ATE203547T1 - Geträgerte metallocenkatalysator für die olefinpolymerisation - Google Patents

Geträgerte metallocenkatalysator für die olefinpolymerisation

Info

Publication number
ATE203547T1
ATE203547T1 AT96200191T AT96200191T ATE203547T1 AT E203547 T1 ATE203547 T1 AT E203547T1 AT 96200191 T AT96200191 T AT 96200191T AT 96200191 T AT96200191 T AT 96200191T AT E203547 T1 ATE203547 T1 AT E203547T1
Authority
AT
Austria
Prior art keywords
metal
catalyst
constituted
porous oxide
olefin polymerization
Prior art date
Application number
AT96200191T
Other languages
English (en)
Inventor
Liliana Gila
Antonio Proto
Evelina Ballato
Diego Vigliarolo
Gabriele Lugli
Original Assignee
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Spa filed Critical Enichem Spa
Application granted granted Critical
Publication of ATE203547T1 publication Critical patent/ATE203547T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT96200191T 1995-02-01 1996-01-27 Geträgerte metallocenkatalysator für die olefinpolymerisation ATE203547T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI950167A IT1272939B (it) 1995-02-01 1995-02-01 Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
ATE203547T1 true ATE203547T1 (de) 2001-08-15

Family

ID=11370383

Family Applications (1)

Application Number Title Priority Date Filing Date
AT96200191T ATE203547T1 (de) 1995-02-01 1996-01-27 Geträgerte metallocenkatalysator für die olefinpolymerisation

Country Status (9)

Country Link
US (1) US5861352A (de)
EP (1) EP0725086B1 (de)
JP (1) JPH08333412A (de)
AT (1) ATE203547T1 (de)
DE (1) DE69614010T2 (de)
DK (1) DK0725086T3 (de)
ES (1) ES2159679T3 (de)
GR (1) GR3036494T3 (de)
IT (1) IT1272939B (de)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
CZ28597A3 (en) * 1994-08-03 1997-07-16 Exxon Chemical Patents Inc Ionic catalytic supported composition
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
US5747404A (en) * 1996-05-28 1998-05-05 Lyondell Petrochemical Company Polysiloxane supported metallocene catalysts
US6635778B1 (en) 1996-10-30 2003-10-21 Repsol Quimica S.A. Catalysts systems for the polymerization and copolymerization of alpha-olefins
NO318716B1 (no) * 1996-10-31 2005-05-02 Repsol Quimica Sa Katalysatorsystem for polymerisering
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
KR20000068804A (ko) 1997-08-21 2000-11-25 고오사이 아끼오 개질된 입자, 이로부터 제조된 담체, 이로부터 제조된 올레핀 중합용 촉매 성분, 이로부터 제조된 올레핀 중합용 촉매 및 올레핀중합체의 제조방법
EP0933383A1 (de) * 1998-01-29 1999-08-04 Union Carbide Chemicals & Plastics Technology Corporation Katalysatorzusammensetzung für die Olefinpolymerisation
PT953581E (pt) 1998-04-27 2004-07-30 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
DE69916358T2 (de) * 1998-04-29 2005-04-21 Repsol Quimica Sa Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
US6300271B1 (en) * 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) * 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
US6040261A (en) * 1999-04-15 2000-03-21 Equistar Chemicals, Lp Supported single-site catalyst and olefin polymerization process
US6376415B1 (en) * 1999-09-28 2002-04-23 Phillips Petroleum Company Organometal catalyst compositions
NO20013880L (no) 2000-08-22 2002-02-25 Rohm & Haas Matriks og fremgangsmåte for fremstilling av polyolefiner
US7102006B2 (en) * 2002-09-12 2006-09-05 Dow Global Technologies Inc. Preparation of metal complexes
JP2005539059A (ja) * 2002-09-12 2005-12-22 ダウ・グローバル・テクノロジーズ・インコーポレイテッド 金属アミド錯体の製造方法
WO2004026925A1 (en) 2002-09-17 2004-04-01 Dow Global Technologies Inc. Improved process for manufacture of polymers
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
KR101141359B1 (ko) * 2005-09-09 2012-05-03 에스케이이노베이션 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계
CA2621307C (en) * 2005-09-09 2014-12-02 Sk Energy Co., Ltd. Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins
WO2007066546A1 (ja) 2005-12-06 2007-06-14 Tri Chemical Laboratories Inc. ハフニウム系化合物、ハフニウム系薄膜形成材料、及びハフニウム系薄膜形成方法
US8399056B2 (en) 2006-06-02 2013-03-19 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method of forming high-k dielectric films based on novel titanium, zirconium, and hafnium precursors and their use for semiconductor manufacturing
WO2009106433A1 (en) 2008-02-27 2009-09-03 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for forming a titanium-containing layer on a substrate using an atomic layer deposition (ald) process
US7884165B2 (en) * 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US9663547B2 (en) 2014-12-23 2017-05-30 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Silicon- and Zirconium-containing compositions for vapor deposition of Zirconium-containing films
US9499571B2 (en) 2014-12-23 2016-11-22 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Germanium- and zirconium-containing compositions for vapor deposition of zirconium-containing films
US10106568B2 (en) 2016-10-28 2018-10-23 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Hafnium-containing film forming compositions for vapor deposition of hafnium-containing films
GB201714756D0 (en) 2017-09-13 2017-10-25 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters
TWI873083B (zh) * 2018-09-14 2025-02-21 英商三菱化學英國有限公司 用於製造乙烯性不飽和羧酸或酯之催化劑及方法
US11806694B2 (en) 2020-03-12 2023-11-07 Mitsubishi Chemical UK Limited Catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988008432A1 (fr) * 1987-04-20 1988-11-03 Mitsui Petrochemical Industries, Ltd. Catalyseur et procede de polymerisation d'olefines
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
DE69226564T3 (de) * 1991-05-20 2004-04-08 Mitsui Chemicals, Inc. Katalysator und Verfahren für Olefinpolymerisation
JP2955400B2 (ja) * 1991-07-16 1999-10-04 三井化学株式会社 オレフィン重合用固体触媒成分の製造方法
IT1256603B (it) * 1992-10-30 1995-12-12 Enichem Polimeri Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine

Also Published As

Publication number Publication date
ITMI950167A0 (it) 1995-02-01
DK0725086T3 (da) 2001-10-01
GR3036494T3 (en) 2001-11-30
JPH08333412A (ja) 1996-12-17
IT1272939B (it) 1997-07-01
US5861352A (en) 1999-01-19
DE69614010D1 (de) 2001-08-30
EP0725086A3 (de) 1997-05-28
DE69614010T2 (de) 2002-03-21
EP0725086B1 (de) 2001-07-25
ITMI950167A1 (it) 1996-08-01
ES2159679T3 (es) 2001-10-16
EP0725086A2 (de) 1996-08-07

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UEP Publication of translation of european patent specification