ATE47254T1 - Gegen schwefel unempfindliche anode fuer brennstoffzellen mit geschmolzenem carbonat und verfahren. - Google Patents
Gegen schwefel unempfindliche anode fuer brennstoffzellen mit geschmolzenem carbonat und verfahren.Info
- Publication number
- ATE47254T1 ATE47254T1 AT86102616T AT86102616T ATE47254T1 AT E47254 T1 ATE47254 T1 AT E47254T1 AT 86102616 T AT86102616 T AT 86102616T AT 86102616 T AT86102616 T AT 86102616T AT E47254 T1 ATE47254 T1 AT E47254T1
- Authority
- AT
- Austria
- Prior art keywords
- molten carbonate
- carbonate fuel
- fuel cells
- carbon monoxide
- sulfur resistant
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M8/141—Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers
- H01M8/142—Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers with matrix-supported or semi-solid matrix-reinforced electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8684—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M2008/147—Fuel cells with molten carbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0048—Molten electrolytes used at high temperature
- H01M2300/0051—Carbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/717,447 US4925745A (en) | 1985-03-29 | 1985-03-29 | Sulfur tolerant molten carbonate fuel cell anode and process |
EP86102616A EP0196465B1 (de) | 1985-03-29 | 1986-02-28 | Gegen Schwefel unempfindliche Anode für Brennstoffzellen mit geschmolzenem Carbonat und Verfahren |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE47254T1 true ATE47254T1 (de) | 1989-10-15 |
Family
ID=24882071
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT86102616T ATE47254T1 (de) | 1985-03-29 | 1986-02-28 | Gegen schwefel unempfindliche anode fuer brennstoffzellen mit geschmolzenem carbonat und verfahren. |
Country Status (5)
Country | Link |
---|---|
US (1) | US4925745A (de) |
EP (1) | EP0196465B1 (de) |
JP (1) | JPH0810598B2 (de) |
AT (1) | ATE47254T1 (de) |
DE (1) | DE3666313D1 (de) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4755439A (en) * | 1987-03-25 | 1988-07-05 | International Fuel Cells Corporation | Fuel cell configuration for contaminated fuel gases and method of using the same |
US5071718A (en) * | 1987-03-26 | 1991-12-10 | Institute Of Gas Technology | Use of sulfur containing fuel in molten carbonate fuel cells |
ATE79486T1 (de) * | 1987-03-26 | 1992-08-15 | Inst Gas Technology | Verwendung von schwefel enthaltendem brennstoff in brennstoffzellen mit geschmolzenem carbonat. |
JPH01186561A (ja) * | 1988-01-14 | 1989-07-26 | Hitachi Ltd | 燃料電池 |
US5198310A (en) * | 1991-09-11 | 1993-03-30 | Institute Of Gas Technology | Thermal management in fuel cell system by feed gas conditioning |
US5213912A (en) * | 1991-12-30 | 1993-05-25 | International Fuel Cells Corporation | Molten carbonate fuel cell sulfur scrubber |
DE4340486C1 (de) * | 1993-11-27 | 1995-06-01 | Forschungszentrum Juelich Gmbh | Brennstoffzelle und Verfahren zur Herstellung der Brennstoffzelle |
DK112994A (da) * | 1994-09-29 | 1996-03-30 | Haldor Topsoe As | Fremgangsmåde til fremstilling af elektricitet i en intern reformet højtemperatur brændselscelle |
US6653009B2 (en) | 2001-10-19 | 2003-11-25 | Sarnoff Corporation | Solid oxide fuel cells and interconnectors |
US7067208B2 (en) * | 2002-02-20 | 2006-06-27 | Ion America Corporation | Load matched power generation system including a solid oxide fuel cell and a heat pump and an optional turbine |
JP4517949B2 (ja) * | 2005-06-13 | 2010-08-04 | 住友金属鉱山株式会社 | 固体電解質型燃料電池の電極用酸化ニッケル粉及びその製造方法 |
US7968245B2 (en) * | 2006-09-25 | 2011-06-28 | Bloom Energy Corporation | High utilization stack |
US10615444B2 (en) | 2006-10-18 | 2020-04-07 | Bloom Energy Corporation | Anode with high redox stability |
US8748056B2 (en) | 2006-10-18 | 2014-06-10 | Bloom Energy Corporation | Anode with remarkable stability under conditions of extreme fuel starvation |
US20080254336A1 (en) * | 2007-04-13 | 2008-10-16 | Bloom Energy Corporation | Composite anode showing low performance loss with time |
US20080261099A1 (en) * | 2007-04-13 | 2008-10-23 | Bloom Energy Corporation | Heterogeneous ceramic composite SOFC electrolyte |
US9246184B1 (en) | 2007-11-13 | 2016-01-26 | Bloom Energy Corporation | Electrolyte supported cell designed for longer life and higher power |
US8067129B2 (en) | 2007-11-13 | 2011-11-29 | Bloom Energy Corporation | Electrolyte supported cell designed for longer life and higher power |
US9287571B2 (en) * | 2008-07-23 | 2016-03-15 | Bloom Energy Corporation | Operation of fuel cell systems with reduced carbon formation and anode leading edge damage |
US8617763B2 (en) * | 2009-08-12 | 2013-12-31 | Bloom Energy Corporation | Internal reforming anode for solid oxide fuel cells |
JP5323269B2 (ja) * | 2010-01-26 | 2013-10-23 | ブルーム エナジー コーポレーション | 燃料電池の構成物、特に固形酸化物型燃料電池の電解質材料 |
US8440362B2 (en) | 2010-09-24 | 2013-05-14 | Bloom Energy Corporation | Fuel cell mechanical components |
JP6084404B2 (ja) * | 2012-08-31 | 2017-02-22 | 株式会社Ti | 燃料電池の電極板の製造方法 |
CN104798237B (zh) | 2012-11-20 | 2018-12-14 | 博隆能源股份有限公司 | 经掺杂氧化钪稳定的氧化锆电解质组合物 |
US9755263B2 (en) | 2013-03-15 | 2017-09-05 | Bloom Energy Corporation | Fuel cell mechanical components |
US10651496B2 (en) | 2015-03-06 | 2020-05-12 | Bloom Energy Corporation | Modular pad for a fuel cell system |
WO2016154198A1 (en) | 2015-03-24 | 2016-09-29 | Bloom Energy Corporation | Perimeter electrolyte reinforcement layer composition for solid oxide fuel cell electrolytes |
US10680251B2 (en) | 2017-08-28 | 2020-06-09 | Bloom Energy Corporation | SOFC including redox-tolerant anode electrode and system including the same |
US11476486B2 (en) | 2018-11-30 | 2022-10-18 | ExxonMobil Technology and Engineering Company | Fuel cell staging for molten carbonate fuel cells |
CN113261133B (zh) * | 2018-11-30 | 2023-09-01 | 燃料电池能有限公司 | 以提高的co2利用率操作的燃料电池的重整催化剂图案 |
WO2020112812A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Research And Engineering Company | Operation of molten carbonate fuel cells with enhanced co 2 utilization |
US11742508B2 (en) | 2018-11-30 | 2023-08-29 | ExxonMobil Technology and Engineering Company | Reforming catalyst pattern for fuel cell operated with enhanced CO2 utilization |
KR20220107183A (ko) | 2019-11-26 | 2022-08-02 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 높은 전해질 충전 수준을 갖는 용융 탄산염 연료 전지의 작동 |
US11978931B2 (en) | 2021-02-11 | 2024-05-07 | ExxonMobil Technology and Engineering Company | Flow baffle for molten carbonate fuel cell |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3431146A (en) * | 1964-08-13 | 1969-03-04 | Texas Instruments Inc | Method of oxidizing residual h2s to so2 in a fuel cell |
US3393100A (en) * | 1965-10-01 | 1968-07-16 | Gen Electric | Process of generating electrical energy utilizing a fuel containing carbon monoxide and a fuel cell electrode structure therefor, comprising a carbon-monoxide resistant electrode body |
US3453146A (en) * | 1966-01-03 | 1969-07-01 | Texas Instruments Inc | Method and apparatus for reforming carbonaceous fuels and operating fuel cell |
US3453314A (en) * | 1966-08-01 | 1969-07-01 | Leuna Werke Veb | Production of propionitrile |
DE1767064A1 (de) * | 1968-03-27 | 1970-09-17 | Basf Ag | Katalysator fuer die Herstellung von Wasserstoff aus kohlenmonoxidhaltigen Gasen |
DE1939882A1 (de) * | 1968-08-10 | 1970-02-19 | Mitsubishi Chem Ind | Verfahren zur Herstellung von Ta?rahydrofuran |
US4009321A (en) * | 1969-03-28 | 1977-02-22 | American Gas Association, Inc. | High temperature fuel cell electrolyte |
US4247604A (en) * | 1978-11-20 | 1981-01-27 | Institute Of Gas Technology | Carbonate fuel cell anodes |
CA1214514A (en) * | 1982-08-19 | 1986-11-25 | Pinakin S. Patel | Electrode structure and method of making same |
EP0124262B1 (de) * | 1983-03-31 | 1987-11-11 | Kabushiki Kaisha Toshiba | Brennstoffzelle mit einem Elektrolyt aus Karbonatschmelze |
US4548876A (en) * | 1984-10-17 | 1985-10-22 | The United States Of America As Represented By The United States Department Of Energy | Integrated current collector and catalyst support |
-
1985
- 1985-03-29 US US06/717,447 patent/US4925745A/en not_active Expired - Lifetime
-
1986
- 1986-02-28 DE DE8686102616T patent/DE3666313D1/de not_active Expired
- 1986-02-28 AT AT86102616T patent/ATE47254T1/de not_active IP Right Cessation
- 1986-02-28 EP EP86102616A patent/EP0196465B1/de not_active Expired
- 1986-03-29 JP JP61072367A patent/JPH0810598B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4925745A (en) | 1990-05-15 |
DE3666313D1 (en) | 1989-11-16 |
EP0196465A1 (de) | 1986-10-08 |
JPS61269856A (ja) | 1986-11-29 |
EP0196465B1 (de) | 1989-10-11 |
JPH0810598B2 (ja) | 1996-01-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE47254T1 (de) | Gegen schwefel unempfindliche anode fuer brennstoffzellen mit geschmolzenem carbonat und verfahren. | |
PT85578A (pt) | Uma estrutura anodica de dupla compartimentacao e processo para a sua utilizacao em pilhas de combustivel de carbonato fundido | |
GB2009792B (en) | Generation of halogens by electrolysis of hydrogen halides in a cell having catalytic electrodes bonded to a solid polymer electrolyte | |
ATE454721T1 (de) | Verwendung von schwefelhaltigen brennstoffen für direktoxidationsbrennstoffzellen | |
PT564796E (pt) | Processo para a producao de energia a partir de biomassa | |
EP0127595A3 (de) | Wasserstoffsulfid-Zerlegungszelle und katalytische Stoffe dafür | |
MY100329A (en) | Generation of anaerobic or microaerophilic atmosphere | |
SE8601474D0 (sv) | Method for using anodes having nico?712o?714 catalyst for the electrolysis of potassium hydroxide solutions and method of making an anode containing nico?712o?714 catalyst | |
US5071718A (en) | Use of sulfur containing fuel in molten carbonate fuel cells | |
ATE79486T1 (de) | Verwendung von schwefel enthaltendem brennstoff in brennstoffzellen mit geschmolzenem carbonat. | |
REMICK et al. | Contaminant resistant molten carbonate fuel cell(Final Report, Jun. 1986-Sep. 1988) | |
DE3874278D1 (de) | Beseitigung von wasserstoff und sauerstoff im elektrolyten von im schwerelosen raum betriebenen wasserstoff/sauerstoff-brennstoffzellenbatterien. | |
Remick | Effects of H2S on molten carbonate fuel cells. Literature review on the impact of SO2 in the oxidant supplied to molten carbonate fuel cells | |
ZA785586B (en) | Generation of halogens by electrolysis of hydrogen halides in a cell having catalytic electrodes bonded to a solid polymer electrolyte | |
REMICK et al. | Sulfur-tolerant anode materials(Final Report) | |
REMICK | Effects of H 2 S on molten carbonate fuel cells(Progress Report, 1 Jul.- 30 Sep. 1984) | |
SU1568715A1 (ru) | Электрохимическая ячейка для анализа серусодержащих газовых сред |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification | ||
REN | Ceased due to non-payment of the annual fee |