AT72306B - Process for obtaining products of tar distillation with heating with phosphoric acid. - Google Patents

Process for obtaining products of tar distillation with heating with phosphoric acid.

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Publication number
AT72306B
AT72306B AT72306DA AT72306B AT 72306 B AT72306 B AT 72306B AT 72306D A AT72306D A AT 72306DA AT 72306 B AT72306 B AT 72306B
Authority
AT
Austria
Prior art keywords
sep
phosphoric acid
heating
obtaining products
tar distillation
Prior art date
Application number
Other languages
German (de)
Inventor
Meilich Dr Melamid
Louis Groetzinger
Original Assignee
Meilich Dr Melamid
Louis Groetzinger
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Meilich Dr Melamid, Louis Groetzinger filed Critical Meilich Dr Melamid
Application granted granted Critical
Publication of AT72306B publication Critical patent/AT72306B/en

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  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Description

  

   <Desc/Clms Page number 1> 
 
 EMI1.1 
 
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<tb> bis <SEP> 200  <SEP> siedend <SEP> 6#49 <SEP> Prozent <SEP> spezifisches <SEP> Gewicht <SEP> 0#950.
<tb> von <SEP> 200 <SEP> # <SEP> 230  <SEP> # <SEP> 16#53 <SEP> # <SEP> # <SEP> # <SEP> 1#001,
<tb> # <SEP> 230 <SEP> # <SEP> 270  <SEP> # <SEP> 7#76 <SEP> # <SEP> # <SEP> # <SEP> 1#005,
<tb> # <SEP> 270 <SEP> # <SEP> 320  <SEP> # <SEP> 24#16 <SEP> # <SEP> # <SEP> # <SEP> 1#005,
<tb> Pech <SEP> ....... <SEP> 44#30 <SEP> ,,
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<tb> von <SEP> 200 <SEP> 330  <SEP> 900 <SEP> n <SEP> n <SEP> n <SEP> 0-990,
<tb> # <SEP> 230 <SEP> # <SEP> 270  <SEP> 23#14 <SEP> # <SEP> # <SEP> # <SEP> 0#992,
<tb> " <SEP> 2ïO <SEP> " <SEP> 3200 <SEP> 14'08 <SEP> "
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 <Desc/Clms Page number 2> 

 Beispiel 3 : 
Das   bis 2000 siedende.   nach Beispiel 2 gewonnene Destillat wird nochmals mit 25 Prozent Phosphorsäure unter denselben Bedingungen wie oben behandelt. Dabei ergaben sich 
 EMI2.1 
 
<tb> 
<tb> 80 <SEP> Prozent <SEP> bis <SEP> 1200 <SEP> sie <SEP> (rend <SEP> spezifisches <SEP> Gewicht <SEP> 0860.
<tb> 6 <SEP> # <SEP> # <SEP> 150  <SEP> # <SEP> # <SEP> # <SEP> 0#867,
<tb> 14 <SEP> # <SEP> # <SEP> 180  <SEP> # <SEP> # <SEP> # <SEP> 0#880.
<tb> 
 



   Aus diesem Beispiel ergibt sich, dass sämtliche bis 2000 siedende Kohlenwasserstoffe in leichtore Kohlenwasserstoffe mit niedrigerem spezifischen Gewicht umgewandelt wurden. 



   Beispiel4 :
Wenn das von 200 bis 2700 siedende, nach Beispiel 2 gewonnene Destillat abermals mit   25   kg Phosphorsäuro vermischt, wie bei Beispiel 2 destilliert wurde, ergab sich folgende überraschendes Ergebnis : 
 EMI2.2 
 
<tb> 
<tb> 20 <SEP> Prozent <SEP> bis <SEP> 120  <SEP> siedend <SEP> sperifisches <SEP> Gewicht <SEP> 0867.
<tb> 



  25 <SEP> # <SEP> 180  <SEP> # <SEP> # <SEP> # <SEP> 0#884,
<tb> 55 <SEP> " <SEP> " <SEP> 2300,, <SEP> - <SEP> - <SEP> 0 <SEP> 965.
<tb> 
 



   Auch hiemit ist bewiesen, dass sämtliche Oie in leichter siedende sowie spezifisch leichtere Kohlenwasserstoffe umgewandelt wurden. Bei weiteren Behandlungen werden, wie Beispiele 3 und 4 beweisen, die schweren Kohlenwasserstoffe immer wieder leichter siedende von niedrigerem spezifischen Gewicht abspalten. 



   Aus obigem folgt weiter, dass das bis 1200 gewonnene Destillat kein Benzol darstellt, sondern ein vollständig neues Produkt ist. 90er Handelsbenzol hat z. B. ein 
 EMI2.3 
 Benzinvergaser ausprobiert. Mit diesem Vergaser arbeitet der Motor sehr schlecht oder überhaput nicht bei Verwendung von bekanntem 90er Handelsbenzol. Mit dem obigen neuen Produkt hat aber das Automobil mit dem   Benzin ergaser Torzuglich gearbeitet   und die Auspuffgase waren nahezu geruchlos gegenüber den Auspuffgasen des Benzins und Benzols. Noch interessanter ist aber, dass der Motor eine   ! 0 Prozent grössere Ce-   
 EMI2.4 
   Gewicht von 0#716   oder bei Benzol. Ferner war das neue Produkt zirka 20 Prozent ergiebiger wie Benzin von 0 720 spezifischem Gewicht. 
 EMI2.5 
 

**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.



   <Desc / Clms Page number 1>
 
 EMI1.1
 
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<tb>
<tb> to <SEP> 200 <SEP> boiling <SEP> 6 # 49 <SEP> percent <SEP> specific <SEP> weight <SEP> 0 # 950.
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<tb> # <SEP> 230 <SEP> # <SEP> 270 <SEP> # <SEP> 7 # 76 <SEP> # <SEP> # <SEP> # <SEP> 1 # 005,
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<tb> from <SEP> 200 <SEP> 330 <SEP> 900 <SEP> n <SEP> n <SEP> n <SEP> 0-990,
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 <Desc / Clms Page number 2>

 Example 3:
That boiling until 2000. The distillate obtained according to Example 2 is treated again with 25 percent phosphoric acid under the same conditions as above. It resulted
 EMI2.1
 
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<tb> 80 <SEP> percent <SEP> to <SEP> 1200 <SEP> they <SEP> (rend <SEP> specific <SEP> weight <SEP> 0860.
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<tb> 14 <SEP> # <SEP> # <SEP> 180 <SEP> # <SEP> # <SEP> # <SEP> 0 # 880.
<tb>
 



   This example shows that all hydrocarbons boiling up to 2000 were converted into lighter hydrocarbons with a lower specific weight.



   Example4:
If the distillate boiling from 200 to 2700 and obtained according to Example 2 was mixed again with 25 kg of phosphoric acid, as was distilled in Example 2, the following surprising result resulted:
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<tb> 20 <SEP> percent <SEP> to <SEP> 120 <SEP> boiling <SEP> specific <SEP> weight <SEP> 0867.
<tb>



  25 <SEP> # <SEP> 180 <SEP> # <SEP> # <SEP> # <SEP> 0 # 884,
<tb> 55 <SEP> "<SEP>" <SEP> 2300 ,, <SEP> - <SEP> - <SEP> 0 <SEP> 965.
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   This also proves that all oils were converted into lower-boiling and specifically lighter hydrocarbons. In further treatments, as examples 3 and 4 show, the heavy hydrocarbons repeatedly split off lower-boiling hydrocarbons with a lower specific weight.



   From the above it also follows that the distillate obtained up to 1200 is not benzene, but is a completely new product. 90s commercial benzene has z. B. a
 EMI2.3
 Tried petrol carburetor. With this carburetor, the engine works very poorly or not at all when using the well-known 90s commercial benzene. With the above new product, however, the automobile has worked with the gasoline gasifier Torzuglich and the exhaust gases were almost odorless compared to the exhaust gases of gasoline and benzene. But what is even more interesting is that the engine is a! 0 percent larger Ce
 EMI2.4
   Weight of 0 # 716 or for benzene. Furthermore, the new product was around 20 percent more productive than gasoline with a specific weight of 0.720.
 EMI2.5
 

** WARNING ** End of DESC field may overlap beginning of CLMS **.

 

Claims (1)

**WARNUNG** Ende CLMS Feld Kannt Anfang DESC uberlappen**. ** WARNING ** End of CLMS field may overlap beginning of DESC **.
AT72306D 1912-04-19 1914-08-13 Process for obtaining products of tar distillation with heating with phosphoric acid. AT72306B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT63255T 1912-04-19
DE72306X 1913-08-18

Publications (1)

Publication Number Publication Date
AT72306B true AT72306B (en) 1916-08-25

Family

ID=30444645

Family Applications (1)

Application Number Title Priority Date Filing Date
AT72306D AT72306B (en) 1912-04-19 1914-08-13 Process for obtaining products of tar distillation with heating with phosphoric acid.

Country Status (1)

Country Link
AT (1) AT72306B (en)

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