ATE298322T1 - Ss'-bis-(alpha, alpha'-disubstituierte-alpha''- essigsäure)-trithio-carbonate und derivate davon als initiatoren, kettentransfer-verbindung, kettenabbruch-verbindung für kontrollierte radikalische polymerisationen sowie verfahren zu deren herstellung - Google Patents

Ss'-bis-(alpha, alpha'-disubstituierte-alpha''- essigsäure)-trithio-carbonate und derivate davon als initiatoren, kettentransfer-verbindung, kettenabbruch-verbindung für kontrollierte radikalische polymerisationen sowie verfahren zu deren herstellung

Info

Publication number
ATE298322T1
ATE298322T1 AT01901976T AT01901976T ATE298322T1 AT E298322 T1 ATE298322 T1 AT E298322T1 AT 01901976 T AT01901976 T AT 01901976T AT 01901976 T AT01901976 T AT 01901976T AT E298322 T1 ATE298322 T1 AT E298322T1
Authority
AT
Austria
Prior art keywords
alpha
compound
initiators
derivatives
trithio
Prior art date
Application number
AT01901976T
Other languages
English (en)
Inventor
John T Lai
Original Assignee
Noveon Ip Holdings Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Noveon Ip Holdings Corp filed Critical Noveon Ip Holdings Corp
Application granted granted Critical
Publication of ATE298322T1 publication Critical patent/ATE298322T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
    • C07C329/12—Dithiocarbonic acids; Derivatives thereof
    • C07C329/14—Esters of dithiocarbonic acids
    • C07C329/16—Esters of dithiocarbonic acids having sulfur atoms of dithiocarbonic groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
    • C07C329/12—Dithiocarbonic acids; Derivatives thereof
    • C07C329/14—Esters of dithiocarbonic acids
    • C07C329/18—Esters of dithiocarbonic acids having sulfur atoms of dithiocarbonic groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/14—Dithiocarbamic acids; Derivatives thereof
    • C07C333/18—Esters of dithiocarbamic acids
    • C07C333/24—Esters of dithiocarbamic acids having nitrogen atoms of dithiocarbamate groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/28—Polythiocarbonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Resins (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)
AT01901976T 2000-02-16 2001-01-11 Ss'-bis-(alpha, alpha'-disubstituierte-alpha''- essigsäure)-trithio-carbonate und derivate davon als initiatoren, kettentransfer-verbindung, kettenabbruch-verbindung für kontrollierte radikalische polymerisationen sowie verfahren zu deren herstellung ATE298322T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/505,749 US6596899B1 (en) 2000-02-16 2000-02-16 S,S′BIS-(α, α′-DISUBSTITUTED-α″-ACETIC ACID)- TRITHIOCARBONATES AND DERIVATIVES AS INITIATOR-CHAIN TRANSFER AGENT-TERMINATOR FOR CONTROLLED RADICAL POLYMERIZATIONS AND THE PROCESS FOR MAKING THE SAME
PCT/US2001/000850 WO2001060792A1 (en) 2000-02-16 2001-01-11 S,S'-BIS-(α,α'-DISUBSTITUTED-α'-ACETIC ACID)-TRITHIOCARBONATES AND DERIVATIVES AS INITIATOR - CHAIN TRANSFER AGENT - TERMINATOR FOR CONTROLLED RADICAL POLYMERIZATIONS AND THE PROCESS FOR MAKING THE SAME

Publications (1)

Publication Number Publication Date
ATE298322T1 true ATE298322T1 (de) 2005-07-15

Family

ID=24011664

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01901976T ATE298322T1 (de) 2000-02-16 2001-01-11 Ss'-bis-(alpha, alpha'-disubstituierte-alpha''- essigsäure)-trithio-carbonate und derivate davon als initiatoren, kettentransfer-verbindung, kettenabbruch-verbindung für kontrollierte radikalische polymerisationen sowie verfahren zu deren herstellung

Country Status (9)

Country Link
US (7) US6596899B1 (de)
EP (1) EP1255731B1 (de)
JP (1) JP4914553B2 (de)
KR (1) KR100712801B1 (de)
AT (1) ATE298322T1 (de)
AU (1) AU781636B2 (de)
CA (1) CA2399690C (de)
DE (1) DE60111612T2 (de)
WO (1) WO2001060792A1 (de)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7557235B2 (en) * 2000-02-16 2009-07-07 Lubrizol Advanced Materials, Inc. Hydroxyl-terminated thiocarbonate containing compounds, polymers, and copolymers, and polyurethanes and urethane acrylics made therefrom
US20050014910A1 (en) * 2000-02-16 2005-01-20 Lepilleur Carole A. Toughened vinyl ester resins
US7495050B2 (en) * 2000-02-16 2009-02-24 Lubrizol Advanced Materials, Inc. Associative thickeners for aqueous systems
US7335788B2 (en) * 2000-02-16 2008-02-26 Lubrizol Advanced Materials, Inc. S-(α, α′-disubstituted-α″-acetic acid) substituted dithiocarbonate derivatives for controlled radical polymerizations, process and polymers made therefrom
JP3971705B2 (ja) * 2001-04-04 2007-09-05 株式会社カネカ 熱可塑性樹脂組成物およびエラストマー組成物
FR2829137B1 (fr) * 2001-08-28 2003-12-19 Rhodia Chimie Sa Procede de polymerisation radicalaire realise en presence de composes disulfures
FR2868068B1 (fr) 2004-03-29 2006-07-14 Coatex Soc Par Actions Simplif Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications
US6756457B2 (en) * 2002-07-16 2004-06-29 Eastman Kodak Company Polymerization process
FR2844264B1 (fr) * 2002-09-11 2006-10-20 Rhodia Chimie Sa Nouveaux composes comprenant un groupement thiocarbonylsulfanyle utiles pour la synthese de composes alpha-perfluoroalkylamines par voie radicalaire
FR2848556B1 (fr) 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
WO2005000924A1 (en) * 2003-06-26 2005-01-06 Symyx Technologies, Inc. Photoresist polymers
CN100549051C (zh) * 2003-06-26 2009-10-14 捷时雅株式会社 光刻胶聚合物组合物
US7250475B2 (en) * 2003-06-26 2007-07-31 Symyx Technologies, Inc. Synthesis of photoresist polymers
US7517934B2 (en) * 2003-07-31 2009-04-14 Basf Corporation Modified anionically polymerized polymers
US20070051928A1 (en) * 2003-11-14 2007-03-08 Polyone Corporation Dispersions of inherently conductive polymer in non-ionic waterborne polymers
DE602005020603D1 (de) * 2004-05-12 2010-05-27 Du Pont Synthese von trithiocarbonat-raft-agentia und zwischenprodukte daraus
FR2868072B1 (fr) * 2004-07-28 2006-06-30 Coatex Soc Par Actions Simplif Polymeres obtenus par l'utilisation de composes soufres comme agents de transfert pour la polymerisation radicalaire controlee de l'acide acrylique et leurs applications
US7851572B2 (en) 2004-07-28 2010-12-14 Coatex S.A.S. Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof
EP1786848A1 (de) 2004-08-06 2007-05-23 Noveon, Inc. Aus hydroxylgruppenterminierten thiocarbonatverbindungen hergestellte polyurethane und urethanacrylate
US8137754B2 (en) * 2004-08-06 2012-03-20 Lubrizol Advanced Materials, Inc. Hydroxyl-terminated thiocarbonate containing compounds, polymers, and copolymers, and polyurethanes and urethane acrylics made therefrom
WO2006023790A1 (en) * 2004-08-20 2006-03-02 Noveon, Inc. Curable thiocarbonate compounds and compositions
US7423082B2 (en) * 2004-08-20 2008-09-09 Lubrizol Advanced Materials, Inc. Associative thickeners for aqueous systems
EP3575332A1 (de) 2004-10-25 2019-12-04 The Lubrizol Corporation Verfahren zur herstellung von polymeren und zusammensetzungen daraus
WO2006086646A2 (en) * 2005-02-10 2006-08-17 The Regents Of The University Of Colorado, A Body Corporate Stress relaxation in crosslinked polymers
US8877830B2 (en) 2005-02-10 2014-11-04 The Regents Of The University Of Colorado, A Body Corporate Stress relief for crosslinked polymers
DE102005058744A1 (de) * 2005-12-08 2007-06-14 Wacker Polymer Systems Gmbh & Co. Kg Polyvinylester- und Poly(meth)acrylat - Festharze mit hoher Polydispersität
US7671152B2 (en) * 2005-12-22 2010-03-02 The Goodyear Tire & Rubber Company Surfactantless synthesis of amphiphilic cationic block copolymers
US7230063B1 (en) * 2005-12-22 2007-06-12 The Goodyear Tire & Rubber Company Functional trithiocarbonate RAFT agents
US7411053B2 (en) * 2006-05-25 2008-08-12 Harruna Issifu I Ligand-functionalized/azo compounds and methods of use thereof
US7442746B2 (en) 2006-10-19 2008-10-28 The Goodyear Tire & Rubber Company Epoxidation of unsaturated cationically stabilized polymer latex
US20080153982A1 (en) * 2006-12-20 2008-06-26 John Ta-Yuan Lai Vinyl-Thiocarbonate and Polyol Containing Block Copolymers
US7335714B1 (en) 2007-01-18 2008-02-26 The Goodyear Tire & Rubber Company Sulfine control agents for synthesizing polymers
FI122734B (fi) * 2007-05-21 2012-06-15 Kemira Oyj Prosessikemikaali käytettäväksi paperin tai kartongin valmistuksessa
JP2009001776A (ja) * 2007-06-11 2009-01-08 Rohm & Haas Co 水性エマルジョンポリマー会合性増粘剤
US7875213B2 (en) * 2007-07-13 2011-01-25 Kemira Oyj Mineral dispersants and methods for preparing mineral slurries using the same
JP5341088B2 (ja) * 2007-08-09 2013-11-13 ザ ルブリゾル コーポレイション 置換されたトリチオカーボネート誘導体を作製するためのプロセス
KR101750907B1 (ko) 2008-03-20 2017-06-27 애버리 데니슨 코포레이션 작용기의 위치가 조절된 아크릴 중합체
WO2009153162A1 (de) 2008-06-17 2009-12-23 Basf Se Verfahren zur herstellung einer wässrigen polymerisatdispersion
FR2934861B1 (fr) * 2008-08-05 2012-12-28 Arkema France Nouveaux modifiants chocs du type coeur-ecorce pour matrices polymeres transparentes.
US8822610B2 (en) * 2008-12-22 2014-09-02 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8815971B2 (en) * 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US9783628B2 (en) 2009-04-23 2017-10-10 ATRP Solutions, Inc. Dual-mechanism thickening agents for hydraulic fracturing fluids
BR112012006015B1 (pt) 2009-09-17 2019-07-09 Arlanxeo Deutschland Gmbh Processo para a produção de borrachas de nitrila, borracha de nitrila, misturas vulcanizáveis, processo para a produção de vulcanizados, e vulcanizados
EP2298824A1 (de) 2009-09-17 2011-03-23 LANXESS Deutschland GmbH Nitrilkautschuke und deren Herstellung in organischen Lösungsmitteln
EP2385074A1 (de) 2010-05-07 2011-11-09 LANXESS Deutschland GmbH Nitrilkautschuke und deren Herstellung in organischen Lösungsmitteln
EP2368916B1 (de) * 2010-03-25 2012-08-22 LANXESS International SA Verfahren zur Herstellung von wasser- und lösemittelfreien Nitrilgummis
KR101849686B1 (ko) 2010-05-19 2018-04-17 애버리 데니슨 코포레이션 규칙적인 구성의 아크릴 폴리머
EP2423234A1 (de) 2010-08-31 2012-02-29 LANXESS Deutschland GmbH Kautschukblends aus verschiedenen Nitrilkautschuken
US9428649B2 (en) 2010-11-05 2016-08-30 E Ink California, Llc Electrophoretic dispersion
US9587064B2 (en) 2010-12-08 2017-03-07 ATRP Solutions, Inc. Salt-tolerant star macromolecules
CN102351765A (zh) * 2011-07-15 2012-02-15 天津大学 高效RAFT链转移剂S,S’-二(α,α’-甲基- α”-乙酸)三硫代碳酸酯及其制备方法
EP2554558A1 (de) 2011-08-02 2013-02-06 Lanxess Deutschland GmbH Verfahren zur Herstellung von Nitrilkautschuken in organischen Lösungsmitteln
US9758597B2 (en) * 2011-08-05 2017-09-12 The Regents Of The University Of Colorado, A Body Corporate Reducing polymerization-induced shrinkage stress by reversible addition-fragmentation chain transfer
KR101939108B1 (ko) 2011-10-14 2019-01-16 애버리 데니슨 코포레이션 조절된 구조 폴리머
CN102690217B (zh) * 2012-05-31 2014-04-16 同济大学 一种用于可逆加成断裂链转移聚合的高效链转移剂三硫酯的制备方法
EP2890760A4 (de) 2012-08-30 2016-10-12 Atrp Solutions Inc Doppelmechanismus-verdickungsmittel für hydraulische frackingfluide
IN2015MN00420A (de) * 2012-09-26 2015-09-04 Coatex Sas
CN103058902B (zh) * 2012-12-21 2014-08-13 江西科技师范大学 光活性可逆加成-断裂链转移试剂及其制备与应用
EP2951220B1 (de) 2013-02-04 2020-11-25 Pilot Polymer Technologies, Inc. Salztolerante sternmakromoleküle
EP2956517B1 (de) * 2013-02-18 2021-12-08 3M Innovative Properties Company Druckempfindliches klebeband und daraus hergestellte artikel
CN103113502A (zh) * 2013-02-20 2013-05-22 中国科学院新疆理化技术研究所 一种抗磨性粘度指数改进剂的制备方法
JP6222973B2 (ja) * 2013-04-19 2017-11-01 日本テルペン化学株式会社 ジベンジルトリチオカーボネート誘導体
EP2810956A1 (de) 2013-06-03 2014-12-10 LANXESS Deutschland GmbH Über Bisdihydropyrazol-Gruppen gekuppelte Nitrilkautschuke, deren Herstellung und Verwendung
WO2015065831A1 (en) 2013-11-01 2015-05-07 Lubrizol Advanced Materials, Inc. Dispersants with multiple aromatic imide anchor groups
WO2015065829A1 (en) 2013-11-01 2015-05-07 Lubrizol Advanced Materials, Inc. Dispersants with multiple aromatic imide anchor groups
FR3013711B1 (fr) * 2013-11-26 2015-12-11 Coatex Sas Procede de polymerisation de l'acide (meth)acrylique en solution, solutions de polymeres obtenues et leurs utilisations
CN103709283B (zh) * 2013-12-17 2015-12-02 聊城大学 一种四臂星形聚合物蜂窝状多孔膜及制备方法
US9085542B1 (en) 2014-06-12 2015-07-21 General Electric Company Method for synthesis of N-methyl piperazine diphenolamide and related composition
MX385886B (es) 2014-07-03 2025-03-18 Pilot Polymer Tech Inc Macromoleculas estrellas compatibles con tensoactivos.
EP3018151A1 (de) 2014-11-06 2016-05-11 Universiteit Gent Verfahren zur herstellung von inerten raft-polymeren
JP2018520994A (ja) 2015-05-08 2018-08-02 ザ ルブリゾル コーポレイションＴｈｅ Ｌｕｂｒｉｚｏｌ Ｃｏｒｐｏｒａｔｉｏｎ 水溶性連鎖移動剤
WO2017115632A1 (ja) * 2015-12-28 2017-07-06 綜研化学株式会社 粘着剤用組成物、粘着剤層および粘着シート
CN106380435B (zh) * 2016-09-05 2018-03-30 中南大学 一种制备硫氨酯并联产二苄基二硫醚的方法
CN106380434B (zh) * 2016-09-05 2018-03-30 中南大学 一种制备硫氨酯并联产三硫代碳酸盐的方法
US9988348B1 (en) 2017-06-06 2018-06-05 King Saud University Synthesis and antimicrobial use of a trithiocarbonate derivative
US10526484B2 (en) 2017-12-20 2020-01-07 Covestro Llc Dithiocarbonate containing polyols as polymer polyol stabilizers
EP3502154A1 (de) * 2017-12-21 2019-06-26 Covestro Deutschland AG Polyurethanhybridpolymere und ein verfahren zu ihrer herstellung
EP3502094A1 (de) * 2017-12-21 2019-06-26 Covestro Deutschland AG Verfahren zur herstellung von telechelen polyolen aus trithiocarbonaten
GB201800249D0 (en) * 2018-01-08 2018-02-21 Univ Of Sussex Pickering emulsions
US12448477B2 (en) 2018-07-17 2025-10-21 Polyanalytik Inc. Synthetic method for the preparation of rheological modifying polymers and the use thereof
CN111154049B (zh) * 2018-11-08 2022-07-26 华东理工大学华昌聚合物有限公司 一种耐温可增稠光固化环氧乙烯基酯树脂及其制备方法
US11667734B2 (en) 2019-02-14 2023-06-06 Drexel University Oxygen tolerant and room temperature raft through alkylborane initiation
CN110628181B (zh) * 2019-09-27 2022-03-29 大连理工大学 一种基于哑铃型共聚物的增韧型环氧树脂及其制备方法
CN110982582B (zh) * 2019-12-04 2022-05-13 重庆昆崧科技有限公司 润滑油抗磨剂的制备方法
CN116444768B (zh) * 2023-04-19 2025-11-21 华北电力大学（保定） 高效损伤自修复可降解的双重动态交联Vitrimer树脂
CN121086472B (zh) * 2025-11-10 2026-03-27 中国人民解放军国防科技大学 可重复赋型环氧树脂基复合材料、制备及重复赋型方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3285945A (en) 1966-11-15 Process for the production of ester salts
US110072A (en) * 1870-12-13 Improvement in baskets for tile-grinders
US2858292A (en) * 1953-10-08 1958-10-28 Gen Tire & Rubber Co Composition containing compound stabilized with a trithiocarbonate
US3285949A (en) 1964-04-17 1966-11-15 Goodrich Co B F Carboxyl-terminated butadiene polymers prepared in tertiary butanol with bis-azocyano acid initiation
US3992432A (en) 1967-04-05 1976-11-16 Continental Oil Company Phase transfer catalysis of heterogeneous reactions by quaternary salts
FI42085B (de) 1968-05-20 1970-02-02 Laeaeketehdas Orion Oy
US3770698A (en) 1971-12-17 1973-11-06 C Riew Phenol terminated carboxy containing diene elastomers
US3860641A (en) * 1972-10-21 1975-01-14 Akzo Nv Process for the production of thioglycolic acid, beta-mercaptopropionic acid or salts thereof
US3928491A (en) 1973-12-26 1975-12-23 Youngstown Sheet And Tube Co Modified vinyl ester resin and pipe made therefrom
DE3044811A1 (de) * 1980-11-28 1982-07-01 Bayer Ag, 5090 Leverkusen Xanthogendisulfide, deren herstellung und verwendung als molgewichtsregler bei der polymerisation von chloropren
US4769419A (en) 1986-12-01 1988-09-06 Dawdy Terrance H Modified structural adhesives
US5055515A (en) 1988-09-09 1991-10-08 The B. F. Goodrich Company Flexible overpolymers of vinyl chloride polymers on ethylene copolymers
US5258445A (en) 1990-03-08 1993-11-02 The B. F. Goodrich Company Fiber-reinforced thermoplastic molding compositions using a copolyester
JPH03291265A (ja) * 1990-04-06 1991-12-20 Tosoh Corp アルキルキサンテート系化合物、その製造方法、及びその使用
US5157077A (en) 1990-04-27 1992-10-20 The B. F. Goodrich Company Epoxy resin systems modified with statistical monofunctional reactive polymers
US5140068A (en) 1990-04-27 1992-08-18 The B. F. Goodrich Company Epoxy resin systems modified with low viscosity statistical monofunctional reactive polymers
CA2040035A1 (en) 1990-04-27 1991-10-28 Robert J. Bertsch Synthesis of low viscosity non-functional terminated polymers
US5198510A (en) 1990-04-27 1993-03-30 The B. F. Goodrich Company Modification of vinyl ester resins with reactive liquid polymers
US5385963A (en) 1992-01-30 1995-01-31 Gencorp Inc. Unsaturated polyester-modified flexible copolymers for use in sheet molding compositions
IT1254480B (it) * 1992-02-28 1995-09-25 Dispositivo per eliminare occlusioni di frammenti di calcoli presenti nell'apparato urinario
EP0704460B1 (de) 1994-03-23 1998-11-04 Kuraray Co., Ltd. Verfahren zur herstellung von polymeren mit eventuell geschützten funktionellen endgruppen
WO1996002003A1 (en) * 1994-07-08 1996-01-25 City Of Hope N-terminal protein sequencing reagents and methods which form amino acid derivatives
GB9423266D0 (en) * 1994-11-18 1995-01-11 Minnesota Mining & Mfg Chemical sensitisation of silver halide emulsions
WO1998001478A1 (en) 1996-07-10 1998-01-15 E.I. Du Pont De Nemours And Company Polymerization with living characteristics
FR2764892B1 (fr) * 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
US6512081B1 (en) 1997-07-21 2003-01-28 E.I. Dupont Nemours And Company Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
BR9815179A (pt) 1997-12-18 2000-10-10 Du Pont Processo para produzir um polìmero, polìmero, composição de revestimento e agente de transferência de cadeia.
CA2315914A1 (fr) 1997-12-31 1999-07-15 Xavier Franck Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithiocarbamates
US6380335B1 (en) 2000-09-28 2002-04-30 Symyx Technologies, Inc. Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same
US6395850B1 (en) 2000-09-28 2002-05-28 Symyx Technologies, Inc. Heterocycle containing control agents for living-type free radical polymerization

Also Published As

Publication number Publication date
US20030187138A1 (en) 2003-10-02
EP1255731A1 (de) 2002-11-13
US6894116B2 (en) 2005-05-17
AU781636B2 (en) 2005-06-02
US7495128B2 (en) 2009-02-24
KR20030007424A (ko) 2003-01-23
EP1255731B1 (de) 2005-06-22
WO2001060792A1 (en) 2001-08-23
AU2782601A (en) 2001-08-27
US6962961B2 (en) 2005-11-08
JP4914553B2 (ja) 2012-04-11
DE60111612D1 (de) 2005-07-28
CA2399690C (en) 2010-03-30
CA2399690A1 (en) 2001-08-23
KR100712801B1 (ko) 2007-05-02
US20090005529A1 (en) 2009-01-01
US7851582B2 (en) 2010-12-14
DE60111612T2 (de) 2006-05-24
US20050267274A1 (en) 2005-12-01
US20080004461A1 (en) 2008-01-03
US7279591B2 (en) 2007-10-09
JP2003522816A (ja) 2003-07-29
US7659345B2 (en) 2010-02-09
US20030233006A1 (en) 2003-12-18
US20080214773A1 (en) 2008-09-04
US6596899B1 (en) 2003-07-22

Similar Documents

Publication Publication Date Title
DE60111612D1 (de) Ss'-bis-(alpha, alpha'-disubstituierte-alpha''-essigsäure)-trithio-carbonate und derivate davon als initiatoren, kettentransfer-verbindung, kettenabbruch-verbindung für kontrollierte radikalische polymerisationen sowie verfahren zu deren herstellung
EP1281722A4 (de) Hyaluronsäuregel, verfahren zu dessen herstellung sowie das gel enthaltendes medizinisches material
ATE318867T1 (de) Thermoplastische zusammensetzung, welche einen hyperverzweigten polymer enthält, und daraus hergestellte gegenstände
ATE335123T1 (de) Verfahren zum frakturieren einer unterirdischen lagerstätten unter verwendung von geliersäuren
DE69624475D1 (de) Heterotelechelische blockcopolymere und verfahren zu deren herstellung
ATE271075T1 (de) Verfahren zur herstellung von polyethylen
DK1648518T3 (da) Konjugerede biologiske molekyler og deres fremstilling
DE60315472D1 (de) Glycolsaüre copolymer und verfahren zu dessen herstellung
BR9815112B1 (pt) processo para a preparaÇço de polÍmeros sintÉticos com teor de monâmero residual muito baixo.
ATE312823T1 (de) Verfahren zur herstellung heteroarylsubstituierter ureaverbindungen
FR2737406B1 (fr) Gel a activite physique pour produits cosmetiques
ATE278714T1 (de) Verfahren zur herstellung eines polymeren umsetzungsprodukts
ES2160584T3 (es) Iniciadores solubles de la polimerizacion anionica y productos de los mismos.
ATE277899T1 (de) 8-8,6-6 und 6-8 catechin und epicatechin dimere und verfahren zu ihrer herstellung
ES2124846T3 (es) Composicion y metodo para la clarificacion de agua y tratamiento de aguas residuales.
MA27232A1 (fr) Derives d'acide n-benzoylureidocinnamique, leurs procedes de preparation et leurs utilisations
TR28332A (tr) Arilasetik asit türevleri.
ATE295716T1 (de) Mittel und verfahren zu dauerhaften haarverformung auf basis von 2- mercaptopropionsäureamiden sowie verfahren zu deren herstellung
ATE362953T1 (de) Silikonhaltiges copolymer und verfahren zu dessen herstellung
BR0001629A (pt) Composição para reduzir o intumescimento da madeira na presença de água, e, processos de reduzir o intumescimento da madeira na presença de água e de reduzir a taxa de lixiviamento de um ou mais biocidas da madeiras
DE60133019D1 (de) Metallaminkomplex enthaltende fluorpolymer- zusammensetzungen
ATE299858T1 (de) Verfahren zur herstellung von diaminodiphenylmethan und seiner höheren homologen
DE69710909D1 (de) Substituierte tetrahydropyridinderivate, verfahren zu ihrer herstellung und diese enthaltende arzneimittel
CA2515385A1 (en) Novel polymer and process for producing the same
EP1721912A4 (de) Verfahren zur herstellung von polymer mit funktioneller endgruppe

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties