AT47154B - Process for the preparation of yellow disazo dyes for wool. - Google Patents
Process for the preparation of yellow disazo dyes for wool.Info
- Publication number
- AT47154B AT47154B AT47154DA AT47154B AT 47154 B AT47154 B AT 47154B AT 47154D A AT47154D A AT 47154DA AT 47154 B AT47154 B AT 47154B
- Authority
- AT
- Austria
- Prior art keywords
- wool
- preparation
- disazo dyes
- yellow disazo
- dyes
- Prior art date
Links
- 239000000975 dye Substances 0.000 title claims description 10
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 title claims description 5
- 210000002268 wool Anatomy 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 3
- 238000002360 preparation method Methods 0.000 title claims description 3
- 239000002253 acid Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Coloring (AREA)
Description
<Desc/Clms Page number 1>
Verfahren zur Darstellung gelber Disazofarbstoffe für Wolle. Es wurde gefunden, dass durch Kombination der Tetrazoverbindnng des m-Dichlor- benzidin der lionstitution
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mit 2 Molekülen 1-Sulfoaryl-3-methyl-5-pyrazolon Disazofarbstoffe entstehen, welche sich vor den bekannten Farbstoffen aus 1-Sulfoary-3-methyl-5-pyrazolon dadurch auszeichnen, dass sie die Wolle in gelben Nüancen anfürben, welche auch ohne Nachbehandlung mit Chromsalzen gegen weisse Wolle und Baumwolle walkccht sind. Dieses Resultat konnte nicht vorausgesehen werden.
Zwar sind in der deutschen Patentschrift Nr. 160675 Disazofarb-
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Walkechthnit von WoHfarbstoffcn die SteHung der Sulfogruppe tm Farbstoffmoiekil mass- gebend ist, und schon die Benzidin-o-disulfosäure wesentlich andere Resultate liefert, wie die Benzidin-m-disolfosüure, so konnten die angaben der deutschen Patentschrift Nr. 160675 keine Anhaltspunkte für die Beurteilung der Farbstoffe aus einem nicht sulfurierten Diamin bieten.
Das gleiche gilt für die deutsche Patentschrift Nr. 196989. Der daselbst beschriebene Farbstoff aus m-Dichlorhenzidin und 2 Molekülen 2-Naphtol-3 : 6-disulfosäure ist für einen Vergleich von den vorliegenden doch zu verschieden. und zu der Annahme. dass etwa alle Disazofarbstoffe aus m-Dichlorbenzidin walkecht seien. berechtigten die Angaben dieser Patentschrift nicht im mindesten
Beispiel :
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<Desc / Clms Page number 1>
Process for the preparation of yellow disazo dyes for wool. It has been found that by combining the tetrazo compound of m-dichlorobenzidine, the lionstitution
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With 2 molecules of 1-sulfoaryl-3-methyl-5-pyrazolone disazo dyes are formed, which distinguish themselves from the known dyes from 1-sulfoary-3-methyl-5-pyrazolone in that they dye the wool in yellow shades, which also without After-treatment with chromium salts against white wool and cotton. This result could not be foreseen.
Although in the German patent no. 160675 disazo color
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Milling fasthnite of where the position of the sulfo group to the dye molecule is decisive, and even benzidine-o-disulfonic acid gives significantly different results than benzidine-m-disulfonic acid, the information in German patent specification No. 160675 could not provide any clues for the assessment of the dyes from a non-sulfurized diamine.
The same applies to German patent specification No. 196989. The dye described there, composed of m-dichlorohenzidine and 2 molecules of 2-naphthol-3: 6-disulfonic acid, is too different from the present ones for comparison. and to the assumption. that about all disazo dyes made from m-dichlorobenzidine are stable to water. do not justify the information in this patent specification in the least
Example:
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Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE47154X | 1909-05-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT47154B true AT47154B (en) | 1911-03-27 |
Family
ID=5625540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT47154D AT47154B (en) | 1909-05-15 | 1910-04-23 | Process for the preparation of yellow disazo dyes for wool. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT47154B (en) |
-
1910
- 1910-04-23 AT AT47154D patent/AT47154B/en active
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