AT35859B - Method for representing Kamphen. - Google Patents
Method for representing Kamphen.Info
- Publication number
- AT35859B AT35859B AT35859DA AT35859B AT 35859 B AT35859 B AT 35859B AT 35859D A AT35859D A AT 35859DA AT 35859 B AT35859 B AT 35859B
- Authority
- AT
- Austria
- Prior art keywords
- kamphen
- representing
- parts
- acids
- salt
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 2
- 241000723346 Cinnamomum camphora Species 0.000 claims description 2
- 229930008380 camphor Natural products 0.000 claims description 2
- 229960000846 camphor Drugs 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- XXZAOMJCZBZKPV-WEDXCCLWSA-N (1r,3s,4r)-3-chloro-4,7,7-trimethylbicyclo[2.2.1]heptane Chemical compound C1C[C@@]2(C)[C@@H](Cl)C[C@@H]1C2(C)C XXZAOMJCZBZKPV-WEDXCCLWSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- 229930006739 camphene Natural products 0.000 description 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- -1 fatty acid salts Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
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verhält sie)) auch* das Bleisalz der Palmitinsänre, Es ist aber durchaus Dicht notwendig, die genannten Säuren in reinem Zustande zu verwenden, man nimmt vielmehr Gemische der Säuren, wie man sie heim Verseifen von Ölen oder Fetton erhält.
Beispiel 11 : Ein Gemisch von Ölsäure und Stearinsäure, eventuell auch mit Palmitinsäure, wird mit der berechneten Menge frisch gefälltem Kupferkarbonat oder Kupferoxyd in bekannter Weise in das Knpfersalz Übergeführt. 300 Teile von dem trockenen Kupfersalz worden mit 100 Teilen Pinenhydrochlorid während etwa 5 Stunden auf 195-200 erhitzt. (Man nimmt fallweise Proben ans dem im Rückflusskühler kondensierten Öl und untersucht das Produkt, ob es chlorfrei ist). Das Kamphen wird mit Wasserdampf uberdestilliert und die Fettsäuren regeneriert. Bei nicht so leicht schmelzbaren fettsauren Salzen, wie die genannten, wendet man zweckmässig noch ein Verdussignngsmittel, wie z. B. Diaethylanilin, an.
Beispiel III : Durch Fällen einer Oleinseifenlösung mit Mangansulfat wurde Manganoleat dargestellt. 240 Teile desselben werden mit 100 Teilen Pinenhydrochlorid und 100 Teilen
Diaethylanilin 8 Stunden lang auf 195-200 erhitzt. Nach vollendeter Reaktion wird mit Wasserdampf dostilliert und im Destillat das Diethylanilin durch Ansäuern vom Kamphen getrennt.
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if it behaves)) also * the lead salt of the palmitic acid, but it is absolutely necessary to use the acids mentioned in the pure state, one rather takes mixtures of acids such as those obtained by saponifying oils or fats.
EXAMPLE 11 A mixture of oleic acid and stearic acid, possibly also with palmitic acid, is converted into the button salt in a known manner with the calculated amount of freshly precipitated copper carbonate or copper oxide. 300 parts of the dry copper salt was heated to 195-200 with 100 parts of pinene hydrochloride for about 5 hours. (Occasionally, samples are taken of the oil condensed in the reflux condenser and the product is examined to see whether it is chlorine-free) The camphor is distilled over with steam and the fatty acids are regenerated. In the case of fatty acid salts that are not so easily meltable, such as those mentioned, it is advisable to use a Verdussignngsmittel such. B. diaethylaniline.
Example III: Manganoleate was prepared by precipitating an olein soap solution with manganese sulfate. 240 parts of the same are made with 100 parts of pinene hydrochloride and 100 parts
Diaethylaniline heated to 195-200 for 8 hours. When the reaction is complete, the mixture is distilled with steam and the diethylaniline in the distillate is separated from the camphene by acidification.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT35859T | 1906-08-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT35859B true AT35859B (en) | 1909-01-11 |
Family
ID=3552561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT35859D AT35859B (en) | 1906-08-25 | 1906-08-25 | Method for representing Kamphen. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT35859B (en) |
-
1906
- 1906-08-25 AT AT35859D patent/AT35859B/en active
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