AR098010A1 - Catalizador para producción de gas de síntesis y procedimiento de obtención del mismo - Google Patents
Catalizador para producción de gas de síntesis y procedimiento de obtención del mismoInfo
- Publication number
- AR098010A1 AR098010A1 ARP140103806A ARP140103806A AR098010A1 AR 098010 A1 AR098010 A1 AR 098010A1 AR P140103806 A ARP140103806 A AR P140103806A AR P140103806 A ARP140103806 A AR P140103806A AR 098010 A1 AR098010 A1 AR 098010A1
- Authority
- AR
- Argentina
- Prior art keywords
- values
- range
- impregnated
- air
- comprised
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 239000000463 material Substances 0.000 abstract 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 abstract 3
- 238000001354 calcination Methods 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910000421 cerium(III) oxide Inorganic materials 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 229910052746 lanthanum Inorganic materials 0.000 abstract 1
- 150000002815 nickel Chemical class 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- 238000000629 steam reforming Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0213—Preparation of the impregnating solution
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B01J35/40—
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- B01J35/613—
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- B01J35/635—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
Reivindicación 1: Catalizador para producción de gas de síntesis, a base de níquel para ser empleado en procesos de reformado con vapor, dotado de mayor resistencia a la deposición de coque en su superficie y mayor actividad catalítica, caracterizado por comprender: un soporte de óxido inorgánico; una mezcla de óxidos de Níquel, Lantano y Cerio, en la forma de sus óxidos (NiO, La₂O₃ y Ce₂O₃), los cuales son impregnados simultáneamente al soporte de óxido inorgánico, estando la proporción entre la mezcla de NiO y La₂O₃ comprendida en una franja de valores entre 6:1 (p/p) y 15:1 (p/p); la proporción entre la mezcla de CeO₃ y La2O₃ comprendida en una franja de valores entre 2:1 (p/p) y 4:1 (p/p) y el contenido total de NiO comprendido en una franja de valores entre 5% (p/p) y 50% (p/p), preferiblemente entre 7% (p/p) y 30% (p/p); un elemento promotor, comprendido en una franja de valores entre 0,3% (p/p) a 2,0% (p/p). Reivindicación 9: Procedimiento de obtención de catalizador conforme a lo descripto en la reivindicación 1, caracterizado porque el referido procedimiento comprende las siguientes etapas: 1) preparar una solución acuosa impregnante de una sal inorgánica de Níquel, preferiblemente nitrato, acetato o carbonato de Níquel, y de Lantano y Cerio, preferiblemente en forma de nitrato; 2) impregnar el soporte de óxido inorgánico por medio de la técnica de punto húmedo o por medio de la colocación del referido soporte de óxido orgánico en un exceso de solución; 3) secar el material impregnado al aire, a una temperatura comprendida en una franja de valores entre 50ºC a 150ºC, y durante un intervalo comprendido en una franja de valores entre 1 y 24 horas; 4) calcinar el material impregnado en aire estático o en corriente de aire a una temperatura comprendida en una franja de valores entre 250ºC y 650ºC y durante un intervalo comprendido en una franja de valores entre 1 y 4 horas; 5) adicionar al material calcinado un elemento promotor, el cual puede ser seleccionado entre Boro, Plata o mezclas de éstos compuestos, por medio de la técnica de impregnación; 6) secar el material impregnado al aire a una temperatura comprendida en una franja de valores entre 50ºC y 150ºC; y 7) calcinar el material impregnado al aire a una temperatura comprendida en una franja de valores entre 250ºC y 650ºC.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/BR2013/000424 WO2015054755A1 (pt) | 2013-10-17 | 2013-10-17 | Catalisador para produção de gás de síntese e processo de obtenção do mesmo |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR098010A1 true AR098010A1 (es) | 2016-04-27 |
Family
ID=52827475
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP140103806A AR098010A1 (es) | 2013-10-17 | 2014-10-14 | Catalizador para producción de gas de síntesis y procedimiento de obtención del mismo |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20160236183A1 (es) |
| CN (1) | CN105813737A (es) |
| AR (1) | AR098010A1 (es) |
| BR (1) | BR112014020135B1 (es) |
| UY (1) | UY35786A (es) |
| WO (1) | WO2015054755A1 (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2017306504B2 (en) | 2016-08-05 | 2020-05-21 | Korea Advanced Institute Of Science And Technology | Dry reforming catalyst using metal oxide support, and method for preparing synthetic gas by using same |
| US10294102B2 (en) * | 2016-12-15 | 2019-05-21 | Praxair Technology, Inc. | Method of catalyst reduction in a hydrogen plant |
| GB201814874D0 (en) * | 2018-09-13 | 2018-10-31 | Agt Man & Engineering Ag | Catalytic chemical vapour deposition |
| BR102019024932B1 (pt) * | 2019-11-26 | 2023-12-12 | Petróleo Brasileiro S.A. - Petrobras | Processo de gaseificação catalítica, catalisador, uso do catalisador e processo para a preparação do catalisador |
| CN114746180B (zh) * | 2020-01-31 | 2024-02-13 | 托普索公司 | 重整催化剂 |
| BR102021002346A2 (pt) * | 2021-02-08 | 2022-08-23 | Petróleo Brasileiro S.A. - Petrobras | Catalisadores, processos de obtenção e processo de pré-reforma a vapor de hidrocarbonetos |
| US20230150823A1 (en) * | 2021-11-16 | 2023-05-18 | Dennis Schuetzle | CO2 hydrogenation catalysts for the commercial production of syngas |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4060498A (en) * | 1972-06-02 | 1977-11-29 | Hitachi, Ltd. | Process for steam reforming of hydrocarbons |
| CN85102194B (zh) * | 1985-04-01 | 1988-08-24 | 四川化工厂催化剂分厂 | 烃类蒸汽重整催化剂 |
| WO1999047257A1 (en) * | 1998-03-18 | 1999-09-23 | United Catalysts, Inc. | A steam reforming catalyst and process for production thereof |
| US20020006374A1 (en) * | 1999-11-05 | 2002-01-17 | Kostantinos Kourtakis | Chromium-based catalysts and processes for converting hydrocarbons to synthesis gas |
| WO2003072492A1 (en) * | 2002-02-22 | 2003-09-04 | Conoco Inc. | Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas |
| US7700005B2 (en) * | 2006-12-26 | 2010-04-20 | Saudi Arabian Oil Company | Oil-based thermo-neutral reforming with a multi-component catalyst |
| CN101371993A (zh) * | 2007-08-13 | 2009-02-25 | 中国科学院成都有机化学有限公司 | 一种高抗结碳的烃类蒸汽转化催化剂制备方法 |
| CN101450312A (zh) * | 2007-11-29 | 2009-06-10 | 南化集团研究院 | 一种天然气蒸汽转化催化剂及其制备方法 |
| CN101733119B (zh) * | 2008-11-25 | 2012-12-05 | 中科合成油技术有限公司 | 一种用于费托合成油加氢的催化剂、其制备方法和应用 |
| US20100147749A1 (en) * | 2008-12-11 | 2010-06-17 | American Air Liquide, Inc. | Multi-Metallic Catalysts For Pre-Reforming Reactions |
| AT507215B1 (de) * | 2009-01-14 | 2010-03-15 | Boehler Edelstahl Gmbh & Co Kg | Verschleissbeständiger werkstoff |
| BRPI1002970B1 (pt) * | 2010-08-18 | 2020-10-13 | Petroleo Brasileiro S. A. | processo para a produção de hidrogênio a partir do etanol |
| GB201018152D0 (en) * | 2010-10-27 | 2010-12-08 | Johnson Matthey Plc | Catalyst preparation method |
| WO2012067505A2 (en) * | 2010-11-16 | 2012-05-24 | Stichting Energieonderzoek Centrum Nederland | Catalyst for hydrogen production |
| BRPI1107073B1 (pt) * | 2011-11-30 | 2020-03-17 | Petróleo Brasileiro S.A. - Petrobras | Catalisador de reforma a vapor, processo para a preparação do referido catalisador e processo para a produção de hidrogênio e gás natural sintético |
| CN102527405B (zh) * | 2012-02-15 | 2013-10-16 | 华东理工大学 | 一种高温合成气完全甲烷化催化剂及其制备方法 |
-
2013
- 2013-10-17 WO PCT/BR2013/000424 patent/WO2015054755A1/pt active Application Filing
- 2013-10-17 US US15/029,958 patent/US20160236183A1/en not_active Abandoned
- 2013-10-17 CN CN201380080311.7A patent/CN105813737A/zh active Pending
- 2013-10-17 BR BR112014020135-8A patent/BR112014020135B1/pt active IP Right Grant
-
2014
- 2014-10-14 AR ARP140103806A patent/AR098010A1/es active IP Right Grant
- 2014-10-16 UY UY0001035786A patent/UY35786A/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014020135A8 (pt) | 2019-01-29 |
| BR112014020135B1 (pt) | 2020-11-24 |
| US20160236183A1 (en) | 2016-08-18 |
| CN105813737A (zh) | 2016-07-27 |
| BR112014020135A2 (pt) | 2017-07-04 |
| UY35786A (es) | 2015-04-30 |
| WO2015054755A1 (pt) | 2015-04-23 |
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