ATE433798T1 - Katalysator, umfassend einen euo-zeolith, einen 10-mr-zeolith und einen 12-mr-zeolith, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen - Google Patents

Katalysator, umfassend einen euo-zeolith, einen 10-mr-zeolith und einen 12-mr-zeolith, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen

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Publication number
ATE433798T1
ATE433798T1 AT06841855T AT06841855T ATE433798T1 AT E433798 T1 ATE433798 T1 AT E433798T1 AT 06841855 T AT06841855 T AT 06841855T AT 06841855 T AT06841855 T AT 06841855T AT E433798 T1 ATE433798 T1 AT E433798T1
Authority
AT
Austria
Prior art keywords
zeolite
catalyst
isomerization
euo
aromatic compounds
Prior art date
Application number
AT06841855T
Other languages
German (de)
English (en)
Inventor
Emmanuelle Guillon
Eric Sanchez
Sylvie Lacombe
Original Assignee
Inst Francais Du Petrole
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Filing date
Publication date
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Application granted granted Critical
Publication of ATE433798T1 publication Critical patent/ATE433798T1/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
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    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/88—Ferrosilicates; Ferroaluminosilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
AT06841855T 2005-12-22 2006-12-01 Katalysator, umfassend einen euo-zeolith, einen 10-mr-zeolith und einen 12-mr-zeolith, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen ATE433798T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0513176A FR2895283B1 (fr) 2005-12-22 2005-12-22 Catalyseur comprenant une zeolithe euo, une zeolithe 10mr et une zeolithe 12mr et son utilisation en isomerisation des composes c8 aromatiques
PCT/FR2006/002647 WO2007080246A1 (fr) 2005-12-22 2006-12-01 Catalyseur comprenant une zeolithe euo, une zeolithe 10 mr et une zeolithe 12 mr et son utilisation en isomerisation des composes c8 aromatiques

Publications (1)

Publication Number Publication Date
ATE433798T1 true ATE433798T1 (de) 2009-07-15

Family

ID=36910934

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Application Number Title Priority Date Filing Date
AT06841855T ATE433798T1 (de) 2005-12-22 2006-12-01 Katalysator, umfassend einen euo-zeolith, einen 10-mr-zeolith und einen 12-mr-zeolith, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen

Country Status (9)

Country Link
US (1) US7982083B2 (enExample)
EP (1) EP1965914B1 (enExample)
JP (1) JP5202329B2 (enExample)
KR (1) KR101357913B1 (enExample)
CN (1) CN101340977B (enExample)
AT (1) ATE433798T1 (enExample)
DE (1) DE602006007380D1 (enExample)
FR (1) FR2895283B1 (enExample)
WO (1) WO2007080246A1 (enExample)

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US7456124B2 (en) * 2006-09-12 2008-11-25 Uop Llc Rhenium-containing transalkylation catalysts and processes for making the same
US7939701B2 (en) 2007-12-12 2011-05-10 Uop Llc Aromatic isomerization catalyst and a process of use thereof
US20100029467A1 (en) * 2008-07-30 2010-02-04 Tomoyuki Inui Multiple zeolite catalyst
US8466080B2 (en) * 2010-09-15 2013-06-18 Uop Llc Catalysts, processes for preparing the catalysts, and processes for transalkylating aromatic hydrocarbon compounds
FR2976941B1 (fr) * 2011-06-24 2014-11-21 IFP Energies Nouvelles Procede ameliore d'isomerisation d'une coupe c8 aromatique
US9309170B2 (en) * 2011-11-14 2016-04-12 Uop Llc Aromatics isomerization using a dual-catalyst system
JP6134335B2 (ja) 2011-12-22 2017-05-24 ユーオーピー エルエルシー Ｕｚｍ−３９アルミケイ酸塩ゼオライト
WO2013096072A2 (en) 2011-12-22 2013-06-27 Uop Llc Layered conversion synthesis of zeolites
EP2794525B1 (en) 2011-12-22 2018-10-10 Uop Llc Aromatic transformation using uzm-39 aluminosilicate zeolite
US8609911B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-44 aluminosilicate zeolite
US8921634B2 (en) 2012-12-12 2014-12-30 Uop Llc Conversion of methane to aromatic compounds using UZM-44 aluminosilicate zeolite
US8889939B2 (en) 2012-12-12 2014-11-18 Uop Llc Dehydrocyclodimerization using UZM-44 aluminosilicate zeolite
WO2014093416A1 (en) 2012-12-12 2014-06-19 Uop Llc Dehydrocyclodimerization using uzm-39 aluminosilicate zeolite
US20140163281A1 (en) 2012-12-12 2014-06-12 Uop Llc Conversion of methane to aromatic compounds using a catalytic composite
US8609919B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transformation using UZM-44 aluminosilicate zeolite
US8618343B1 (en) 2012-12-12 2013-12-31 Uop Llc Aromatic transalkylation using UZM-39 aluminosilicate zeolite
US8623321B1 (en) 2012-12-12 2014-01-07 Uop Llc UZM-44 aluminosilicate zeolite
US8609921B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transalkylation using UZM-44 aluminosilicate zeolite
US8609910B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-39 aluminosilicate zeolite
FR3006608B1 (fr) * 2013-06-10 2021-01-01 Ifp Energies Now Adsorbant a base d'une zeolithe et d'une argile riche en silice et procede de purification de charges d'hydrocarbures contenant des molecules insaturees
WO2016064452A1 (en) * 2014-10-24 2016-04-28 Chevron U.S.A. Inc. Processes using molecular sieve ssz-102
CN106179486B (zh) * 2015-04-29 2018-06-19 中国石油化工股份有限公司 一种含贵金属和euo型分子筛催化剂的再生方法
CN106179489B (zh) * 2015-04-29 2018-06-15 中国石油化工股份有限公司 失活催化剂的再生方法
CN106179488B (zh) * 2015-04-29 2018-07-03 中国石油化工股份有限公司 一种含贵金属和ton型分子筛催化剂的再生方法
CN106179487B (zh) * 2015-04-29 2018-06-19 中国石油化工股份有限公司 含贵金属和ton型分子筛催化剂的再生方法
EP3386633B1 (en) * 2015-12-11 2020-05-13 Shell International Research Maatschappij B.V. Catalyst composition and isomerisation process
CN106976889B (zh) * 2017-06-02 2019-02-15 中山大学 具有bog结构的硅铝沸石分子筛及其制备方法
CN107297221A (zh) * 2017-07-11 2017-10-27 太原大成环能化工技术有限公司 一种乙苯脱烷基催化剂及其制备方法
KR102085652B1 (ko) * 2017-12-29 2020-03-06 현대자동차 주식회사 규칙적인 메조 기공을 가진 제오라이트 입자에 금속이 함침된 탄화수소 흡착제 및 그 제조방법
CN110075910A (zh) * 2018-01-26 2019-08-02 中国科学院大连化学物理研究所 一种用于乙醇和苯烷基化反应im-5分子筛催化剂的改性方法
FR3083230B1 (fr) * 2018-06-29 2021-04-23 Axens Procede de production de paraxylene utilisant une etape en lit mobile simule, et une etape de fractionnement via une colonne de 3 coupes
CN112299433B (zh) * 2019-07-29 2022-06-03 中国石油天然气股份有限公司 一种氢型zsm-5/eu-1共晶沸石、芳烃异构化催化剂及制备方法和应用
CN112573987B (zh) * 2019-09-29 2024-02-09 中国石油化工股份有限公司 一种由含乙苯的c8芳烃生产对二甲苯和乙苯的方法
KR102788458B1 (ko) * 2019-10-30 2025-03-28 에스케이이노베이션 주식회사 저감된 에틸벤젠 함량을 갖는 c8 방향족 탄화수소 제조용 촉매 및 이의 제조방법
WO2022018526A1 (en) * 2020-07-21 2022-01-27 Chevron U.S.A. Inc. Molecular sieve ssz-122, its synthesis and use
AR125184A1 (es) * 2021-02-26 2023-06-21 Dow Global Technologies Llc Procesos para preparar hidrocarburos c₂ a c₄
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US20090093661A1 (en) 2009-04-09
EP1965914B1 (fr) 2009-06-17
JP2009520592A (ja) 2009-05-28
CN101340977A (zh) 2009-01-07
EP1965914A1 (fr) 2008-09-10
KR101357913B1 (ko) 2014-02-03
FR2895283B1 (fr) 2008-02-01
FR2895283A1 (fr) 2007-06-29
JP5202329B2 (ja) 2013-06-05
US7982083B2 (en) 2011-07-19
KR20080080994A (ko) 2008-09-05
DE602006007380D1 (de) 2009-07-30
WO2007080246A1 (fr) 2007-07-19

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