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 4
- 150000004756 silanes Chemical class 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- 238000004383 yellowing Methods 0.000 description 4
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 3
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 229930003268 Vitamin C Natural products 0.000 description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 3
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- 125000004432 carbon atom Chemical group C* 0.000 description 3
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- 229920001296 polysiloxane Polymers 0.000 description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
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- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 2
- QUJATIZORFBTII-UHFFFAOYSA-N 3,3-dimethylbutane-1,1-diol Chemical compound CC(C)(C)CC(O)O QUJATIZORFBTII-UHFFFAOYSA-N 0.000 description 2
- VYZKQGGPNIFCLD-UHFFFAOYSA-N 3,3-dimethylhexane-2,2-diol Chemical compound CCCC(C)(C)C(C)(O)O VYZKQGGPNIFCLD-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004846 x-ray emission Methods 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
- C09C1/3661—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3615—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C1/3623—Grinding
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/66—Hue (H*)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31942—Of aldehyde or ketone condensation product
- Y10T428/31949—Next to cellulosic
- Y10T428/31964—Paper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/135,584 US7276231B2 (en) | 2005-05-23 | 2005-05-23 | Lower-energy process for preparing passivated inorganic nanoparticles |
| US11/135,584 | 2005-05-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2006202179A1 AU2006202179A1 (en) | 2006-12-07 |
| AU2006202179B2 true AU2006202179B2 (en) | 2011-09-22 |
Family
ID=36847640
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2006202179A Ceased AU2006202179B2 (en) | 2005-05-23 | 2006-05-23 | Lower-energy process for preparing passivated inorganic nanoparticles |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US7276231B2 (https=) |
| EP (1) | EP1726625A1 (https=) |
| JP (1) | JP2006342348A (https=) |
| KR (1) | KR20060121695A (https=) |
| AU (1) | AU2006202179B2 (https=) |
| CA (1) | CA2546309A1 (https=) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050129634A1 (en) * | 2003-12-16 | 2005-06-16 | Frerichs Scott R. | Passivated nano-titanium dioxide particles and methods of making the same |
| US7276231B2 (en) * | 2005-05-23 | 2007-10-02 | E I Du Pont De Nemours And Company | Lower-energy process for preparing passivated inorganic nanoparticles |
| US7790658B2 (en) | 2005-05-27 | 2010-09-07 | University of Florida Research Foundaction, Inc. | Inert wear resistant PTFE-based solid lubricant nanocomposite |
| GB0526328D0 (en) * | 2005-12-23 | 2006-02-01 | Ici Plc | Particulate metal oxide |
| TW200737520A (en) * | 2006-03-17 | 2007-10-01 | Univ Nat Chiao Tung | Gate dielectric structure and an organic thin film transistor based thereon |
| ES2679120T3 (es) | 2006-08-25 | 2018-08-22 | Venator Germany Gmbh | Partículas ultrafinas modificadas en superficie de manera inorgánica |
| AU2009296281A1 (en) * | 2008-09-29 | 2010-04-01 | E. I. Du Pont De Nemours And Company | Coating compositions having improved solar reflectivity and UV protection |
| US9982209B2 (en) | 2012-05-14 | 2018-05-29 | University Of Florida Research Foundation, Inc | Low-wear fluoropolymer composites |
| CA2891172A1 (en) * | 2012-11-13 | 2014-05-22 | E. I. Du Pont De Nemours And Company | Silica containing self-dispersing pigments |
| AU2013345220B2 (en) * | 2012-11-13 | 2016-09-08 | The Chemours Company Fc,Llc | Laminates prepared from decor paper comprising self-dispersing pigments |
| CN104937040B (zh) * | 2012-11-13 | 2017-11-21 | 纳幕尔杜邦公司 | 自分散性颜料 |
| WO2014078050A1 (en) * | 2012-11-13 | 2014-05-22 | E. I. Du Pont De Nemours And Company | Laminates prepared from décor paper comprising self-dispersing pigments |
| CN104919008B (zh) * | 2012-11-13 | 2017-07-18 | 纳幕尔杜邦公司 | 用于制备包含二氧化硅的自分散性颜料的方法 |
| WO2014078040A1 (en) * | 2012-11-13 | 2014-05-22 | E. I. Du Pont De Nemours And Company | Process for preparing self-dispersing pigments |
| ES2687230T3 (es) * | 2012-11-13 | 2018-10-24 | The Chemours Company Fc, Llc | Papel decorativo que comprende pigmentos autodispersantes |
| CA2891191A1 (en) * | 2012-11-13 | 2014-05-22 | E. I. Du Pont De Nemours And Company | Decor paper comprising self-dispersing pigments |
| AU2015343361B2 (en) * | 2014-11-06 | 2019-06-20 | The Chemours Company Fc, Llc | Preparation of lacing resistant, titanium dioxide particles for use in photodurable thin film production |
| CN104877393B (zh) * | 2015-04-08 | 2018-03-30 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种低吸油量钛白粉及其制备方法 |
| US10472530B2 (en) | 2015-07-20 | 2019-11-12 | Hewlett-Packard Development Company, L.P. | White inks |
| CN107636086B (zh) | 2015-07-20 | 2021-04-02 | 惠普发展公司，有限责任合伙企业 | 白色墨水 |
| WO2017014747A1 (en) | 2015-07-20 | 2017-01-26 | Hewlett-Packard Development Company, L.P. | Non-newtonian white inks |
| US10486029B2 (en) | 2015-11-17 | 2019-11-26 | Acushnet Company | Golf ball displaying improved adhesion between TiO2-pigmented layer incorporating silane-containing adhesion promoter and an adjacent differing layer |
| JP7313110B2 (ja) * | 2016-05-10 | 2023-07-24 | アセテート・インターナショナル・エルエルシー | 二酸化チタンを含有するスラリー |
| JP7064580B2 (ja) * | 2017-09-05 | 2022-05-10 | ビゾール，リミティド ライアビリティ カンパニー | より高度な紫外線防御を有する無機日焼け防止剤 |
| MX2022004648A (es) | 2019-10-18 | 2022-08-10 | Ineos Pigments Usa Inc | Pigmento con durabilidad mejorada y materiales plasticos hechos con el mismo. |
| CN111621171B (zh) * | 2020-05-22 | 2022-02-08 | 中信钛业股份有限公司 | 一种提高钛白粉表面二氧化硅包覆层致密性的方法 |
| CN111484756B (zh) * | 2020-05-22 | 2022-02-08 | 中信钛业股份有限公司 | 一种提高氧化铝包覆钛白粉分散稳定性的方法 |
| CN112142353B (zh) * | 2020-10-16 | 2021-09-21 | 东北大学 | 一种高效无害化处理铝灰的方法 |
| CN120349592B (zh) * | 2025-06-23 | 2026-01-23 | 辽宁双巍环保科技有限责任公司 | 一种高韧性的复合再生塑料及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0244180A1 (en) * | 1986-04-30 | 1987-11-04 | E.I. Du Pont De Nemours And Company | Titanium dioxide pigment coated with cerium cations, selected acid anions, and alumina |
| WO1995023193A1 (en) * | 1994-02-28 | 1995-08-31 | E.I. Du Pont De Nemours And Company | ORGANOSILICON TREATMENT OF TiO2 PIGMENT BEARING A COATING WITH FLUORIDE IONS |
| US20050069706A1 (en) * | 2001-12-21 | 2005-03-31 | Kessell Lorna Margaret | Particulate metal oxide |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE870242C (de) | 1941-09-26 | 1953-03-12 | Degussa | Verfahren zum Verdicken von Fluessigkeiten |
| US3834924A (en) * | 1972-06-08 | 1974-09-10 | Huber Corp J M | Process for manufacturing surface modified inorganic pigments |
| US3915735A (en) * | 1974-03-06 | 1975-10-28 | Malvern Minerals Company | Process for preparing modified silicic fillers |
| US4141751A (en) * | 1975-10-24 | 1979-02-27 | Malvern Minerals Company | Process for preparing modified particulate and/or fibrous, crystalline and amorphous inorganic substances |
| US4191737A (en) * | 1978-10-02 | 1980-03-04 | Conoco, Inc. | Increasing alumina slurry life |
| US4416699A (en) * | 1982-01-21 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Alumina coated TiO2 |
| US4460655A (en) * | 1983-04-04 | 1984-07-17 | E. I. Du Pont De Nemours And Company | TiO2 Pigment bearing a coating with fluoride ions and laminate and coating based thereon |
| GB8908995D0 (en) | 1989-04-20 | 1989-06-07 | Tioxide Group Plc | Particulate material |
| DE4202695C2 (de) * | 1992-01-31 | 1993-12-09 | Degussa | Oberflächenmodifiziertes, pyrogen hergestelltes Titandioxid |
| US5393510A (en) * | 1992-07-22 | 1995-02-28 | Rheox, Inc. | High solids content titanium dioxide suspension |
| DE4235996A1 (de) * | 1992-10-24 | 1994-04-28 | Degussa | Flammenhydrolytisch hergestelltes Titandioxid-Mischoxid, Verfahren zu seiner Herstellung und Verwendung |
| US6193795B1 (en) * | 1993-08-02 | 2001-02-27 | Degussa Corporation | Low structure pyrogenic hydrophilic and hydrophobic metallic oxides, production and use |
| US5607994A (en) * | 1994-02-28 | 1997-03-04 | E. I. Du Pont De Nemours And Company | Processibility and lacing resistance when silanized pigments are incorporated in polymers |
| US5698177A (en) * | 1994-08-31 | 1997-12-16 | University Of Cincinnati | Process for producing ceramic powders, especially titanium dioxide useful as a photocatalyst |
| DE19500674A1 (de) * | 1995-01-12 | 1996-07-18 | Degussa | Oberflächenmodifizierte pyrogen hergestellte Mischoxide, Verfahren zu ihrer Herstellung und Verwendung |
| BR0015535A (pt) * | 1999-11-12 | 2002-06-25 | Millennium Inorganic Chem | Processos para preparação de pigmentos óxido inorgânico hidrofóbico |
| WO2001080253A1 (en) * | 2000-04-13 | 2001-10-25 | E.I. Dupont De Nemours And Company | Process for coating wire conductor |
| US20020155059A1 (en) * | 2001-04-24 | 2002-10-24 | Tekna Plasma Systems Inc. | Plasma synthesis of titanium dioxide nanopowder and powder doping and surface modification process |
| US20030027897A1 (en) * | 2001-04-26 | 2003-02-06 | Mei Henry L. | Modified silane treated pigments or fillers and compositions containing the same |
| EP1558015B1 (en) * | 2002-08-30 | 2009-10-07 | Sony Corporation | Image extraction device, image extraction method, image processing device, image processing method, and imaging device |
| US6962006B2 (en) * | 2002-12-19 | 2005-11-08 | Acusphere, Inc. | Methods and apparatus for making particles using spray dryer and in-line jet mill |
| US20050129634A1 (en) * | 2003-12-16 | 2005-06-16 | Frerichs Scott R. | Passivated nano-titanium dioxide particles and methods of making the same |
| US7276231B2 (en) * | 2005-05-23 | 2007-10-02 | E I Du Pont De Nemours And Company | Lower-energy process for preparing passivated inorganic nanoparticles |
-
2005
- 2005-05-23 US US11/135,584 patent/US7276231B2/en not_active Expired - Fee Related
-
2006
- 2006-05-11 CA CA 2546309 patent/CA2546309A1/en not_active Abandoned
- 2006-05-12 EP EP20060009814 patent/EP1726625A1/en not_active Withdrawn
- 2006-05-22 KR KR1020060045679A patent/KR20060121695A/ko not_active Withdrawn
- 2006-05-23 AU AU2006202179A patent/AU2006202179B2/en not_active Ceased
- 2006-05-23 JP JP2006143019A patent/JP2006342348A/ja not_active Withdrawn
-
2007
- 2007-08-06 US US11/890,399 patent/US20080085967A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0244180A1 (en) * | 1986-04-30 | 1987-11-04 | E.I. Du Pont De Nemours And Company | Titanium dioxide pigment coated with cerium cations, selected acid anions, and alumina |
| WO1995023193A1 (en) * | 1994-02-28 | 1995-08-31 | E.I. Du Pont De Nemours And Company | ORGANOSILICON TREATMENT OF TiO2 PIGMENT BEARING A COATING WITH FLUORIDE IONS |
| US20050069706A1 (en) * | 2001-12-21 | 2005-03-31 | Kessell Lorna Margaret | Particulate metal oxide |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2006202179A1 (en) | 2006-12-07 |
| KR20060121695A (ko) | 2006-11-29 |
| US20060264552A1 (en) | 2006-11-23 |
| US7276231B2 (en) | 2007-10-02 |
| CA2546309A1 (en) | 2006-11-23 |
| JP2006342348A (ja) | 2006-12-21 |
| US20080085967A1 (en) | 2008-04-10 |
| EP1726625A1 (en) | 2006-11-29 |
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