ATE195665T1 - Verfahren zur herstellung von beschichtungspulver, katalysatoren und trockenen überzugsmitteln auf wässriger basis durch sprühtrocknen mit komprimierten fluiden - Google Patents
Verfahren zur herstellung von beschichtungspulver, katalysatoren und trockenen überzugsmitteln auf wässriger basis durch sprühtrocknen mit komprimierten fluidenInfo
- Publication number
- ATE195665T1 ATE195665T1 AT95308100T AT95308100T ATE195665T1 AT E195665 T1 ATE195665 T1 AT E195665T1 AT 95308100 T AT95308100 T AT 95308100T AT 95308100 T AT95308100 T AT 95308100T AT E195665 T1 ATE195665 T1 AT E195665T1
- Authority
- AT
- Austria
- Prior art keywords
- compressed fluids
- catalysts
- spray
- spray drying
- water
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/025—Processes for applying liquids or other fluent materials performed by spraying using gas close to its critical state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/16—Evaporating by spraying
- B01D1/18—Evaporating by spraying to obtain dry solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0232—Coating by pulverisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/122—Pulverisation by spraying
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/021—Aerosols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2401/00—Form of the coating product, e.g. solution, water dispersion, powders or the like
- B05D2401/90—Form of the coating product, e.g. solution, water dispersion, powders or the like at least one component of the composition being in supercritical state or close to supercritical state
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Catalysts (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/338,900 US5716558A (en) | 1994-11-14 | 1994-11-14 | Method for producing coating powders catalysts and drier water-borne coatings by spraying compositions with compressed fluids |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE195665T1 true ATE195665T1 (de) | 2000-09-15 |
Family
ID=23326615
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT95308100T ATE195665T1 (de) | 1994-11-14 | 1995-11-13 | Verfahren zur herstellung von beschichtungspulver, katalysatoren und trockenen überzugsmitteln auf wässriger basis durch sprühtrocknen mit komprimierten fluiden |
Country Status (11)
Country | Link |
---|---|
US (3) | US5716558A (de) |
EP (1) | EP0711586B1 (de) |
KR (1) | KR100239613B1 (de) |
AT (1) | ATE195665T1 (de) |
AU (1) | AU692936B2 (de) |
CA (1) | CA2162744C (de) |
DE (1) | DE69518487T2 (de) |
DK (1) | DK0711586T3 (de) |
ES (1) | ES2151581T3 (de) |
GR (1) | GR3034890T3 (de) |
PT (1) | PT711586E (de) |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9413202D0 (en) * | 1994-06-30 | 1994-08-24 | Univ Bradford | Method and apparatus for the formation of particles |
US5849862A (en) * | 1995-06-07 | 1998-12-15 | Cytec Technology Corp. | Processes of spray drying polymer-containing dispersions, water-in-oil emulsions and water-in-oil microemulsions |
US6011089A (en) * | 1995-06-07 | 2000-01-04 | Cytec Technology Corp. | Spray drying of polymer-containing dispersions, water-in-oil emulsions and water-in-oil microemulsions, and dry polymer products formed thereby |
US5869542A (en) * | 1995-06-07 | 1999-02-09 | Cytec Technology Corp. | Spray drying of polymer-containing dispersions, water-in-oil emulsions and microemulsions and dry polymer products formed thereby |
JP4047382B2 (ja) * | 1995-08-04 | 2008-02-13 | マイクロコーティング テクノロジーズ | 超臨界付近および超臨界の流体溶液の溶射を用いた化学蒸着および粉体形成 |
US20030203036A1 (en) * | 2000-03-17 | 2003-10-30 | Gordon Marc S. | Systems and processes for spray drying hydrophobic drugs with hydrophilic excipients |
GB9703673D0 (en) * | 1997-02-21 | 1997-04-09 | Bradford Particle Design Ltd | Method and apparatus for the formation of particles |
EP1023127A1 (de) | 1997-10-10 | 2000-08-02 | Union Carbide Chemicals & Plastics Technology Corporation | Aufsprühen von einer hilfsmittelzusammensetzung auf bahnförmige materialien |
DE19749989A1 (de) * | 1997-11-12 | 1999-05-27 | Herberts Gmbh | Verfahren zur Herstellung von Pulverlackzusammensetzungen |
US6426136B1 (en) | 1998-02-10 | 2002-07-30 | R & D Technology, Inc. | Method of reducing material size |
US6184270B1 (en) | 1998-09-21 | 2001-02-06 | Eric J. Beckman | Production of power formulations |
EP1185248B1 (de) | 1999-06-09 | 2012-05-02 | Robert E. Sievers | Überkritische fluidgestützte verneblung und blasen trochnen |
US6459901B1 (en) * | 1999-07-01 | 2002-10-01 | At&T Corp. | Wireless network resource allocation |
GB9915975D0 (en) * | 1999-07-07 | 1999-09-08 | Bradford Particle Design Ltd | Method for the formation of particles |
CN1239269C (zh) * | 1999-11-26 | 2006-02-01 | 旭硝子株式会社 | 有机材料的制膜方法及装置 |
US6663954B2 (en) | 2000-01-03 | 2003-12-16 | R & D Technology, Inc. | Method of reducing material size |
JP4802355B2 (ja) * | 2000-03-29 | 2011-10-26 | Dic株式会社 | 粉体塗料の製造方法 |
US7575761B2 (en) * | 2000-06-30 | 2009-08-18 | Novartis Pharma Ag | Spray drying process control of drying kinetics |
AU2001277230A1 (en) * | 2000-08-01 | 2002-02-13 | Inhale Therapeutic Systems, Inc. | Apparatus and process to produce particles having a narrow size distribution andparticles made thereby |
GB0027357D0 (en) | 2000-11-09 | 2000-12-27 | Bradford Particle Design Plc | Particle formation methods and their products |
US6743835B2 (en) * | 2000-12-07 | 2004-06-01 | Goldschmidt Ag | Preparation of nondusting free-flowing pigment concentrates |
US20020130430A1 (en) * | 2000-12-29 | 2002-09-19 | Castor Trevor Percival | Methods for making polymer microspheres/nanospheres and encapsulating therapeutic proteins and other products |
US7708915B2 (en) * | 2004-05-06 | 2010-05-04 | Castor Trevor P | Polymer microspheres/nanospheres and encapsulating therapeutic proteins therein |
US20020146509A1 (en) * | 2001-02-06 | 2002-10-10 | Kodokian George K. | Micronization process and polymer particles produced therefrom |
GB0117696D0 (en) * | 2001-07-20 | 2001-09-12 | Bradford Particle Design Plc | Particle information |
GB0216562D0 (en) * | 2002-04-25 | 2002-08-28 | Bradford Particle Design Ltd | Particulate materials |
US9339459B2 (en) | 2003-04-24 | 2016-05-17 | Nektar Therapeutics | Particulate materials |
US6780475B2 (en) | 2002-05-28 | 2004-08-24 | Battelle Memorial Institute | Electrostatic deposition of particles generated from rapid expansion of supercritical fluid solutions |
US6749902B2 (en) | 2002-05-28 | 2004-06-15 | Battelle Memorial Institute | Methods for producing films using supercritical fluid |
US6756084B2 (en) | 2002-05-28 | 2004-06-29 | Battelle Memorial Institute | Electrostatic deposition of particles generated from rapid expansion of supercritical fluid solutions |
DE10234165B4 (de) * | 2002-07-26 | 2008-01-03 | Advanced Micro Devices, Inc., Sunnyvale | Verfahren zum Füllen eines Grabens, der in einem Substrat gebildet ist, mit einem isolierenden Material |
US6884737B1 (en) * | 2002-08-30 | 2005-04-26 | Novellus Systems, Inc. | Method and apparatus for precursor delivery utilizing the melting point depression of solid deposition precursors in the presence of supercritical fluids |
KR100508518B1 (ko) * | 2002-11-13 | 2005-08-17 | 한미약품 주식회사 | 초임계유체 공정을 이용한 파클리탁셀 고체분산체의 제조방법 및 이 방법으로 제조된 파클리탁셀 고체분산체 |
US20040097371A1 (en) * | 2002-11-19 | 2004-05-20 | Juzer Jangbarwala | Application of conductive adsorbents, activated carbon granules and carbon fibers as substrates in catalysis |
US6927415B2 (en) * | 2002-12-06 | 2005-08-09 | Eastman Kodak Company | Compressed fluid formulation containing electron transporting material |
KR20050088243A (ko) * | 2002-12-30 | 2005-09-02 | 넥타르 테라퓨틱스 | 프리필름화 분무기 |
KR20060013486A (ko) * | 2003-02-24 | 2006-02-10 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 프로필렌 중합용 촉매의 복합 담체, 촉매 성분 및 이를포함하는 촉매 |
US8535720B2 (en) * | 2003-02-24 | 2013-09-17 | Ferro Corporation | Method and apparatus for enhanced size reduction of particles |
US20050121827A1 (en) * | 2003-12-09 | 2005-06-09 | Lear Corporation | Method of heating in-mold coating composition |
KR100804442B1 (ko) | 2004-01-28 | 2008-02-20 | 도쿠리쓰교세이호징 가가쿠 기주쓰 신코 기코 | 초임계 유체로부터 빈용매 속으로의 급속 팽창법을이용하는 미립자 제조방법 |
US20050182210A1 (en) | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
US7153626B2 (en) * | 2005-05-23 | 2006-12-26 | Eastman Kodak Company | Method of forming dye donor element |
US20070120281A1 (en) * | 2005-11-08 | 2007-05-31 | Boris Khusid | Manufacture of fine particles and nano particles and coating thereof |
DE102006005807A1 (de) | 2006-02-08 | 2007-08-16 | BSH Bosch und Siemens Hausgeräte GmbH | Filterelement für Dunstabzugshaube |
NL1031224C2 (nl) * | 2006-02-23 | 2007-09-03 | Friesland Brands Bv | Het bereiden van gedroogde deeltjes met behulp van een superkritisch medium. |
EP1834978A1 (de) * | 2006-03-14 | 2007-09-19 | Basf Aktiengesellschaft | Verfahren zur Mikronisierung von Polymeren |
JP2008027799A (ja) * | 2006-07-24 | 2008-02-07 | Toyota Motor Corp | 燃料電池用接合体、燃料電池、及び燃料電池の製造方法 |
JP5060791B2 (ja) * | 2007-01-26 | 2012-10-31 | 独立行政法人森林総合研究所 | 木材の乾燥方法、木材への薬剤浸透方法及び乾燥装置 |
US8942636B2 (en) * | 2008-01-28 | 2015-01-27 | Qualcomm Incorporated | Adaptive transmission of resource utilization messages based on throughput |
US8139528B2 (en) * | 2008-01-28 | 2012-03-20 | Qualcomm Incorporated | Adaptive transmission of resource utilization messages |
ES2526975T3 (es) | 2010-04-05 | 2015-01-19 | Dow Global Technologies Llc | Procedimiento para polimerizar polímeros de base olefínica que contienen fracciones de alto peso molecular en modos condensado y súper-condensado |
US8809220B2 (en) | 2010-04-13 | 2014-08-19 | Union Carbide Chemicals & Plastics Technology Llc | Method of making Ziegler-Natta type catalysts |
US9808030B2 (en) | 2011-02-11 | 2017-11-07 | Grain Processing Corporation | Salt composition |
EP2750797B1 (de) | 2011-11-08 | 2020-04-01 | Univation Technologies, LLC | Verfahren zur herstellung eines katalysatorsystems |
IN2015DN02467A (de) | 2012-11-01 | 2015-09-04 | Univation Tech Llc | |
DE102013018690A1 (de) * | 2013-11-08 | 2015-05-13 | Uts Biogastechnik Gmbh | Rühreinrichtung für einen Fermenter einer Biogasanlage und Verfahren zur Herstellung einer Rühreinrichtung |
US10414887B2 (en) | 2015-10-02 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and methods of using same |
WO2018075243A1 (en) | 2016-10-19 | 2018-04-26 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and methods of using same |
EP3559058A1 (de) | 2016-12-22 | 2019-10-30 | ExxonMobil Chemical Patents Inc. | Sprühgetrocknete polymerisierungskatalysatorzusammensetzungen und polymerisationsverfahren zur verwendung davon |
US10479759B2 (en) | 2017-02-08 | 2019-11-19 | Clariant Corporation | Synthetic methods for the preparation of propylene ammoxidation catalysts |
WO2022266662A1 (en) * | 2021-06-17 | 2022-12-22 | University Of Florida Research Foundation, Inc. | Methods and systems for producing hyperpolarized fluid samples |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5916701A (ja) * | 1982-07-20 | 1984-01-27 | 追浜工業株式会社 | 携帯用チエンソ−の作動状態表示装置 |
US4734451A (en) * | 1983-09-01 | 1988-03-29 | Battelle Memorial Institute | Supercritical fluid molecular spray thin films and fine powders |
US4582731A (en) * | 1983-09-01 | 1986-04-15 | Battelle Memorial Institute | Supercritical fluid molecular spray film deposition and powder formation |
US4734227A (en) * | 1983-09-01 | 1988-03-29 | Battelle Memorial Institute | Method of making supercritical fluid molecular spray films, powder and fibers |
US4737384A (en) * | 1985-11-01 | 1988-04-12 | Allied Corporation | Deposition of thin films using supercritical fluids |
DK159907C (da) * | 1986-02-14 | 1991-05-21 | Grindsted Prod As | Fremgangsmaade ved fremstilling af additiver til brug ved fremstilling af haevede bageriprodukter og piskede desserter |
EP0321607B1 (de) * | 1987-12-21 | 1993-09-22 | Union Carbide Corporation | Verwendung von superkritischen Flüssigkeiten als Verdünner beim Aufsprühen von Überzügen |
US5057342A (en) * | 1987-12-21 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Methods and apparatus for obtaining a feathered spray when spraying liquids by airless techniques |
JPH01176437A (ja) * | 1987-12-29 | 1989-07-12 | Ono Pharmaceut Co Ltd | 有機物質の微粒化方法 |
US5066522A (en) * | 1988-07-14 | 1991-11-19 | Union Carbide Chemicals And Plastics Technology Corporation | Supercritical fluids as diluents in liquid spray applications of adhesives |
US5106650A (en) * | 1988-07-14 | 1992-04-21 | Union Carbide Chemicals & Plastics Technology Corporation | Electrostatic liquid spray application of coating with supercritical fluids as diluents and spraying from an orifice |
US4882107A (en) * | 1988-11-23 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Mold release coating process and apparatus using a supercritical fluid |
US5141786A (en) * | 1989-02-28 | 1992-08-25 | Shin-Etsu Chemical Co., Ltd. | Synthetic silica glass articles and a method for manufacturing them |
ATE95540T1 (de) * | 1989-03-22 | 1993-10-15 | Union Carbide Chem Plastic | Vorlaeuferbeschichtungszusammensetzungen. |
US5009367A (en) * | 1989-03-22 | 1991-04-23 | Union Carbide Chemicals And Plastics Technology Corporation | Methods and apparatus for obtaining wider sprays when spraying liquids by airless techniques |
US5106659A (en) * | 1989-10-04 | 1992-04-21 | Nordson Corporation | Method and apparatus for spraying a liquid coating containing supercritical fluid or liquified gas |
US5088443A (en) * | 1989-10-04 | 1992-02-18 | Nordson Corporation | Method and apparatus for spraying a liquid coating containing supercritical fluid or liquified gas |
US5092959A (en) * | 1990-04-27 | 1992-03-03 | Yamato Scientific Co., Ltd. | Organic solvent spray dryer device |
US5290827A (en) * | 1991-03-27 | 1994-03-01 | University Of Delaware | Precipitation of homogeneous polymer mixtures from supercritical fluid solutions |
US5312862A (en) * | 1992-12-18 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Methods for admixing compressed fluids with solvent-borne compositions comprising solid polymers |
US5290603A (en) * | 1992-12-18 | 1994-03-01 | Union Carbide Chemicals & Plastics Technology Corporation | Method for spraying polymeric compositions with reduced solvent emission and enhanced atomization |
US5302566A (en) * | 1993-01-25 | 1994-04-12 | E. I. Du Pont De Nemours And Company | Process for preparing attrition resistant catalysts |
US5419487A (en) * | 1993-09-29 | 1995-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Methods for the spray application of water-borne coatings with compressed fluids |
-
1994
- 1994-11-14 US US08/338,900 patent/US5716558A/en not_active Expired - Lifetime
-
1995
- 1995-11-13 PT PT95308100T patent/PT711586E/pt unknown
- 1995-11-13 AU AU37794/95A patent/AU692936B2/en not_active Ceased
- 1995-11-13 AT AT95308100T patent/ATE195665T1/de not_active IP Right Cessation
- 1995-11-13 EP EP95308100A patent/EP0711586B1/de not_active Expired - Lifetime
- 1995-11-13 ES ES95308100T patent/ES2151581T3/es not_active Expired - Lifetime
- 1995-11-13 KR KR1019950041760A patent/KR100239613B1/ko not_active IP Right Cessation
- 1995-11-13 DK DK95308100T patent/DK0711586T3/da active
- 1995-11-13 DE DE69518487T patent/DE69518487T2/de not_active Expired - Lifetime
- 1995-11-14 CA CA002162744A patent/CA2162744C/en not_active Expired - Fee Related
-
1999
- 1999-04-19 US US09/294,104 patent/US6106896A/en not_active Expired - Lifetime
- 1999-04-19 US US09/294,105 patent/US6124226A/en not_active Expired - Lifetime
-
2000
- 2000-11-22 GR GR20000402579T patent/GR3034890T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US6124226A (en) | 2000-09-26 |
DE69518487D1 (de) | 2000-09-28 |
GR3034890T3 (en) | 2001-02-28 |
DK0711586T3 (da) | 2000-12-27 |
CA2162744A1 (en) | 1996-05-15 |
AU3779495A (en) | 1996-05-23 |
US5716558A (en) | 1998-02-10 |
ES2151581T3 (es) | 2001-01-01 |
AU692936B2 (en) | 1998-06-18 |
PT711586E (pt) | 2000-12-29 |
EP0711586A3 (de) | 1996-11-06 |
KR960017800A (ko) | 1996-06-17 |
EP0711586A2 (de) | 1996-05-15 |
EP0711586B1 (de) | 2000-08-23 |
KR100239613B1 (ko) | 2000-01-15 |
CA2162744C (en) | 2000-01-04 |
DE69518487T2 (de) | 2001-04-19 |
US6106896A (en) | 2000-08-22 |
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