AR105359A1 - Hidrazidas de ácido carboxílico arilo y heteroarilo sustituidas o sus sales y su uso para aumentar la tolerancia al estrés en plantas - Google Patents

Hidrazidas de ácido carboxílico arilo y heteroarilo sustituidas o sus sales y su uso para aumentar la tolerancia al estrés en plantas

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AR105359A1
AR105359A1 ARP160102141A ARP160102141A AR105359A1 AR 105359 A1 AR105359 A1 AR 105359A1 AR P160102141 A ARP160102141 A AR P160102141A AR P160102141 A ARP160102141 A AR P160102141A AR 105359 A1 AR105359 A1 AR 105359A1
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Argentina
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alkyl
aryl
heteroaryl
alkoxycarbonyl
cycloalkyl
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ARP160102141A
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English (en)
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Desbordes Philippe
Strek Harry
Pedro Ruiz-Santaella Moreno Juan
Jeffrey Hills Martin
Bickers Udo
Heinemann Ines
Schmutzler Dirk
Dittgen Jan
Brchner Peter
Lehr Stefan
Adelt Isabelle
Helmke Hendrik
Brnjes Marco
Bojack Guido
Franckenpohl Jens
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Bayer Cropscience Ag
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Publication of AR105359A1 publication Critical patent/AR105359A1/es

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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
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    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A—HUMAN NECESSITIES
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/48—Nitro-carboxylic acids; Derivatives thereof
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
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    • C07C255/57—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton
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    • C07C255/66—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to nitrogen atoms having cyano groups and nitrogen atoms being part of hydrazine or hydrazone groups bound to the same carbon skeleton
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    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Plural Heterocyclic Compounds (AREA)
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  • Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
  • Pyridine Compounds (AREA)
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Abstract

Para aumentar la tolerancia al estrés abiótico, así como para aumentar el crecimiento de las plantas y/o para aumentar el rendimiento de la planta. Reivindicación 1: Hidrazidas de ácido carboxílico arilo y heteroarilo sustituidas de la fórmula general (1) o sales de los mismos, donde R¹, R² y R⁷ son independientemente hidrógeno, halógeno, ciano, nitro, NR²¹ R²², OR²³, S(O)ₙR²⁴, tiocianato, isotiocianato, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, pentafluortio, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, C₁₋₈-haloalcoxi-C₁₋₈-haloalquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈- haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, COOR²³, CONR²¹R²², COR²³, -C=NOR²³, R²³OOC-C₁₋₈-alquilo, arilo-C₁₋₈-alquinilo, heteroarilo-C₁₋₈-alquinilo, heterociclilo-C₁₋₈-alquinilo, tris-[C₁₋₈-alquil]silil-C₂₋₈-alquinilo, bis-[C₁₋₈-alquil](aril)silil-C₂₋₈-alquinilo, bis-aril[C₁₋₈-alquil]silil-C₂₋₈-alquinilo, C₃₋₈-cicloalquilo-C₂₋₈-alquinilo, arilo-C₂₋₈-alquenilo, heteroarilo-C₂₋₈-alquenilo, heterociclilo-C₂₋₈-alquenilo, C₃₋₈-cicloalquilo-C₂₋₈-alquenilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈ alquilaminosulfonilamino, C₃₋₈-cicloalquilaminosulfonilamino, diazo, arildiazo, tris-[C₁₋₈-alquil]sililo, -bis-[C₁₋₈-alquil](aril)sililo, bis-aril[C₁₋₈-alquil]sililo; X¹, X², X³ y X⁴ son iguales o diferentes y son independientemente N (nitrógeno) o la agrupación C-R², sin embargo en ningún caso más de dos átomos N son adyacentes, y en el que R² en la agrupación C-R² tiene los mismos o diferentes significados respectivamente según se define más arriba, y en el que R¹ y R² no son simultáneamente hidrógeno si X¹, X², X³ y X⁴ representan C-R²; W es O (oxígeno) o S (azufre); A¹, A², A³, A⁴ y A⁵ son iguales o diferentes y son independientemente (nitrógeno) o la agrupación C-R⁷, sin embargo en ningún caso más de dos átomos N son adyacentes, y en el que R⁷ en la agrupación C-R⁷ tiene los mismos o diferentes significados respectivamente según la definición anterior; R³ representa C₁₋₈-alquilo, ciano-C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, R²¹R²²N-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo; R⁴ representa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alquilamino-C₁₋₈-alquilo, bis-[C₁₋₈-alquil]amino-C₁₋₈-alquilo, C₃₋₈-cicloalquilamino-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo, C₂₋₈-alqueniloxicarbonilo, C₂₋₈ alquiniloxicarbonilo, arilo-C₁₋₈-alcoxicarbonilo, heteroarilo-C₁₋₈-alcoxicarbonilo, C₃₋₈-cicloalquilo-C₁₋₈-alcoxicarbonilo, CONR²¹R²², SO₂R²⁴, hidroxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alqueniloxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alquiniloxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, heteroarilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, heterociclilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alquilsulfonilo-C₁₋₈-alquilo, C₁₋₈-alquilsulfinilo-C₁₋₈-alquilo; R⁵ y R⁶ son independientemente hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, COOR²³, CONR²¹R²², hidroxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alqueniloxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alquiniloxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈ alcoxicarbonilo-C₁₋₈-alquilo, heteroarilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, heterociclilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo; R⁵ y R⁶ con el átomo al que están unidos forman un anillo de 5 a 7 miembros, totalmente saturado o parcialmente saturado, eventualmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; R¹ y X¹, si X¹ es un grupo C-R², con los átomos a los que están unidos forman un anillo de 5 a 7 miembros, totalmente saturado, parcialmente saturado o totalmente insaturado, eventualmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; X¹ y X², si ambos son un grupo C-R², con los átomos a los que están unidos forman un anillo de 5 a 7 miembros, totalmente saturado, parcialmente saturado o totalmente insaturado, eventualmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; A¹ y A², si ambos son un grupo C-R⁷, con los átomos a los que están unidos forman un anillo de 5 a 7 miembros, totalmente saturado, parcialmente saturado o totalmente insaturado, eventualmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; A² y A³, si ambos son un grupo C-R⁷, con los átomos a los que están unidos forman un anillo de 5 a 7 miembros, totalmente saturado, parcialmente saturado o totalmente insaturado, eventualmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; A³ y A⁴, si ambos son un grupo C-R⁷, con los átomos a los que están unidos forman un anillo de 5 a 7 miembros, totalmente saturado, parcialmente saturado o totalmente insaturado, eventualmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; Y es un enlace o representa los grupos Y-1 a Y-7 del grupo de fórmulas (2) donde R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷, R¹⁸ y R¹⁹ tiene cada uno el significado que se define a continuación y en el que la flecha representa un enlace del anillo de 6 miembros con los grupos A¹, A², A³, A⁴ y A⁵; R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴,R¹⁵, R¹⁶, R¹⁷, R¹⁸ y R¹⁹ son independientemente hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, COOR²³; n es 0, 1 ó 2; R²¹ y R²² son iguales o diferentes y son independientemente hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenilo-C₁₋₈-alquilo, COR²³, SO₂R²⁴, C₁₋₈-alquilo-HNO₂S-, C₃₋₈-cicloalquilo-HNO₂S-, heterociclilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo, arilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxicarbonilo, heteroarilo-C₁₋₈-alcoxicarbonilo, C₂₋₈- alqueniloxicarbonilo, C₂₋₈-alquiniloxicarbonilo, heterociclilo-C₁₋₈-alquilo; R²³ representa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀ cicloalquenilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alqueniloxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, hidroxicarbonilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo; y R²⁴ representa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, heterociclilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenilo-C₁₋₈-alquilo, NR²¹R²².
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