AU2003295643A1 - Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrile - Google Patents
Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrileInfo
- Publication number
- AU2003295643A1 AU2003295643A1 AU2003295643A AU2003295643A AU2003295643A1 AU 2003295643 A1 AU2003295643 A1 AU 2003295643A1 AU 2003295643 A AU2003295643 A AU 2003295643A AU 2003295643 A AU2003295643 A AU 2003295643A AU 2003295643 A1 AU2003295643 A1 AU 2003295643A1
- Authority
- AU
- Australia
- Prior art keywords
- acrylonitrile
- manufacture
- oxide catalyst
- mixed oxide
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0081—Preparation by melting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43016202P | 2002-12-02 | 2002-12-02 | |
| US60/430,162 | 2002-12-02 | ||
| US10/717,846 | 2003-11-19 | ||
| PCT/US2003/036937 WO2004050240A1 (en) | 2002-12-02 | 2003-11-19 | Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrile |
| US10/717,846 US7348291B2 (en) | 2002-12-02 | 2003-11-19 | Catalyst for the manufacture of acrylonitrile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2003295643A1 true AU2003295643A1 (en) | 2004-06-23 |
Family
ID=32474549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2003295643A Abandoned AU2003295643A1 (en) | 2002-12-02 | 2003-11-19 | Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrile |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7348291B2 (https=) |
| EP (1) | EP1567263A1 (https=) |
| JP (2) | JP4688499B2 (https=) |
| KR (1) | KR101010890B1 (https=) |
| AU (1) | AU2003295643A1 (https=) |
| BR (1) | BR0316852B1 (https=) |
| CA (1) | CA2507182A1 (https=) |
| MX (1) | MXPA05005760A (https=) |
| RU (1) | RU2349379C2 (https=) |
| WO (1) | WO2004050240A1 (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7576232B2 (en) * | 2006-05-02 | 2009-08-18 | Ineos Usa Llc | In situ modification of molybdenum-based catalysts |
| DE102007009981A1 (de) * | 2007-03-01 | 2008-09-04 | Evonik Degussa Gmbh | Aus hohlen Formen bestehende Mischoxidkatalysatoren |
| WO2009048553A2 (en) * | 2007-10-11 | 2009-04-16 | Ineos Usa Llc | Process for the ammoxidation or oxidation of propane and isobutane |
| US8153546B2 (en) * | 2010-03-23 | 2012-04-10 | Ineos Usa Llc | Mixed metal oxide ammoxidation catalysts |
| US8455388B2 (en) * | 2010-03-23 | 2013-06-04 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
| RU2575933C2 (ru) * | 2010-03-23 | 2016-02-27 | ИНЕОС ЮЭсЭй ЭлЭлСи | Высокоэффективный способ аммоксидирования и катализаторы на основе смешанных оксидов металлов |
| US8258073B2 (en) * | 2010-03-23 | 2012-09-04 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
| US9433929B2 (en) * | 2011-09-21 | 2016-09-06 | Ineos Europe Ag | Mixed metal oxide catalysts |
| DE102013006251A1 (de) * | 2013-04-11 | 2014-10-16 | Clariant International Ltd. | Verfahren zur Herstellung eines Katalysators zur partiellen Oxidation von Olefinen |
| CN104549340B (zh) * | 2013-10-28 | 2017-12-15 | 中国石油化工股份有限公司 | 氨氧化制不饱和腈流化床催化剂 |
| RU2668554C2 (ru) * | 2014-05-29 | 2018-10-02 | ИНЕОС Юроп АГ | Улучшенные селективные катализаторы аммоксидирования |
| WO2018043007A1 (ja) * | 2016-08-31 | 2018-03-08 | 旭化成株式会社 | 触媒の製造方法、及びアクリロニトリルの製造方法 |
| US10626082B2 (en) | 2016-10-11 | 2020-04-21 | Ineos Europe Ag | Ammoxidation catalyst with selective co-product HCN production |
| CN113164928B (zh) * | 2019-09-30 | 2024-09-17 | 株式会社Lg化学 | 用于丙烯的氨氧化催化剂、该催化剂的制造方法、使用所述催化剂的氨氧化方法 |
| US12226753B2 (en) | 2019-09-30 | 2025-02-18 | Lg Chem, Ltd. | Ammoxidation catalyst for propylene, manufacturing method of the same catalyst, ammoxidation method using the same catalyst |
| KR102519507B1 (ko) | 2019-09-30 | 2023-04-07 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57130548A (en) | 1981-02-05 | 1982-08-13 | Mitsubishi Chem Ind Ltd | Catalyst composition |
| US4746753A (en) | 1981-04-29 | 1988-05-24 | The Standard Oil Company | Preparation of acrylonitrile from propylene, oxygen and ammonia in the presence of an alkali metal promoted bismuth, cerium, molybdenum, tungsten catalyst |
| US4939286A (en) | 1985-09-10 | 1990-07-03 | The Standard Oil Company | Promoted bismuth cerium molybdate catalysts |
| US5093299A (en) * | 1990-01-09 | 1992-03-03 | The Standard Oil Company | Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile |
| US5175334A (en) | 1990-01-09 | 1992-12-29 | The Standard Oil Company | Process for the manufacture of acrylonitrile and methacrylonitrile |
| US5212137A (en) | 1990-01-09 | 1993-05-18 | Standard Oil Company | Catalyst for the manufacture of acrylonitrile and methacrylonitrile |
| US5235088A (en) | 1990-03-19 | 1993-08-10 | The Standard Oil Company | Process and catalyst for propylene ammoxidation to acrylonitrile |
| US5134105A (en) | 1990-03-19 | 1992-07-28 | The Standard Oil Company | Catalyst for propylene ammoxidation to acrylonitrile |
| RU2077528C1 (ru) * | 1992-06-22 | 1997-04-20 | Дзе Стандарт Ойл Компани | Способ получения ненасыщенных нитрилов и катализатор для их получения |
| DE4220859A1 (de) | 1992-06-25 | 1994-01-05 | Basf Ag | Multimetalloxidmassen |
| US5583086A (en) | 1993-03-09 | 1996-12-10 | Basf Aktiengesellschaft | Cesium containing multimetal oxide catalyst compositions for the preparation of methacrolein by gas-phase-catalytic oxidation |
| JP3534431B2 (ja) | 1993-08-06 | 2004-06-07 | 旭化成ケミカルズ株式会社 | 不飽和ニトリルの製法 |
| US5658842A (en) | 1993-08-10 | 1997-08-19 | Asahi Kasei Kogyo Kabushiki Kaisha | Ammoxidation catalyst composition, and process for producing acrylonitrile or methacrylonitrile using the same |
| US5780664A (en) | 1993-08-17 | 1998-07-14 | Asahi Kasei Kogyo Kabushi Kaisha | Ammoxidation catalyst composition |
| RU2105757C1 (ru) * | 1993-09-02 | 1998-02-27 | Стандарт Ойл Компани | Способ парофазного аммоксидирования с3 - с5-моноолефинов |
| DE4332542A1 (de) | 1993-09-24 | 1995-03-30 | Basf Ag | Katalysator auf der Basis von Fe-, Co-, Bi- und Mo-Oxiden |
| DE4405059A1 (de) | 1994-02-17 | 1995-08-24 | Basf Ag | Multimetalloxidmassen |
| JP3214975B2 (ja) | 1994-04-25 | 2001-10-02 | 旭化成株式会社 | アンモ酸化触媒組成物および製造方法 |
| CN1114915A (zh) | 1994-07-13 | 1996-01-17 | 中国石油化工总公司 | 生产丙烯腈的流化床催化剂 |
| US5834394A (en) | 1996-08-06 | 1998-11-10 | China-Petro-Chemical Corporation | Fluidized-bed catalyst for propylene ammoxidation to acrylonitrile |
| US5840648A (en) | 1997-09-02 | 1998-11-24 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile and hydrogen cyanide |
| CN1086154C (zh) | 1998-03-30 | 2002-06-12 | 中国石油化工总公司 | 丙烯氨氧化催化剂 |
| US6143690A (en) | 1998-05-07 | 2000-11-07 | Asahi Kasei Kogyo Kabushiki Kaisha | Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane |
| CN1092540C (zh) | 1999-06-24 | 2002-10-16 | 中国石油化工集团公司 | 丙烯氨氧化流化床催化剂 |
| WO2001014057A1 (en) | 1999-08-19 | 2001-03-01 | China Petro-Chemical Corporation | Fluid bed catalyst for ammoxidation of propylene to acrylonitrile |
| RO121181B1 (ro) * | 1999-10-18 | 2007-01-30 | Mitsubishi Rayon Co., Ltd. | Procedeu pentru producerea acrilonitrilului, catalizator utilizabil în acest procedeu şi procedeupentru prepararea acestuia |
| JP4159729B2 (ja) * | 1999-10-18 | 2008-10-01 | ダイヤニトリックス株式会社 | アクリロニトリルの製造方法 |
| CN1104282C (zh) | 1999-10-28 | 2003-04-02 | 中国石化上海石油化工股份有限公司 | 丙烯、异丁烯氨氧化流化床催化剂 |
| CN1136980C (zh) | 2000-02-24 | 2004-02-04 | 中国石油化工集团公司 | 丙烯氨氧化生产丙烯腈的流化床催化剂 |
| CN1102576C (zh) | 2000-02-24 | 2003-03-05 | 中国石油化工集团公司 | 丙烯氨氧化制丙烯腈的流化床催化剂 |
| US6458742B1 (en) | 2000-08-17 | 2002-10-01 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
| JP3872268B2 (ja) * | 2000-09-21 | 2007-01-24 | 三菱レイヨン株式会社 | シアン化水素の製法 |
| JP4030740B2 (ja) * | 2001-10-11 | 2008-01-09 | ダイヤニトリックス株式会社 | アンモ酸化用触媒の製造方法 |
| US7071140B2 (en) * | 2002-12-02 | 2006-07-04 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
-
2003
- 2003-11-19 WO PCT/US2003/036937 patent/WO2004050240A1/en not_active Ceased
- 2003-11-19 RU RU2005120778/04A patent/RU2349379C2/ru active
- 2003-11-19 US US10/717,846 patent/US7348291B2/en not_active Expired - Lifetime
- 2003-11-19 MX MXPA05005760A patent/MXPA05005760A/es active IP Right Grant
- 2003-11-19 KR KR1020057009892A patent/KR101010890B1/ko not_active Expired - Lifetime
- 2003-11-19 JP JP2004557222A patent/JP4688499B2/ja not_active Expired - Lifetime
- 2003-11-19 AU AU2003295643A patent/AU2003295643A1/en not_active Abandoned
- 2003-11-19 EP EP03786844A patent/EP1567263A1/en not_active Withdrawn
- 2003-11-19 BR BRPI0316852-2A patent/BR0316852B1/pt active IP Right Grant
- 2003-11-19 CA CA002507182A patent/CA2507182A1/en not_active Abandoned
-
2010
- 2010-10-22 JP JP2010237299A patent/JP5610975B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20050085259A (ko) | 2005-08-29 |
| BR0316852A (pt) | 2005-10-18 |
| RU2005120778A (ru) | 2006-01-20 |
| JP5610975B2 (ja) | 2014-10-22 |
| BR0316852B1 (pt) | 2013-03-19 |
| JP4688499B2 (ja) | 2011-05-25 |
| EP1567263A1 (en) | 2005-08-31 |
| MXPA05005760A (es) | 2005-09-08 |
| RU2349379C2 (ru) | 2009-03-20 |
| JP2011062692A (ja) | 2011-03-31 |
| US7348291B2 (en) | 2008-03-25 |
| WO2004050240A1 (en) | 2004-06-17 |
| JP2006507936A (ja) | 2006-03-09 |
| US20040110978A1 (en) | 2004-06-10 |
| KR101010890B1 (ko) | 2011-01-25 |
| CA2507182A1 (en) | 2004-06-17 |
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